五配位Cu(Ⅰ)配合物[Cu(4'-Phtpy)(PPh3)2](BF4)的合成、结构及光谱性质研究

由[Cu(MeCN)2(PPh3)2](BF4)和4'-苯基-2,2':6',2"-三联吡啶(4'-Phtpy)在室温下反应,合成了一个新颖的具有光致发光性能的五配位配合物[Cu(4'-Phtpy)(PPh3)2](BF4).对配合物进行了X射线衍射结构表征,并进行了红外光谱、紫外可见光谱、荧光光谱等光谱学分析.晶体属单斜晶系,空间群Pn,晶胞参数:α=1.0807(6)nm,b=1.0943(6)nm,c=2.1610(12)nm,α=90°,β=102.785(10)°,γ=90°,V=2.492(2)nm3,Z=2,Dc=1.354g@cm-3.配合物中,Cu(Ⅰ)与4'-Phtpy的3个N,2个PPh3的P配位呈变形三角双锥型结构,其轴向由Cu键合联吡啶的末端2个N所组成,赤道平面由联吡啶的中心N原子和2个PPh3的P原子所组成.     

[K_2(TNR)(H_2O)]_n的制备、分子结构和热分解机理

2,4,6-三硝基间苯二酚(斯蒂芬酸)及其盐类,如斯蒂芬酸铅、斯蒂芬酸钡等是常用的含能材料犤1犦,但斯蒂芬酸铅盐及钡盐在爆炸后产生重金属污染,对使用人员的健康及环境都产生危害。同时,斯蒂芬酸铅盐和钡盐存在一些缺陷,如斯蒂芬酸铅对静电敏感、生产不安全等,这就要求人们寻求新的产品来代替它们。近年来钾含能配合物以其低毒性、良好的安定性引起了火工药剂专家和研究人员的重视犤2～9犦,成为了含能材料行业一个重要研究方向。因此,我们选择了斯蒂芬酸与氢氧化钾反应制备了斯蒂芬酸钾,并就其晶体结构及热分解机理进行了研究。1实验部分1.1仪…     

[Eu(C_(10)H_9N_2O_4)(C_(10)H_8N_2O_4)(H_2O)_3]·0.5bipy·3H_2O配合物的合成、晶体结构及荧光性质

在水-乙醇混合体系中,以2-羰基丙酸水杨酰腙(C_(10)H_(10)N_2O_4)、2,2-联吡啶(C_(10)H_8N_2,简写bipy)与Eu(NO_3)_3·4H_2O反应,首次培养出黄色单晶[Eu(C_(10)H_9N_2O_4)(C_(10)H_8N_2O_4)(H_2O)_3]·0.5bipy·3H_2O.该晶体属三斜晶系,空间群为P-1,晶胞参数a=0.93392(16)nm,b=1.3100(2)nm,c=1.3895(2)nm,α=97.205(3)°,β=105.411(2)°,γ=106.364(2)°,V=15.35(2)nm~3,Z=2,μ=2.118mm~(-1),Dc=1.686Mg/m~3,F(000)=786,R=0.0116,wR=0.0507,GOF=0.995.晶体测试结果表明,该单晶结构为铕的9配位配合物,两个2-羰基丙酸水杨酰腙分别以负一价和负二价酮式和三个水分子同时参与配位;每个2-羰基丙酸水杨酰腙中的羧基氧、酰胺基中的羰基氧和C=N中的氮与Eu~(3+)配位,形成两个共边的稳定五元环,另三个配位原子则分别来自三个水分子中的氧原子,该配合物在空间呈扭曲的单帽四方反棱柱,而在不对称单位中还有游离的一个2,2-联吡啶分子和三个水分子,这些游离分子与配位分子之间存在大量分子内和分子间氢键,整个分子在空间呈三维网状结构.发光性能测试表明该配合物具有很好的荧光性质.     

五配位Cu(Ⅰ)配合物[Cu(4′-Phtpy)(PPh_3)_2](BF_4)的合成、结构及光谱性质研究

由[Cu(MeCN)2 (PPh3)2 ](BF4 )和 4′ 苯基 2,2′:6′,2″ 三联吡啶(4′ Phtpy)在室温下反应,合成了一个新颖的具有光致发光性能的五配位配合物[Cu(4′ Phtpy)(PPh3)2 ](BF4 ).对配合物进行了X射线衍射结构表征,并进行了红外光谱、紫外可见光谱、荧光光谱等光谱学分析.晶体属单斜晶系,空间群Pn,晶胞参数:a =1 0 80 7(6)nm,b =1 0 943 (6)nm,c=2 1610(12 )nm,α =90°,β =10 2 785(10 )°,γ =90°,V =2 492(2 )nm3,Z =2,Dc=1 3 5 4g·cm-3.配合物中,Cu(Ⅰ)与 4′ Phtpy的 3个N,2个PPh3的P配位呈变形三角双锥型结构,其轴向由Cu键合联吡啶的末端 2个N所组成,赤道平面由联吡啶的中心N原子和 2个PPh3的P原子所组成     

四元混合阴离子配合物[La(C6H5COO)2(NO3)(bipy)]2的合成和晶体结构

合成了新型镧系四元混合阴离子配合物〖Ｌａ（Ｃ６Ｈ５ＣＯＯ）２（ＮＯ３）（ｂｉｐｙ）〗２,化学经验式为Ｃ２４Ｈ１８Ｎ３Ｏ７６Ｌａ,Ｍｒ＝５９９．３３,晶体属三斜晶系,Ｐ＾－１空间群,晶胞参数：ａ＝１１．０２０（４）,ｂ＝１１．１８２（２）,ｃ＝１０．２８５（３）＾°Ａ,ａ＝１０２．８３（２）,β＝１０９．１６（２）,γ＝８２．２３（３）°,Ｚ＝１,Ｄｃ＝１．７０９ｇ／ｃｍ＾３,Ｖ＝１１６４．７（６）     

两个基于4-羧酸-2,2':6',2"-三联吡啶的铜配合物的合成、晶体结构及性质

水热法合成了2个配合物{[Cu₂(L)₂(tp)]·2H₂O}_n(1)和[CuL(ClO₄)]_n(2)(L=4-羧酸-2,2':6',2"-三联吡啶,H₂tp=对苯二甲酸)。对其晶体结构进行了分析,结果表明配合物1和2都通过配体和金属离子组装成一维链结构;配合物1属于三斜晶系,P1空间群,并通过链间的氢键作用形成三维的网状结构;配合物2通过链与链间的氢键作用形成二维的层状结构。对其热稳定性和荧光性质进行了研究。     

Cu(I)配位聚合物 [Cu3(CN)3(3-pytpy)]n的合成、晶体结构及其荧光性质

在160 °C下, 以4"-(4-吡啶基)-3,2":6",3"-三联吡啶 (3-pytpy) 为配体,Cu(OAc)2.H2O为金属盐, 通过水热法在乙腈/水的混合溶剂中合成了一个Cu(I) 配位聚合物 [Cu3(CN)3(3-pytpy)]n (1)。通过元素分析、红外光谱 (IR)、X-射线粉末衍射 (XRD) 和热重分析 (TGA) 对配合物1进行了表征,并用X-射线单晶衍射分析确定了晶体结构。结果表明, 其晶体属单斜晶系, 空间群为P21/c, Mr = 579.03, a = 7.132 (6) ?, b = 17.431 (13) ?, c = 18.388 (13) ?, β = 94.284 (14)°, V =2280 (3) ?3, F(000) =1152, Z = 4, ?(MoKα) = 2.799 mm-1, Dc = 1.687 g/cm3, 最终残差因子R1 = 0.0447 , wR2 = 0.1238。Cu(I) 均为畸变三角形配位模式, 配位原子分别为：三联吡啶配体吡啶环上的N原子、CN-基N原子和另一个CN-基C原子。CN-基桥联Cu(I) 离子形成沿ac平面对角线方向延伸的一维内消旋螺旋链 [Cu(I)-CN]n, 配体3-pytpy则进一步桥联这些一维链形成二维 “波浪型” 网络结构, 2D层以ABAB方式堆积并通过吡啶环间的π...π堆积作用拓展为三维超分子结构。     

一维链状4-乙基苯甲酸镧配合物[La(EBA)_3(EBAH)(H_2O)]_n的合成、晶体结构和性质研究(英文)

水热法合成了配位聚合物[La(EBA)3(EBAH)(H2O)]n(EBA=4-乙基苯甲酸根,EBAH=4-乙基苯甲酸),并通过X-射线衍射单晶结构分析、红外光谱、紫外光谱、荧光光谱以及热重分析对配合物进行了结构和性质研究。配合物属三斜晶系,P1空间群。该配合物具有一维链状结构。La3+离子与9个O原子配位,其中4个O原子来自4个双齿桥联的4-乙基苯甲酸根,3个O原子来自2个螯合-桥联的4-乙基苯甲酸根,1个O原子来自1个中性的4-乙基苯甲酸,1个O原子来自配位水分子。La3+离子处于九配位扭变的三帽三角棱柱构型中。相邻La3+离子通过双齿桥联或螯合桥联的4-乙基苯甲酸根联结成一维链状结构。存在于分子内的氢键使一维链状结构更加稳定。由于相邻一维链的苯环间存在弱的π…π堆积作用,使分子沿着a轴堆积形成二维层状结构。同时,标题配合物固体具有光致发光特性,蓝光区的较强发射归于配体的π→π*电子跃迁。     

配合物[Ln(C6H5COO)2(NO3)(Bipy)]2的合成及表征

镧系含杂环胺三元配合物的研究从六十年代至今已进行了大量探索 ,但四元配合物的研究一直不多 ,并且由于联吡啶 (Ｂｉｐｙ)的配位能力相对较弱 ,有关其四元配合物的研究报道更为少见[1～ 3] 。我们探索合成了 [Ｌｎ(Ｃ6 Ｈ5ＣＯＯ) 2 (ＮＯ3)(Ｂｉｐｙ) ]2 ,且在合成过程中首次观察到了热力学与动力学竞争的现象。1　实验部分1 1　试剂和仪器稀土氧化物纯度超过 99.99% (上海跃龙有色金属有限公司 ) ,其余试剂均为分析纯。ＣａｒｌｏＥｒｂａ 1 1 0 6型元素分析仪 ;ＤＤＳ 1 1Ａ型电导率仪 (1 .0× 1 0 -3ｍｏｌ·Ｌ-1ＤＭＦ) ;日本岛津 47…     

[phenH][La(NO3)4(H2O)(phen)]·H2O 的合成和晶体结构

标题化合物由La(NO3)3·nH2O,1,10-邻菲罗啉(phen)和乙酰丙酮等在无水乙醇和水的混合溶剂中合成并用IR谱和X射线结构分析进行表征.晶体学数据如下:C24 H21LaN 8O14,Mr=784.40,三斜,P1,a=7.124(1),b=11.047(2),c=19.393(4)A,α=81.10(3),β=87.79(3),γ=74.36(3)°,V=1452.0(5)A3,Z=2,Dc=1.794g/cm3,F(000)=780,μ(MoKα)=1.557mm-1.化合物由阳离子[phenH]+和配合阴离子[La(NO3)4(H2O)(phen)]-及一个结晶水分子组成.配合阴离子中以La原子为中心,周围被2个N原子(来自phen)和9个O原子(来自NO3-和H2O)所占据,构成较为罕见的11配位.晶胞中两两阳离子[phenH]+及两两配体phen平面之间均相互平行堆积,并有多种类型的氢键存在,这些都可以降低能量,有利于化合物在晶体中的堆积.     

Synthesis,Crystal Structure,Thermal Decomposition and Sensitivity Properties of (AIM)(HTNR) and (AIM)(PA)

Two new energetic compounds (AIM)(HTNR) and (AIM)(PA)(AIM=2-azidoimidazole, TNR=2,4,6-trinitroresorcinol, PA=picric acid) have been prepared by AIM(2-azidoimidazolium) and TNR(2,4,6-trinitroresorcinol) or PA(picric acid) and characterized by elemental analysis and FTIR spectrum. Their crystal structures were determined by X-ray single-crystal diffraction analysis. The obtained results show that (AIM)(HTNR) crystal belongs to monoclinic, P2₁/c space group, a=1.1306(2) nm, b=0.70305(14) nm, c=1.7398(4) nm, β=106.91°, V=1.3231(5) nm³, D_c=1.778 g/cm³, Z=4, R₁=0.0524, wR₂[I>2σ(I)]=0.1067 and S=1.092 and (AIM)(PA) crystal belongs to monoclinic P2₁/c space group, a=0.80303(16) nm, b=0.81395(16) nm, c=2.0471(4) nm, β=93.93(3)°, V=1.3349(5) nm³, D_c=1.683 g/cm³, Z=4, R₁=0.0784, wR₂[I>2σ(I)]=0.1814 and S=1.098. Both the compounds have electrostatic attraction and hydrogen bonds, which contribute to making the constructions more stable. The decomposition of the two compounds was studied via differential scanning calorimetry(DSC) and thermogravimetry-derivative thermogravimetry(TG-DTG) techniques at a heating rate of 10 ℃/min, and the results show that both the compounds underwent one intensive exothermic decomposition stage. Sensitivity tests reveal that the title compounds were insensitive to friction and impact and sensitive to flame and could be applied in potential pyrotechnics.     

[K(HTNR)(H_2O)]_n的制备、晶体结构和热分解机理

通过2，4，6－三硝基间苯二酚（斯蒂芬酸，TNR）与氢氧化钾在乙醇溶液中反 应，首次合成出配位聚合物[K(HINR)-(H_2O)]_n，并测定了其晶体结构。该晶体属 单斜晶系, P2_1/c空间群；晶胞参数： a = 0.7888(1)nm, b = 1.38002(2) nm, c = 0.9520(1) nm, β=8.91(1)°；V = 1.0238(2) nm~3; D_c = 1.954 g/cm~3; Z = 4; F(000) = 608; μ(MoKα) = 0.575 mm~(-1)。用DSC，TG－DTG及FT－IR 等分析方法研究了该配位聚合物的热分解机理。在线性升温条件下，该配合物的热 分解包含两个重叠的弱吸热过程和两个强放热分解过程。分解残渣的红外分析表明 ，在271.9 ℃时，分解残渣中有KNCO与羧酸钾，357.1 ℃时，残渣中只有KNC存在 。     

Synthesis,Crystal Structure,Thermal Decomposition and Sensitive Properties of a New Complex [Cu(IMI)4](PA)2

A new coordination complex [Cu(IMI)₄](PA)₂ had been synthesized with imidazole(IMI) as ligands and picrate(PA^-) groups as outer anions, and characterized by Fourier transform infrared(FTIR) spectrum and elemental analysis. Its crystal structure was determined by single crystal X-ray diffraction(XRD) analysis. The crystallographic data show that the crystal belongs to monoclinic, C2/c space group, a=2.542(5) nm, b=0.91773(18) nm, c=1.3778(3) nm, β=107.854(3)° and Z=4. Furthermore, the central copper(II) ion is coordinated by four N atoms from four imi- dazole ligands. All the molecular units are linked into a zigzag pattern along a-axis by the hydrogen bonds, and extended to the distance regularly. Thermal decomposition mechanisms were determined based on differential scanning calorimetry(DSC) and thermogravimetry-differential thermogravimetry(TG-DTG) analysis, and kinetic parameters of the first exothermic process were studied using Kissinger’s and Ozawa-Doyle’s method, respectively. Sensitivity tests show that the title complex has low sensitivity to external stimulus, but it has a higher energy of combustion of 14.2 kJ/g due to which it may be used as the additives of energetic materials to improve the explosive performance.     

Synthesis and crystal structure of [Ln(4-Pyta)3(H2O)2] n (Ln = Nd,Ce, Eu,Gd; 4-Pyta = 4-pyridylthioacetate)

Four new lanthanide complexes, [Nd(4-Pyta)₃(H₂O)₂] _n (1), [Ce(4-Pyta)₃(H₂O)₂] _n (2), [Eu(4-Pyta)₃(H₂O)₂] _n (3) and [Gd(4-Pyta)₃(H₂O)₂] _n (4), have been obtained from reaction of lanthanide(III) nitrate with 4-Pyta (4-pyridylthioacetate) in water. Their structures were characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystals belong to triclinic, space group P 1 and all complexes exhibit one-dimensional chains that arrange to form a three-dimensional supramolecular architecture by hydrogen bonds between the chains.     

稀土配合物Sm2(CH3COO)4(NO3)2(phen)2 的合成、 结构及非等温热分解动力学研究

在水-乙醇混合体系中, 将浓硝酸硝化的Sm2O3与1,10-邻菲啰啉反应, 用冰醋酸调节pH≈4, 形成醋酸根桥联的双核钐配合物［Sm2(CH3COO)4(NO3)2(phen)2］(phen=1,10-邻菲啰啉), 用元素分析、红外光谱和核磁共振谱等进行了表征, 并用X射线衍射测定了配合物的晶体结构, 此外, 对配合物进行了非等温热分解动力学研究. 该晶体属于三斜晶系, P1空间 群, 晶胞参数a=0.979 6(3) nm, b=0.981 3(4) nm, c=1.127 3(4) nm, α=106.666(5)°, β=113.034(5)°, γ=102.656(5)°, V=0.885 4(5) nm3, Z=1, μ=3.361 mm-1, Dc=1.915 g/cm3, F(000)=498, R1=0.059 6, wR2=0.144 8. 该配合物是双核分子, 2个Sm(Ⅲ)离子通过4个醋酸根的羧基桥联, 每个中心离子分别与周围5个来自羧基的桥氧原子、 一个硝酸根的两个氧原子和一个邻菲啰啉分子中的两个氮原子配位, 形成九配位扭曲多面体. 非等温热分解动力学研究结果表明， 配合物第一步热分解反应可能为二级反应, 其动力学方程为dα/dT=A/［βe-E/RT(1-α)2］, 分解反应的表观活化能为344.84 kJ/mol, 指前因子lnA=66.52.     

[Cu(NBOCTB)](ClO4)2·2DMF的合成、晶体结构和热分解过程研究

制备了二(N,N-二甲基甲酰胺)-高氯酸N,N,N'',N''-四[(1''-苄基-2''-苯并咪唑)甲基]-1,2-环己二胺合铜(Ⅱ){[Cu(NBOCTB)](ClO4)2·2DMF}.X射线测定表明其晶体属三斜晶系,空间群P1,晶胞参数α=1.1851(5)nm,b=1.2255(3)nm,c=2.5237(5)nm;α=92.37(2)°,β=98.01(2)°,γ=107.82(3)°,V=3.442(4)nm3,M=1403.93,Z=2,Dx=1.36g/cm3,μ=4.60cm(-1),F(000)=1470.TG-DTG技术研究结果表明,配合物的热分解过程分为以下4个阶段:(19941106-1597-1.jpg)     

二聚体[Ni(TSSB)(Phen)(H2O)]·4H2O的合成、表征、晶体结构及热分解研究

The new compound, [Ni(TSSB)(Phen)(H₂O)]·4H₂O (TSSB=Taurine Salicylic Schiff Base, phen=O-Phenanthroline) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction. The compound crystal data: triclinic, space group P1, a=1.049 7(2), b=1.122 5(2), c=2.384 3(4) nm, α=87.676(3)°, β=82.957(3)°, γ=62.924(3)°; V=2.482 3(7) nm³, Z=4; D_c=1.488 g·cm^-3, μ=0.920 mm^-1, F(000)=1 160, Goof=1.032, (Δρ)_max=899 e·nm^-3, (Δρ)_min=-624 e·nm^-3. The compound is a dimmer. In the complex, two Ni(Ⅱ) were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac^- groups did not coordinate. The Ni(Ⅱ) formed a distorted octahedron geometry. The compound is an three dimensional net connecting with hydrogen bonding. CCDC: 275474.     

Synthesis and Crystal Structure of [Cu2（DMF）（H2O）（C7H4NO4）2（C7H3NO4）]2·3.5DMF

A new copper（H） complex [Cu2（DMF）（H2O）（C7H4NO4）2（C7H3NO4）]2-3.5DMF has been synthesized and its structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1^- with a = 10.722（3）, b = 18.170（4）, c = 20.923（7）A,α = 105.297（9）, β = 101.701（10）, γ = 105.74（1）°, V= 3615（1）A^3, Z = 2, C58.50H64.50Cu4N1l.50O3150, Mr = 1686.90, Dc = 1.550 g/cm^3,μ= 1.255 mm^-1, F（000） = 1728.00, T = 150（2） K, the final R = 0.0640 and wR = 0.173 for 11310 observed reflections with I 〉 2σ（I）. In the crystal, each formular unit consists of two dinuclear copper（H） compounds, between which the O-H…O hydrogen bonds exist. Each Cu^Ⅱ cation is six-coordinated in an octahedral geometry. The intermolecular hydrogenbonding interaction leads to a 3-D framework of the title compound.     

2, 4, 6-三甲基苯甲酸与5, 5'-二甲基-2, 2'-联吡啶构筑的系列镧系超分子配合物的晶体结构、热分解机理和性能

Six ternary lanthanide complexes formulated as [Ln(2, 4, 6-TMBA)₃(5, 5'-DM-2, 2'-bipy)]₂ (Ln = Pr 1, Nd 2, Sm 3, Eu 4, Gd 5, Dy 6; 2, 4, 6-TMBA = 2, 4, 6-trimethylbenzoate; 5, 5'-DM-2, 2'-bipy = 5, 5'-dimethyl-2, 2'-bipyridine) have been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, etc. The results of crystal diffraction analysis show that complexes 1–6 are binuclear units, crystallizing in the triclinic Pī space group. Complexes 1–5 are isostructural, and each of the central metal ions has a coordination number of 9. The asymmetric unit of complexes 1–5 consists of one Ln³⁺, one 5, 5'-DM-2, 2'-bipy ligand, and three 2, 4, 6-TMBA^- moieties with three coordination modes: chelation bidentate, bridging bidentate, and bridging tridentate. The coordination geometry of Ln³⁺ is distorted monocapped square antiprismatic. The binuclear units of complexes 1–5 form a one-dimensional (1D) supramolecular chain along the c-axis via π–π stacking interactions between the 2, 4, 6-trimethylbenzoic acid rings. The 1D chains are linked to form a supramolecular two-dimensional (2D) sheet in the bc plane via π–π stacking interactions between the pyridine rings. Although the molecular formulae of complex 6 and complexes 1–5 are similar, the coordination environment of the lanthanide ions is different in the two cases. The asymmetric unit of complex 6 contains a Dy³⁺ ion coordinated by a bidentate 5, 5'-DM-2, 2'-bipy and three 2, 4, 6-TMBA^- ligands adopting bidentate and bridging bidentate coordination modes. The Dy³⁺ metal center has a coordination number of 8, with distorted square antiprismatic molecular geometry. The binuclear molecule of 6 is assembled into a six-nuclear unit by π–π weak staking interactions between two 5, 5'-DM-2, 2'-bipy ligands; then, adjacent six-nuclear units form a 1D chain via offset π–π interactions between 5, 5'-DM-2, 2'-bipy ligands on different adjacent units. The adjacent 1D chains are linked by C―H···O hydrogen bonding interactions to form a 2D supramolecular structure. The thermal stability and thermal decomposition mechanism of all the complexes are investigated by the combination of thermogravimetry and infrared spectroscopy (TG/FTIR) techniques under a simulated air atmosphere in the temperature range of 298–973 K at a heating rate of 10 K·min^-1. Thermogravimetric studies show that this series of complexes have excellent thermal stability. During the thermal decomposition of the complex, the neutral ligand is lost first, followed by the acid ligand, and finally, the complex is decomposed into rare earth oxides. The three-dimensional infrared results are consistent with the thermogravimetric results. The photoluminescence spectra of complex 4 show the strong characteristic luminescence of Eu³⁺. The five typical emission peaks at 581, 591, 621, 651, and 701 nm correspond to the ⁵D₀ → ⁷F₀, ⁵D₀ → ⁷F₁, ⁵D₀ → ⁷F₂, ⁵D₀ → ⁷F₃, and ⁵D₀ → ⁷F₄ electronic transitions of Eu³⁺, respectively. The emission at 621 nm is due to the electric dipole transition ⁵D₀ → ⁷F₂, while that at 591 nm is assigned to the ⁵D₀ → ⁷F₁ the magnetic dipole transition. The lifetime (τ) of complex 4 is calculated as 1.15 ms based on the equation τ = (B₁τ₁² + B₂τ₂²))/(B₁τ₁ + B₂τ₂), and the intrinsic quantum yield is calculated to be 45.1%. Further, the magnetic properties of complex 6 in the temperature range of 2–300 K are studied under an applied magnetic field of 1000 Oe.