Far-infrared laser stark spectroscopy of CH3OH and13CH3OH

The high resolution laser Stark spectra of methanol and¹³C-substituted methanol have been studied up to Stark fields of about 60 000V/cm with the HCN and DCN lasers. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations. For methanol, the transitions J _k =7₅ 6₄ A, _t=0; J _k =11₄ 10₃ E _l , _t=0; and J _k =17₃ 16₂ E₂, _t=0 have been identified while the assignments for¹³C-substituted methanol are J _k =14₈ 15₇ A, _t=0; J _k =15₃ 14₂ A⁺, _t=0; J _k =10₇ 9₆ A, _t=0; and J _k =27₉ 27₈ E₁, _t=0. Zero-field frequencies for the assigned transitions are given with improved accuracy over those calculated from available molecular constants, especially for¹³CH₃OH.     

Far-Infrared Laser Stark Spectroscopy of CH3OD

The high resolution Stark spectra of the singly deuterated methanol isotope, CH₃OD, have been studied using the HCN laser with Stark fields up to approximately 60 000 V/cm. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations, resulting in the following assignments: with the 311 m line – J _K = 18₁ 18₀ E ₂, _t = 1; and with the 337 m line – J _k = 6₄ 5₃ E ₂, _t = 0 and J _K = 14₆ 13₅ A, _t = 1. Zero-field frequencies for the assigned transitions are in agreement with Fourier transform measurements and those calculated from the available molecular constants.     

Massive spin-two particle in a gravitational field

The spin-two particle is described by a symmetric tensorh subject to the subsidiary conditionsh = h =0. Their covariant generalization and the wave equation have been obtained directly from the Eulerian variational equations by algebraic methods only. In addition to the tensor fieldh a symmetric third-rank tensor = as well as a vector fieldA have been added, neither of which enter in the final result. The Lagrangian function is taken as a linear sum of all combinations which can be constructed from these functions, as well as terms involving the curvature tensor and its two possible contractions. Variation with respect toh , andA independently gives the Euler equations. Combining the various trace equations and choice of arbitrary constants yields the subsidiary conditions, while the Euler equations themselves give the connection between the auxiliary functions and the tensorh as well as the generalization of the wave equationD D h + 2R h -R h -R h +g R h +Rh =m ² h Finally, variation with respect tog yields the energy-momentum tensor.     

Parity operator and quantization of δ-functions

In the Weyl quantization scheme, the -function at the origin of phase space corresponds to the parity operator. The quantization of a functionf() on phase space is the operator f(/2)W()dM, whereM is the parity andW() the Weyl operator.     

Matter and light wave interferometry in gravitational fields

We consider the problem of finding the quantum mechanical phase associated with the propagation of a particle in a given external gravitational field, and conclude that it ism ds. In weak fieldsh this allows us to calculate the gravitationally induced phase on a freely traveling particle as 1/2 h P dx whereP is the ordinary momentum. This formula has the expected Newtonian limit and is then used to calculate effects in matter wave interferometry such as those due to gravity waves and the dragging of the ether frame by rotating bodies. Light wave interferometry is then considered and is shown to be also described by 1/2 h K dx , whereK is the wave vector of the light, and the integral is along the path of the ray. Matter and light wave interferometry are compared in various cases.A preliminary version of this work was presented at the Grenoble Workshop on Neutron Interferometry, June 1978.     

Four-wave mixing in CO via the C 1Σ+ (υ′=0) state

Coherent vacuum ultraviolet (VUV) radiation was generated by four-wave difference frequency mixing (_VUV=2₁–₂) of pulsed dye laser radiation in carbon monoxide (CO). The frequency ₁ was tuned to the C ¹⁺(=0)X ¹⁺(=0) two-photon transition, while the dye laser frequency ₂ was scaned around 17650 cm^–1 which corresponds to the A ¹(=7)«C ¹⁺(=0) transition energy. The VUV intensity was found to be strongly wavelength dependent. The analysis of the spectrum revealed (i) that the VUV intensity was enhanced by the rotational levels of the A ¹(=7) state and (ii) that the off-resonance excitation in the C ¹⁺(=0)X ¹⁺(=0) two-photon transition greatly contributed to the present four-wave mixing process. The effects of pumping laser detuning, saturation and foreign gases are briefly discussed.     

State-to-state rotational energy transfer in OH (A 2Σ+, υ′=1)

State-to-state rotational energy transfer (RET) coefficients for thermal collisions of OH (A ²⁺, =1) with He, Ar, N₂, CO₂, and H₂O at 300K were determined from time-resolved laser-induced fluorescence (LIF) measurements. The RET coefficients are very similar in both qualitative behaviour and absolute magnitude to those measured previously for OH (A ²⁺, =0).     

Optically pumped submillimeter laser lines from CH2F2 and CD2Cl2 using a12C18O2 CW laser

Thirty-nine new submillimetre laser lines in CH₂F₂ and twelve in CD₂Cl₂ have been obtained in a Fabry-Perot FIR resonator by optically pumping with a CW¹²C¹⁸O₂ laser. The wavelength range obtained for CH₂F₂ is 126m to 1091m and for CD₂Cl₂ 212m to 774m. The wavelength measurements are accurate to within 5.10^–3. The relative polarisations of the pump laser and the FIR laser output were also determined. Tentative assignments of the IR and FIR transitions were made using existing microwave data.     

On a Static Solution of the Einstein Equation with Incoming and Outgoing Radiation

The Einstein equation with T = k k + where k, l are null is considered with spherical symmetry and staticity. The solution has a naked singularity and is not asymptotically flat. However, it may be interpreted as an envelope for any static spherical body making it more massive. Such an interpretation and some of its implications are detailed.     

Spectral superbroadening of self-focused picosecond laser pulses in D2O

Intense picosecond light pulses of a mode-locked Nd: glass laser at _L =1054 nm (fundamental wavelength) and _SH =527 nm (second harmonic wavelength) are passed through a sample of D₂O under self-focusing conditions. Spectrally structured superbroadened, spatially bell-shaped emission in the forward direction is obtained. Primary generation processes are pump-pulse-degenerate stimulated parametric four-photon interaction (₁ + _{1 3} + ₄) and stimulated Raman scattering (_{1 R} + ), which occur concurrently (₁= _L or _SH angular pump frequency, #x03C9; _R first Stokes frequency, #x03C9; signal frequency, #x03C9;₃ signal frequency, #x03C9;₄ idler frequency). The parametric four-photon interaction occurs under collinear non-phase-matched conditions and under longitudinally phase-matched, transversally non-phase-matched (erenkov-like) conditions. Subsequent interaction processes are pump-pulse-nondegenerate four-photon interaction of the type ₁ + _{R 3} + ₄, coherent antiStokes Raman scattering (CARS, ₁ + ₁ – _{4 3}), inverse Raman scattering ( _A + ₁ + ), and cascading light up-conversion of the type ₁ + _(i) – _{R (i+1)}.     

On the bimetric theory of gravitation

Rosen's bimetric theory is analyzed anew and is shown to have deficiencies if the space is assumed to be Riemannian. The problems are due mainly to the introduction of the flat metric , and the identification of the stress-energy tensor,T . It is indicated that if the Riemannian interpretation could be avoided the theory still holds promise as a viable theory of gravitation.     

Long-time tails in lattice Lorentz gases

We consider a Lorentz gas on a square lattice with a fraction c of scattering sites. The collision laws are deterministic (fixed mirror model) or stochastic (with transmission, reflection, and deflection probabilities ,, and respectively). If all mirrors are parallel, the mirror model is exactly solvable. For the general case a self-consistent ring kinetic equation is used to calculate the longtime tails of the velocity correlation function (0) (t) and the tensor correlation Q(0)Q(t) withQ= _{x y} . Both functions showt ^–2 tails, as opposed to the continuous Lorentz gas, where the tails are respectivelyt ^–2 andt ^–3. Inclusion of the self-consistent ring collisions increases the low-density coefficient of the tail in (0)(t) by 30–100% as compared to the simple ring collisions, depending on the model parameters.     

Direct observation of the second-order Stark effect of theX-B transition in molecular iodine

The second-order Stark shift of the components of the hyperfine structure of the transition¹ _g ⁺ ( = 0,j = 13, 15) ³ _ou ⁺ ( = 43,j = 12, 16) (of molecular iodine have been studied by means of saturated absorption spectroscopy in an external cell with the I₂ vapour located in an electric field. The anisotropic polarizabilities of the upper and lower levels together with the difference between the isotropic polarizabilities of the levels of the transition have been obtained.     

Kinetic studies of laser-induced synthesis of thin vanadium pentoxide films

The kinetics of Ar⁺ laser-induced oxidation of 100 nm thick vanadium films on glass substrates is followed by measuring time-dependent changes in reflected and transmitted intensity of a He-Ne probe beam. The growth rate of the vanadium pentoxide layer increases with increasing laser powerP as = ₀ exp(-a/P). At power densities above kW/cm² vanadium pentoxide crystallizes from the melt.     

Potts ferromagnet: Transformations and critical exponents in planar hierarchical lattices

We prove that the duality transformation for a Potts ferromagnet on two-rooted planar hierarchical lattices (HL) preserves the thermal eigenvalue. This leads to a relation between the correlation length critical exponents of a HL and its corresponding dual lattice. Using hyperscaling, we show that their specific heat critical exponents coincide. For a smaller class of HL—namely of diamond and tress types—we prove that another transformation also preserves and .     

Speculations on the cluster radius below the percolation threshold

We suggest the average radius of percolation clusters withs sites to vary belowp _c ass ⁰, where ₀ is the exponent for the mean radius of self-avoiding walks. This result gives the desired asymptotic behavior of the correlation function for percolation (connectivity) and is consistent with Leath's Monte Carlo data.     

Gravitational and Electroweak Interactions

Schrodinger considered the variational principle , whereg is the determinant of the metricg, but noted that ifg is varied, the resultingEuler-Lagrange equations cannot serve as field equations. We writeg =g_ijh ⁱh ^j, where g_ij = diag(-1, 1,1, 1), and express the vectors of the tetradh ⁱ as derivatives ofnonintegrable functions xⁱ of the typecommonly used for phase factors in gauge theory, i.e.,h ⁱ =x_, ⁱ. We have previously shownthat if the xⁱ are varied, the resultingEuler–Lagrange equations serve as field equations which imply the validity of Einstein equationswith a stress-energy tensor for the electroweak fieldand associated currents. In this paper, we express theseEinstein equations into two new forms, and use these forms to derive Lorentz-force-likeequations of motion. The electroweak field appears as aconsequence of the field equations (rather than as acompensating field introduced to secure local gauge invariance). There is no need forsymmetry breaking to accommodate mass, because the gaugesymmetry is approximate from the outset.     

The progressive-stiffness method applied to XY4 molecules in the light of the theory of characteristic frequencies

It is shown that the success of progressive stiffness when applied to tetrahedral XY₄ molecules is due to the existence of three approximate characteristics. On separating the group of all angular coordinates for the ₄(F₂) vibrations, the noncharacteristic frequency and form coefficients a and _s are approximately equal to zero; on separating the group of all the valence coordinates for the ₃(F₂) vibrations, is approximately zero.     

Frequency measurements on far-infrared emissions from12C16O2-pumped methyl chloride and from12C18O2-pumped difluoromethane

The frequencies of 42 far-infrared laser lines have been measured by mixing with high-order harmonics of microwave frequencies in a Josephson junction. A total of 5 emissions between 334 and 1887 m have been measured from¹²C¹⁶O₂-pumped methyl chloride (CH₃Cl) and 37 emissions between 116 and 1092 m in¹²C¹⁸O₂-pumped difluoromethane (CH₂F₂). Additional data is given on the laser emission characteristics.Division of Electrical Science, National Physical Laboratory     

New far-infrared laser lines produced by resonant Q-branch-pumping of CH3F

Conclusion We showed that by pumping the ₃-Q-branch of CH₃F using the 9P-branch radiation produced by a continuously tunable 20 atmospheres CO₂ laser all Q-branch transitions with quantum number 5J28 can be pumped. From the 23 laser lines with frequencies from 10 cm^–1 to 47 cm^–1, 13 were detected for the first time. The optimum operating pressure for the FIR laser was 11 Torr.