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1.
Abolhassani,M.D.一:Hejazi,M.;Ah- madian,A.;and Amjadi,A.:Comparison of optieal deteetion system,PVDF deteetion system,and PVDF needle hydroPhone for oPtoacoustie tomograPh扒593 Ahmadian,人.see Abolhassani,M,D.,593 All劝 adi,A.see Abolhassani,M.D.,593 Bai,Ming see Zhang,Douguo,107 Bao,Huanmin see丫V么ng,Yanyong,4; W么ng,Yanyong,6;Jia,Doxlgfang,311 Bao,N.K.see Chen,Zhongyu,319 Bi,Jinzi see Yu,Ting,92 Bian,Jing see Xie,Hongyun,156 Bu,Ydng see …  相似文献   

2.
An,Geng see Liang,Gongying,59 B乙,Peng一;and Liu,Junhua:Mixture gas component eoneentration analysis based on supPort veetor maehine and infrared spee- trum,243 Bai,XiangZhong see Chen,Mingyang,63 Bi,Guojiong see Zhang,Shenjin,658 Bi,Jin活1 s  相似文献   

3.
ICP—AES法测定锌及其化合物中的杂质元素   总被引:3,自引:0,他引:3  
采用样品溶解后直接测定及氢氧化钇共沉淀将锌与被测杂质元素分离后测定相结合,研究了锌及其化合物中Ag,Co,Al,Ni,Fe,Cu,Cd,Cr,Mn,In,As,Pb,Sn,Sb,Bi等15个杂质元素的ICP-AES测定方法,相对标准偏差1.6-8.1%。  相似文献   

4.
采用可见-近红外高光谱成像技术结合化学计量学方法检测灵武长枣维生素C(VC)含量,探究一种全新的水果内部成分的快速无损检测方法。采用高效液相色谱法(HPLC)测得长枣的VC含量化学值,可见-近红外高光谱成像系统采集164个灵武长枣400~1 000 nm的高光谱图像,利用ENVI4.8软件提取图像的感兴趣区域(region of interest,ROI),计算其平均光谱,获得光谱值,将化学值与光谱值通过The UnsecramblerX 10.4软件建立模型。利用蒙特卡洛交叉验证法剔除异常值,采用光谱理化值共生距离法(sample set partitioning based on joint x-y distance,SPXY)进行样本划分以提高模型的预测性能;对光谱采用移动平滑(moving average)、中值滤波(median filter)、归一化(normalize)、基线校准(baseline)、多元散射校正(multiple scattering correction,MSC)、去趋势(detrending)和标准正态变量变换(standard normal variate,SNV)等7种方法进行预处理;为进一步减少数据量,降低维度,提高运算速度,使用竞争性自适应加权算法(competitive adaptive reweighted sampling,CARS)、无信息变量消除算法(uninformative variable elimination ,UVE)和连续投影算法(successive projections algorithm,SPA)提取特征波长,以期实现以少数波段代替全波段;将全波段光谱(full spectrum,FS)以及CARS, UVE和SPA三种方法提取的特征波长分别建立偏最小二乘(partial least squares wavelength regression,PLSR)和支持向量机(support vector machine,SVM)模型,从而确定最优的建模模型。利用蒙特卡洛交叉验证法共剔除7个异常样本,采用SPXY法将剔除异常样本后的157个数据区分为校正集和预测集,校正集中样本个数为117,预测集中样本个数为40。将未经光谱预处理的建模结果与分别经过七种光谱预处理的建模结果相比,选择未经光谱预处理的数据进行后续分析;将未经光谱预处理的光谱值采用CARS,UVE,SPA方法进行提取特征波长,CARS共优选出406,415,487,631,636,655,660,665,670,684,689,694,723,732,747和881 nm下的光谱变量16个,利用CARS提取出的特征波长占总波长的12.8%;UVE共优选出406,415,627,631,636,651,655,660,665,670,675,679,684,689,694,699,703,708,742,747,751,756,761,766,771,775,780,785,790,795,919和924 nm下的32个特征波长,利用UVE提取出的特征波长占总波长的25.6%;SPA共优选出401,665,684 nm三个特征波长,利用SPA提取出的特征波长占总波长的2.4%。将全波段光谱与提取出的特征波长建立PLSR模型和SVM模型,对比模型结果显示UVE-SVM模型最优,其R2c为0.847 1,R2p为0.714 9,说明UVE有效地对光谱进行降维,简化了数据处理过程。本研究对高光谱成像技术在水果领域的应用进行了有益探索,探究了一种全新的灵武长枣VC含量的无损检测方法,相应建立的可见-近红外高光谱模型为其他水果成分的快速检测提供了理论基础。  相似文献   

5.
ICP-AES法同时测定茶叶中的锌、铁、锰、铜、镍、镁   总被引:6,自引:0,他引:6  
研究了用硝酸+硫酸+高氯酸消解样品,用ICP-AES法同时测定茶叶中锌,铁,锰,铜,镍,镁的新方法,在选定的最佳条件下,测锌,铁,锰,铜,镍,镁的检出限分别为4.2,7.8,0.4,7.3,7.6,4.8ng.mL^-1,回收率为94.7%-104.2%,RSD为0.3%-4.7%,该法准确,快速,简便,适用于茶叶样品的测定,结果令人满意。  相似文献   

6.
非碳纳米管研究的新进展   总被引:4,自引:0,他引:4  
张立德  张玉刚 《物理》2005,34(3):191-198
文章系统地论述了非碳纳米管的制备,较详尽地介绍了多种非碳纳米管制备最新的进展,包括硫化物、氮化物、氧化物等等,特别重点地总结了非碳纳米管前沿材料,例如WS2,Bi2S,,ZnS,GaN,BN,AlN,InP,Eu2O3,,V2O3等.最后对非碳纳米管的研究趋势作了展望.  相似文献   

7.
循环流化床热电气三联产装置研究   总被引:14,自引:0,他引:14  
循环流化床热电气三联产装置研究岑可法,方梦祥,骆仲泱,李绚天,陈飞,王勤辉,陈冠益,倪明江(浙江大学热能工程研究所杭州310027)关键词循环流化床,气化,煤气蒸汽联产1前言在近几年来,我国能源仍主要以煤炭为主,而目前煤炭的绝大部分作为燃料直接燃用,...  相似文献   

8.
中药方剂煎煮液中ICP—AES法同时测定16个元素   总被引:5,自引:0,他引:5  
本文提出了用硝酸-过氧化氢对中药方剂煎煮液进行处理,ICP-AES法对煎煮液中Li,Na,Be,Ca,Sr,Ba,Mg,Cu,Co,Ni,Zn,Mn,Cd,Fe,Cr,V16个元素进行同时测定的方法,该方法简单,快速,准确度高,所测元素的加标回收率均在85~103%之间,样品分析结果满意。  相似文献   

9.
元素在探针表面上的原子化机理研究   总被引:3,自引:0,他引:3  
探针原子人经法是一种新技术,本文系统地总结了用探针原子化法研究Au(1B),Sr(ⅡA),Cd(ⅡB),Al(ⅢA),La,Sm,Fu(ⅢB),Ge,Sn,Pb(ⅣA),Sb,Bi(ⅤA),V(ⅤB),Cr,Mo(ⅥB),Mn(ⅦB),Fe,Co,Ni,Pt(Ⅷ)等20个元素的原子化机理了起源于卤化物分解的元素有Au与Pt,起源于氧化物分解的元素有Cd,Al,La,Sm,Eu,Ge,Mn与Fe。  相似文献   

10.
X射线荧光光谱法测定硅酸盐中硫等20个主、次、痕量元素   总被引:39,自引:1,他引:39  
本文使用新研制的偏硼酸锂和四硼酸锂混合熔剂,在1000℃熔融制样,以X射线荧光光谱法测定硅酸盐等样品中的S,Na,Mg,Al,Si,P,K,Ca,Ti,Mn,Fe,Ba,Cr,V,Sr,Zr,Rb,Cu,Ni和Nb等20种元素,采用理论α系数和康普顿散射线作内标校正元素间的吸收-增强效应。其分析结果的精密度和准确度可与化学法相比  相似文献   

11.
12.
Spherical shells of fluid in general relativity are considered. The density is assumed to be spatially uniform and it is found that there may be three cases of positive, negative and vanishing Schwarzschild mass of the shell although the density and the pressure are both positive throughout. However the negative mass case has to be associated with a singularity representing a negative mass particle and so is unphysical. The zero mass solution has the intriguing feature that the geometry on either side of the shell is Minkowskian and the space is closed. This closure of the space saves the present result from being in contradiction with the positive energy theorems. Earlier investigations claiming zero-mass distributions are also discussed. A short report giving some of the results of the present paper is published inPhys. Lett. A140 285 (1989).  相似文献   

13.
Based on the use of a single ion, isolated at the center of a cryogenically cooled Penning trap, an environment is produced which makes this mass spectrometer remarkably free of systematic errors. The most notable developments in our quest for an ultra-high accuracy instrument were (a) the compensation of the trapping potential, (b) the discovery that motional sidebands could manipulate radial energies, (c) the use of multiply-charged ions that could improve signal-to-noise, and (d) the use of an ultra-stable superconducting magnet/cryostat system with drift <0.010 ppb/h. The dominant systematic errors are associated with radial electric fields caused by image charges in the trap electrodes and with the rf-electrical drive field used to determine the harmonic axial resonance. To illustrate the potential of this improved spectrometer, the four-fold improved measurement of the proton's mass and the eight-fold improved measurement of oxygen's atomic mass will be described. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

14.
A nuclear mass formula is derived using a few extremely reasonable assumptions within an independent particle model with residual interactions. The parameters in the mass formula are determined by a least square fit to the experimental energies. The mass formula is further used to study Garvey-Kelson and Franzini-Radicati mass relationships.  相似文献   

15.
 The combination of in-flight fragment separator and the isochronous mass spectrometry(IMS) in storage rings have been proven to be a powerful tool for the precision mass measurements of shortlived exotic nuclei. In IMS, the mass-over-charge ratio is only related to the revolution period of stored ions, and the relative mass resolution can reach up to the order of 10−6. However, the instability of the magnetic field of storage ring deteriorates the resolution of revolution period, making it very difficult to distinguish the ions with very close mass-over-charge ratio via their revolution periods. To improve the resolution of revolution periods, a new method of weighted shift correction (WSC) has been developed to accurately correct the influence of the magnetic field instabilities in the isochronous mass measurements of 58Ni projectile fragments. By using the new method, the influence of unstable magnetic fields can be greatly reduced, and the mass resolution can be improved by a factor up to 1.7. Moreover, for the ions that still cannot be distinguished after correcting the magnetic field instabilities, we developed a new method of pulse height analysis for particle identification. By analyzing the mean pulse amplitude of each ion from the timing detector, the stored ions with close mass-over-charge ratios but different charge states such as 34Ar and 51Co can be identified, and thus the mass of 51Co can be determined. The charge-resolved IMS may be helpful in the future experiments of isochronous mass measurement even for N =Z nuclei.  相似文献   

16.
A pilot experiment for mass measurement at CSRe   总被引:1,自引:0,他引:1  
A pilot experiment of mass measurement was performed at CSRe with the method of isochronous mass spectrometry. The secondary fragments produced via RIBLL2 with the primary beam of 400 MeV/u 36Ar delivered by CSRm were injected into CSRe. The revolution periods of the stored ions, which depend on the mass-to-charge ratios of the stored ions, were measured with a time-of-flight detector system. The results show that the mass resolution around 8×10-6 for Δm/m is achieved.  相似文献   

17.
The present status of mass measurements from reactions producing nuclei at the driplines, including those unstable to nucleon or cluster emission, is discussed. The results of recent heavy ion and π-meson induced experiments on the study of the superheavy hydrogen isotopes (4H, 5H, 6H), helium (9He, 10He), lithium (10Li, 11Li) and beryllium (13Be) are given. The possibilities of mass measurements in radioactive ion beam experiments are also considered. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

18.
The velocity component effect to the mass resolution was considered for two different positions of beam source in the time-of-flight mass spectrometer based on de Heer and Milani criteria. The results estimated for various potassium cluster sizes showed that resolution is reduced at considerable level and the cluster range is limited to the small mass sizes for the position along with the cluster beam axis. The resolution is high and the effect appears close to K1000 cluster sizes depending upon perpendicular axis used.  相似文献   

19.
It is resented the theory and the operation diagram of a cyclotronic resonance mass spectrometer, based on the fact that the synchronous ion is neither accelerated nor decelerated. It is shown that its resolving power is the same with that of a device working with n distinct modulators, having the advantage of a much higher intensity of the ionic current. A practical example for the separation ofa multiplet of mass 30 is computed and discussed.  相似文献   

20.
吴宁  阮图南  郑志鹏 《中国物理》2001,10(7):611-612
After considering its mixing with the glueball, we give a new mass relation for the meson nonet. According to this mass relation and the predicted mass of the pseudoscalar glueball given by lattice calculations and the effective Hamiltonian, the expected mass of the mixed pseudoscalar glueball is about 1.7 GeV. This result is helpful in the experimental search for the mixed isoscalar pseudoscalar glueball. η(1760) is discussed as a possible candidate for this type of particle.  相似文献   

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