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A protoilludane sesquiterpene (named xanthocerapene) was isolated from the wood of Xanthoceras sorbifolia Bunge. Its structure, including the relative configuration was established by spectroscopic and chemical methods. 相似文献
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CHI Guo-Chen② CHEN Ru-Yu② 《结构化学》2002,(1)
1 INTRODUCTION It is well known that natural and modified nucleosides have potential antiviral and anticancer activities[1,2]. These observations prompted us to synthesize the title compound -a new kind of spironucleoside, whose structure was determined by 1HNMR, 31PNMR and elemental analysis. The configuration was assigned by means of nuclear Overhauser effect. To further confirm the structure and configuration unambiguously, the title compound was subjected to X-ray diffractio… 相似文献
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FAN Lin-Lin PENG Shu-Hui WEN Cheng-Rong HE Ming-Xiang WEI Xue-Qi WU Chun-Hua YAO Min-Na FENG Rui PANG Jie 《结构化学》2012,31(4):605-613
Biological activity of konjac glucomannan is closely related to its structure,in particular to its high-level structure.Researches on the activity mechanism of konjac glucomannan are significant for revealing the mysteries of participation in life activity.In this paper,analysis of the effects of konjac glucomannan configuration and various factors on its structure and activity was conducted,mechanism of biological activity of konjac glucomannan was explored,and the hot research topic of konjac glucomannan was given. 相似文献
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CHEN Wen-Sen South China Institute of Botany Chinese Academy of sciences Guangzhou Guangdong ChinaYAO Zhu-Jun ZHANG Yi-Bin XU Yong-Zhen WU Yu-LinState Key Laboratory of Bio-organic & Natural Products Chemistry Shanghai Instutute of Organic Chemistry Chinese Academy of Sciences Fenglin Lu Shanghai China 《中国化学》1995,13(3):263-266
Atemoyacin A, a new annonaceous acetogenin was isolated from the alcoholic extract of the seeds of Annona atemoya Hort (Annonaceae). Its structure and relative configuration were elucidated on the basis of the spectral analysis. 相似文献
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《中国化学快报》1990,(2)
A new protoilludane sesquiterpenoid aromatic ester,named armillarizin(1)has been isolated from the artificially cultured mycelium of Armillaria me-llea(Vahl.ex Fr)Quel.(Tricholomataceae).Its structure was deduced on the ba-sis of spectral analyses.The relative configuration was established from thenuclear Overhauser effects and from the values of ~1H-~1H coupling constants. 相似文献
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A new alkaloid from Stemona sessilifolia 总被引:1,自引:0,他引:1
Peng Wang Hai Lin Qin Zhi Hong Li Ai Lin Liu Guan Hua Du Institute of Materia Medica Chinese Academy of Medical Sciences & Peking Union Medical College Beijing China 《中国化学快报》2007,18(2):152-154
A new alkaloid, named sessilistemonamine D, was isolated from the roots of Stemona sessilifolia and the structure and relative configuration were determined on the basis of NMR and MS spectrometric data analysis. 相似文献
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HUA Er-BingCoordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing Jiangsu ChinaYANG Pin LI Qing-Shan YANG Bin-ShengInstitute of Molecular Science Shanxi University Taiyuan Shanxi China 《中国化学》1996,14(4):297-302
The effect of Cu2+ on the triple-stranded helical structure of poly(A:2I) was studied by means of circular dichroism spectral method with the help of ultraviolet spectral and ethidium bromide fluorescence probe methods. It was found that Cu2+ destabilizes the structure of the triple helix poly(A:2I) and induces its structural transformations, meanwhile, the transformations can be partially reversed by a higher NaCl concentration. The structural transformations may be expressed by the following scheme: poly(A:2I) - poly(A:I) + poly(I)- poly(A) + 2poly(I) 相似文献
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《结构化学》1988,(2)
<正> The title compound crystallized in orthorhombic system with space group P212121 and cell dimensions a=9.805(2),b=11.381(4), c=13.865(4) A,V= 1547.0A3, Z=4,Dc=1.345 g.cm-3,λ=1.5418A,μ=13.067 cm-1.The structure was solved by direct methods and refined by block-diagonal least-squares method to the final discrepancy factors R=0.042 and Rw=0.042 for 1101 reflections with I>2.50σ(I). The absolute configuration was determined by utilizing the anomalous scattering of the Si and Cl atoms.It has the S configuration. The Si←N bond length is 2.146(5)A. 相似文献
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One novel(named palcernuine, 1) and five known cernuane-type(2–6) alkaloids were isolated from the whole plant of Palhinhaea cernua f. sikkimensis. The structure of 1, possessing an unprecedented [5/6/6/6]-tetracyclic ring system containing two nitrogen atoms, was established on the basis of spectroscopic methods, and its absolute configuration was determined by comparison of the experimental and calculated electronic circular dichroism(ECD) spectra. A plausible biosynthetic pathway to 1 is proposed. 相似文献
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On the basis of systematic modification of the structure of componds of antiepilepsirine type, more than 200 cinnamamides were synthesized and tested by animal assay (maximal electroshock seizure, MES). Pharmacological evaluation showed that the configuration and the substituents on the phenyl ring and the nitrogen of amides, and substituents on the double bond displayed an important effect on the anticonvulsant activity.For studying the effect of the modification of structure to anticonvulsant activity, Hansch approach was employed to study the QSAR among 38 cinnamamides, and Hopfinger' s MSA was employed to study the MSA-QSAR among 26 cinnamamides. 相似文献
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流动注射在线吸附预富集原子光谱联用技术在痕量 (形态)分析中的应用 总被引:1,自引:0,他引:1
深入系统地讨论了以编结反应器(KR)为吸附介质的流动注射(FI)在线预富集分离与原子光(质)谱联用技术及其在环境和生物样品中(超)痕量元素(形态)分析中的应用。与常用的FI在线C18微柱预富体系相比,KR体系不需填料作吸附剂、反压低、可用较大样品流速以补偿其富集效率低的缺点,并且使用寿命几乎无限长。KR吸附体系具有经济、简便和易操作等优点,是替代常用的FI在线C18微柱预富集的比较理想的体系。 相似文献
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卷积伏安法(新极谱法)是近十年发展起来的一种新电化学分析方法, 本文报导了逐级电子转移过程的0.51次微分电分析法的理论和实验结果, 用计算机模拟了理论极谱图, 讨论了标准分离电位和电子转移数对极谱的影响 。并选择0.1M的NH~4Cl-NH~4OH作为缓冲溶液中铜(II)的还原作为检验理论和实验之间的关系。 相似文献
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本文应用多目标罚函数单纯形法对汞I(II)催化亚铁氰化钾与硫脲配体置换反应测定汞(II)的实验条件优化,并对其机理进行了较深入的研究。本法用于标准水样中痕量(II)的测定,得到满意结果。 相似文献
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本文提出线性变位极谱卷积和去卷积配位吸附不可逆波理论, 并进行了验证,实验结果与理论相符。 相似文献
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研究了以meso-四(N-甲基-3-吡啶基)卟啉测定锌痕量锌的荧光光度法, 其灵敏度较其它水溶性卟啉衍生物测定锌的分光光度法要高, 检出量为1ppb, 线性范围为0-1.0μg/25mL. 方法已用于测定自来水和头发中的微量锌, 结果满意. 相似文献
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