Rate equations in the hopping transport

The usual kinetic equations for the site occupation probabilities in an external field are solved exactly in a simple one-dimensional periodic model with two kinds of atoms using a) free boundary conditions and order of limitsN, 0 needed for a proper treatment of the dc conductivity here b) boundary conditions with metallic contacts and order of limitsN, 0 and c) the same boundary conditions but reversed order of limiting processes 0,N typical of e.g. numerical and percolation treatments. (N and are the number of sites and frequency.) It is demonstrated that though the bulk dc conductivity is the same in all three cases, local bulk properties of the material are strongly dependent on the régime used. The role of the order of all three limiting processes 0,N+ andn+ (N–n+) for local shifts of the chemical potential _n in the dc limit is examined (n is the number of the relevant site calculated from a boundary of the chain). It is shown especially that the rate equation treatment (régime a) on the one hand and numerical or percolation treatments (régime c) on the other hand never yield the same bulk values of _r.     

Notes on the classical and the nonrelativistic limits in quantum mechanics

A method is presented which can be used to discuss both the classical and also the nonrelativistic limit of quantum mechanics. A one-to-one correspondence may be established between the asymptotic convergence of the resolvent and that of the timedependent solution. In so far as the question of dynamics is concerned we investigate the relation between families of nonrelativistic Hamiltonians and the corresponding Dirac-Hamiltonians when c± or when c±0. The nonrelativistic free theory formally shows the same pattern when ±0 (the classical limit) or when ±. The investigation finally shows how the asymptotic convergence of the relativistic theory can take place under some fairly general conditions of the radiation field.     

Spin-orbit coupling in the chlorobenzene molecule

The possible ways of drawing of the intensity of the S₀ T* transition in the chlorobenzene molecule are investigated. The effective spin-orbit coupling of either S* or S* states with the T* state leads to the out-of-plane polarized component of phosphorescence in the chlorobenzene. The in-plane polarized component cannot be explained by the mechanism under consideration — by drawing of intensity of the S₀ S₀* transitions through spin-orbit coupling of first order.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 134–138, August, 1974.     

Four-baryon weak interactions with ΔS = 1 and SU (6) symmetry

Relations are found among the amplitudes for four-baryon processes with S = 1 under the assumption that the Lagrangian for s-wave weak interactions has the transformation properties of a component of the SU(6) 35-plet. In particular, it is found that the amplitudes for the¹S₀ ¹S₀ and³S₁ ³S₁ transitions for the p pn reaction are the same, within a sign.Translated from Izvestiya VUZ. Fizika, No. 10, pp. 70–77, October, 1969.     

TheK S 0 →π0 l + l − andK L 0 →π0 l + l − decays in the standard model and the extended Nambu-Jona-Lasinio model

TheK _S ^{0 0} l ⁺ l ^– andK _L ^{0 0} l ⁺ l ^– decays are considered within the framework of the Standard model in the one-photon exchange approximation, i.e.K _S,L ^{0 0}+ *⁰ +l ⁺ l ^–. To evaluate the low-energy matrix elements of theK ⁰(¯K ⁰)⁰+ * transitions, the constituentquark-loop approximation, based on the extended Nambu-Jona-Lasino (NJL) model, is used. The obtained results are compared with other theoretical estimates and the experimental bounds.     

Symmetries in quantum logics

A symmetry in the quantum logic (L, M) is defined as a pair of bijections :L L andv :M M such that the probabilities are preserved. Some properties of the symmetries are investigated.     

The van der Waals limit for classical systems

For a -dimensional system of particles with the two-body potentialq(r)+ ^v K(r) and density , it is proved under fairly weak conditions onq andK that the canonical pressure (, ) and chemical potential (, ) tend to definite limits when 0. The limiting functions are absolutely continuous and are given in terms of the derivative of the limiting free energy density which was found in Part I.     

Spectral superbroadening of self-focused picosecond laser pulses in D2O

Intense picosecond light pulses of a mode-locked Nd: glass laser at _L =1054 nm (fundamental wavelength) and _SH =527 nm (second harmonic wavelength) are passed through a sample of D₂O under self-focusing conditions. Spectrally structured superbroadened, spatially bell-shaped emission in the forward direction is obtained. Primary generation processes are pump-pulse-degenerate stimulated parametric four-photon interaction (₁ + _{1 3} + ₄) and stimulated Raman scattering (_{1 R} + ), which occur concurrently (₁= _L or _SH angular pump frequency, #x03C9; _R first Stokes frequency, #x03C9; signal frequency, #x03C9;₃ signal frequency, #x03C9;₄ idler frequency). The parametric four-photon interaction occurs under collinear non-phase-matched conditions and under longitudinally phase-matched, transversally non-phase-matched (erenkov-like) conditions. Subsequent interaction processes are pump-pulse-nondegenerate four-photon interaction of the type ₁ + _{R 3} + ₄, coherent antiStokes Raman scattering (CARS, ₁ + ₁ – _{4 3}), inverse Raman scattering ( _A + ₁ + ), and cascading light up-conversion of the type ₁ + _(i) – _{R (i+1)}.     

Particle polarizations in decays of5HeΛ and4HΛhypernuclei

Nucleon polarizations are examined in the hypernucleus decays⁵He, ⁴He + p + _–,⁴H, ³H + p + _–, and⁴H, ³He + n + _–. The effect of the strong interaction in the final state is taken into account. A significant role is predicted for the resonance interaction in the p-⁴He system in the formation of the proton polarization in the⁵He decay. It is also shown that in the⁴H, ³H + p + _– decay the proton-polarization components should attain significant magnitudes, while in the charge-exchange decay⁴H, ³He + n + _–, the neutron polarization is expected to be not too large.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 100–103, October, 1988.     

Stimulated IR- and vacuum-UV emission following two-photon-excitation of molecular hydrogen using an ArF laser

Hydrogen molecules are excited by two 193 nm-photons [X¹ _g ⁺ E,F¹ _g ⁺ ;Q₀₂(1)] generated with a commerical oscillator-amplifier ArF laser. Stimulated emission is subsequently observed in the IR (=752.4 nm to 836.6 nm;E, FB) and in the VUV (=134.0 nm to 160.9 nm;BX) with a VUV conversion efficiency of 0.2%. The rotational fine-structure, the saturation behaviour, pump depletion as well as SRS-onset on and off two-photon resonance are investigated.     

Phase diagram and scattering intensity of binary amphiphilic systems

A Ginzburg-Landau model with a scalar and a vector order parameter, which describe the concentration and orientation of the amphiphile, respectively, is used to study the phase diagram and the scattering intensity of binary amphiphilic systems. With increasing amphiphile concentration, the calculated phase diagram shows the typical sequence of ordered phases observed experimentally, that is micellar liquid cubic micellar hexagonal lamellar cubic bicontinuous invers hexagonal. The scattering intensity in the homogeneous phase is calculated in the oneloop approximation. In the vicinity of a phase transition to an ordered phase, the intensity is found to show a 1/q behavior for not too small wave vectorsq, followed by a small peak, and a 1/q ² decay for large wave vectors, in agreement with experimental observations in theL ₃-(or sponge-)phase.Dedicated to Prof. H. Wagner on the occasion of his 60th birthday     

The classical limit of quantum partition functions

We extend Lieb's limit theorem [which asserts that SO(3) quantum spins approachS ² classical spins asL] to general compact Lie groups. We also discuss the classical limit for various continuum systems. To control the compact group case, we discuss coherent states built up from a maximal weight vector in an irreducible representation and we prove that every bounded operator is an integral of projections onto coherent vectors (i.e. every operator has diagonal form).Supported by USNSF Grant MCS-78-01885     

One- and Two-Photon Fluorescence Anisotropy of Selected Fluorene Derivatives

The steady-state excitation anisotropy spectra of fluorene derivatives were measured in viscous solvents, under the one- and two-photon excitation, over a broad spectral range (UV–Visible). The orientation of their absorption transition moments for the first, S₀S₁, and second, S₀S₂, excited states were determined. It was shown experimentally that a decrease in the angle between S₀S₁and S₀S₂ transitions corresponded to an increased value of two-photon absorption (2PA) cross section for these molecules. Two-photon excitation anisotropy was nearly constant over the spectral region investigated (in contrast to one-photon excitation anisotropy spectra) and can be roughly explained by a simple model of 2PA based on the single intermediate state approximation. For comparison, the same trend in two-photon excitation anisotropy was observed for Rhodamine B inglycerol.     

Relativistic Hypernuclei: Old Problems and New Prospects

The first experiments with relativistic hypernuclei (Bowen; Khorozov and Lukstins) were done many years ago. They demonstrated not only that such extremely difficult experiments are manageable but also their great advantage, a possibility of observing and studying independently the production and weak decay of hypernuclei: the points of the production and decay of relativistic hypernuclei are separated by tens of centimeters instead of some microns in classical experiments. At the same time these first experiments revealed a huge problem with selection of the proper trigger.Recently we proposed to explore a unique feature of the ⁹Be nucleus: after removing a neutron from its ground state several groups of alpha-particles appear from different excited states of a residual nucleus ⁸Be. Detection of the correlated pair of -particles produced in a vacuum volume at a distance of some 40 cm from target is an unambiguous signal of nonmesonic decay of hypernucleus ¹⁰ Be(++n+n) or ¹⁰ Be(++n+p). In this particular case it is possible to take exclusive decay rates (on different excited states of ⁸Be^*). This open a way for a phenomenological analysis of matrix elements of the four-baryon weak interaction.The experiment is approved for new accelerator Nuclotron at JINR, Dubna.     

Variance calculations and the Bessel kernel

In the Laguerre ensembleof n xN Hermitian matrices, it is of interest both theoretically and for applications to quantum transport problems to compute the variance of a linear statistic, denoted var_N f, asN . Furthermore, this statistic often contains an additional parameter a for which the limit is most interesting and most difficult to compute numerically. We derive exact expressions for both lim_N var_N f and lim , lim_N var_N f.     

Long-range order in the XXZ model

The existence of long-range order is proved under certain conditions for the antiferromagnetic quantum spin system with anisotropic interactions (XXZ model) on the simple cubic or the square lattice. In three dimensions (the simple cubic lattice), finite long-range order exists at sufficiently low temperatures for any anisotropy(0) ifS1, and for 0<0.29 (XY-like) or>1.19 (Ising-like) ifS=1/2. In two dimensions (the square lattice), ground-state long-range order exists under the following conditions: for any anisotropy (0) ifS3/2; 0<0.032 (XY-like) or 0.67<<1.34 (almost isotropic) or>1.80 (Ising-like) ifS=1;>1.93 (Ising-like) ifS=1/2. We conjecture that the two-dimensional spin-1/2XY model (=0) has finite ground-state long-range order. Numerical evidence supporting this conjecture is given.     

Experimental study of cw carbon monoxide flame chemical laser of the CS2/O2/CO2 type

The performance of a continuous-wave (cw) CO flame chemical laser (FCL) of the CS₂/O₂/CO₂ type is presented. The laser gives up to 0.7 W cw output power on a number ofP _v (J) lines corresponding to 1110, ..., 76 vibrational bands of CO molecule. The measured values of chemical efficiency based on the reaction O+CSCO^*(v)+S and the specific power are 0.1% and 0.7J/g, respectively. The spectral composition of the CO FCL of the CS₂/O₂/CO₂ type shows lasing in the region from 5.194 to 5.573 m. All experimental measurements are conducted with a nondispersive optical cavity.     

Energy-Momentum Properties and the Spin of Short-Lived Particles

The space–time translation property of a stable particle is characterized by a time-like Lorentz vector (E, _k ). We show in this contribution that unstable particles are, in addition, characterized by a space-like Lorentz 4-vector of uncertainties, or spreads, ( E, k). This is true for unstable states created in formation-, in production-, and in decay-experiments. The space-like nature of the spread vector causes a nonzero momentum spread to be present in all Lorentz frames so that there is no Lorentz frame in which the unstable particle is entirely at rest. With the space-like spreadvector ( E, k) in addition to the time-like (E, _k ), also the rotation property of an unstable particle is affected, and unstable states have an uncertainty in their spin. This means neighboring spin states are occupied in addition to the original spin. Experiments are discussed that show a principal limitation of the accuracy of spin measurement from finite lifetimes. Wave functions for unstable particles are discussed, and we show in the example of a short-lived spin-0 state that the appearance of a spin neighbor in the amplitude is proportional to the inverse lifetime.     

830 nm emission in sodium vapor

We demonstrate that the intriguing 830 nm coherent emission, which is observed when sodium vapor is pumped with a high-power pulsed laser tuned near the 3S4D two-photon transition, is due to an axially phase-matched six-wave mixing process. This conclusion is based upon the observation of emission near 584 nm, which is coupled to the 830 nm emission in the six-wave mixing process: ₁+₂=2_L–_4D4P –_4P3D . In addition, we have observed coherent emission near 1.16 m, which is due to an analogous process involving cascade through the 4S (as opposed to the 3D) state. We calculate the wavelengths of all photons involved in these processes using the standard formulas of parametric wave-mixing theory, and show that they can be predicted to within experimental uncertainties. Finally we report observations of significant blue shifts of the 830 nm and 1.16 m emissions in a mixed sodium-potassium vapor. These shifts can be readily understood by considering the effect of the potassium on the frequency-dependent refractive index of the vapor. Due to these results, other recent interpretations of the 830 nm emission as stimulated excimer emission on the Na₂ 1³ _g ⁺ 1³ _u ⁺ band must now be rejected.     

Scalar particle with polarizability in a uniform external magnetic field

The model of a scalar structured particle is considered, which possesses polarizability in an external electromagnetic field. The expression for the 4-dimensional current density is found. The exact solution of the equations describing a scalar particle with polarizability in a uniform external magnetic field is obtained. Up to the terms of order O(H²), the energy spectrum can be formally obtained by the substitution of the particle mass in the expression for a pointlike scalar particle: mm–H²/2, where is the magnetic polarizability of the particle. It is shown that the rms radius of a trajectory can be obtained by the substitution of the charge in the well-known formula for a structureless scalar particle: ee(1{-H²/m)^1/2 (where is the electric polarizability).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 91–94, January, 1991.I thank A. I. L'vov for discussions.