Bis(1,2-cyclopentylenedithio)- and bis(1,2-cyclohexylenedithio)tetrathiafulvalenes

New homologs of bis(ethylenedithio)tetrathiafulvalene, viz., bis(cyclopentylenedithio)tetrathiafulvalene and bis(cyclohexylenedithio)tetrathiafulvalene, were obtained via a known scheme and characterized.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1317–1319, October, 1991.     

The reaction of para-tolydiazonium tetrafluoroborate with bis (dinitrogen)-bis(1,2-bis(diphenylphosphino)ethane)molybdenum

Reactions of para-tolyldiazonium tetrafluoroborate with trans-Mo(N₂)₂ (dppe)₂ (where dppe = 1,2-bis(diphenylphosphino ethane) result in the oxidation of the molybdenum complex with complete loss of dinitrogen. A similar reaction occurs with MoBr(N₂)(dppe)₂.     

Stereoselective preparation of (E)-(1,2-difluoro-1,2-ethenediyl) bis[tributylstannane] and stereospecific synthesis of (E)-1,2-difluorostilbenes

[reaction: see text]. The novel bisstannane (E)-(1,2-difluoro-1,2-ethenediyl) bis[tributylstannane] 2 was stereoselectively prepared in a high overall yield through a sequential synthetic route from chlorotrifluoroethylene 1. The synthetic application of this novel bisstannane 2 was exemplified in the Pd(PPh3)4/CuI-catalyzed cross-coupling reactions with aryl iodides, yielding (E)-1,2-difluorostilbenes 3 in moderate to high yields.     

利用四氯乙烷胺化反应合成联氢化嘧啶衍生物的研究

利用均四氯乙及二氯甲烷的胺化反应,合成了联氢化嘧啶衍生物1～5,4a,8b-反-4,5,8a,9a-四氮杂全氢芴(6)和8b,8c-顺-3a,4a,7a,8a-四氮杂环戊并全氢芴(7)。化合物(6)和(7)的顺反异构体在酸催化下开环,异构生成较稳定的6b和7a。     

The reaction of bis(phenyldimethylphosphine)bis(diphenylsilyl)platinum(II) with acetylenes

The synthesis and the reactions of cationic complexes of rhodium(I) and iridium(I) of the type [M(NN′)(COD)]⁺ and [M(NN′)(CO)₂]⁺ (NN′  Schiff bases of pyridine-2-aldehyde; COD  cis,cis-1,5-cyclooctadiene) are reported.     

Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)- pentacarbonyltungsten complexes

Russian Chemical Bulletin - A reaction of Bu4N[8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2] with (MeCN)3W(CO)3 in dichloromethane gave a mixture of...     

Flow-injection investigation of the chemiluminescent reaction of bis(2,4,6-(trichlorophenyl)oxalate) with free chlorine

This work investigated the chemiluminescent reaction of free chlorine with bis(2,4,6-(trichlorophenyl)oxalate) (TCPO) in the presence of 9,10-diphenylanthracene in acetonitrile/water medium, with analytical application for free chlorine in tap water. In the absence of free chlorine, the background signal increased with the pH and the chemiluminescence emission showed strong dependence with the sample acidity. A flow injection analysis system, for free chlorine determination, was developed. The linear range for free chlorine was (0.2-3.0)×10⁻⁵ mol l⁻¹. Chloramine 1.0×10⁻⁵ mol l⁻¹ and chlorite 1.0×10⁻⁶ mol l⁻¹ also enhanced the chemiluminescence intensity.     

Preparation of E-(1,2-difluoro-1,2-ethenediyl)bis(tributylstannane)

Chlorotrifluoroethene is converted in situ to [F₂CCFSiMe₃]. The crude [F₂CCFSiMe₃] solution is reduced with lithium aluminum hydride to (HFCCFSiMe₃), which (without isolation) is converted to (Z)-HFCCFSnBu₃. Subsequent metallation and trapping of the vinyllithium reagent with Bu₃SnCl gives (E)-Bu₃SnCFCFSnBu₃ in 73% overall yield. Only two isolation steps are required and the use of Me₃SiCl and F₂CCFCl provides a cheap, economical route to this useful synthon.     

Ferromagnetic ordering in bis(benzene)chromium(+) Bis(4,5-dimethoxybenzene-1,2-dithiolato)nickel(-)

The compound bis(benzene)chromium(+) bis(4,5-dimethoxy-1,2-benzenedithiolato)nickel(-), [Cr(bz)(2)](+)[Ni(dmox)(2)](-), was prepared as well-defined crystals by a metathesis reaction. X-ray single-crystal structure confirms the expected symmetries of the cations (D6h) and anions (D2h). The Ni-S bond length is typical for a monoanionic bis(arene)-1,2-dithiolato nickel complex thus confirming the ascribed charges. The structure reveals interpenetrating cation and anion sublattices where all ions are well separated from other ions of the same charge and with almost perpendicular symmetry planes of cations and anions. Above ca. 10 K the compound is paramagnetic and follows the Curie-Weiss law for S = 1/2 on each ion with a Weiss temperature of 8.5 K. Magnetic susceptibility and magnetization studies reveal the transition to a ferromagnetically ordered phase at 3.4 K. The ferromagnetic interaction is likely to occur through short contacts between anion heteroatoms (O and Ni) and cation H atoms, forming a 2-D network. A third dimension is possible through somewhat longer interionic S-H contacts. The Curie-Weiss law behavior can be modeled for 1-D chains with a ferromagnetic interaction of J = 11.6 K.