Characterization for elastic constants of fused deposition modelling-fabricated materials based on the virtual fields method and digital image correlation

Fused deposition modelling (FDM), a widely used rapid prototyping process, is a promising technique in manufacturing engineering. In this work, a method for characterizing elastic constants of FDM-fabricated materials is proposed. First of all, according to the manufacturing process of FDM, orthotropic constitutive model is used to describe the mechanical behavior. Then the virtual fields method (VFM) is applied to characterize all the mechanical parameters \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) using the full-field strain, which is measured by digital image correlation (DIC). Since the principal axis of the FDM-fabricated structure is sometimes unknown due to the complexity of the manufacturing process, a disk in diametrical compression is used as the load configuration so that the loading angle can be changed conveniently. To verify the feasibility of the proposed method, finite element method (FEM) simulation is conducted to obtain the strain field of the disk. The simulation results show that higher accuracy can be achieved when the loading angle is close to \(30^{\circ }\). Finally, a disk fabricated by FDM was used for the experiment. By rotating the disk, several tests with different loading angles were conducted. To determine the position of the principal axis in each test, two groups of parameters \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) are calculated by two different groups of virtual fields. Then the corresponding loading angle can be determined by minimizing the deviation between two groups of the parameters. After that, the four constants \((Q_{11}\), \(Q_{22}\), \(Q_{12}\), \(Q_{66})\) were determined from the test with an angle of \(27^{\circ }\).     

Models of Elastic Shells in Contact with a Rigid Foundation: An Asymptotic Approach

We consider a family of linearly elastic shells with thickness \(2\varepsilon\) (where \(\varepsilon\) is a small parameter). The shells are clamped along a portion of their lateral face, all having the same middle surface \(S\), and may enter in contact with a rigid foundation along the bottom face.We are interested in studying the limit behavior of both the three-dimensional problems, given in curvilinear coordinates, and their solutions (displacements \(\boldsymbol{u}^{\varepsilon}\) of covariant components \(u_{i}^{\varepsilon}\)) when \(\varepsilon\) tends to zero. To do that, we use asymptotic analysis methods. On one hand, we find that if the applied body force density is \(O(1)\) with respect to \(\varepsilon\) and surface tractions density is \(O(\varepsilon)\), a suitable approximation of the variational formulation of the contact problem is a two-dimensional variational inequality which can be identified as the variational formulation of the obstacle problem for an elastic membrane. On the other hand, if the applied body force density is \(O(\varepsilon^{2})\) and surface tractions density is \(O(\varepsilon^{3})\), the corresponding approximation is a different two-dimensional inequality which can be identified as the variational formulation of the obstacle problem for an elastic flexural shell. We finally discuss the existence and uniqueness of solution for the limit two-dimensional variational problems found.     

Insight into Heterogeneity Effects in Methane Hydrate Dissociation via Pore-Scale Modeling

A large number (1253) of high-quality streaming potential coefficient (\(C_\mathrm{sp})\) measurements have been carried out on Berea, Boise, Fontainebleau, and Lochaline sandstones (the latter two including both detrital and authigenic overgrowth forms), as a function of pore fluid salinity (\(C_\mathrm{f})\) and rock microstructure. All samples were saturated with fully equilibrated aqueous solutions of NaCl (10\(^{-5}\) and 4.5 mol/dm\(^{3})\) upon which accurate measurements of their electrical conductivity and pH were taken. These \(C_\mathrm{sp}\) measurements represent about a fivefold increase in streaming potential data available in the literature, are consistent with the pre-existing 266 measurements, and have lower experimental uncertainties. The \(C_\mathrm{sp}\) measurements follow a pH-sensitive power law behaviour with respect to \(C_\mathrm{f}\) at medium salinities (\(C_\mathrm{sp} =-\,1.44\times 10^{-9} C_\mathrm{f}^{-\,1.127} \), units: V/Pa and mol/dm\(^{3})\) and show the effect of rock microstructure on the low salinity \(C_\mathrm{sp}\) clearly, producing a smaller decrease in \(C_\mathrm{sp}\) per decade reduction in \(C_\mathrm{f}\) for samples with (i) lower porosity, (ii) larger cementation exponents, (iii) smaller grain sizes (and hence pore and pore throat sizes), and (iv) larger surface conduction. The \(C_\mathrm{sp}\) measurements include 313 made at \(C_\mathrm{f} > 1\) mol/dm\(^{3}\), which confirm the limiting high salinity \(C_\mathrm{sp}\) behaviour noted by Vinogradov et al., which has been ascribed to the attainment of maximum charge density in the electrical double layer occurring when the Debye length approximates to the size of the hydrated metal ion. The zeta potential (\(\zeta \)) was calculated from each \(C_\mathrm{sp}\) measurement. It was found that \(\zeta \) is highly sensitive to pH but not sensitive to rock microstructure. It exhibits a pH-dependent logarithmic behaviour with respect to \(C_\mathrm{f}\) at low to medium salinities (\(\zeta =0.01133 \log _{10} \left( {C_\mathrm{f} } \right) +0.003505\), units: V and mol/dm\(^{3})\) and a limiting zeta potential (zeta potential offset) at high salinities of \({\zeta }_\mathrm{o} = -\,17.36\pm 5.11\) mV in the pH range 6–8, which is also pH dependent. The sensitivity of both \(C_\mathrm{sp}\) and \(\zeta \) to pH and of \(C_\mathrm{sp}\) to rock microstructure indicates that \(C_\mathrm{sp}\) and \(\zeta \) measurements can only be interpreted together with accurate and equilibrated measurements of pore fluid conductivity and pH and supporting microstructural and surface conduction measurements for each sample.     

Information entropies of multi-qubit Rabi model beyond the rotating wave approximation

In this paper, we present an analytical solution for the multi-qubit Rabi model for the general case without the rotating wave approximation. We discuss three different cases, one-qubit, two-qubit and three-qubit Rabi model, as applications to the presented solution. In addition, we study the effect of the qubit-photon coupling constants and the detuning parameters on the information entropies \(H(\sigma _{X})\), \(H(\sigma _{Y})\) and \(H(\sigma _{Z}),\) by which we note that, in the case of two-qubit Rabi model, there are collapse and revivals in the curves of the information entropies \(H(\sigma _{Z})\) and \(H(\sigma _{X})\) that vary in their numbers and amplitudes depending on the detuning parameter. The effects of the coupling constants and the detuning parameters on other cases are discussed. Besides, we explain that the dynamic nonlinear properties of the system have strong proportional relationship with the number of atoms.     

A Simple Method for the Determination of Adsorption Kinetic Parameters Using Recycle Fixed-Bed Adsorber

This study focuses on the development of a novel analysis technique for determining the intraparticle diffusivity \((D_{\mathrm{S}})\) and fluid film mass transfer coefficient \((k_\mathrm{F})\) from a concentration history curve of a recycle fixed-bed reactor without using the linear driving force approximation and empirical equations for the estimation of \(k_\mathrm{F}\). The recycle fixed-bed method requires lesser amounts of working fluid for experiment purposes, which is an advantage over the usual fixed-bed method. Based on the characterization results of the concentration history curves, simulated by rigorous numerical calculations, a novel analysis technique was established. The \(D_{\mathrm{S}}\) value can be determined from the experimentally obtained time at which the concentration of the curve is minimal \((t_{C\mathrm{min}})\). The \(k_\mathrm{F}\) value can be determined from the \(D_{\mathrm{S}}\) value and Biot number (Bi), which can be estimated from the experimental ratio of the maximum concentration to the minimum concentration \((c_{\max }/c_{\min })\). The \(D_{\mathrm{S}}\) and \(k_\mathrm{F}\) values of phenol adsorption on an activated carbon material were determined experimentally using the proposed analysis method. This method enables the determination of reliable adsorption kinetic parameters through a simple and economical experiment. However, appropriate experimental data must be acquired under regulated experimental conditions, especially in the case of fluctuation of the concentration history curve.     

Chaotic characteristics analysis of the sintering process system with unknown dynamic functions based on phase space reconstruction and chaotic invariables

We develop a local discontinuous Galerkin finite element method for the distributed-order time and Riesz space-fractional convection–diffusion and Schrödinger-type equations. The stability of the presented schemes is proved and optimal order of convergence \(\mathcal {O}(h^{N+1}+(\Delta t)^{1+\frac{\theta }{2}}+\theta ^{2})\) for the Riesz space-fractional diffusion and Schrödinger-type equations with distributed order in time, an order of convergence of \(\mathcal {O}(h^{N+\frac{1}{2}}+(\Delta t)^{1+\frac{\theta }{2}}\) \(+\theta ^{2})\) is provided for the Riesz space-fractional convection–diffusion equations with distributed order in time where h, \(\theta \) and \(\Delta t\) are space step size, the distributed-order variables and the step sizes in time, respectively. Finally, the performed numerical examples confirm the optimal convergence order and illustrate the effectiveness of the method.     

Representation of a Smooth Isometric Deformation of a Planar Material Region into a Curved Surface

We consider the problem of characterizing the smooth, isometric deformations of a planar material region identified with an open, connected subset \({\mathcal{D}}\) of two-dimensional Euclidean point space \(\mathbb{E}^{2}\) into a surface \({\mathcal{S}}\) in three-dimensional Euclidean point space \(\mathbb{E}^{3}\). To be isometric, such a deformation must preserve the length of every possible arc of material points on \({\mathcal{D}}\). Characterizing the curves of zero principal curvature of \({\mathcal{S}}\) is of major importance. After establishing this characterization, we introduce a special curvilinear coordinate system in \(\mathbb{E}^{2}\), based upon an à priori chosen pre-image form of the curves of zero principal curvature in \({\mathcal{D}}\), and use that coordinate system to construct the most general isometric deformation of \({\mathcal{D}}\) to a smooth surface \({\mathcal{S}}\). A necessary and sufficient condition for the deformation to be isometric is noted and alternative representations are given. Expressions for the curvature tensor and potentially nonvanishing principal curvature of \({\mathcal{S}}\) are derived. A general cylindrical deformation is developed and two examples of circular cylindrical and spiral cylindrical form are constructed. A strategy for determining any smooth isometric deformation is outlined and that strategy is employed to determine the general isometric deformation of a rectangular material strip to a ribbon on a conical surface. Finally, it is shown that the representation established here is equivalent to an alternative previously established by Chen, Fosdick and Fried (J. Elast. 119:335–350, 2015).     

Uniaxial experimental study of the acoustic emission and deformation behavior of composite rock based on 3D digital image correlation (DIC)

In this paper, uniaxial compression tests were carried out on a series of composite rock specimens with different dip angles, which were made from two types of rock-like material with different strength. The acoustic emission technique was used to monitor the acoustic signal characteristics of composite rock specimens during the entire loading process. At the same time, an optical non-contact 3 D digital image correlation technique was used to study the evolution of axial strain field and the maximal strain field before and after the peak strength at different stress levels during the loading process. The effect of bedding plane inclination on the deformation and strength during uniaxial loading was analyzed. The methods of solving the elastic constants of hard and weak rock were described. The damage evolution process, deformation and failure mechanism, and failure mode during uniaxial loading were fully determined. The experimental results show that the θ = 0?–45?specimens had obvious plastic deformation during loading, and the brittleness of the θ = 60?–90?specimens gradually increased during the loading process. When the anisotropic angle θincreased from 0?to 90?, the peak strength, peak strain,and apparent elastic modulus all decreased initially and then increased. The failure mode of the composite rock specimen during uniaxial loading can be divided into three categories:tensile fracture across the discontinuities(θ = 0?–30?), slid-ing failure along the discontinuities(θ = 45?–75?), and tensile-split along the discontinuities(θ = 90?). The axial strain of the weak and hard rock layers in the composite rock specimen during the loading process was significantly different from that of the θ = 0?–45?specimens and was almost the same as that of the θ = 60?–90?specimens. As for the strain localization highlighted in the maximum principal strain field, the θ = 0?–30?specimens appeared in the rock matrix approximately parallel to the loading direction,while in the θ = 45?–90?specimens it appeared at the hard and weak rock layer interface.     

Non-classical continuum theory for fluids incorporating internal and Cosserat rotation rates

This paper presents a non-classical continuum theory for fluent continua in which the conservation and balance laws are derived by incorporating both internal rotation rates arising from the velocity gradient tensor and the rotation rates of the Cosserats. Specifically, in this non-classical continuum theory we have (1) the usual velocities (\(\bar{ \pmb {\varvec{v }}}\)), (2) the three internal rotation rates (\({}_i^t\bar{ \pmb {\varvec{\Theta }}}\)) about the axes of a fixed triad whose axes are parallel to the x-frame arising from the velocity gradient tensor \((\bar{ \pmb {\varvec{L }}})\) that are completely defined by the antisymmetric part of the velocity gradient tensor, and (3) three additional rotation rates (\({}_e^t\bar{ \pmb {\varvec{\Theta }}}\)) about the axes of the same triad located at each material point as additional three unknown degrees of freedom, referred to as Cosserat rotation rates. This gives rise to \(\bar{ \pmb {\varvec{v }}}\) and \({}_e^t\bar{ \pmb {\varvec{\Theta }}}\) as six degrees of freedom at a material point. The internal rotation rates \({}_i^t\bar{ \pmb {\varvec{\Theta }}}\), often neglected in classical fluid mechanics, exist in all deforming fluent continua as these are due to velocity gradient tensor. When the internal rotation rates \({}_i^t\bar{ \pmb {\varvec{\Theta }}}\) are resisted by deforming fluent continua, conjugate moment tensor arises that together with \({}_i^t\bar{ \pmb {\varvec{\Theta }}}\) may result in energy storage and/or dissipation, which must be considered in the conservation and balance laws. The Cosserat rotation rations \({}_e^t\bar{ \pmb {\varvec{\Theta }}}\) also result in conjugate moment tensor that together with \({}_e^t\bar{ \pmb {\varvec{\Theta }}}\) may also result in energy storage and/or dissipation. The main focus of this paper is a consistent derivation of conservation and balance laws for fluent continua that incorporate the aforementioned physics and associated constitutive theories for thermofluids using the conditions resulting from the entropy inequality. The material coefficients derived in the constitutive theories are clearly defined and discussed.     

In Situ Chemically-Selective Monitoring of Multiphase Displacement Processes in a Carbonate Rock Using 3D Magnetic Resonance Imaging

Accurate monitoring of multiphase displacement processes is essential for the development, validation and benchmarking of numerical models used for reservoir simulation and for asset characterization. Here we demonstrate the first application of a chemically-selective 3D magnetic resonance imaging (MRI) technique which provides high-temporal resolution, quantitative, spatially resolved information of oil and water saturations during a dynamic imbibition core flood experiment in an Estaillades carbonate rock. Firstly, the relative saturations of dodecane (\(S_{\mathrm{o}})\) and water (\(S_{\mathrm{w}})\), as determined from the MRI measurements, have been benchmarked against those obtained from nuclear magnetic resonance (NMR) spectroscopy and volumetric analysis of the core flood effluent. Excellent agreement between both the NMR and MRI determinations of \(S_{\mathrm{o}}\) and \(S_{\mathrm{w}}\) was obtained. These values were in agreement to 4 and 9% of the values determined by volumetric analysis, with absolute errors in the measurement of saturation determined by NMR and MRI being 0.04 or less over the range of relative saturations investigated. The chemically-selective 3D MRI method was subsequently applied to monitor the displacement of dodecane in the core plug sample by water under continuous flow conditions at an interstitial velocity of \(1.27\times 10^{-6}\,\hbox {m}\,\hbox {s}^{-1}\) (\(0.4\,\hbox {ft}\,\hbox {day}^{-1})\). During the core flood, independent images of water and oil distributions within the rock core plug at a spatial resolution of \(0.31\,\hbox {mm}\times 0.39\,\hbox {mm} \times 0.39\,\hbox {mm}\) were acquired on a timescale of 16 min per image. Using this technique the spatial and temporal dynamics of the displacement process have been monitored. This MRI technique will provide insights to structure–transport relationships associated with multiphase displacement processes in complex porous materials, such as those encountered in petrophysics research.     

The Effect of Grain Size Distribution on Nonlinear Flow Behavior in Sandy Porous Media

The current study provides new experimental data on nonlinear flow behavior in various uniformly graded granular materials (20 samples) ranging from medium sands (\(d_{50 }>0.39\) mm) to gravel (\(d_{50}=6.3\) mm). Generally, theoretical equations relate the Forchheimer parameters a and b to the porosity, as well as the characteristic pore length, which is assumed to be the median grain size \((d_{50})\) of the porous medium. However, numerical and experimental studies show that flow resistance in porous media is largely determined by the geometry of the pore structure. In this study, the effect of the grain size distribution was analyzed using subangular-subrounded sands and approximately equal compaction grades. We have used a reference dataset of 11 uniformly graded filter sands. Mixtures of filter sands were used to obtain a slightly more well-graded composite sand (increased \(C_{u}\) values by a factor of 1.19 up to 2.32) with respect to its associated reference sand at equal median grain size \((d_{50})\) and porosity. For all composite sands, the observed flow resistance was higher than in the corresponding reference sand at equal \(d_{50}\), resulting in increased a coefficients by factors up to 1.68, as well as increased b coefficients by factors up to 1.44. A modified Ergun relationship with Ergun constants of 139.1 for A and 2.2 for B, as well as the use of \(d_{m}-\sigma \) as characteristic pore length predicted the coefficients a and b accurately.     

On the Justification of Viscoelastic Elliptic Membrane Shell Equations

We consider a family of linearly viscoelastic shells with thickness \(2\varepsilon\), clamped along their entire lateral face, all having the same middle surface \(S=\boldsymbol{\theta}(\bar{\omega})\subset \mathbb{R}^{3}\), where \(\omega\subset\mathbb{R}^{2}\) is a bounded and connected open set with a Lipschitz-continuous boundary \(\gamma\). We make an essential geometrical assumption on the middle surface \(S\), which is satisfied if \(\gamma\) and \(\boldsymbol{\theta}\) are smooth enough and \(S\) is uniformly elliptic. We show that, if the applied body force density is \(O(1)\) with respect to \(\varepsilon\) and surface tractions density is \(O(\varepsilon)\), the solution of the scaled variational problem in curvilinear coordinates, \(\boldsymbol{u}( \varepsilon)\), defined over the fixed domain \(\varOmega=\omega\times (-1,1)\) for each \(t\in[0,T]\), converges to a limit \(\boldsymbol{u}\) with \(u_{\alpha}(\varepsilon)\rightarrow u_{\alpha}\) in \(W^{1,2}(0,T,H ^{1}(\varOmega))\) and \(u_{3}(\varepsilon)\rightarrow u_{3}\) in \(W^{1,2}(0,T,L^{2}(\varOmega))\) as \(\varepsilon\to0\). Moreover, we prove that this limit is independent of the transverse variable. Furthermore, the average \(\bar{\boldsymbol{u}}= \frac{1}{2}\int_{-1}^{1} \boldsymbol{u}dx_{3}\), which belongs to the space \(W^{1,2}(0,T, V_{M}( \omega))\), where

$$V_{M}(\omega)=H^{1}_{0}(\omega)\times H^{1}_{0}(\omega)\times L ^{2}(\omega), $$

satisfies what we have identified as (scaled) two-dimensional equations of a viscoelastic membrane elliptic shell, which includes a long-term memory that takes into account previous deformations. We finally provide convergence results which justify those equations.

     

Transitional and Turbulent Flow in a Bed of Spheres as Measured with Stereoscopic Particle Image Velocimetry

Stereoscopic particle image velocimetry has been used to investigate inertia dominated, transitional and turbulent flow in a randomly packed bed of monosized PMMA spheres. By using an index-matched fluid, the bed is optically transparent and measurements can be performed in an arbitrary position within the porous bed. The velocity field observations are carried out for particle Reynolds numbers, \({Re}_{{p}}\), between 20 and 3220, and the sampling is done at a frequency of 75 Hz. Results show that, in porous media, the dynamics of the flow can vary significantly from pore to pore. At \({Re}_{{p}}\) around 400 the spatially averaged time fluctuations of total velocity reach a maximum and the spatial variation of the time-averaged total velocity, \(u_\mathrm{tot}\) increases up to about the same \({Re}_{{p}}\) and then it decreases. Also in the studied planes, a considerable amount of the fluid moves in the perpendicular directions to the main flow direction and the time-averaged magnitude of the velocity in the main direction, \(u_{x}\), has an averaged minimum of 40% of the magnitude of \(u_\mathrm{tot}\) at \({Re}_{{p}}\) about 400. For \({Re}_{{p}} > 1600\), this ratio is nearly constant and \(u_{x}\) is on average a little bit less than 50% of \(u_\mathrm{tot}\). The importance of the results for longitudinal and transverse dispersion is discussed.     

Whirl Mappings on Generalised Annuli and the Incompressible Symmetric Equilibria of the Dirichlet Energy

In this paper we show a striking contrast in the symmetries of equilibria and extremisers of the total elastic energy of a hyperelastic incompressible annulus subject to pure displacement boundary conditions. Indeed upon considering the equilibrium equations, here, the nonlinear second order elliptic system formulated for the deformation \(u=(u_{1}, \ldots, u_{N})\):

$$ {\mathbb{E}} {\mathbb{L}}[u, {\mathbf {X}}] = \left \{ \textstyle\begin{array}{l@{\quad}l} \Delta u = \operatorname{div}(\mathscr{P} (x) \operatorname{cof} \nabla u) & \textrm{in }{\mathbf {X}},\\ \det\nabla u = 1 & \textrm{in }{\mathbf {X}},\\ u \equiv\varphi& \textrm{on }\partial{\mathbf {X}}, \end{array}\displaystyle \right . $$

where \({\mathbf {X}}\) is a finite, open, symmetric \(N\)-annulus (with \(N \ge2\)), \(\mathscr{P}=\mathscr{P}(x)\) is an unknown hydrostatic pressure field and \(\varphi\) is the identity mapping, we prove that, despite the inherent rotational symmetry in the system, when \(N=3\), the problem possesses no non-trivial symmetric equilibria whereas in sharp contrast, when \(N=2\), the problem possesses an infinite family of symmetric and topologically distinct equilibria. We extend and prove the counterparts of these results in higher dimensions by way of showing that a similar dichotomy persists between all odd vs. even dimensions \(N \ge4\) and discuss a number of closely related issues.

     

Displacement and Dissolution Characteristics of CO$$_{}$$/Brine System in Unconsolidated Porous Media

This study investigated the dynamic displacement and dissolution of \(\hbox {CO}_{2}\) in porous media at 313 K and 6/8 MPa. Gaseous (\(\hbox {gCO}_{2}\)) at 6 MPa and supercritical \(\hbox {CO}_{2 }(\hbox {scCO}_{2}) \) at 8 MPa were injected downward into a glass bead pack at different flow rates, following upwards brine injection. The processes occurring during \(\hbox {CO}_{2}\) drainage and brine imbibition were visualized using magnetic resonance imaging. The drainage flow fronts were strongly influenced by the flow rates, resulting in different gas distributions. However, brine imbibition proceeded as a vertical compacted front due to the strong effect of gravity. Additionally, the effects of flow rate on distribution and saturation were analyzed. Then, the front movement of \(\hbox {CO}_{2}\) dissolution was visualized along different paths after imbibition. The determined \(\hbox {CO}_{2}\) concentrations implied that little \(\hbox {scCO}_{2}\) dissolved in brine after imbibition. The dissolution rate was from \(10^{-8}\) to \(10^{-9}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) and from \(10^{-6}\) to \(10^{-8}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) for \(\hbox {gCO}_{2}\) at 6 MPa and \(\hbox {scCO}_{2 }\) at 8 MPa, respectively. The total time for the \(\hbox {scCO}_{2}\) dissolution was short, indicating fast mass transfer between the \(\hbox {CO}_{2}\) and brine. Injection of \(\hbox {CO}_{2}\) under supercritical conditions resulted in a quick establishment of a steady state with high storage safety.     

Mixing and Bimolecular Reaction Kinetics in a Plane Poisseulle Flow

Mixing and a nonlinear bimolecular chemical reaction (reactant A + reactant B → product; reaction rate r?=?κc ₁ c ₂) in laminar shear flow are investigated. It is found that asymptotically the dominant balance between the rates of production and dissipation of the mean-squared concentration fluctuations \((\sigma_{c_1 }^2 ,\sigma_{c_2 }^2)\) and cross-covariance of concentration fluctuations \((\overline {c_1 c_2 })\) occurs under nonreactive and reactive conditions. Longitudinal dispersion of the cross-sectional averages (C ₁, C ₂), and variances and the cross-covariance of reactant concentrations can be asymptotically quantified by the classic Taylor dispersion coefficient (D) even under reactive conditions. The characteristic time-scale (τ) over which molecular diffusion dissipates concentration variance and the cross-covariance of reactant concentrations is also shown to be the same under nonreactive and reactive conditions. A variational estimate of τ is shown to be close to the values inferred from detailed numerical simulation. The production-dissipation balance implies that the cross-sectional averaged reaction rate follows \(\overline r =\kappa_{eff} C_1 C_2 \) and \(\kappa _{eff} \approx \kappa \left[ {1+2D\tau \left( {{\partial \ln C_1 } \mathord{\left/ {\vphantom {{\partial \ln C_1 } {\partial x}}} \right. \kern-\nulldelimiterspace} {\partial x}} \right)\left( {{\partial \ln C_2 } \mathord{\left/ {\vphantom {{\partial \ln C_2 } {\partial x}}} \right. \kern-\nulldelimiterspace} {\partial x}} \right)} \right]\). The effective reaction rate parameter (κ _eff ) is higher than that of well-mixed batch test reaction rate constant (κ) for initially overlapping species and κ _eff is smaller than κ for initially non-overlapping species.     

The Unstable Set of a Periodic Orbit for Delayed Positive Feedback

In the paper [Large-amplitude periodic solutions for differential equations with delayed monotone positive feedback, JDDE 23 (2011), no. 4, 727–790], we have constructed large-amplitude periodic orbits for an equation with delayed monotone positive feedback. We have shown that the unstable sets of the large-amplitude periodic orbits constitute the global attractor besides spindle-like structures. In this paper we focus on a large-amplitude periodic orbit \({\mathcal {O}}_{p}\) with two Floquet multipliers outside the unit circle, and we intend to characterize the geometric structure of its unstable set \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \). We prove that \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) is a three-dimensional \(C^{1}\)-submanifold of the phase space and admits a smooth global graph representation. Within \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \), there exist heteroclinic connections from \({\mathcal {O}}_{p}\) to three different periodic orbits. These connecting sets are two-dimensional \(C^{1}\)-submanifolds of \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) and homeomorphic to the two-dimensional open annulus. They form \(C^{1}\)-smooth separatrices in the sense that they divide the points of \({\mathcal {W}}^{u}\left( {\mathcal {O}}_{p}\right) \) into three subsets according to their \(\omega \)-limit sets.     

Influence of hydrodynamic slip on convective transport in flow past a circular cylinder

The presence of a finite tangential velocity on a hydrodynamically slipping surface is known to reduce vorticity production in bluff body flows substantially while at the same time enhancing its convection downstream and into the wake. Here, we investigate the effect of hydrodynamic slippage on the convective heat transfer (scalar transport) from a heated isothermal circular cylinder placed in a uniform cross-flow of an incompressible fluid through analytical and simulation techniques. At low Reynolds (\({\textit{Re}}\ll 1\)) and high Péclet (\({\textit{Pe}}\gg 1\)) numbers, our theoretical analysis based on Oseen and thermal boundary layer equations allows for an explicit determination of the dependence of the thermal transport on the non-dimensional slip length \(l_s\). In this case, the surface-averaged Nusselt number, Nu transitions gradually between the asymptotic limits of \(Nu \sim {\textit{Pe}}^{1/3}\) and \(Nu \sim {\textit{Pe}}^{1/2}\) for no-slip (\(l_s \rightarrow 0\)) and shear-free (\(l_s \rightarrow \infty \)) boundaries, respectively. Boundary layer analysis also shows that the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) holds for a shear-free cylinder surface in the asymptotic limit of \({\textit{Re}}\gg 1\) so that the corresponding heat transfer rate becomes independent of the fluid viscosity. At finite \({\textit{Re}}\), results from our two-dimensional simulations confirm the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) for a shear-free boundary over the range \(0.1 \le {\textit{Re}}\le 10^3\) and \(0.1\le {\textit{Pr}}\le 10\). A gradual transition from the lower asymptotic limit corresponding to a no-slip surface, to the upper limit for a shear-free boundary, with \(l_s\), is observed in both the maximum slip velocity and the Nu. The local time-averaged Nusselt number \(Nu_{\theta }\) for a shear-free surface exceeds the one for a no-slip surface all along the cylinder boundary except over the downstream portion where unsteady separation and flow reversal lead to an appreciable rise in the local heat transfer rates, especially at high \({\textit{Re}}\) and Pr. At a Reynolds number of \(10^3\), the formation of secondary recirculating eddy pairs results in appearance of additional local maxima in \(Nu_{\theta }\) at locations that are in close proximity to the mean secondary stagnation points. As a consequence, Nu exhibits a non-monotonic variation with \(l_s\) increasing initially from its lowermost value for a no-slip surface and then decreasing before rising gradually toward the upper asymptotic limit for a shear-free cylinder. A non-monotonic dependence of the spanwise-averaged Nu on \(l_s\) is observed in three dimensions as well with the three-dimensional wake instabilities that appear at sufficiently low \(l_s\), strongly influencing the convective thermal transport from the cylinder. The analogy between heat transfer and single-component mass transfer implies that our results can directly be applied to determine the dependency of convective mass transfer of a single solute on hydrodynamic slip length in similar configurations through straightforward replacement of Nu and \({\textit{Pr}}\) with Sherwood and Schmidt numbers, respectively.     

Resolvent Estimates for High-Contrast Elliptic Problems with Periodic Coefficients

We study the asymptotic behaviour of the resolvents \({(\mathcal{A}^\varepsilon+I)^{-1}}\) of elliptic second-order differential operators \({{\mathcal{A}}^\varepsilon}\) in \({\mathbb{R}^d}\) with periodic rapidly oscillating coefficients, as the period \({\varepsilon}\) goes to zero. The class of operators covered by our analysis includes both the “classical” case of uniformly elliptic families (where the ellipticity constant does not depend on \({\varepsilon}\)) and the “double-porosity” case of coefficients that take contrasting values of order one and of order \({\varepsilon^2}\) in different parts of the period cell. We provide a construction for the leading order term of the “operator asymptotics” of \({(\mathcal{A}^\varepsilon+I)^{-1}}\) in the sense of operator-norm convergence and prove order \({O(\varepsilon)}\) remainder estimates.     

L.A.S. and Negative Schwarzian Derivative Do Not Imply G.A.S. in Clark’s Equation

It has been conjectured that a locally attracting equilibrium of Clark’s equation \(x_{n+1}=\alpha x_n + (1-\alpha )h(x_{n-k})\) is also globally attracting whenever h is a unimodal or decreasing map with negative Schwarzian derivative. The main aim of this paper is to show that the conjecture is false when \(k\ge 3\). This is done by studying the (Neimark–Sacker) bifurcation at the parameter \(\alpha \) where the locally attracting equilibrium of the equation becomes unstable. Our results, on the other hand, reinforce the validity of the conjecture in the cases \(k=1,2\).