共查询到20条相似文献,搜索用时 46 毫秒
1.
Zhi-Qiang Dong Fang-Ming Liu Yong-Ming Zeng 《Journal of chemical crystallography》2011,41(8):1158-1164
Abstract
A series of new heterocyclic compounds bearing 1,2,3-triazole moiety were synthesized using 4-acetyl-2-phenyl-1,2,3-triazole 1 as the starting material. The target compounds were prepared and the structures were characterized by IR, 1H NMR, MS and elemental analysis. Meanwhile, the crystal structures of the synthesized compounds were also furthered confirmed by X-ray diffraction analysis. Compound 3b crystallized in the monoclinic P2(1)/c space group with unit cell parameters a = 10.6974(17) ?, b = 20.356(3) ?, c = 7.8049(12) ?, α = 90°, β = 102.840(3)°, γ = 90o, V = 1657.1(5) ?3, Z = 4, T = 293(2) K. Compound 7c crystallized in the Triclinic P-1 space group with unit cell parameters a = 7.364(2) ?, b = 7.366(2) ?, c = 26.089(8)?, α = 87.114(7)°, β = 87.040(7) (3)°, γ = 82.337(7)°, V = 1399.2(7) ?3, Z = 2, T = 293(2) K. Compound 10c crystallized in the Triclinic P-1 space group with unit cell parameters a = 9.8152(10) ?, b = 10.0806(13) ?, c = 11.1267(14) ?, α = 100.344(3)°, β = 111.975(3)°, γ = 107.852(3)°, V = 916.18(19) ?3, Z = 2, T = 293(2) K. 相似文献2.
Shi-Qiang Liu Bin Quan Hong-Ru Dong Heng-Shan Dong 《Journal of chemical crystallography》2009,39(2):87-90
Abstract 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3
was synthesized from 1-aminonaphthalene. The yielded product 3 was investigated
with X-ray crystallographic, NMR, MS and IR techniques. Compound 3,
C14H11N3O2, Mr = 253.26,
crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4)
?, V = 2500.1(8) ?3, Z = 8, Dx = 1.346 Mgm-3. The final R was
0.0474. The molecular packing is stabilized by intermolecular O–H···N interactions.
Index Abstract 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3 was synthesized from 1-aminonaphthalene. The yielded product 3
was investigated with X-ray crystallographic, NMR, MS and IR techniques. Compound 3, C14H11N3O2, Mr = 253.26,
crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4) ?,
α = β = γ = 90.00o. V = 2,500.1(8) ?3, Z = 8, Dx = 1.346 Mgm−3. The final R was 0.0474. The molecular packing is stabilized by
intermolecular O–H···N interactions.
相似文献
3.
Geremia Jennings Mark D. Smith Shan-Ming Kuang L. Mark Hodges John Tyrell R. Thomas Williamson Pamela Seaton 《Journal of chemical crystallography》2012,42(2):159-164
Abstract
Chalcones, 1,3-diphenyl-2-propene-1-ones, exist naturally and synthetically, and are characterized by the linkage of two aromatic rings joining a three carbon α-β-unsaturated carbonyl entity. We report the observation of two new polymorphs of a hydroxy chalcone, C6H5–CO–CH=CH–C6H4 (m-OH), identified as a result of a Claisen–Schmidt synthesis and manual screening technique. One polymorph of this compound has been reported previously and exists in the monoclinic system, space group P2/n, with unit cell parameters a = 13.295(6) ?, b = 5.659(2) ?, c = 16.144(8) ?, β = 109.73(5)°, V = 1143.3(9) ?3, and Z = 4. Two crystalline forms (II and III) reported herein, are polymorphs of the reported monoclinic form (I). Form II exists in the orthorhombic system, space group Pca21, with unit cell constants a = 11.631 (2) ?, b = 13.163 (3) ?, c = 7.3977 (14) ?, V = 1132.6 (4) ?3, and Z = 4. Form III also crystallizes in the orthorhombic system, however in space group Pbca, with unit cell parameters a = 11.8100(8) ?, b = 7.4075(5) ?, c = 25.8729(19) ?, V = 2263.4(3) ?3, and Z = 8. Variations in the hydrogen bonding connectivity help to distinguish these two forms from the monoclinic, whereas crystal packing differentiates the two orthorhombic forms. The conformation of the C=C (C2–C3) is E for both orthorhombic forms. 相似文献4.
Matloob Ahmad Hamid Latif Siddiqui Saeed Ahmad Graham John Tizzard Masood Parvez 《Journal of chemical crystallography》2010,40(12):1188-1194
Abstract
The crystal structures of four derivatives of pyrazolo[4,3-c][1,2]benzothiazine-2,4-dihydro-3,4-dimethyl-,5,5-dioxide containing benzothiazine dioxide and pyrazolo fused rings that have been synthesized were determined. (C11 H11 N3 O2 S): Mr = 249.29, monoclinic, P21/c, a = 8.3070(3), b = 13.6331(5), c = 10.1661(3) ?, β = 106.924(2)°, V = 1101.45(7) ?3, Z = 4. (C12 H13 N3 O2 S): Mr = 263.31, monoclinic, P21/n, a = 9.729(3), b = 11.224(4), c = 11.436(3) ?, β = 98.85(2)°, V = 1233.9(7) ?3, Z = 4. (C14 H15 N3 O4 S): Mr = 321.35, monoclinic, P21/c, a = 9.2534(3), b = 19.3920(7), c = 7.9489(2) ?, β = 95.323(2)°, V = 1420.21(8) ?3, Z = 4. (C14 H15 N3 O3 S): Mr = 305.35, monoclinic, P21 /c, a = 13.816(7), b = 7.464(3), c = 14.674(8) ?, β = 109.05(3)°, V = 1430.3(12) ?3, Z = 4. The heterocyclic thiazine rings adopt half-chair conformations, and the mean-planes of the phenyl and pyrazolo rings lie between 10.43(11) and 15.93(16)° with respect to each other. In each case, the geometry about thiazine N-atom is trigonal pyramidal and only the first compound containing a donor N-atom shows classical hydrogen bonds. However, non-classical H-bonding of the type C–H···O is observed in all structures. 相似文献5.
Mariolino Carta James Raftery Neil B. McKeown 《Journal of chemical crystallography》2011,41(2):98-104
Abstract
The structures of three spirobisindanes 1, 2a and 2b are reported. Each compound is a precursor to a Polymers of Intrinsic Microporosity (PIM) and is the component that provides the necessary site of contortion within the polymer. Of particular importance are the angles formed between the aromatic units around the spiro-centre as it may have direct relevance to the inefficiency of packing in the solid state packing, we think, induces microporosity in the final polymer. Compound 1 crystallized in the monoclinic P21/c space group with unit cell parameters a = 9.8000(5) Ǻ, b = 17.8710(9) Ǻ, c = 10.4100(5) Ǻ, β = 106.6280(10)°, V = 1746.92(15) A3, Z = 4, D = 1.401 Mg/m3. Compound 2a crystallized in the monoclinic P21/c space group with unit cell parameters a = 9.7460(13) Ǻ, b = 30.291(4) Ǻ, c = 8.6740(12) Ǻ, β = 97.111(3)°, 2541.0(6) A3, Z = 4, D = 1.319 Mg/m3. Compound 2b crystallized in the monoclinic P21/n space group with unit cell parameters a = 13.5670(9) Ǻ, b = 12.7930(8) Ǻ, c = 22.1960(14) Ǻ, β = 96.6630(10)°, V = 3826.4(4) A3, Z = 4, D = 1.265 Mg/m3. 相似文献6.
Rachel C. Severance Ankur M. Patel Mark D. Smith Hans-Conrad zur Loye 《Journal of chemical crystallography》2012,42(3):258-262
Abstract
Two lead coordination compounds, Pb(PYTAC)2 (1), and Pb(PYTAC)2(NO3) (2), were grown as single crystals via hydrothermal synthesis (PYTAC = 2-(4-pyridyl) thiazole-4-carboxylate). Both compounds have been identified via single crystal X-ray diffraction. Coordination polymer 1 crystallizes in a triclinic space group P-1 (a = 5.5097(4) ?, b = 7.2822(5) ?, c = 11.3134(8) ?, α = 103.5580(10)°, β = 99.4330(10)°, γ = 97.1050(10)°), and forms 2-D layers parallel to the crystallographic (ac) plane. Coordination polymer 2 crystallizes in a triclinic space group P-1 (a = 9.8102(5) ?, b = 10.5972(6) ?, c = 14.8076(8) ?, α = 91.9350(10)°, β = 100.8050(10)°, γ = 103.1350(10)°), and forms an infinite 1-D chains along the a axis. 相似文献7.
Prinessa Chellan Kelly Chibale Gregory S. Smith 《Journal of chemical crystallography》2011,41(5):747-750
Abstract
Reaction of a salicylaldehyde semicarbazone ligand with PdCl2(PPh3)2 yields an unexpected binuclear Pd(II) complex, 2. The complex crystallizes in a triclinic system with a P-1 space group, with unit cell parameters a = 14.0283(3) ?, b = 15.2603(3) ?, c = 18.7142(3) ?, α = 66.662(10)°, β = 86.162(10)°, γ = 76.265(10)°, Z = 2. The semicarbazone ligand acts as a tridentate chelating donor to one palladium metal centre, forming a five- and six- membered ring, and a monodentate donor to the second palladium centre. There are four molecules of solvent per complex molecule in the asymmetric unit. Each metal centre is contained within a slightly distorted square-planar environment. 相似文献8.
Ayesha Jacobs Luigi R. Nassimbeni Kanyisa L. Nohako Gaëlle Ramon Baganetsi K. Sebogisi 《Journal of chemical crystallography》2011,41(5):610-616
Abstract
The host compound 9,9′-(ethyne-1,2-diyl)-bis(fluoren-9-ol), H, forms inclusion compounds with caffeine (H·CAF) and methanol (H·MeOH). The host and guest ratios were 1:2 and 1:1, respectively. Both of these structures were successfully solved in P-1 with unit cell dimensions for H·CAF: a = 7.2121(14) ?, b = 9.2782(19) ?, c = 15.206(3) ?, α = 73.23(3)°, β = 84.20(3)°, γ = 73.39(3)°, Z = 2 and for H·MeOH : a = 9.7592(10) ?, b = 11.2584(11) ?, c = 20.7854(19) ?, α = 97.161(2)°, β = 99.263(2)°, γ = 95.257(2) ?, Z = 2. These crystal structures were studied together with that of a mixed clathrate, H·CAF·MeOH with stoichiometry 2:1:1.5. For H·CAF·MeOH which was solved in P21/c : a = 12.2051(5) ?, b = 46.8023(19) ?, c = 9.0121(4) ?, β = 91.9650(10)°, Z = 4. The kinetics of desolvation of the methanol solvate (H·MeOH) yielded an activation energy of 69.6–83.9 kJ mol−1. 相似文献9.
Gautam Prasanna Kar Anirban Karmakar Jubaraj B. Baruah 《Journal of chemical crystallography》2010,40(8):702-706
Abstract
Crystal structures of two bis-phenols namely bis-(3,5-dimethyl-2-hydroxyphenyl)(3-amino phenyl)methane 1 and bis-(3,5-dimethyl-4-hydroxyphenyl)(3-aminophenyl) methane 2 are determined. The compound 1 crystallises in monoclinic P21/c with a = 12.2579(16) ?, b = 16.0906(19) ?, c = 10.6664(13) ?, β = 115.417(7)°, V = 1900.2(4) ?3 whereas 2 crystallizes in monoclinic C2/c, a = 9.2538(2) ?, b = 18.6579(4) ?, c = 23.2725(5) ?, β = 98.796(2)°, V = 3970.89(15) ?3. The crystal lattice of both the compounds shows presence of N–H···π interactions but no O–H···π interactions. 相似文献10.
Katayoun Marjani Mohsen Mousavi Fatemeh Namazian 《Journal of chemical crystallography》2011,41(10):1451-1455
Abstract
The crystal structure of amino containing Schiff base, N-(2-pyridylmethylene)benzene-1,4-diamine, was determined via X-ray diffraction analysis. The title compound crystallizes in orthorhombic system, space group Pc2 1 n, with unit cell dimensions a = 5.8945(6), b = 11.9233 (10), c = 14.5356 (16) ?, V = 1021.59 (18) ?3, Z = 4. The molecules are linked by intermolecular N–H···N hydrogen bonds to form supramolecular sheets along with the bc crystallographic plane. The crystal structure is further stabilized by C–H···π stacking interactions. 相似文献11.
Miguel Guerrero Josefina Pons Mercè Font-Bardia Teresa Calvet Josep Ros 《Journal of chemical crystallography》2011,41(5):721-726
Abstract
The crystal structure of the title compound C22H30N4O2·H2O (L), has been determined using X-ray diffraction at 293 K. The crystal of 1,2-bis[4-(3,5-dimethyl-1H-pyrazol-1-yl)-2-oxobutyl]benzene is in triclinic crystal system with space group P(−1) (Z = 2), lattice parameters a = 8.225(6) ?, b = 10.967(6) ?, c = 12.903(6) ?, V = 1119.1(11) ?3. Analyses of single crystals of L, crystallized from dichloromethane/diethyl ether (1:1), revealed that the molecules are arranged in couples, which adopt a pseudo chair conformation, by means of intermolecular O–H···N hydrogen bonding interactions. Moreover, the extended structure revealed a 1D chain caused by several C–H···N intermolecular interactions. 相似文献12.
Ilham Halime Abdoulillah Bezgour Mohammed Fahim Michal Dusek Karla Fejfarova Mohammed Lachkar Brahim El Bali 《Journal of chemical crystallography》2011,41(2):223-229
Abstract
Using 1,4,8,11-tetraazacyclotetradecane (cyclam) as a template, two new layered zincophosphites, Zn(HPO3)2·0.5(C10H28N4) (1) and Zn2(HPO3)3·0.5(C10H28N4) (2), were synthesized and characterized by single crystal X-ray diffraction. The two new compounds crystallize in the triclinic system with the space group P − 1 and the cell parameters: a = 8.3130 ?, b = 8.7289 ?, c = 9.0055 ?, α = 106.90(1), β = 95.56(1), γ = 105.30(1), V = 592.31 ?3, Z = 2 for 1 and a = 9.0406 ?, b = 9.4234 ?, c = 9.4519 ?, α = 91.19(1), β = 100.73(1), γ = 106.85(1), V = 754.82 ?3, Z = 2 for 2. Both structures are described in terms of phosphometallic slabs hosting the cyclam cation. 相似文献13.
Abstract
Two crystal structures of acridinediones namely, TMHAD and MPHAD were studied by X-ray crystallographic method in view of their occurrence in numerous commercial products including pharmaceuticals, fragrances and dyes. Crystal data of TMHAD are: C17H23NO2, orthorhombic, Fdd2, with cell parameters a = 40.417(6) ?, b = 5.744(1) ?, c = 12.979(2) ?, V = 3013.1(7) ?3, Z = 8, Dcal = 1.205 Mg/m3, μ = 0.078 mm−1. Crystal data of MPHAD are: C20H18NO3; monoclinic, P21/c with cell parameters a = 10.182(9) ?, b = 17.105(14) ?, c = 10.895(9) ?, β = 117.857(1)°, V = 1678(2) ?3, Z = 4, Dcal = 1.268 Mg/m3, μ = 0.085 mm−1. Both data were collected using λ (MoKα) = 0.71073 ?. The central ring in the acridinedione moieties tends to be planar while the outer two rings adopt sofa conformations. Intermolecular interactions of C–H···O type of hydrogen bond help the molecules to stabilize into the crystal packing. Interestingly, a week forces of C–H···π interactions also helps the molecules for stabilization. 相似文献14.
Amal Cherian Kathalikkattil P. S. Subramanian Suresh Eringathodi 《Journal of chemical crystallography》2010,40(12):1087-1093
Abstract
Two metal organic frameworks involving α, ω-dicarboxylates and 2,2′-bpy, [Cu(2,2Bpy)(μ-adipate-H2)] n ·2·H2O 1 and [Cu2 (2,2′-bpy)2(μ-adipate-H)2(μ-adipate-H2)]·3H2O 2 have been synthesized by one pot reaction and structurally characterized. Pentacoordinated Cu(II) zigzag polymeric chain of 1 is composed of linking the adjacent Cu(2,2′-bpy)(H2O) units through terminal craboxylate oxygens of two different adipate dianion in cis coordination pattern with the metal center. Both the Complexes were crystallized in triclinic system, P-1 space group with cell parameters a = 6.8948(5), b = 10.7098(7), c = 12.4332(8) ?; α = 82.1120(10), β = 80.4950(10), γ = 72.9560(10)°, V = 861.87(10) ?3 for 1, a = 9.5058(6), b = 9.9341(7), c = 12.6460(8) ?; α = 70.5080(10), β = 73.5740(10), γ = 75.0720(10)°, V = 1062.05(12) ?3 for 2 respectively. Extensive hydrogen bonding interaction is observed between the lattice water molecules and the coordination network. Compound 2 is a layered architecture, where the neutral framework is constructed by two different adipate anions (in monoanionic and dianionic form) coordinating to the metal center. Interestingly, three water molecules present in the lattice of compound 2 are involved in hydrogen bonding network among themselves, creating a centro-symmetric hexameric water cluster composed of a tetracyclic ring with dangling water molecules attached at alternate positions of the rectangle, which interact with the carboxylate oxygen, thereby extending the hydrogen bonded water network. 相似文献15.
Abstract Bis(isothiocyanato)-bis(pyridine) zinc(II) crystal has been prepared at room temperature and characterized by elemental analysis,
IR spectrum and X-ray single crystal determination. The complex crystallizes in monoclinic space group P21/m with unit cell parameters: a = 5.5786(3), b = 11.0587(5), c = 12.1616(6) ?, β = 96.776(3)°, V = 745.03(6) ?3, Z = 2, D
x
= 1.514 g cm−3. The X-ray structure determination has revealed that the crystal is centered-symmetrical and the crystallographic symmetry
face runs the two isothiocyanate ligands and the Zn(II) cation.
Index Abstract The title compound, bis(isothiocyanato)-bis(pyridine) zinc(II), was synthesized by zinc compound, KSCN and C5H5N (pyridine) and its crystal structure was determined. Single crystal X-ray structure determination reveals that the crystal
is centered-symmetrical, and the crystallographic symmetry face runs the two isothiocyanate ligands and the Zn(II) cation.
相似文献
16.
Abstract Two cadmium coordination polymers of benzenedicarboxylic: [C8H6CdO5]n (1) and [C8H10CdO7]n·4H2O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction. Our experimental results
suggest that complex 1 crystallizes in orthorhombic space group Pbcm with a = 6.4978(8) ?, b = 6.9475(9) ?, c = 18.319(2)
?, and Z = 4. Structural analysis reveals that complex 1 features a three-dimensional framework structure formed by strong
coordination bond and weak hydrogen bond force. Complex 2 crystallizes in orthorhombic space group Pcca with a = 7.293(2),
b = 9.980(3), c = 19.889(6), and Z = 4. Complex 2 exhibits a layered framework structure formed by extensive inter-chain hydrogen
bond interaction.
Index Abstract Two cadmium coordination polymers of benzenedicarboxylic: [C8H6CdO5]n (1) and [C8H10CdO7]n·4H2O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction
相似文献
17.
Saima Jabeen Rex A. Palmer Brian S. Potter Madeleine Helliwell Trevor J. Dines Babur Z. Chowdhry 《Journal of chemical crystallography》2009,39(2):151-156
Abstract Rhodanines (2-thio-4-oxothiazolidines) are synthetic small molecular weight organic molecules with diverse applications in
biochemistry, medicinal chemistry, photochemistry, coordination chemistry and industry. The X-ray crystal structure determination
of two rhodanine derivatives, namely (I), 3-aminorhodanine [3-amino-2-thio-4-oxothiazolidine], C3H4N2OS2, and (II) 3-methylrhodanine [3-methyl-2-thio-4-oxothiazolidine], C4H5NOS2, have been conducted at 100 K. I crystallizes in the monoclinic space group P21/n with unit cell parameters a = 9.662(2), b = 9.234(2), c = 13.384(2) ?, β = 105.425(3)°, V = 1151.1(3) ?3, Z = 8 (2 independent molecules per asymmetric unit), density (calculated) = 1.710 mg/m3, absorption coefficient = 0.815 mm−1. II crystallizes in the orthorhombic space group Iba2 with unit cell a = 20.117(4), b = 23.449(5), c = 7.852(2) ?, V = 3703.9(12)
?3, Z = 24 (three independent molecules per asymmetric unit), density (calculated) = 1.584 mg/m3, absorption coefficient 0.755 mm−1. For I in the final refinement cycle the data/restraints /parameter ratios were 2639/0/161, goodness-of-fit on F2 = 0.934, final R indices [I > 2sigma(I)] were R1 = 0.0299, wR2 = 0.0545 and R indices (all data) R1 = 0.0399, wR2 = 0.0568.
The largest difference peak and hole were 0.402 and −0.259 e ?−3. For II in the final refinement cycle the data/restraints/parameter ratios were 3372/1/221, goodness-of-fit on F2 = 0.950, final R indices [I > 2sigma(I)] were R1 = 0.0407, wR2 = 0.1048 and R indices (all data) R1 = 0.0450, wR2 = 0.1088.
The absolute structure parameter = 0.19(9) and largest difference peak and hole 0.934 and −0.301 e ?−3. Details of the geometry of the five molecules (two for I and three for II) and the crystal structures are fully discussed. Corresponding features of the molecular geometry are highly consistent and
firmly establish the geometry of the rhodanine ring.
Index Abstract Low temperature X-ray structures of (I) 3-aminorhodanine [3-amino-2-thio-4-oxothiazolidine] and (II) 3-methylrhodanine3-methyl-2-thio-4-oxothiazolidine are presented. Crystals of I are monoclinic and occupy space group P21/n with eight molecules (2 per asymmetric unit cell) and (II) is orthorhombic in space group Iba2 with 24 molecules (3 per asymmetric unit). This study has provided five highly consistent
copies of the rhodanine ring at high resolution thus enabling its geometry to be established with confidence.
The two independent molecules in the asymmetric unit of 3-aminorhodanine (left) and the three independent molecules in the
asymmetric unit of 3-methylrhodanine (right) showing space filling and van der Waals contacts (drawn with MERCURY [Bruno et al.
Acta Cryst B58:389, 2002]). 相似文献
18.
Abstract The title compound bis(3-chlorophenyl)-[5-methyl-1-(4-methylphenyl)-1,2,3-triazol-4-yl]-methanol 8 has been synthesized and established by H NMR, IR and MS spectra and X-ray diffraction crystallography. Compound 8, C23H29Cl2N3O, Mr = 424.31, crystallizes in the monoclinic space group P21/c with unit cell parameters a = 14.5402(6) ?, b = 12.5888(5) ?, c = 11.6510(5) ?, α = 90o, β = 100.183o(2), γ = 90o, V = 2099.05(15) ?3, Dx = 1.343 mg m−3 and Z = 4. The final R was 0.0514. The molecular conformation and packing is stabilized by interactions of intermolecular
O1–H1···N3′.
Index Abstract The structure of bis(3-chlorophenyl)-[5-methyl-1-(4-methylphenyl)-1,2,3-triazol-4-yl]-methanol by the reaction of compound
4 and Grignard regent is studied.
相似文献
19.
Ayesha Jacobs Serwalo M. Makgosi Luigi R. Nassimbeni Jana H. Taljaard 《Journal of chemical crystallography》2009,39(3):163-168
Abstract The inclusion compounds of 14-hydroxy-14-toluenyldibenzo[a:j]xanthene (H) with the guests acetone (H·ACE), pyridine (H·PYR) and N,N-dimethylformamide (H·DMF) were all successfully solved in the triclinic spacegroup P-1 with unit cell dimensions for H·ACE: a = 9.415(2) ?, b = 9.730(2) ?, c = 12.994(3) ?, α = 82.65(3), β = 76.69(3), γ = 88.67(3), Z = 2; for H·PYR: a = 9.482(2) ?, b = 10.169(2) ?, c = 13.089(3) ?, α = 106.59(3), β = 95.91(3), γ = 90.35(3), Z = 2 and for H·DMF: a = 9.537(19) ?, b = 10.055(2) ?, c = 13.129(3) ?, α = 79.18(3), β = 74.42(3), γ = 86.46(3), Z = 2. The thermal stabilities
for all compounds were investigated and in particular the kinetics of desolvation for the DMF compound was determined using
both isothermal and non-isothermal methods.
Index Abstract The host compound 14-hydroxy-14-toluenyldibenzo[a:j]xanthene forms inclusion compounds with the guests acetone, pyridine and
N,N-dimethylformamide. The crystal structures were determined and their thermal stabilities investigated. The kinetics of
desolvation for the DMF compound was determined using both isothermal and non-isothermal methods.
相似文献
20.
Junqing Chen Min Sun Jin Cai Meng Cao Wen Zhou Min Ji 《Journal of chemical crystallography》2011,41(4):519-522