共查询到20条相似文献,搜索用时 125 毫秒
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1前言 关于利用离子色谱分离技术测定一价和二价阳离子的工作,国内外已有报道。然而,由于二价阳离子对离子交换树脂的亲合力明显强于一价阳离子,使用单一组分淋洗液难于同时获得一价和二价阳离子的较好分离。国外有人采用DAP(2,3-二氨基丙酸)/HCI淋洗体系,配合其它分析技术,成功地同时分离了一价和二价阳离子。但其淋洗体系中使用的DAP试剂价格十分昂贵,难于在我国推广。本文提出用L-组氨酸/盐酸为淋洗的新淋洗体系用于一价和二价阳离子的分离。方法试用于多种样品的分析,得到满意的结果。 2实验部分 相似文献
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亲水单分散聚合物基质阳离子色谱柱的制备及其应用 总被引:2,自引:0,他引:2
以自制5.0 μm单分散大孔亲水交联聚甲基丙烯酸环氧丙酯微球为基质,合成一种新型弱酸性阳离子色谱填料.选用甲烷磺酸作淋洗液,在流速为1.0 mL/min时,对6种无机阳离子(Li+, Na+, NH+4, K+, Mg2+, Ca2+)和有机胺进行了良好分离.考察了淋洗液种类、浓度以及流速对6种无机阳离子分离的影响,选择了合适的色谱分离条件.测得6种离子在一定浓度范围内具有良好的线性关系和低的检出限.将其用于决明茶中阳离子的分析,4种离子在20 min内完全分离,各离子标准加入回收率在96%~107%之间.此色谱柱的分离效果与Dionex IonPacCS12A商品柱接近,但分析时间缩短了44 min. 相似文献
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离子色谱作为离子性物质(特别是无机阴离子)的最佳分离分析方法,一直受到分析工作者的关注[1].在离子色谱中,固定相是关键之一[2].当前广泛使用的离子色谱固定相主要有两类:一类是聚合物基质,如Dionex公司推广的薄壳型阴离子树脂填料,动力学性能十分出色].这类填料不仅用于无机正负离子,而且由于其对生物活性分子的相容性,也用于蛋白质等生物样品,它们的pH值适用范围宽,但不耐有机溶剂,刚性较差,高压下会变形,影响溶质传递速率.第二类是聚合物-载体复合基质,最常见的是在硅胶微粒表面键合上各种离子交换基团,如聚苯乙烯涂敷硅胶离子交换剂用于蛋白质、核苷酸的分离[4],国内杨瑞琴也报道了用聚马来酸包覆硅胶分离一价阳离子[5]. 相似文献
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Kazutoku Ohta Kazuhiko Tanaka Brett Paull Paul R. Haddad 《Journal of chromatography. A》1997,770(1-2):219-227
An unmodified silica gel (Develosil 30-5) column (150×4.6 mm I.D.) has been applied to the ion chromatographic separation of alkali, alkaline earth and transition metal cations. The retention behavior of the above cations on the bare substrate was investigated using a number of weak inorganic and organic acid eluents. During this investigation, several separations were achieved and the most suitable eluent conditions were identified. It was concluded that: (a) 1.5 mM HNO3-0.5mM pyridine-2,6-dicar☐ylic acid eluent was the most effective for the simultaneous separation of common alkali and alkaline earth metal cations, (b) 1.5 mM oxalic acid eluent resulted in the best separation of alkali, alkaline earth, and transition metal cations, (c) 0.5 mM CuSO4 eluent could be used for the separation of alkali metal cations alone and (d) 0.5 mM ethylenediamine-oxalic acid eluent at pH 5.5 resulted in themost efficient separation of both alkaline earth and transition metal cations. 相似文献
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Gold electrodes were chemically modified with thioctic acid monolayer designed to mimic biological ion-channel membranes. The technique was then used in the determination of alkali, alkaline earth, thallium(I), and lanthanum metal cations as analytes. Cyclic voltammograms (CV) of [Fe(CN)6]3− an electroactive marker, were measured in the presence of the various types of analyte cations. In the absence of the analyte cation, electrostatic repulsion between the marker anions and the carboxylate groups of the receptor monolayer hindered the approach of the marker anion to the electrode surface and hence hindered its reduction. The modified electrodes responded well to the metal cations except the alkali metal cations. The sensors could detect the trivalent cation La3+ at concentrations as low as 10−8 M. The response of the sensor to the metal cations increase in the order alkali metal3+ can be discriminated in the ratio 1:100. This makes it possible to determine the trivalent ion in a sample matrix containing monovalent and divalent cations. Thallium(I) ion showed marked deviation in its response as compared to monovalent ions of the alkali metals. The ion-channel sensor based on self-assembled monolayer of thioctic acid therefore offers a potential alternative technique for the selective determination of metal ions. 相似文献
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The use of poly(maleic acid–styrene)-encapsulated silica for the determination of monovalent and divalent cations is well accepted in ion chromatography. The separation of Mn2+, alkali and alkaline earth metal cations is obtained under the same chromatographic conditions. The influences of pH and the concentration of eluent on the retention of cations have been studied. The preparation conditions of packings were studied. The metal ions in the boiler water samples from a thermal power plant were quantitatively determined using this column. The results are in agreement with those determined by ICP and Volumetric analysis methods. 相似文献
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A facile strong cation-exchange stationary phase based on propylsulfonic acid functionalized silica was prepared through the oxidation in situ of 3-mercaptopropyl silica and characterized by elemental analysis and X-ray photoelectron spectroscopy. The phase was used to separate monovalent and divalent inorganic cations with strong acid as mobile phase. Simultaneous separation of alkali metals and alkaline earth metals was examined and the cations sodium, magnesium and calcium in tap water were determined. 相似文献
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Novel monoazacryptand-type fluorescent chemosensors, (derived from an 18-crown-6) and (derived from a 15-crown-5) both with a pyrene ring as their photoresponsive moiety, were synthesized. Their fluorescence properties for alkali metal and alkaline earth metal cations in water were then examined. The detection of metal cations was accomplished by a change in the fluorescence intensity of the host compounds, based on a photoinduced electron transfer (PET) mechanism. In aqueous solution, showed little fluorescence upon the addition of Ba2+ because of the very weak complexation with Ba2+, but the presence of micelles of polyoxyethylene(10) isooctylphenyl ether (Triton X-100) enabled to show highly sensitive and selective Ba2+ detection among alkali metal and alkaline earth metal cations. With respect to the selective fluorescent detection of important metal cations (Na+, K+, Mg2+, Ca2+) relevant to living organisms, was found to detect K+ with high selectivity in aqueous micellar solutions of polyoxyethylene(20) sorbitan monostearate (Tween-60). The selectivity for metal cations was mainly dependent on the goodness of fit of the host cavity and the metal cation size. In the presence of anionic surfactants, detected alkaline earth metal cations more effectively than alkali metal cations. 相似文献
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Dishon M Zohar O Sivan U 《Langmuir : the ACS journal of surfaces and colloids》2011,27(21):12977-12984
Application of two complementary AFM measurements, force vs separation and adhesion force, reveals the combined effects of cation size and charge (valency) on the interaction between silica surfaces in three 1:1, three 2:1, and three 3:1 metal chloride aqueous solutions of different concentrations. The interaction between the silica surfaces in 1:1 and 2:1 salt solutions is fully accounted for by ion-independent van der Waals (vdW) attraction and electric double-layer repulsion modified by cation specific adsorption to the silica surfaces. The deduced ranking of mono- and divalent cation adsorption capacity (adsorbability) to silica, Mg(2+) < Ca(2+) < Na(+) < Sr(2+) < K(+) < Cs(+), follows cation bare size as well as cation solvation energy but does not correlate with hydrated ionic radius or with volume or surface ionic charge density. In the presence of 3:1 salts, the coarse phenomenology of the force between the silica surfaces as a function of salt concentration resembles that in 1:1 and 2:1 electrolytes. Nevertheless, two fundamental differences should be noticed. First, the attraction between the silica surfaces is too large to be attributed solely to vdW force, hence implying an additional attraction mechanism or gross modification of the conventional vdW attraction. Second, neutralization of the silica surfaces occurs at trivalent cation concentrations that are 3 orders of magnitude smaller than those characterizing surface neutralization by mono- and divalent cations. Consequently, when trivalent cations are added to our cation adsorbability series the correlation with bare ion size breaks down abruptly. The strong adsorbability of trivalent cations to silica contrasts straightforward expectations based on ranking of the cationic solvation energies, thus suggesting a different adsorption mechanism which is inoperative or weak for mono- and divalent cations. 相似文献
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Xuefang Liu Chen Yang Feifang Zhang Huiliang Geng Bingcheng Yang 《Journal of separation science》2020,43(8):1474-1478
A novel weak cation exchanger is described by encapsulating silica with a (or multiple) layer(s) of maleic anhydride–modified polyvinyl alcohol coating(s). The preparation method is facile and fast, which is simply performed by dipping silica particles into maleic anhydride–modified polyvinyl alcohol solution as‐synthesized, then filtering and curing thermally, and finally generating a thin coating onto silica particles. Multiple layers of maleic anhydride–modified polyvinyl alcohol coatings can be generated by repeating above steps, offering an easy way to manipulate the capacity. The obtained weak cation exchanger demonstrated high separation efficiency and good selectivity toward common inorganic cations, for example, high plate count of 81 000 per meter was obtained for NH4+. Simultaneous separation of alkali and alkaline earth metals could be achieved within 14 min under isocratic conditions. 相似文献
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Summary The allyl bonded phase is used as an intermediate in the synthesis of a weak cation exchange material. The double bond is first converted to an aldehyde by an ozonation reaction and then subsequent oxidation to the carboxylate group is accomplished with dichromate. Diffuse reflectance Fourier transform infrared spectroscopy (DRIFT) is used to monitor the conversion process. The presence of the aldehyde functional group is confirmed by reaction with 2,4-dinitrophenylhydrazine. ESCA spectra reveal no residual chromium on the silica surface. The product is tested chromatographically by the retention of alkylarylketones, the ion-exchange behavior of both monovalent and divalent cations, the retention of nucleosides and bases, and the separation of a mixture of hemoglobins. 相似文献
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Mostafa Mimouni Sébastien Perrier Yvon Pointud Jean Juillard 《Journal of solution chemistry》1993,22(9):769-785
Interactions of ionophore monensin with heavy metal monovalent cations, Ag+, Tl+, Hg
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2+
, were studied in methanol and in various biphasic waterorganic solvent systems to supplement previous data on alkali-metal cations. The species formed were identified and the corresponding formation constants determined. Enthalpies of formation were also obtained in methanol for Ag+ and Tl+ from calorimetric measurements. The results for monovalent cations in general are discussed in terms of cation size and solvation, and structure of the ionophore anion. 相似文献
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Flood C Cosgrove T Espidel Y Howell I Revell P 《Langmuir : the ACS journal of surfaces and colloids》2007,23(11):6191-6197
Sodium polyacrylate is well known for its application as a scale inhibitor in common household products, and the effects of both monovalent and divalent metal cations on its structure have been covered by a range of previous publications. In the present article, we extend this work by using solvent relaxation NMR to look at the adsorption of the polyelectrolyte onto both positively and negatively charged silica and how this is altered by calcium chloride. In the anionic case, we found that polyacrylate adsorption was predictably very weak, and interestingly, perhaps counterintuitively, it was further reduced by calcium ions. This is probably linked to NaPA-Ca2+ binding, which changes the conformation and charge of the polyelectrolyte. In contrast, NaPA adsorbs very strongly on cationic silica, to the point that precipitation often occurs, particularly on addition of salt. 相似文献