强迫耗散系统的有序结构和系统的发展(Ⅰ)，最小熵产生原理和有序结构

一个系统的发展总是由不可逆热力过程和非线性动力过程所驱动.将大气动力学方程组同考虑了动能变化的Gibbs关系结合起来构建的熵平衡方程，才能更好地描述大气系统的不可逆热力过程和非线性动力过程.至今非平衡态热力学仅利用Onsager线性唯象关系证明了最小熵产生原理.利用新建立的熵平衡方程和大气动力学方程的性质证明，最小熵产生原理在热力学线性区和非线性区都是普遍成立的.且当热量输送平衡、水汽输送平衡和动量输送平衡时，系统达到不可逆过程最弱的最小熵产生热力学状态.当系统又是动力平衡且无平流时，这种最小熵产生态就是 关键词： 非线性热力学 熵产生 最小熵产生原理 有序结构     

Quantum Macrostatistical Picture of Nonequilibrium Steady States

We apply our quantum macrostatistical treatment of irreversible processes to prove that, in nonequilibrium steady states, (a) the hydrodynamical observables execute a generalised Onsager–Machlup process and (b) the spatial correlations of these observables are generically of long range. The key assumptions behind these results are a nonequilibrium version of Onsager regression hypothesis, together with certain hypotheses of chaoticity and local equilibrium for hydrodynamical fluctuations.     

On the calculation of memory functions for nonlinear irreversible processes

A linear inhomogeneous Volterra integral equation for the memory functions of the nonlinear theory of irreversible processes is derived. No projection operator is involved. Recursion relations for the solution of the integral equation are given. If the kernels are expanded about equilibrium, the exact linear and nonlinear Onsager coefficients are obtained.     

Local information‐distance thermodynamics of molecular fragments

The Fisher information contained in a probability distribution is summarized. The corresponding measures of the information distance, relative to the reference probability density, are introduced and discussed. These concepts are designed as analogues of the Kullback‐Leibler directed divergence and Kullback's divergence. For these alternative measures of the missing information the equilibrium (“stockholder”) scheme of Hirshfeld, of a division of the molecular electron density into the subsystem components, is derived from the minimum principle of the local or global entropy deficiency relative to the free‐subsystem (“promolecule”) reference. The local information distance densities are used to describe instantaneous electron distributions in molecular subsystems within a thermodynamic‐like approach to the density fluctuations and irreversible processes. The key concepts of such a local irreversible “thermodynamics” are introduced. They include the corresponding local affinities (forces) and the conjugate fluxes (responses), which together determine the local entropy deficiency source. These quantities depend on the adopted measure of the information distance and selected state‐parameters. For each such representation the relevant Onsager‐type reciprocity relations can be derived, which reflect the symmetries between the linear effects of affinities on fluxes.     

Nonlinear transport in the Boltzmann limit

Formal expressions for the irreversible fluxes of a simple fluid are obtained as functionals of the thermodynamic forces and local equilibrium time correlation functions. The Boltzmann limit of the correlation functions is shown to yield expressions for the irreversible fluxes equivalent to those obtained from the nonlinear Boltzmann kinetic equation. Specifically, for states near equilibrium, the fluxes may be formally expanded in powers of the thermodynamic gradients and the associated transport coefficients identified as integrals of time correlation functions. It is proved explicitly through nonlinear Burnett order that the time correlation function expressions for these transport coefficients agree with those of the Chapman-Enskog expansion of the nonlinear Boltzmann equation. For states far from equilibrium the local equilibrium time correlation functions are determined in the Boltzmann limit and a similar equivalence to the Boltzmann equation solution is established. Other formal representations of the fluxes are indicated; in particular, a projection operator form and its Boltzmann limit are discussed. As an example, the nonequilibrium correlation functions for steady shear flow are calculated exactly in the Boltzmann limit for Maxwell molecules.Research supported in part by NSF grant PHY 76-21453.     

Irreversible thermodynamics of fluids

Irreversible thermodynamics of fluids is formulated based on a set of postulates. The theory thus constructed generalizes thermostatics and linear irreversible thermodynamics into the realm of nonlinear irreversible processes. In this theory the extended Gibbs relation and the entropy balance equation appear as a pair of mutually consistent equations under the postulates made. An equivalent theory is also formulated by replacing one of the postulates with another that is basically a variational principle. The variational principle yields the evolution equations for fluxes as the Euler equations that extremize the variational functional postulated. The local form of the extremized variational functional is the entropy balance equation for the irreversible processes in the system. Some further consequences of the theory are also considered. For example, nonequilibrium specific heats are shown to be at least quadratic functions of fluxes and reduce to the equilibrium specific heats in the limit of vanishing fluxes. In order to illustrate an example of possible applications, we have considered nonlinear transport processes in fluids. The connections of the present theory with other theories are discussed.     

Variational properties of irreversible processes

The thermodynamic integral principle, equivalent to the Onsager theory of irreversible thermodynamics, is analyzed in detail for a purely dissipative system. Different reformulations of the principle are also given together with the derivation of the corresponding Euler—Lagrange equations. One of them, the dual field formulation, is of special interest: It is an exact variational principle in terms of the intensive parameters and their dual fields introduced in place of the thermodynamic current densities. Finally, the possibility of deducing variational statements in terms of volume and surface dissipation functionals is discussed.     

Theory of quantum fluctuations and the Onsager relations

A microscopic model is constructed within the theory of normal fluctuations for quantum systems, yielding an irreversible dynamics satisfying the Onsager relations. The property of return to equilibrium and the principle of minimal entropy production are proved.     

A Variational Principle for Thermodynamical Waves

When the dissipative processes are dominant in the system, the assumption of local equilibrium holds good and the space time evolution of irreversible system can be described by the variational principle of GYARMATI. However when imposed changes in the state variables are fast, the system can not be in a state of local equilibrium and to define the nonequilibrium state of the system it is necessary to extend the formalism of classical irreversible thermodynamics. The wave approach of Onsagerian thermodynamics is one such pursuit and is a direct generalization of the original Onsager-Machlup proposition. An important consequence of this theory is that it leads to transport equations with finite propagation velocities, which are referred to as thermodynamical waves. In this note we endeavour to write the appropriate form of GYARMATI'S variational principle for thermodynamical waves.     

A field analysis of nonlinear irreversible thermodynamic processes

The generalized thermodynamic potential analysis of nonlinear irreversible processes precludes the analysis of rotational processes. The nonexistence of scalar potential functions necessitates a thermodynamic analysis of the system forces. A field analysis in the phase space of the generalized displacements and velocities treats the force components as tensors of second order that tend to deform and rotate the irreversible process, which is viewed as an elastic material. The analysis of chemical oscillatory processes involves the introduction of the thermodynamic vector potential, which is subsequently used in the formulation of a variational principle and to define an energy flux vector. The direction of energy flow elucidates the mechanism by which steady motion is maintained and it is a characteristic property of open systems. Field analyses of systems that are described by half and single degrees of freedom are contrasted.     

A new approach to irreversibility from maximum entropy estimation

This paper deals with the study of some irreversible processes like slow heating of a thermodynamic system or of inhomogeneity, i.e. spatially local equilibrium in it, based on the principle of maximum entropy estimation, in a stochastic model.     

Dynamics of a D’Alembert wave and a soliton molecule for an extended BLMP equation

The D’Alembert solution of the wave motion equation is an important basic formula in linear partial differential theory.The study of the D’Alembert wave is worthy of deep consideration in nonlinear partial differential systems.In this paper,we construct a(2+1)-dimensional extended Boiti-Leon-Manna-Pempinelli(eBLMP)equation which fails to pass the Painleve property.The D’Alembert-type wave of the eBLMP equation is still obtained by introducing one arbitrary function of the traveling-wave variable.The multi-solitary wave which should satisfy the velocity resonance condition is obtained by solving the Hirota bilinear form of the eBLMP equation.The dynamics of the three-soliton molecule,the three-kink soliton molecule,the soliton molecule bound by an asymmetry soliton and a one-soliton,and the interaction between the half periodic wave and a kink soliton molecule from the eBLMP equation are investigated by selecting appropriate parameters.     

Thermodynamics of nonlinear,interacting irreversible processes. II

The scope of the thermodynamic theory of nonlinear irreversible processes is widened to include the nonlinear stability analysis of system motion. The emphasis is shifted from the analysis of instantaneous energy flows to that of the average work performed by periodic nonlinear processes. The principle of virtual work separates dissipative and conservative forces. The vanishing of the work of conservative forces determines the natural period of oscillation. Stability is then determined by the variations of the dissipative forces with amplitude of oscillation. If the work is a minimum, under certain conditions, the motion is stable. Reduction to linear analysis shows the coincidence with the impedance analysis of electrical circuit theory. The theory is applied to the analysis of temporal interactions of nonlinear irreversible processes in the particular cases of synchronization and hysteresis. Characteristic nonequilibrium phenomena of directional energy transfers, self-excitation, system passivity, wave modulation, and beat phenomena are observed. Possible relationships with biological processes are discussed.     

Thermodynamik der Vorgänge in einfachen fluiden Medien und die Charakterisierung der Thermodynamik irreversibler Prozesse

Thermodynamics of processes in continuous matter has found several treatments: (1) classical thermodynamics of irreversible processes, (2) the nonlinear field theory of mechanics with the incorporation of thermodynamic aspects, (3) the new entropyfree thermodynamics of processes. An important feature of the last theory is the fundamental inequality. It provides a basis for the formulation of constitutive equations, which are discussed for simple thermodynamic fluid materials. Classical thermodynamics of irreversible processes results as a well defined special case with a modification that has been overlooked previously. It is shown by an example that this modification which differentiates between a dynamic and a thermostatic temperature is necessary in order to make classical thermodynamics of irreversible processes consistent.     

On the relationship between fluctuating irreversible thermodynamics and “extended” irreversible thermodynamics

The relationship between fluctuating irreversible thermodynamics and theories of irreversible processes which include the thermodynamic fluxes as independent variables is explored. It is shown that the usual fluctuating linear theory of irreversible thermodynamics is a contraction of the extended theory. This contraction contains non-Markovian effects dependent upon the relaxation times associated with the thermodynamic fluxes. In the limit that these relaxation times are small, the extended theory is shown to be equivalent to the usual fluctuating thermodynamic theory. A critique of the extended theories is given from the point of view of the mechanistic statistical theory of irreversible processes.     

Quantum thermodynamics of nonequilibrium. Onsager reciprocity and dispersion-dissipation relations

A generalized Onsager reciprocity theorem emerges as an exact consequence of the structure of the nonlinear equation of motion of quantum thermodynamics and is valid for all the dissipative nonequilibrium states, close and far from stable thermodynamic equilibrium, of an isolated system composed of a single constituent of matter with a finite-dimensional Hilbert space. In addition, a dispersion-dissipation theorem results in a precise relation between the generalized dissipative conductivity that describes the mutual interrelation between dissipative rates of a pair of observables and the codispersions of the same observables and the generators of the motion. These results are presented together with a review of quantum thermodynamic postulates and general results.