Evidence of Hg-chain formation in Hg x TiS2: a199mHg-TDPAC study

We determined the^199mHg nuclear quadrupole interaction in the misfit or superstoichiometric compound Hg _x TiS₂ by time differential perturbed angular correlation. A unique Hg-site withv _Q =511(1) MHz and =0.410(4) was observed, irrespective of the Hg-uptake (2/3x4/3). We propose a model of Hg-Hg zig-zag chains which accounts for these observations as well as for the X-ray diffraction data.     

Intrinsic point defects in niobium: Trapping at100Pd and111In impurities observed by PAC

Radiation-induced lattice defects in high-purity niobium have been investigated in the temperature range of 30K to 540 K by means of - perturbed angular correlation (PAC) measurements using the radioactive probes¹⁰⁰Pd/¹⁰⁰Rh and¹¹¹In/¹¹¹Cd. Both probes were produced within the niobium samples by means of heavy-ion nuclear reactions. At the Pd impurities trapping of defects occurred during heavy-ion irradiation at about 30 K in two defined configurations: defect 1(Pd) withv _Q1=e ² qQ/h=42(±2) MHz, ₁=0 and defect 2 (Pd) withv _Q2=(±2) MHz, ₂=1. Two defects were observed at the In impurities in annealing stage III (around 250 K) after heavy-ion as well as electron irradiations: defect 1(In) withv _Q1=87(±1) MHz, ₁=0 and defect 2(In) withv _Q2=105(±2) MHz, ₂=0.65(±0.02). A third defect (defect 3(In):v _Q3=177(±2) MHz, ₃0.2) appeared above 260 K after heavy-ion irradiation only. The data are interpreted in terms of interstitial trapping at the Pd impurities and vacancy trapping at the In impurities. Information on the microscopic structure of defect 1(In) and 2(In) is obtained from a PAC-single-crystal experiment. For defect 1(In) axial 111-symmetry is found, which leads us to identify this defect with a monovacancy as nearest neighbor with respect to the In probe. Defect 2(In) is the trapped divacancy for which an orientation is found that is consistent with both vacancies being nearest neighbor to the probe but second nearest neighbors to each other.     

TDPAC studies of internal AgIn alloy oxidation

The internal oxidation of dilute AgIn alloys in open air versus In concentration and oxidation temperature was investigated by the TDPAC technique. The¹¹¹In interaction described by the broad quadrupole frequencies distribution aroundv _Q = 115 MHz and =0.5–0.7 was observed and interpreted as due to nonstoichiometric In–O_X cluster formation. For higher temperatures and more concentrated alloys additionally quasiunique frequencyv _Q 157 MHz with 0.28 was evidenced and ascribed to¹¹¹In interaction inside In₂O₃ precipitates. The internal oxidation under reduced oxygen pressures was studied and the thermal stability of the complex formed was tested. The effect of surface preparation on internal oxidation was observed.     

Integrability conditions for Killing spinors

The conditions for the existence of solutions ofD _µ=±c_µ are discussed. In general, it is not sufficient to consider only the first integrability condition [D _µ,D _v ]=–2c ²_{µv}; in particular, the second integrability condition is needed to explain why, in certain cases, only for one choice of sign does a solution exist. The Killing spinor-tensors, as defined by Walker and Penrose, are shown to be the spinorial equivalent of conformal Killing tensors. Their relationship to the Killing spinors and spinor-vectors used in supergravity, is given.On leave from the Institute for Theoretical Physics of the State University of New York at Stony BrookWork supported in part by the U.S. Department of Energy under Contract No. DEAC-03-81-ER 40050 and Weingart Fellowship     

Intramolecular energy transfer in compounds with two 1-pyrenoate groups separated by methylene spacers

Steady-state fluorescence anisotropy (r) and fluorescence lifetime () measurements have been used to study the efficiency of nonradiative singlet energy transfer as a function of alkane size in 1-pyrenecarboxylic acid alkanediyl esters (as a function ofm in Py-COO-(CH₂) _m -OOC-Py, where Py denotes pyrene substituted in the 1-position, andm=2–6). Experiments were performed in media of different viscosity, , obtained by changing the temperature (from –20 to 40°C) of dilute solutions in ethylene glycol and by examination of the compounds in a solid matrix of poly(methyl methacrylate) (PMMA) at ambient temperature. The Py-COO-(CH₂)_m-OOC-Py exhibit intramolecular excimer emission in ethylene glycol at these temperatures, but the intensity of this emission is much lower than when these compounds are placed in common solvents of lower . The values of indicate that excitation hopping or intramolecular energy transfer takes place between the chromophores attached to the ends of the alkane bridges. Values ofr obtained by the extrapolationsT/0 orT/0 in ethylene glycol, as well as the values obtained in the rigid matrix of PMMA, show very little dependence onm. A theoretical conformational analysis, using the rotational isomeric state (RIS) model, was also performed. The combination of the experimental results forr in the media of high with the theoretical (RIS) analysis produces an estimated value of 21 ±2 Å for the Förster radius in Py-COO-(CH₂)_m-OOC-Py.     

On the directional dependence of composite field operators

The Wilson expansion of the field operator productA ₁(x ₁)A ₂(x ₂) may be used to define composite operators which are local with respect to 1/2(x ₁+x ₂) and depend in addition on a vector proportional to the distancex ₁–x ₂. It is proved that the composite operators are polynomials in , for fixed ² 0, and that their dependence on ² only involves powers of ² and lg².This work was supported in part by the National Science Foundation Grant No. GP-25609.     

Kinetics of small perturbations in an isotropic world

Long-wavelength gravitational perturbations are studied in an isotropic expanding universe filled with an ultrarelativistic gas. A kinetic study in the collisionless approximation shows that scalar and vector perturbations which appear at a time ₀ 1/n, where N is the wave vector and is the time coordinate x⁴, grow if the perturbation of the macroscopic momentum density of the gas at time ₀ is nonvanishing. The growth continues until the time ₁=27₀, at which the perturbation of the macroscopic momentum density of the gas vanishes. A solution is also derived for tensor perturbations in the limit n 1.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 37–45, April, 1978.     

The influence of a surface on Ising and conjugate model spin correlations atT=T c

We calculate rigorously the two-point correlation function in the 2-d Ising model on a quasi-cylindrical lattice at the critical temperatureT _c .The scaling predictions for the surface critical exponents = 5/8, = 1 are confirmed and the change from surface to bulk behavior is studied. By a correspondence relation the results are mapped to the conjugate model, a subcase of the 8-vertex model. We find in this model = 5/4, = 2.     

The Transit Time Effect of a Modulated Electron Beam

Energy change of an electron beam is studied numerically when it transits a rf field gap of width L. For a premodulated beam, the transit time L/0> for maximum energy extraction is shortened to 0.475 T (T=2/, 0> is the average velocity of the electrons) when the modulation frequency _m is matched to the rf field frequency . Enhancement of the extraction efficiency _o is dependent on the modulation coefficient h₁ and h₂. For a uniform beam with V=500 kV, _o is less than 2%. _o reaches 11% for a prebunched beam with h₁=0.7 and h₂=0.1 and will surpass 20% for an ideally modulated beam.     

The C1 Σ +-B1-Σ + amplified spontaneous emission in CO

The first observation of the amplified spontaneous emission (ASE) from the RydbergC ^{1 +}( = 0) state of CO is reported. When theC ^{1 +}( = 0) state was populated through the two-photon excitation, infrared radiation near 2.0 m was ejected in forward as well as backward directions along the laser propagation. The assignment as theC ^{1 +}( = 0) B ^{1 +}( = 0) transition was confirmed. Several characteristics of ASE from theC ^{1 +}( = 0) state are presented.This work was supported by the Morino Foundation, a Grant-in-Aid (No. 07640697) and that on Priority-Area-Research Photoreaction Dynamics (No. 07228268) from the Ministry of Education, Science, Sports and Culture, Japan.     

Further exact solutions of the eight-vertex SOS model and generalizations of the Rogers-Ramanujan identities

The restricted eight-vertex solid-on-solid (SOS) model is an exactly solvable class of two-dimensional lattice models. To each sitei of the lattice there is associated an integer heightl _i restricted to the range 1l _i r–1. The Boltzmann weights of the model are expressed in terms of elliptic functions of period 2K, and involve a parameter. In an earlier paper we considered the case=K/r. Here we generalize those considerations to the case=sK/r, s an integer relatively prime tor. We are again led to generalizations of the Rogers-Ramanujan identities.     

Feynman integral and complex classical trajectories

Let _t be an analytic solution of the Schrödinger equation with the initial condition . Let _t be the solution of the Schrödinger equation with the initial condition =, where is an analytic function. When 0, then _t (x) _t (x)¹ ( _t (x)), where _t (x) trajectory starting from x. We relate this result to Feynman's sum over trajectories and complex stochastic differential equations.     

Collision term of the Fokker Planck equation in strong external magnetic field

The collision term of the Fokker-Planck-type magnetized kinetic equation is approximated for an electron-ion plasma in a strong external uniform magnetic field. The collision term is evaluated explicitly in the case of unmagnetized Maxwellian ions for 1<= _e / _pi 2<. It is shown that the dominant effects are determined by the parameter ln (/) which replaces the Coulomb logarithm ln in the components of the diffusion coeficientD.     

The η N interaction cross section near the S11N*(1535) resonance

Calculations are presented for the integral cross-sections ofN N, N N incorporating the one-particle intermediate state, theS₁₁N * resonance; cross-sections are given for kinetic energies of the meson from 0 to 200 MeV for various values of the width of the resonance. The calculated cross-sections agree with experiment for r 160 MeV.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, Vol. 16, No. 7, pp. 119–122, July, 1973.We are indebted to our colleagueat the Institute G. N. Radutskom forvaluable advice and discussion on this paper.     

KL,S → l+l− decays in the quark model of superconductivity type

The probabilities of K_L,S l⁺l^– decays are calculated by considering only the dominant two-lepton channel K_L,S ^{* *} l⁺l^–. The transitions K⁰ X, where X=⁰,, or (700) dominating in the K_L,S ^{* *}decay amplitudes, are described by the effective weak Lagrangian. The matrix elements of four-quark operators are calculated within the framework of the quark model of superconductivity type. It is shown that the leading contribution to matrix elements of K⁰ X transitions comes from the penguin operator matrix elements.     

The role of weak resonances in ac-driven Brownian motion and rate processes

In recent paper a theory of the effect of ac drive on the distribution function and escape rate of a multidimensional underdamped nonlinear oscillator subject to thermal damping and noise was suggested. The approach was based on describing the dynamics in terms of isolated nonlinear resonances and supposing that the noise intensity is asymptotically small,0. In the present work, the case of finite is considered, when weak resonances cannot be described asymptotically. It is shown that forp _r/1(p _r, is the resonance width) the asymptotic results are valid. Forp _r/1, a semiphenomenological theory is developed.     

Spectral characteristics for a fiber grating external cavity laser

A numerical investigation has been carried out on the influence of the antireflection (AR) coating of laser, the coupling efficiency of laser and fiber (), and the reflectivity of fiber grating (R _g) on the side-mode suppression ratio (SMSR) of the fiber grating external cavity laser (FGECL). The FGECL was fabricated by the assembly of the multimode Fabry–Perot (FP) laser chip and fiber grating. The results showed that the FGECL with a lower AR coating, higher and R _g exhibited a better SMSR. A comparison of the SMSR dependence on the and R _g showed that SMSR increased more rapidly with increasing than SMSR for R _g. These spectral characteristic studies of the SMSR dependence on the device parameters of the AR coating, , and R _g may provide useful device designs for the practical fabrication of a FGECL for use in dense wavelength division multiplexing (DWDM) applications.     

Eight-vertex SOS model and generalized Rogers-Ramanujan-type identities

The eight-vertex model is equivalent to a solid-on-solid (SOS) model, in which an integer heightl _i is associated with each sitei of the square lattice. The Boltzmann weights of the model are expressed in terms of elliptic functions of period 2K, and involve a variable parameter . Here we begin by showing that the hard hexagon model is a special case of this eight-vertex SOS model, in which =K/5 and the heights are restricted to the range 1l _i4. We remark that the calculation of the sublattice densities of the hard hexagon model involves the Rogers-Ramanujan and related identities. We then go on to consider a more general eight-vertex SOS model, with =K/r (r an integer) and 1l _ir–1. We evaluate the local height probabilities (which are the analogs of the sublattice densities) of this model, and are automatically led to generalizations of the Rogers-Ramanujan and similar identities. The results are put into a form suitable for examining critical behavior, and exponents, , are obtained.Supported by the Guggenheim Foundation and in part by the National Science Foundation, grant MCS 8201733.     

Computer simulation of driven diffusive systems with exchanges

The field-driven Kawasaki model with a fractionp admixture of Glauber dynamics is studied by computer simulation:p=0 corresponds to the order-parameter-onserving driven diffusive system, whilep=1 is the equilibrium Ising model. Forp=0.1 our best estimates of critical exponents based on a system of size 4096×128 are0.22, ^RS0.45, andv v 1. These exponents differ from both the values predicted by a field-theoretic method forp=0 and those of the equilibrium Ising model. Anisotropic finite-size scaling analyses are carried out, both for subsystems of the large system and for fully periodic systems. The results of the latter, however, are inconsistent, probably due to the complexity of the size effects. This leaves open the possibility that we are in a crossover regime fromp=0 top0 and that our critical exponents are effective ones. Forp=0 our results are consistent with the predictionsv >v .     

The theory of melting in heteropolymers. I. Random chains

A method is developed for the calculation of the ground-state melting curves ( _o vs.T) for random, infinite heteropolymers. Here _o is the ground-state value of the fraction of melted links ( _o in the strong cooperativity approximation). It is shown that the differential melting curves (d /d T vs.T) can have a fine structure in the form of several peaks on the bell-shaped main curve. Positions, magnitudes, and widths of these peaks are estimated. The accidental fine structure of melting curves, which is caused by a finite length of the polymer, is briefly discussed.Work supported in part by NSF Material Research Laboratory at Case Western Reserve University.Part of this work was submitted to the faculty of the Graduate School at SUNY Buffalo in partial fulfillment of the requirements for the Ph.D. degree.