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Two novel tetradentate platinum (II) 3,6-substituted salophen complexes of Pt-2 and Pt-3 were synthesized and characterized, in which the substituted group is a donor (D) unit of 4,4′-di(tert-butyl)triphenylamine (ButTPA) for Pt-2 and a donor-acceptor (D-A) framework of ButTPA and benzothiadiazole (BT) for Pt-3. Their thermal, optophysical, electrochemical and electroluminescent properties were primarily investigated. It is found that the emission for this type of tetradentate platinum (II) complexes is tuned from deep red to near infrared by appending D-A framework under photo-excitation. As a result, Pt-3 presented a significant near infrared electroluminescence peaked at 703 nm in its doped polymer light-emitting devices (PLEDs). The maximum external quantum efficiency of 0.88% is observed in the Pt-3 doped PLEDs using a blend of poly(vinylcarbazole) and 1,3-bis(5-(4-(tert-butyl)phenyl)-1,3,4-oxadiazol-2-yl) benzene as the host matrix. Our work indicates that appending D-A framework into tetradentate Pt(II) salophen complex is a useful strategy to get high-performance near infrared emission for this type of tetradentate Pt (II) complexes. 相似文献
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Cathy K. W. Jim Anjun Qin Jacky W. Y. Lam Faisal Mahtab Yong Yu Ben Zhong Tang 《Advanced functional materials》2010,20(8):1319-1328
A new synthetic route to sulfur‐rich polymers has been developed. The alkyne polyhydrothiolations of 4,4′‐thiodibenzenethiol ( 1 ) and arylene dipropiolates ( 2 – 5 ) mediated by amines proceed at room temperature in a regioselective fashion, furnishing sole anti‐Markovnikov products of poly(vinylenesulfide)s (P 1 / 2 –P 1 / 5 ) with high molecular weights (Mw up to 32 300) and high stereoregularities (Z content up to 81.4%) in high yields (up to 98.2%). Polymers P 1 / 2 –P 1 / 4 are soluble in common organic solvents. They are optically transparent, allowing almost all visible and IR light to transmit through. Thanks to the high sulfur contents of the polymers, their films show high refractive indices (n = 1.73–1.70) in the wavelength region of 500–1700 nm as well as high Abbé numbers (νD' up to 539) and low optical dispersions (D' down to 0.002) at wavelengths important for telecommunications. Their refractivities can be further enhanced (n up to 2.06) by metal complexation and their films can be crosslinked by UV irradiation, which enables ready fabrication of fluorescent photopatterns. 相似文献