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量子相空间理论已用来研究物理学、化学等有关问题, 并为人们研究经典物理和量子物理的对应关系提供了一种有力工具. 在量子相空间中, 基于Wigner表象下的量子刘维尔方程, 建立分子纠缠轨线力学. 与经典分子力学方法不同, 分子纠缠轨线力学中的轨线不再是独立的, 而是“纠缠”在一起的, 这正是体系量子效应的体现. 这种半经典 的理论方法能给出体系的量子效应及具有启示意义的物理图像. 分子纠缠轨线力学被用来研究量子隧穿效应、分子光解反应动力学、自关联函数等. 本文综述了分子纠缠轨线力学最近的发展.
关键词:
纠缠轨线
量子相空间
半经典理论 相似文献
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The classical and quantum physics seem to divide nature into two domains macroscopic and microscopic. It is also certain that
they accurately predict experimental results in their respective regions. However, the reduction theory, namely, the general
derivation of classical results from the quantum mechanics is still a far cry. The outcome of some recent investigations suggests
that there possibly does not exist any universal method for obtaining classical results from quantum mechanics. In the present
work we intend to investigate the problem phenomenonwise and address specifically the phenomenon of scattering. We suggest
a general approach to obtain the classical limit formula from the phase shiftδ
l, in the limiting value of a suitable parameter on whichδ
l depends. The classical result has been derived for three different potential fields in which the phase shifts are exactly
known. Unlike the current wisdom that the classical limit can be reached only in the high energy regime it is found that the
classical limit parameter in addition to other factors depends on the details of the potential fields. In the last section
we have discussed the implications of the results obtained. 相似文献
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外尔于1918年引入的规范变换实际上是相位变换而非真正的尺度变换,但规范不变性、规范理论等概念都沿袭了下来。我们发现,针对由量子化条件[x, p]=iℏ而来的量子体系之本征值问题存在规范变换,或者说尺度变换,x → x/α,p → αp,该变换保体系的能量谱不变。量子谐振子、氢原子问题及一类多体问题的精确解析解证实了这一点。量子化条件 [x, p]=iℏ看来是个对量子力学很强的约束,不止于能量的量子化。这个规范变换提醒我们相空间的体积及其量子化才是物理的关键,这也是量子力学和统计物理在潜意识里一直沿用却未予关注的思路。有趣的是,从量子谐振子体系的相空间表述似乎不能导向这个结论。如同规范理论所断言的电磁学量在给定坐标系下的数值表征与标度无关,我们认为量子体系的物理量,如能量谱等,在给定坐标系下的数值表征亦应与标度无关。此尺度变换与德布罗意关系相恰。 相似文献
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Unitary representations of the Galilei group are studied in phase space, in order to describe classical and quantum systems. Conditions to write in general form the generator of time translation and Lagrangians in phase space are then established. In the classical case, Galilean invariance provides conditions for writing the Liouville operator and Lagrangian for non-linear systems. We analyze, as an example, a generalized kinetic equation where the collision term is local and non-linear. The quantum counter-part of such unitary representations are developed by using the Moyal (or star) product. Then a non-linear Schrödinger equation in phase space is derived and analyzed. In this case, an association with the Wigner formalism is established, which provides a physical interpretation for the formalism. 相似文献
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Recently Auberson, Mahoux, Roy and Singh have proved a long standing conjecture of Roy and Singh: In 2N-dimensional phase space, a maximally realistic quantum mechanics can have quantum probabilities of no more than N+1 complete commuting cets (CCS) of observables coexisting as marginals of one positive phase space density. Here I formulate
a stationary principle which gives a nonperturbative definition of a maximally classical as well as maximally realistic phase
space density. I show that the maximally classical trajectories are in fact exactly classical in the simple examples of coherent
states and bound states of an oscillator and Gaussian free particle states. In contrast, it is known that the de Broglie-Bohm
realistic theory gives highly nonclassical trajectories. 相似文献
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Gonzalo García de Polavieja 《Physics letters. A》1996,220(6):303-314
The causal theory for the coherent state representation of quantum mechanics is derived. The general conditions for the classical limit are given and it is shown that phase space classical mechanics can be obtained as a limit even for stationary states, in contrast to the de Broglie-Bohm quantum theory of motion. 相似文献
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Joseph Samuel 《Pramana》1997,48(5):959-967
We study the behaviour of the geometric phase under isometries of the ray space. This leads to a better understanding of a
theorem first proved by Wigner: isometries of the ray space can always be realised as projections of unitary or anti-unitary
transformations on the Hilbert space. We suggest that the construction involved in Wigner’s proof is best viewed as an use
of the Pancharatnam connection to ‘lift’ a ray space isometry to the Hilbert space. 相似文献
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We study the Klein-Gordon oscillators in non-commutative (NC) phase space.We find that the Klein-Gordon oscillators in NC space and NC phase-space have a similar behaviour to the dynamics of a particle in commutative space moving in a uniform magnetic field.By solving the Klein-Gordon equation in NC phase space,we obtain the energy levels of the Klein-Gordon oscillators,where the additional terms related to the space-space and momentum-momentum non-commutativity are given explicitly. 相似文献
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Klein-Gordon oscillators in noncommutative phase space 总被引:1,自引:0,他引:1
We study the Klein-Gordon oscillators in non-commutative (NC) phase space. We find that the Klein-Gordon oscillators in NC space and NC phase-space have a similar behaviour to the dynamics of a particle in commutative space moving in a uniform magnetic field. By solving the Klein-Gordon equation in NC phase space, we obtain the energy levels of the Klein-Gordon oscillators, where the additional terms related to the space-space and momentum-momentum non-commutativity are given explicitly. 相似文献
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We investigate a quantum physical system that can be naturally separated into fast and slow moving components. A modification of the conventional molecular Born-Oppenheimer approximation is considered by taking the intermolecular position vector to be a slowlyvarying quantum mechanical parameter. It is found that the fast motion (electronic degrees of freedom) induces a non-Abelian vector potential (Berry connection) into the dynamics of the slow system (nucleus), thereby modifying the commutation relations of the slow variables. 相似文献
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A Dirac picture perturbation theory is developed for the time evolution operator in classical dynamics in the spirit of the Schwinger–Feynman–Dyson perturbation expansion and detailed rules are derived for computations. Complexification formalisms are given for the time evolution operator suitable for phase space analyses, and then extended to a two-dimensional setting for a study of the geometrical Berry phase as an example. Finally a direct integration of Hamilton's equations is shown to lead naturally to a path integral expression, as a resolution of the identity, as applied to arbitrary functions of generalized coordinates and momenta. 相似文献
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We study the noncoInmutative nonrelativistic quantum dynamics of a neutral particle, which possesses an electric qaudrupole moment, in the presence of an external magnetic field. First, by intro ducing a shift for the magnetic field, we give the Schrodinger equations in the presence of an external magnetic field both on a noncommutative space and a noncomlnutative phase space, respectively. Then by solving the SchrSdinger equations both on a noneommutative space and a noncommutative phase space, we obtain quantum phases of the electric quadrupole moment, respectively. Wc demonstrate that these phases are geometric and dispersive. 相似文献
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Controlling quantum discord dynamics in cavity QED systems by applying a classical driving field with phase decoherence 下载免费PDF全文
We investigate a two-level atom interacting with a quantized cavity field and a classical driving field in the presence of phase decoherence and find that a stationary quantum discord can arise in the interaction of the atom and cavity field as the time turns to infinity.We also find that the stationary quantum discord can be increased by applying a classical driving field.Furthermore,we explore the quantum discord dynamics of two identical non-interacting two-level atoms independently interacting with a quantized cavity field and a classical driving field in the presence of phase decoherence.Results show that the quantum discord between two atoms is more robust than entanglement under phase decoherence and the classical driving field can help to improve the amount of quantum discord of the two atoms. 相似文献
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Controlling quantum discord dynamics in cavity QED systems by applying a classical driving field with phase decoherence 下载免费PDF全文
We investigate a two-level atom interacting with a quantized cavity field and a classical driving field in the presence of phase decoherence and find that a stationary quantum discord can arise in the interaction of the atom and cavity field as the time turns to infinity. We also find that the stationary quantum discord can be increased by applying a classical driving field. Furthermore, we explore the quantum discord dynamics of two identical non-interacting two-level atoms independently interacting with a quantized cavity field and a classical driving field in the presence of phase decoherence. Results show that the quantum discord between two atoms is more robust than entanglement under phase decoherence and the classical driving field can help to improve the amount of quantum discord of the two atoms. 相似文献
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