Fluorescence and absorption spectra of Rose-Bengal dye in the presence of surfactants

The fluorescence and absorption spectra of Rose Bengal dye in aqueous solution have been studied in the presence of various nonionic, anionic and cationic surfactants. With cationic and nonionic surfactants, shifts occur in the absorption and emission peaks of the dye solution, with a large enhancement in the absorption and fluorescence intensity at the shifted λ_max. No appreciable change in the absorption and fluorescence spectra of the dye has been observed on the addition of anionic surfactants.All the changes observed in the absorption and fluorescence spectra of the dye solution with surfactants may be attributed, to binding of the surfactant with dye molecules and the disaggregation of the dye multimer forms into the monomeric form.     

Electronic absorption spectra of antiviral aminophenol derivatives

Electronic absorption spectra of aminophenol derivatives in solutions have been studied. A general property of the absorption spectra of these compounds, the dependence of the maximum of a long-wavelength absorption band on the solvent polarity, is revealed. As a rule, the absorption band maximum of compounds possessing pharmacological properties shows a greater shift to short wavelength with an increase in the medium polarity than that of inactive compounds. Absorption measurements of solutions of aminophenol derivatives can be used for a tentative estimation of their antiviral activity.     

MOC染料单分子层薄膜聚集体的吸收光谱研究

用吸收光谱对染料的Langmuir-Blodgett(LB)膜的聚集体在不同条件下进行了研究.典型的染料1-methyl-1’-octadecy1-2,2’-cyaninperchlorate(MOC)LB膜聚集体的吸收峰(J带)在580nm附近,吸收为0.09.刚制备好的样品随时间而改变其吸收特性,表明聚集体的结构在2hr后才趋于稳定;测定了不同样品J带的参数;吸收峰值波长位置和峰的半宽度,以及这些参数随温度的变化.吸收随温度变化的可逆性是LB膜聚集体用作光记录介质的一个物理基础.温度超过100℃时,样品吸收的不可逆变化反映相变发生.     

UV absorption spectra of some γ-phenylpyridine derivatives

The derivatives have methyl, carbethoxy, and carbmethoxy groups or are higher homologs with unsaturated substituents. The bond orders and electron density per atom are calculated by the LCAO MO method in the Hückel approximation for the parent compound and the methyl derivatives. The spectra are recorded with an EPS-2 spectrophotometer, the solvents being ethanol and isooctane.The compounds were synthesized in the organic chemistry at the Lumumba Friendship University by K.J. Mathew and A.I. Sirotin under the direction of Professor N.S. Prostakov.     

Understanding the absorption and emission spectra of borondipyrromethene dye and its substituted analogues

Borondipyrromethene (BODIPY) dye possesses a bright and long wavelength emitting fluorescent character with a wide spectral range from visible to near infrared region. In the present work, the spectral properties of BODIPY dyes were analyzed using ab intio and density functional theory methods. The ground and excited state geometries of BODIPY and its substituted analogues in chloroform medium, were optimized using the density functional theory (DFT) and singly excited configuration interaction (CIS) methods. Based on the ground and excited state geometries, the absorption and emission spectra have been calculated using time-dependent density functional theory (TDDFT) method. The TDDFT calculations have been performed using hybrid exchange correlation functionals B3LYP and M06-HF and long-range separated functionals LC-BLYP, LC-BOP, LC-PBE, LC-PBE0 and CAM-B3LYP. The solvent phase calculations were carried out using polarizable continuum model (PCM). The TDDFT investigation reveals that the substitution of acceptor, donor–donor, donor–acceptor–donor and phenyl group in BODIPY dye influence the absorption and emission spectra significantly.     

X-ray photoelectron spectroscopy of merocyanine dyes: III. Structure of the O1s line in the merocyanine 540 dye

The structure of the 01s spectrum for the MC 540 merocyanine dye is resolved using data obtained from XPS analysis of a series of merocyanine dyes displaying less complex O1s signals.The 01s binding energy (BE) of the carbonyl group in these molecules is unusually low and the photoionization peak is accompanied in most cases by a satellite on the high BE side.The data obtained in this study permit a reconstruction of the 01s profile of the MC 540 molecule. The 01s binding energy thus obtained for the carbonyl groups in MC 540 is 531.2 eV. This BE is low when compared to those usually observed for such groups and indicates that, in the MC 540 molecule, they predominantly exist in the ⩾C-O⁻³ form.     

基于太赫兹量子阱探测器的太赫兹量子级联激光器发射谱研究

采用一个光谱匹配的太赫兹(THz)量子阱探测器(QWP)研究了一激射频率约为41 THz的THz量子级联激光器(QCL)在不同驱动电流下的发射谱,分析了测量得到的发射谱谱型和谱峰位置,根据测量的发射谱估算了太赫兹量子级联激光器发射功率随驱动电流变化的情况,从而得到了THz QCL激射的电流密度范围及其阈值电流密度.文中还研究了THz QWP在不同温度下对THz QCL 激光辐射的响应特性.研究结果表明,THz QWP在表征THz QCL的发射谱方面是一种很好的探测器,并有望成为未来THz通信中的接收装置. 关键词： 太赫兹量子阱探测器 太赫兹量子级联激光器 太赫兹通信 Fourier变换红外光谱     

Substituent effects on the triplet-triplet absorption spectra of coumarin and its derivatives

Preliminary work on the triplet-triplet (T-T) absorption of coumarin and two of its 4-hydroxy substituted derivatives is extended to four additional substituted coumarins in order to investigate substituent effects on T-T absorption in these molecules. A steady cross Illumination technique is used in EPA glass at 77° K. Measurements of the decay of T-T absorption are carried out with a flash technique and a comparison made with phosphorescence lifetimes to verify the triplet nature of the absorption. The observed T-T spectra show a marked dependence on the presence and position of hydroxy substitution. An explanation is developed based on the mixing of $\text{nπ}{}^1$ character into the lowest $\text{ππ}{}^1$ triplet state. The effect of methyl substitution is also investigated and, although it leads to relatively small changes in the T-T spectra, the results suggest that it plays a role in the susceptibility of the molecules to photochemical change.     

基于太赫兹量子阱探测器的太赫兹量子级联激光器发射谱研究

采用一个光谱匹配的太赫兹(THz)量子阱探测器(QWP)研究了一激射频率约为41 THz的THz量子级联激光器(QCL)在不同驱动电流下的发射谱,分析了测量得到的发射谱谱型和谱峰位置,根据测量的发射谱估算了太赫兹量子级联激光器发射功率随驱动电流变化的情况,从而得到了THz QCL激射的电流密度范围及其阈值电流密度.文中还研究了THz QWP在不同温度下对THz QCL 激光辐射的响应特性.研究结果表明,THz QWP在表征THz QCL的发射谱方面是一种很好的探测器,并有望成为未来THz通信中的接收装置.     

Sensitive detection of flame absorption spectra of rare-earth elements with a dye laser

The dye-laser amplified absorption method is applied to observe the atomic absorption lines of rare-earth elements in a nitrous-oxide-acetylene flame. All of the rare-earth elements except Pm are analyzed and about 1200 lines have been recorded within the continuous spectral region from 432 to 670 nm. A much larger number of absorption lines can be detected than those measured by the traditional method. The absorption bands of monoxide molecules have also been detected.     

Specific features of photoprocesses in the dye merocyanine 540 and its complexes with water

The electronic structure and spectral-luminescence properties of the dye merocyanine 540 have been calculated within the framework of the semiempirical quantum-chemical method of partial neglect of differential overlap (PNDO) with spectroscopic parameterization. The trans and cis conformations of the molecule, as well as the trans–cis photoisomerization process, have been considered. The calculation has been performed for an isolated molecule of the merocyanine 540 and its complex with water. The results of the calculation have been compared with the experimental spectral-luminescence characteristics of the molecule in different solvents. It has been shown that there is a good agreement between the calculated and experimental spectra, the nature of the excited states, and photoprocesses.