Nuclear spin-lattice relaxation in transition metal compounds with local tetragonal symmetry

We report on the various contributions to the total spin-lattice relaxation rate in metallic materials with local tetragonal symmetry. The analytical formulae are given in the tight-binding approximation. The calculations show the relation between various partial electron densities of states and corresponding contributions to the relaxation rates. The presented formulae can be used to compare theoretically calculated electron band structure parameters with those obtained from NMR spin-lattice relaxation time measurements.     

Study of activation parameters and NMR spin-lattice relaxation time in some substituted amines

The present communication reports the experimental values of NMR spin-lattice relaxation time (T₁) and dielectric relaxation time (τ) of piperidine, pyrrole, pyridine, diethylamine, triethylamine and pyrrolidine. The values of activation energy (ΔE_A) obtained using dielectric relaxation time, have been correlated with calculated values of ΔE_A obtained using Arrhenius equation of NMR relaxation time (T₁) for pyridine, diethylamine and pyrrole. Authors have also established a correlation between the experimental values of NMR spin-relaxation time (T₁) with its calculated values obtained using different equations of dielectric relaxation time (τ).     

In vivo multiecho T2 relaxation measurements using variable TR to decrease scan time

Multiecho T2 relaxation measurements to determine geometric mean T2 (GMT2) and myelin water fraction (MWF) are lengthy, resulting in increased motion artefacts from patient discomfort and reduced patient compliance. The goal of this study was to shorten the acquisition time for multiecho T2 measurements without affecting T1 weighting by varying TR across k-space. Six phantoms and 10 healthy volunteers were imaged with both a constant TR and a variable TR multiecho T2 sequence. T1 weighting was determined by TR at the center of k-space; for variable TR measurement, TR was shortened linearly from the center to the edges of k-space. Phantoms showed excellent agreement for proton density and GMT2 between constant and variable TR measurements. No significant differences were found in proton density or MWF for any of the brain structures between the two measurements. The average GMT2 over all structures between the two experiments was not significantly different. In summary, with the variable TR approach, scan time was reduced by >20%, with minimal loss of image resolution and no significant affect on proton density, MWF or GMT2.     

Formation of p-cresol:piperazine complex in solution monitored by spin-lattice relaxation times and pulsed field gradient NMR diffusion measurements

A study of the nature of the anthelmintic p-cresol:piperazine complex in chloroform solution has been conducted using different NMR techniques: self-diffusion coefficients using DOSY; NOE, NULL, and double-selective T1 measurements to determine inter-molecular distances; and selective and non-selective T1 measurements to determine correlation times. The experimental results in solution and CP-MAS were compared to literature X-ray diffraction data using molecular modeling. It was shown that the p-cresol:piperazine complex exists in solution in a very similar manner as it does in the solid state, with one p-cresol molecule hydrogen bonded through the hydroxyl hydrogen to each nitrogen atom of piperazine. The close correspondence between the X-ray diffraction data and the inter-proton distances obtained by NULL and double selective excitation techniques indicate that those methodologies can be used to determine inter-molecular distances in solution.     

Effect of flow on the apparent transverse relaxation time in a microfluidic nuclear magnetic resonance chip

The detection of samples in a microfluidic nuclear magnetic resonance chip is generally performed under flow condition. To study the effect of sample flow on the apparent transverse relaxation time in a microfluidic nuclear magnetic resonance chip, theoretical calculations were performed on three microfluidic samples (including deionized water, absolute ethanol, and copper sulfate pentahydrate) for flow velocities in the range 1.7–25?mm/s. A microfluidic nuclear magnetic resonance device with a low cost microfluidic solenoid coil was fabricated to verify the theoretical calculations by experiments. The results show that the apparent transverse relaxation time of the sample is a monoexponential decay with respect to flow velocity. In addition, it was found that the experimental values and the theoretical values of the apparent transverse relaxation time are identical when the samples are prepolarized completely; but for the samples that are not prepolarized completely, all the experimental values are smaller than the theoretical values and their difference increases with the flow velocity of the sample. After further study, it was discovered that the relative error between the experimental values and the theoretical values is a monoexponential decay to the level of the sample to be prepolarized. This discovery is very useful, because it can be used to modify the theoretical calculation model of the apparent transverse relaxation time for the samples that are prepolarized incompletely, as well as improve the application of microfluidics on nuclear magnetic resonance.     

Fourier transform microwave spectroscopy of isotopically substituted diacetylenes: rs-structure, quadrupole coupling, and anisotropic nuclear spin-spin interaction

Monodeuterated diacetylene (HCCCCD) and its ¹³C-substituted species H¹³CCCCD, HC¹³CCCD, HCC¹³CCD, and HCCC¹³CD were investigated by Fourier transform microwave spectroscopy. The D nuclear quadrupole splittings were almost completely resolved. For H¹³CCCCD hyperfine splittings caused by the anisotropic nuclear spin-spin interaction between the H and ¹³C nuclei were also observed. The analysis yielded rotational constants, centrifugal distortion constants, and the constants for the nuclear quadrupole coupling and anisotropic nuclear spin-spin interaction. The substitution structure of HCCCCD was calculated as follows: r_s(C-H) = 1.056054(39) Å, r_s(CC) = 1.208631(4) Å, r_s(C-C) = 1.374117(6) Å, r_s(CC) = 1.208116(4) Å, and r_s(C-D) = 1.056231(17) Å, in the order of the arrangement of the bonds. A rough estimate of the equilibrium structure is also presented. The eQq constant for the deuterium nucleus is 0.2061(4) MHz. The anisotropic ¹³C-H spin-spin interaction constant was experimentally determined for the first time as b = −29.2(15) kHz, which is defined as the coefficient of (3I_2zI_3z − I₂ · I₃), where I₂ and I₃ denote the H and ¹³C nuclear spins, respectively, and I_2z and I_3z their components along the molecular axis. The observed b constant is not accounted for by the direct magnetic dipole-dipole interaction only, suggesting a significant contribution from indirect anisotropic interaction.     

Spectral and relaxation-time measurements in the HMBA CrV radical at 150 GHz

Spectral and relaxation characteristics of the HMBA Cr^V complex for polarized nuclear targets have been performed. Long time stability of the HMBA Cr^V complex in I.2 propylene glycol solution is investigated. Spin-lattice relaxation time and spectral diffusion rate versus concentration have been obtained.     

Rapid determination of the RF pulse flip angle and spin-lattice relaxation time for materials imaging

For samples with T1s longer than 10s, calibration of the RF probe and a measurement of T1 can be very time-consuming. A technique is proposed for use in imaging applications where one wishes to rapidly obtain information about the RF flip angle and sample T1 prior to imaging. The flip angle measurement time is less than 1s for a single scan. Prior knowledge of the RF flip angle is not required for the measurement of T1. The resulting time savings in measuring the values of flip angle and T1 are particularly significant in the case of samples with very long T1 and short T2*. An imaging extension of the technique provides RF flip angle mapping without the need for incrementing the pulse duration, i.e., RF mapping can be performed at fixed RF amplifier output.     

石墨烯低温热膨胀和声子弛豫时间随温度的变化规律

考虑到原子非简谐振动和电子-声子相互作用,用固体物理理论和方法研究了石墨烯格林艾森参量和低温热膨胀系数以及声子弛豫时间随温度的变化规律,探讨了原子非简谐振动项对它们的影响.结果表明:1)在低于室温的温度范围内,石墨烯的热膨胀系数为负值,随着温度的升高,其热膨胀系数的绝对值单调增加,室温热膨胀系数为-3.64×10~(-6)K~(-1);2)简谐近似下的格林艾森参量为零.考虑到非简谐项后,格林艾森参量在1.40-1.42之间并随温度升高而缓慢增大,几乎成线性关系,第二非简谐项对格林艾森参量的影响小于第一非简谐项;3)石墨烯声子弛豫时间随着温度的升高而减小,其中,温度很低(T10 K)时变化很快,此后变化很慢,当温度不太低(T300 K)时,声子弛豫时间与温度几乎成反比关系.     

Electronic relaxation processes of all-trans-2,4,6,8-decatetraene vapour revealed by the measurements of the S1 and S2 fluorescence

Fluorescence and excitation spectra of all-trans-2,4,6,8-decatetraene vapour have been measured at different buffer gas pressures from 0 to 1.07 × 10⁵ Pa (800 Torr). The quantum yield of the S₁ fluorescence (Φ_F(S₁)) increases with increasing the buffer gas pressure, while that of the S₂ fluorescence (Φ_F(S₂)) decreases slightly. Φ_F(S₁) decreases significantly with increasing the excitation energy under the collision free condition, while Φ_F(S₂) decreases only slightly. The pressure dependence of the fluorescence yields is interpreted in terms of the relaxation model involving the reversible internal conversion between S₁ and S₂ and the vibrational relaxation in the S₁ manifold. The reverse S₁ → S₂ internal conversion rate is shown to be very slow compared with the forward S₂ → S₁ internal conversion rate.     

Experimental study on T2 relaxation time of protons in water suspensions of iron-oxide nanoparticles: Cases of composite nanospheres

The experimental transverse relaxivity r_2,exp of protons in water suspensions of spherical SiO₂ shelled γ‐Fe₂O₃ nanoparticle clusters of different sizes is analyzed based on existing models. It is shown that r_2,exp can be significantly larger than the modelling relaxivity, which may be attributed to nanosphere aggregations.     

The zonal architecture of human articular cartilage described by T2 relaxation time in the presence of Gd-DTPA2-

The depth-wise variation of T(2) relaxation time is known to reflect the collagen network architecture in cartilage, while the delayed Gadolinium Enhanced MRI of Cartilage (dGEMRIC) technique is sensitive to tissue proteoglycan (PG) concentration. As the cartilage PG content varies along the tissue depth, the depth-dependent accumulation of the contrast agent may affect the inherent T(2) of cartilage in a nonconstant manner. Therefore, T(2) and dGEMRIC are typically measured in separate MRI sessions. In the present in vitro MRI study at 9.4 T, depth-wise T(2) profiles and collagenous zone thicknesses as determined from T(2) maps in the absence and presence of Gd-DTPA(2-) (T(2) and T(2Gd), respectively) were compared in samples of intact human articular cartilage (n=65). These T(2) measures were further correlated with birefringence (BF) of polarized light microscopy (PLM) to quantify the ability of MRI to predict the properties of the collagen fibril network. The reproducibility of the T(2) measurement in the current setup was also studied. Typical tri-laminar collagen network architecture was observed both with and without Gd-DTPA(2-). The inverse of BF (1/BF) correlated significantly with both T(2) and T(2Gd) (r=0.91, slope=0.56 and r=0.90, slope=0.63), respectively. The statistically significant linear correlations between zone thicknesses as determined from T(2) and T(2Gd) were r=0.55 (slope=0.49), r=0.74 (slope=0.71) and r=0.95 (slope=0.94) for superficial, middle and deep tissue zones, respectively. Reproducibility of the T(2) measurement was worst for superficial cartilage. Consistent with PLM, T(2) and T(2Gd) measurements reveal highly similar depth-dependent information on collagen network in intact human cartilage. Thus, dGEMRIC and T(2) measurements in one MRI session are feasible for intact articular cartilage in vitro.     

Angular distribution measurements of Li(p,α)He reaction at 140 keV proton energy using nuclear track detectors

Angular distributions of a ⁶Li(p,α) ³He reaction were measured at six angles for 140 keV proton energy using nuclear track detectors (NTDs). The measurements were carried out over 60°–160° lab. angles in 20° increments using a scattering chamber of 80° beam line of the 350 kV accelerator. A semiconductor silicon surface barrier (SSB) detector was placed at +160° and was used as a monitor. The results have shown that the CR-39 detector has excellent capabilities to distinguish 1.4–2.7 MeV α+ ³He particles from the ⁶Li(p,α) ³He reaction and 8–9.4 MeV α-particles from the ⁷Li(p,α) ⁴He reaction through their track diameters. However, it was not possible to distinguish between the 2.3 MeV ³He ions and the 1.7 MeV ⁴He ions from the ⁶Li(p,α) ³He reaction from their track diameter measurements, but it was possible to differentiate between the two, from the darker contrast of the ³He particles caused by its deeper tracks as compared to those of ⁴He.     

Microwave spectra of the Cl and Cl isotopomers of dichloromethylene: Nuclear quadrupole-, spin-rotation-, and nuclear shielding constants from the hyperfine structures of rotational lines

The rotational spectra of the isotopomers C³⁵Cl³⁷Cl and C³⁷Cl₂ of dichloromethylene in the ground vibronic state were recorded in the range 10-33 GHz using a molecular beam Fourier transform microwave spectrometer. CCl₂ was generated by flash pyrolysis using different precursors. The observed spectra were analyzed to yield rotational and centrifugal distortion constants, as well as the complete Cl nuclear quadrupole coupling tensors and the spin-rotation interaction constants from the hyperfine structure of the rotational lines. With inclusion of data from previous work on the most abundant species C³⁵Cl₂ [N. Hansen, H. Mäder, F. Temps, Phys. Chem. Chem. Phys. (3) (2001) 50-55.] a refined r₀ structure was determined. The spin-rotation interaction constants of all three isotopomers were used to derive ³⁵Cl and ³⁷Cl principal inertial axis nuclear magnetic shielding components which have not yet been determined by NMR spectroscopy.     

Study of the quasi two-dimensional CoxNi1-xTa2O6 compounds by X-ray diffraction and magnetic susceptibility measurements

We report results on the structural and magnetic properties of the Co_xNi_1−xTa₂O₆ series of compounds by X-ray powder diffraction, magnetic susceptibility and magnetization measurements. X-ray refinements carried out by the Rietveld method show that these compounds crystallize in a P4₂/mnm tetragonal structure. Magnetic susceptibility curves show a broadened maximum witnessing that these compounds exhibit two-dimensional antiferromagnetic behaviors. All the Co_xNi_1−xTa₂O₆ compounds order below 10 K and present a large ion anisotropy. The magnetic properties have been determined in both the paramagnetic and antiferromagnetic state. In the hypothesis of two dimensional AF ordering, the near neighbor exchange constants (J₁) and the next near neighbor exchange constants for two different paths (J₂ and J'₂) were determined. The composition dependence of the magnetic properties including ordering temperature, exchange constants and anisotropy factors are discussed. The drastic reduction of the ordering temperature for x=0.20 for Co_xNi_1−xTa₂O₆, suggest the hypothesis of a peculiar magnetic behavior for this composition.     

Structures and luminescence properties of Yb3＋ in the double perovskites Ba2YB＇O6 （B＇=Ta5＋, Nb5＋） phosphors

The Yb³⁺ doped Ba₂YB'O₆ (B'=Ta⁵⁺, Nb⁵⁺) were prepared by high temperature solid-state reaction method, their structures were determined by x-ray diffraction and refined by Rietveld method. The diffuse reflection absorption, excitation and emission spectra of Yb³⁺:Ba₂YB'O₆ (B'=,Ta⁵⁺, Nb⁵⁺) were measured at room temperature. Under the excitation of ultraviolet light, these phosphors exhibit broad charge transfer band emissions of TaO₆ or NbO₆ centre with large Stokes shift. The Yb³⁺ doped into these hosts are situated at Y³⁺ sites of cubic symmetry (O_h). The experimental energy levels of Yb³⁺ in Ba₂YTaO₆ and Ba₂YNbO₆ were determined by photoluminescence and diffuse reflection absorption spectra. Their wavefunctions and theoretical energy levels were obtained by diagonalising the Hamiltonian matrix. The experimental energy levels were fitted by Levenberg--Marquardt iteration algorithm to determine crystal field parameters. Then, the magnetic-pole transition line strengths of Yb³⁺:Ba₂YB'O₆(B'=Ta⁵⁺, Nb⁵⁺) from (²F_5/2)Γ₈^- to the low-energy states were calculated.     

19F nuclear spin relaxation and spin diffusion effects in the single-ion magnet LiYF4:Ho3+

Temperature and magnetic field dependences of the ¹⁹F nuclear spin-lattice relaxation in a single crystal of LiYF₄ doped with holmium are described by an approach based on a detailed consideration of the magnetic dipole-dipole interactions between nuclei and impurity paramagnetic ions and nuclear spin diffusion processes. The observed non-exponential long time recovery of the nuclear magnetization after saturation at intermediate temperatures is in agreement with predictions of the spin-diffusion theory in a case of the diffusion limited relaxation. At avoided level crossings in the spectrum of electron-nuclear states of Ho^{3 +} ions, rates of nuclear spin-lattice relaxation increase due to quasi-resonant energy exchange between nuclei and paramagnetic ions in contrast to the predominant role played by electronic cross-relaxation processes in the low-frequency ac-susceptibility.     

A study on the formation and stability of quasicrystal in Al4Mn and Al6Cr

Abstract

The condition of the formation of quasicrystal in Al₄Mn and Al₆Cr under high static pressure has been investigated for the first time. I-phase and T-phase have been observed in electron diffraction experiment. The structures of Al₄Mn quenched at about 100 K/s are different under various pressure from 0.95GPa to 4.45GPa. The phase transition from I- and T-phase to crystal phase has also been investigated.     

Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr10(VO4)6F2 crystal

In this paper, the relationships between the optical spectra and local lattice structure for Mn⁵⁺ in a Sr₁₀(VO₄)₆F₂ crystal are established by the crystal- and ligand-field theory. The effect of spin–orbital coupling between the central 3d² ions and ligand ions has been considered in the full energy matrix. Using the matrix and superposition model formula, we have calculated the optical spectra and local lattice structure parameters of Mn⁵⁺ in Sr₁₀(VO₄)₆F₂ with a C_3v system. The calculated results are in good agreement with the observed values. In addition, the trigonal compressed distortions of the (MnO₄)^3? centers in Sr₁₀(VO₄)₆F₂ crystals are also obtained from the calculations.