Exponential virial expansion for adsorption isotherm

A new virial equation for adsorption isotherm is proposed based on the idea of the Starling's exponential virial expansion.     

Generalization of the Foldy-Lax formula for the self-energy of a wave propagating in a disordered system of scatterers

We presesent an exact generalization of the Foldy-Lax formula for the self-energy of a wave propagating in a disordered system of identical spherical scatterers. The Foldy-Lax formula yields an expression for the self-energy valid to first order in the density of scatterers. Our exact formula allows a systematic calculation of corrections to this low-density approximation. The formula is based on a renormalized cluster expansion which was presented earlier.     

The neutrino response of low-density neutron matter from the virial expansion

We generalize our virial approach to study spin-polarized neutron matter and the consistent neutrino response at low densities. In the long-wavelength limit, the virial expansion makes model-independent predictions for the density and spin response, based only on nucleon–nucleon scattering data. Our results for the neutrino response provide constraints for random-phase approximation or other model calculations, and we compare the virial vector and axial response to response functions used in supernova simulations. The virial expansion is suitable to describe matter near the supernova neutrinosphere, and this work extends the virial equation of state to predict neutrino interactions in neutron matter.     

Padé approximant approach to singular properties of quantum gases: the ideal cases

In this paper, we show how to recover the low-temperature and high-density information of ideal quantum gases from the high-temperature and low-density approximation by the Padéapproximant. The virial expansion is a high-temperature and low-density expansion and in practice, often, only the first several virial coefficients can be obtained. For Bose gases, we determine the BEC phase transition from a truncated virial expansion. For Fermi gases, we recover the low-temperature and high-density result from the virial expansion.     

Contributions to the self-energy of a wave propagating in a disordered array

We study the self-energy of a scalar wave propagating in a disordered static array of spherical scatterers. We employ the cluster expansion developed in a preceding article and provide detailed expressions for many contributions to the self-energy. The two-body term is covered completely. The three-body term is treated only in part, but we believe that those contributions which are important at not too high density are accounted for. Through resummation some of the contributions to the self-energy involve a large number of scatterers.     

Universality in a 2-component fermi system at finite temperature

Thermodynamic properties of a Fermi system close to the unitarity limit, where the 2-body scattering length a approaches +/-infinity, are studied in the high temperature Boltzmann regime. For dilute systems the virial expansion coefficients in the Boltzmann regime are expected, from general arguments, to be universal. A model independent finite temperature T calculation of the third virial coefficient b3(T) is presented. At the unitarity limit, b3infinity approximately 1.11 is a universal number. The energy density up to the third virial expansion is derived. These calculations are of interest in dilute neutron matter and could be tested in current atomic experiments on dilute Fermi gases near the Feshbach resonance.     

On the summation of the virial expansion for the local density of a gas in contact with a solid

We investigate the density profile of a fluid in contact with a wall. Our analysis is based on the summation of the virial expansion for the local density and the resulting integral equation for the density profile involves the two particle direct correlation function of a non-uniform fluid.     

Non-universal thermodynamics of a strongly interacting inhomogeneous Fermi gas using the quantum virial expansion

Within a quantum virial expansion, we investigate theoretically the violation of universal thermodynamics for a strongly interacting unitary Fermi gas trapped in a harmonic potential. The violation is caused by the existence and anisotropy of the trapping potential and a finite-range of the two-body interaction. We calculate the second virial coefficient by solving a two-fermion problem in 3D uniform harmonic traps, as well as in anisotropic traps. In the unitarity limit, the universal value of the trapped second virial coefficient is 1/4. We discuss in detail the non-universal correction to the second virial coefficient and to the equation of state.     

Virial expansion for a strongly correlated Fermi system and its application to ultracold atomic Fermi gases

A strongly correlated Fermi system plays a fundamental role in very different areas of physics, from neutron stars, quark–gluon plasmas, to high temperature superconductors. Despite the broad applicability, it is notoriously difficult to be understood theoretically because of the absence of a small interaction parameter. Recent achievements of ultracold trapped Fermi atoms near a Feshbach resonance have ushered in enormous changes. The unprecedented control of interaction, geometry and purity in these novel systems has led to many exciting experimental results, which are to be urgently understood at both low and finite temperatures. Here we review the latest developments of virial expansion for a strongly correlated Fermi gas and their applications on ultracold trapped Fermi atoms. We show remarkable, quantitative agreements between virial predictions and various recent experimental measurements at about the Fermi degenerate temperature. For equations of state, we discuss a practical way of determining high-order virial coefficients and use it to calculate accurately the long-sought third-order virial coefficient, which is now verified firmly in experiments at ENS and MIT. We discuss also virial expansion of a new many-body parameter—Tan’s contact. We then turn to less widely discussed issues of dynamical properties. For dynamic structure factors, the virial prediction agrees well with the measurement at the Swinburne University of Technology. For single-particle spectral functions, we show that the expansion up to the second order accounts for the main feature of momentum-resolved rf-spectroscopy for a resonantly interacting Fermi gas, as recently reported by JILA. In the near future, more practical applications with virial expansion are possible, owing to the ever-growing power in computation.     

Multispecies Virial Expansions

We study the virial expansion of mixtures of countably many different types of particles. The main tool is the Lagrange–Good inversion formula, which has other applications such as counting coloured trees or studying probability generating functions in multi-type branching processes. We prove that the virial expansion converges absolutely in a domain of small densities. In addition, we establish that the virial coefficients can be expressed in terms of two-connected graphs.     

Study of the O(N) linear \sigma model at finite temperature using the 2PPI expansion

We show that a new expansion, which sums seagull and bubble graphs to all orders, can be applied to the O(N) linear -model at finite temperature. We prove that this expansion can be renormalized with the usual counterterms in a mass independent scheme and that Goldstone's theorem is satisfied at each order. At the one loop order of this expansion, the Hartree result for the effective potential (daisy and superdaisy graphs) is recovered. We show that at one loop 2PPI order, the self-energy of the -meson can be calculated exactly and that diagrams are summed beyond the Hartree approximation. Received: 22 March 2001 / Revised version: 3 September 2001 / Published online: 14 December 2001     

On the Helmholtz Potential Metric: The Isotherm Length-Work Theorem

In this paper we introduce the Isotherm Length-Work theorem using the Helmholtz potential metric and the virial expansion of pressure in inverse power of molar volume. The theorem tells us what length of a thermodynamical system described by equation of state through virial expansion along isotherms actually is with such a metric. We also give explicit solutions for thermodynamic length along isotherms in the case of first, second and third order expansion     

On the theory of localization in disordered systems

A localization criterion is derived by using the self-consistent determination of the self-energy in the discussion of the convergence of the Green function renormalized perturbation expansion. This criterion depends on the dimensionality and the connectivity of the lattice. It yields localization for all states in one-dimension systems and tends to the Economon-Cohen criterion when the number of neighbours tends to infinity. Moreover, one can show that delocalization occurs when the width of the probability distribution of the self-energy is of the order of magnitude of the hopping integral.     

Low‐temperature Extensions of the Virial Equation of State for Solar Modeling

Low‐order density expansions cannot adequately describe recombination reactions. Therefore, the usefulness of an exact quantum virial expansion truncated at the order of ?^5/2 is limited to the deeper interior of the Sun, where the plasma is nearly fully ionized. Here, intermediate steps towards full‐fledged solar modeling are presented. They are (i) a smooth numerical representation of the quantum virial expansion and (ii) the construction of a smooth transition to the low‐temperature regime (below 50,000 K), where the virial expansions breaks down due to H recombination. These technical steps are realized for a simplified H‐only plasma; the extension to He and heavier elements will be dealt with later. Ultimately, the outcome will be that solar observations can be used to test the accuracy of the virial equation of state and to compare it with current more phenomenological formalisms (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Particle Propagation in Cosmological Backgrounds

We analyse the quantum propagation of interacting particles in cosmological backgrounds. The model we use consists of a doublet of massive scalar fields propagating in an expanding universe filled with massless radiation. The masses are much larger than the Hubble expansion rate, so that the number of massive particles is preserved and the fields adequately described within the adiabatic approximation. We focus on the dissipative effects related to the expansion rate by computing the imaginary part of the self-energy. In the quasi static approximation, we recover the expected result that instantaneous decay rate is governed by the local temperature. We then analyse the long time behavior of the propagator to unravel the secular effects induced by the self-energy. We show that these effects can be expressed in terms of integrals of local quantities. Applications to the trans-Planckian question are briefly discussed.     

Critical properties of non-spherical molecule fluids from the virial expansion

Critical constants of pure fluids (as important reference data in constructing vapour-liquid phase diagrams and basic input of various estimation methods) were determined for systems of non-spherical Kihara molecules; values of the critical temperature, density, compression factor and pressure of fluids composed of prolate and oblate molecules were evaluated from the fourth-order virial expansion. The second and third virial coefficients of the Kihara molecules were determined by applying the recently proposed method in which the effect of molecular core geometry and functional dependence of a pair interaction on the surface-surface distance are factorized and the former contribution determined from a formula for the corresponding hard convex body virial coefficient. The virial expansion for non-spherical Kihara molecules is applied to determine the critical constants of n-alkanes (methane to octane) and cyclic hydrocarbons (cyclopentane, cyclohexane, benzene and naphthalene); a fair agreement with experimental data was found.     

Massive Meson Fluctuation in NJL Model

Based on the self-consistent scheme beyond the mean-field approximation in the large N_c expansion, including current quark mass explicitly, a general scheme of SU(2) NJL model is developed. To ensure the quark self-energy expanded in the proper order of N_c,an approximate internal meson propagator is deduced, which is in order of O(l/N_c). In our scheme, adopting the method of external momentum expansion, all the Feynman diagrams are calculated in a unified way by only expanding the quark propagator. Our numerical results show that, different &om the mean-field approximation in which the explicitly chiral symmetry breaking is invisible, the effect of finite pion mass can be seen clearly when beyond the meanfield approximation.     

Thermodynamics of pseudo-hard body mixtures

Thermodynamic properties of binary mixtures of hard spheres of various size and pseudo-hard bodies, mimicking the short-range non-additive repulsive interactions in realistic models of water, have been determined over the entire concentration range using standard NVT Monte Carlo simulations. Virial coefficients of the mixture have also been computed. Having no other theoretical tool currently available, a perturbed virial expansion is examined with respect to its potential to estimate/predict the properties of the mixture without resorting to any fitting of simulation data. The perturbed virial expansion is found to perform quite accurately for the mixtures containing larger spheres, whereas for small spheres dissolved in water the result is only qualitatively correct.     

Gauge independence of subleading contributions to the operator product pole mass

We prove that the mass-shell gauge independence of the quark condensate contribution to the quark self-energy is not accidental: the same phenomenon is shown to occur for the mixed condensate contribution. This allows one to conclude that the pole mass is gauge-independent in the operator product expansion.