水中受激拉曼散射的能量增强及受激布里渊散射的光学抑制

为提高液体介质中受激拉曼散射的输出能量,提出了通过温度调控来抑制受激布里渊散射的方法,设计了532 nm多纵模宽带脉冲激光泵浦的受激拉曼散射发生系统,测量了不同温度下水中前向受激拉曼散射及后向受激布里渊散射的输出能量,分析了水温、泵浦激光线宽及热散焦效应对受激拉曼散射输出能量影响的物理机制.实验结果表明:通过降低水温可实现对受激布里渊散射过程的有效抑制,同时减小热散焦效应带来的光束畸变,从而有效提高受激拉曼散射的输出能量.研究结果对液体介质中的受激拉曼散射多波长转换具有重要意义.     

CeFePO: a heavy fermion metal with ferromagnetic correlations

The ground state properties of CeFePO, a homologue of the new high temperature superconductors RFePnO1-xFx, were studied by means of susceptibility, specific heat, resistivity, and NMR measurements on polycrystals. All the results demonstrate that this compound is a magnetically nonordered heavy fermion metal with a Kondo temperature TK approximately 10 K, a Sommerfeld coefficient gamma=700 mJ/mol K2, and a mass enhancement factor of the order of 50. Analysis of the susceptibility data and of the spin relaxation time indicates that the strong electronic correlation effects originate from the Ce-4f electrons rather than from Fe-3d electrons. An enhanced Sommerfeld-Wilson ratio R=5.5 as well as a Korringa product S0/T1TK2 approximately 0.065 well below 1 indicate the presence of ferromagnetic correlations. Therefore, CeFePO appears to be on the nonmagnetic side of a ferromagnetic instability.     

Neutron scattering of fragile antiferromagnetic phases in heavy fermion compounds

Results of neutron scattering and specific heat measurements are reported for two kinds of weak antiferromagnetic compounds corresponding to (i) the situation at the quantum critical point and (ii) the double magnetic transition observed in CeRu₂Ge₂.     

Surface plasmon enhanced Brillouin scattering from metal films

The theory of Brillouin scattering in a prism-metal film-air (Kretschmann) geometry is analyzed and numerical estimates are given for a LaSF9 prism-Ag film-air configuration. Signal enhancement of several orders of magnitude is predicted under conditions of coupling to surface plasmon-like fields.     

Form of the long-range potential observed in fast-neutron scattering by heavy nuclei

It is shown that the discrepancy between the results obtained for different neutron-energy ranges, when the neutron polarizability is derived from data on neutron scattering, can be removed if one assumes that a strong-interaction long-range potential of van der Waals (～r ^?6) or of Casimir and Polder (～r ^?7) is observed in fast-neutron scattering. This strong-interaction long-range potential possibly has some experimental confirmation in elastic pp scattering.     

LiV2O4: frustration induced heavy fermion metal

We propose a two-stage spin-quenching scenario for the unusual heavy fermion state realized in the mixed valent metal LiV2O4. In this theory, local valence fluctuations are responsible for the formation of partially quenched, spin-1 / 2 moments below room temperature. Frustration of the intersite spin couplings then drives the system to produce the heavy Fermi liquid seen at low temperatures. The anomalous resistivity and the sign change of the Hall constant can be understood naturally within this model, which also predicts a unique symmetry for the heavy quasiparticle bands that may be observed in de Haas-van Alphen experiments.     

Dynamical conductivity of heavy fermion systems: effect of impurity scattering

The influence of impurity scattering on a heavy fermion system is studied within a mean-field approximation of the Anderson Hamiltonian and using a coherent potential approximation for the impurity scattering. Two types of scattering mechanisms are investigated: missingf-ions and potential scatterring centers. The dynamical conductivity shows a nearow peak at low frequencies scaling with the effective mass of the heavy quasi-particles together with a peak at finite frequencies due to interband transitions. These features are also found in experimental results on heavy fermion systems.     

Enhanced Raman scattering on metal surfaces

We present a theory which describes enhanced Raman scattering from molecules adsorbed on metals. The enhancement is due to the screening fields induced by the optically polarized adsorbate in the presence of the substrate. These fields interact coherently with the applied optical field and the vibrational motion of the adsorbed molecule. The enhancement is shown to be coverage dependent and also rather sensitive to the optical dielectric function of the substrate. Predicted enhancements compare well with experiment.     

Detecting submerged objects by Brillouin scattering

The principle of detecting submerged objects by Brillouin scattering is analyzed. It is based on testing the frequency shift rather than the intensity of the scattered signal. Experiments based on the principle are carried out. An actual detecting system for practical applications is designed, and the experimental results obtained by using the system are given. The experimental results show that the method of Brillouin scattering possesses several advantages compared to the method of testing the signal intensity. The conclusion is that Brillouin scattering is a good method for detecting submerged objects. PACS 42.68.Wt; 42.79.Qx; 78.35.+c     

Elastic constants and softening of acoustic modes in A2MX6-crystals observed by Brillouin scattering

Room-temperature Brillouin-scattering measurements of the longitudinal and transverse sound velocities for the cubic crystals K₂SnCl₆, K₂ReCl₆, (NH₄)₂SnCl₆ and (NH₄)₂SiF₆ are presented. The elastic constantsc ₁₁,c ₁₂ andc ₄₄ are determined from the angular variation of the Brillouin line shifts. Furthermore, for K₂SnCl₆ the sound velocities in the [100]- and [111]-direction are investigated as a function of temperature, 256K≦T≦330K. A strong softening of thec ₁₁–c ₁₂ mode is observed in the para-distortive phase as the temperature approaches the phase transition temperatureT _c1=262K from above, whilec ₄₄ shows no anomaly within the experimental error. These acoustic anomalies are interpreted theoretically by a mechanism based on the coupling of the elastic strain field to the fluctuations of the soft-mode coordinates.     

Superconductivity in heavy fermion systems

The heavy fermion state in the f-electron systems is due to competition between the RKKY interaction and the Kondo effect. The typical compound is CeCu₆. To understand the electronic state, we studied the Fermi surface properties via the de Haas–van Alphen (dHvA) experiment and energy band calculation for CeSn₃,CeRu₂Si₂,UPt₃, and nowadays, transuranium compounds. Pressure is also an important technique to control the electronic state. The Néel temperature T_N decreases with increasing pressure P and becomes zero at the critical pressure for . The typical compound is an antiferromagnet CeRhIn₅, which we studied from the dHvA experiment under pressure. A change of the 4f-electronic state from localized to itinerant is realized at , revealing the first-order phase transition, together with a divergent tendency of the cyclotron mass at P_c. It is stressed that appearance of superconductivity in CeRhIn₅ is closely related to the heavy fermion state. It is also noted that the parity-mixed novel superconducting state might be realized in a pressure-induced superconductor CeIrSi₃ without inversion symmetry in the crystal structure.     

Coherent Brillouin spectroscopy in a strongly scattering liquid by picosecond ultrasonics

In a modification of a picosecond ultrasonic technique, a short acoustic pulse is launched into a liquid sample by a laser pulse absorbed in a semitransparent transducer film and is detected via coherent Brillouin scattering of a time-delayed probe pulse. With both excitation and probing performed from the transducer side, the arrangement is suitable for in vivo study of biological tissues. The signal is collected from a micrometer-thick layer next to the transducer and is not affected by the diffuse scattering of probe light deeper in the sample. The setup, utilizing a 33 nm thick single crystal SrRuO(3) transducer film, is tested on a full fat milk sample, with 11 GHz acoustic frequency recorded.     

Brillouin scattering in layered structures

Theoretical and experimental results on Brillouin scattering in inhomogeneous materials are presented: Normal elastic modes and Brillouin intensities have been calculated for a periodic layer system. Measurements on semicrystalline polybutene-1 are discussed in terms of the theoretical results. Both theory and experiment yield several Brillouin lines in VV scattering instead of the one peak characteristic for homogeneous specimens.     

Critical opalescence in fluids: 1.5-Scattering effects and the Landau-Placzek ratio

We adduce new arguments for the significance of so-called 1.5- (or sesquialteral) molecular light scattering in one-component fluids. For this purpose, we analyze its effect on the Landau-Placzek ratio for the critical opalescence spectrum. The results obtained are used to reveal experimental data which can be interpreted as evidence for its existence and to evaluate both the relative magnitude and the sign of the 1.5 scattering contribution.     

On a negative thermal expansion in heavy fermion systems

We explain negative thermal expansion observed in some heavy fermion systems at low temperatures within a two-component Fermi-liquid picture: α may become negative if Fermi-level falls on a region of steep increase in the density-of-states. The results obtained account for the correlation between the sign of thermal expansion and that of thermopower, and give certain information about the band structure of these systems.     

Pruning-induced phase transition observed by a scattering method

In hyperbolic systems, transient chaos is associated with an underlying chaotic saddle in phase space. The structure of the chaotic saddle of a class of piecewise linear, area-preserving, two-dimensional maps with overall constant Lyapunov exponents has been observed by a scattering method. The free energy obtained in this way displays a phase transition at <0 in spite of the fact that no phase transition occurs in the free energy dedcued from the spectrum of Lyapunov exponents. This is possible because pruning introduces a second effective scaling exponent by creating, at each level of the approximation, particular small pieces in the incomplete Cantor set approximating the saddle. The second scaling arises for a subset of values of the control parameter that is dense in the parameter interval.     

Hall coefficient in heavy fermion metals

Experimental studies of the antiferromagnetic (AF) heavy fermion metal YbRh₂Si₂ in a magnetic field B indicate the presence of a jump in the Hall coefficient at a magnetic-field tuned quantum state in the zero temperature limit. This quantum state occurs at B ≥ B_c0 and induces the jump even though the change of the magnetic field at B = B_c0 is infinitesimal. We investigated this by using the model of heavy electron liquid with the fermion condensate. Within this model, the jump takes place when the magnetic field reaches the critical value B_c0 at which the ordering temperature T_N(B = B_c0) of the AF transition vanishes. We show that at B → B_c0, this second order AF phase transition becomes the first order one, making the corresponding quantum and thermal critical fluctuations vanish at the jump. At T → 0 and B = B_c0 the Grüneisen ratio as a function of the temperature T diverges. We demonstrate that both the divergence and the jump are determined by the specific low temperature behavior of the entropy \(S(T) \propto S_0 + a\sqrt T + bT\) with S₀; a and b are temperature independent constants.