Practical Kedem-Katchalsky equations and their modification

The research problem presented in this work concerns modification of the Kedem-Katchalsky (K-K) equation for volume flow (J _v ) through system (h|M|l), consisting of a membrane M and boundary layers h and l. Such boundary layers appear in the vicinity of the membrane on both sides due to the lack of mixing of solutions. This paper also includes the derivation of the equation for volume flow (J _vr ) dissipated on concentration boundary layers h and l. The derivation of these equations concerns the case in which the substance transport through the membrane is generated by the osmotic pressure gradient . On the basis of the equations for the volume flows (J _v ) and (J _vr ), some calculations for a nephrophane membrane, used in medicine, and for aqueous glucose solutions have been carried out. In order to test the equations for (J _v ) and (J _vr ), we have also carried out calculations for the volume flow (J′ _v ) that is transferred through the membrane in the case of mixed solutions on both sides of the membrane. This volume flux has been calculated on the basis of the original (K-K) equation. The results are presented in Fig. 2.      

Critical fields of a superconducting cylinder

The self-consistent solutions of the nonlinear Ginzburg-Landau equations, which describe the behavior of a superconducting mesoscopic cylinder in an axial magnetic field H (provided there are no vortices inside the cylinder), are studied. Different, vortex-free states (M-, e-, d-, p-), which exist in a superconducting cylinder, are described. The critical fields (H ₁, H ₂, H _p , H _i , H _r ), at which the first or second order phase transitions between different states of the cylinder occur, are found as functions of the cylinder radius R and the GL-parameter . The boundary , which divides the regions of the first and second order (s, n)-transitions in the icreasing field, is found. It is found that at R→∞ the critical value, is . The hysteresis phenomena, which appear when the cylinder passes from the normal to superconducting state in the decreasing field, are described. The connection between the self-consistent results and the linearized theory is discussed. It is shown that in the limiting case and R ≫ λ (λ is the London penetration length) the self-consistent solution (which correponds to the socalled metastable p-state) coincides with the analitic solution found from the degenerate Bogomolnyi equations. The reason for the existence of two critical GL-parameters and in, bulk superconductors is discussed. An erratum to this article is available at.     

Superconducting states of the cylinder with a single vortex in magnetic field according to the Ginzburg-Landau theory

Self-consistent solutions of the nonlinear Ginzburg-Landau (GL) equations are investigated numerically for a superconducting (SC) cylinder, placed in an axial magnetic field, with a single vortex on the axis (m=1). Two modes, which show the original state of the cylinder, SC or normal (s ₀ andn ₀), are studied. The field increase (FI) and the field decrease (FD) regimes are studied. The critical fields destroying the SC state withm=1 are found in both regimes. It is shown that in a cylinder of radiusR and GL-parameter ϰ, there exist a number of solutions depending only on the radial co-ordinater corresponding to different states such as M,e, d, p,i, n, ,n ^*, and the state diagram on the plane of the variables (ϰ,R) is described. The critical fields corresponding to intrastate transitions and the onset of hysteresis are obtained. The critical fieldH ₀(R) dividing the paramagnetic and diamagnetic states of the cylinder withm=1 is determined. The limiting fields of supercooling or superheating of the normal state at which the restoration of the SC state occurs are established. It is shown, that (in both casesm=1,0) there exist two critical parameters, and , which divide bulk SC into three groups (with and ), in accordance with the behavior in a magnetic field. The parameters and mark the boundary for the existence of a supercooled normal -state in FD-regime and a superheated SC M-state in FI-regime respectively. It is shown, that the value , which was claimed in a number of papers as related to type-I superconductors, is illusory. We regret to inform that Professor Gely Zharkov passed away on 9th July 2004.     

Dynamics of low-energy nuclear forces for electromagnetic and weak reactions with the deuteron in the Nambu-Jona-Lasinio model of light nuclei

A dynamics of low-energy nuclear forces is investigated for low-energy electromagnetic and weak nuclear reactions with the deuteron in the Nambu-Jona-Lasinio model of light nuclei by example of the neutron-proton radiative capture (M1-capture) n + p → D + γ, the photomagnetic disintegration of the deuteron γ + D → n + p and weak reactions of astrophysical interest. These are the solar proton burning p + p → D + e⁺ + ν _e, the pep-process p + e⁻ + p → D + ν _e and the neutrino and antineutrino disintegration of the deuteron caused by charged ν _e + D → e⁻ + p + p, + D → e⁺ + n + n and neutral ν _e() + D → ν _e() + n + p weak currents.     

Spin observables of the reactions NN → Δ N and pd → Δ( pp )(1 S 0) in collinear kinematics

A general formalism for double and triple spin correlations of the reaction is developed for the case of collinear kinematics. A complete polarization experiment allowing one to reconstruct all four amplitudes describing this process is suggested. Furthermore, the spin observables of the inelastic charge-exchange reaction (pp)(¹ S ₀ are analyzed in collinear kinematics within the single pN-scattering mechanism involving the subprocess pn → Δ⁰ p. The full set of spin observables, related to the polarization of one or two initial particles and one final particle, is obtained in terms of three invariant amplitudes of the reaction pd → Δ(pp)(¹ S ₀) and the transition form factor d → (pp)(¹ S ₀). A complete polarization experiment for the reaction (pp)(¹ S ₀) is suggested which allows one to determine three independent combinations of the four amplitudes of the elementary subprocess . The text was submitted by the authors in English.     

On the effect of a magnetic field on the yield point and kinetics of macroplasticity in LiF crystals

A strong effect of a static magnetic field B on active deformation kinetics ( =const) in LiF crystals is observed. This is a threshold effect with respect to B and ; it is observed only for B> B _c (B≃0.4 T) and . Magnetic sensitivity is exhibited by the yield stress τ _y , which decreases by approximately a factor of 1.5 for B=0.48 T, and by the stage-II and stage-III hardening coefficients θ_II and θ _III, the former decreasing and the latter increasing in a magnetic field. A physical interpretation is proposed for the observed behavior. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 6, 470–474 (25 March 1997)     

Using the e ± μ? + E Tmiss signature in the search for supersymmetry and lepton-flavor violation in neutralino decays

The LHC (CMS) discovery potential in the search for supersymmetry and lepton-flavor violation in neutralino decays using the e ^± μ^∓ + E _T ^miss signature is studied. A detailed study is done for the CMS test points LM1-LM9. It is shown that, for the point LM1, it is possible to detect lepton-flavor violation in neutralino decays with lepton-flavor-violating branching Br( → μ^± e ^∓ ) ≥ 0.04 Br( → e ⁺ e ⁻ , μ⁺ μ⁻ ) for an integral luminosity of 10 fb⁻¹. The discovery potential in the mSUGRA-SUSY scenario with tan β = 10, sgn(μ) = + in the (m ₀, m _1/2) plane using the e ^± μ^∓ + E _T ^miss signature is determined. The text was submitted by the authors in English.     

Infrared multiple photon dissociation spectroscopy of transition metal oxide cluster cations

Infrared spectra in the range of 530–1400 cm^–1 are presented for tantalum oxide cluster cations (x = 3, 4 and 6). These spectra are obtained via multiple photon dissociation (MPD) spectroscopy of free cluster cations moving in a molecular beam. The IR spectra for are compared to spectra of as well as to the experimental data available for vanadium oxide cluster cations from IR-MPD spectroscopy. For and the IR spectra exhibit very strong similarities (including the band positions), whereas absorption bands in are relatively blue-shifted by about 20–40 cm^–1.     

Excitonic light-absorption and amplification bands in the presence of laser radiation

We examine the absorption and amplification bands of a weak probe signal in the presence of Bose-Einstein condensation of excitons that emerges in nonequilibrium conditions in the field of coherent laser radiation with a wave vector k ₀. We assume that the detuning from resonance between the energy ħω _ex (k ₀)+L ₀ of the exciton level, which is shifted because of exciton-exciton interaction, and the laser photon energy ħω _L , is generally nonzero. The elementary excitation spectrum consisting of the quasiexcitonic and quasienergy branches determines the optical properties of the system. When there is real induced Bose-Einstein condensation, at the two branches touch, as they do in spontaneous Bose-Einstein condensation. In virtual induced Bose-Einstein condensation, when , instabilities emerge in the spectrum in certain regions of the k-space. These instabilities are caused by a real transformation of two laser photons into two extracondensate particles. Nonequilibrium extracondensate excitons strongly affect the absorption and amplification of the probe light signal. We show that light absorption is due to the quantum transition from the ground state of the crystal to the quasiexcitonic branch of the spectrum. On the other hand, amplification of the signal is caused by the transition from the quasienergy branch to the ground state of the crystal. The same transition can be explained by a real transformation of two laser photons into a vacuum photon of frequency ħcq and a crystal exciton with a wave vector 2k ₀−q. Finally, we show that the excitonic absorption and light-amplification bands are essentially anisotropic at and depend on the orientation of the vectors q and k ₀. Zh. éksp. Teor. Fiz. 112, 167–179 (July 1997)     

Negative-ion photoelectron spectroscopy of acrylonitrile clusters containing a sodium atom

Cluster anions of a sodium atom with acrylonitrile molecules, (n = 0–6), have been studied by negative-ion photoelectron spectroscopy. In addition, theoretical calculations by using density functional theory have been performed to obtain optimized structures and vertical detachment energies. For Na(AN)^–, the spectrum can be explained by excitation of two different isomers of the anion. For , a broad band is found in the photoelectron spectrum, whose profile is almost identical with those of previously reported photoelectron spectra of and a negative ion of chemically synthesized 1,3,5-cyclohexanetricarbonitrile (CHTCN) molecule. From this resemblance of band profiles, we conclude that oligomerization of (AN)₃ takes place in and the CHTCN is formed as the intracluster reaction product.     

The radiative decay ϕ → γππ in a coupled-channel model and the structure of f0(980)

A coupled-channel model is used to study the nature of the scalar mesons produced in the decay ϕ → γππ. The K molecular picture of f₀(980) is found to be in a good agreement with the recent experimental data from SND and CMD-2. The structure of the light scalar mesons is elucidated by investigating the S-matrix poles and the q spectral density.     

Properties of a pseudo-Hermitian Hamiltonian for harmonic oscillator decorated with Dirac delta interactions

We have investigated bound state solutions of the Schrodinger equation for one-dimensional harmonic oscillator potential together with even number of Dirac delta functions. These point interactions are located at symmetric points x = x _i and x = −x _i (i = 1, 2,..., N) and they have complex conjugate strengths and , respectively. We present explicit forms of eigenfunctions and an algebraic eigenvalue equation and numerical solutions for this -symmetric Hamiltonian. Presented at the 3rd International Workshop “Pseudo-Hermitian Hamiltonians in Quantum Physics”, Istanbul, Turkey, June 20–22, 2005.     

Running mass m s at low scale from the heavy-light meson decay constants

It is shown that a 25(20)% difference between the decay constants ( ) and f _D (f _B ) occurs due to large differences in the pole masses of the s and d(u) quarks. The values η _D = /f _D ∼ 1.23(15), recently observed in the CLEO experiment, and η _B = /f _B ∼ 1.20, obtained in unquenched lattice QCD, can be reached only if, in the relativistic Hamiltonian the running mass, m _s at low scale is m _s (∼0.5 GeV) = 170–200 MeV. Our results follow from the analytical expression for the pseudoscalar decay constant f _P based on the path-integral representation of the meson Green’s function. The text was submitted by the authors in English.     

Bounds on neutrino mixing with exotic singlet neutrinos

We examine the effects of mixing induced non-diagonal light-heavy neutrino weak neutral currents on the amplitude for the process (with a=e, μ or τ). By imposing constraint that the amplitude should not exceed the perturbative unitarity limit at high energy , we obtain bounds on light-heavy neutrino mixing parameter sin² where is the mixing angle. In the case of one heavy neutrino (mass mξ) or mass degenerate heavy neutrinos, for Λ=1 TeV, no bound is obtained for mξ<0.50 TeV. However, sin² ≤3.8 × 10⁻⁶ for mξ=5 TeV and sin ≤6.0 × 10⁻⁸ for mξ=10 TeV. For Λ=∞, no constraint is obtained for mξ<0.99 TeV and sin² ≤3.8 × 10⁻² (for mξ=5 TeV) and sin² ≤9.6 × 10⁻³ (for mξ=10 TeV).     

Dependence of the Electronic Spectra of the Chlorin Molecule on the Degree of Alternation of the Macrocycle Bond Lengths

The geometric structure of the chlorin molecule (H₂Ch) has been calculated by the restricted and unrestricted Hartree-Fock (RHF and UHF) methods with an AM1 Hamiltonian. Transformations of this molecule into excited electronic states have been calculated by the CNDO/S method. The RHF method without symmetry restrictions gives a plane structure for the chlorin macrocycle with an alternation of the lengths of the bonds along the 18-member azacyclopolyene and a C_1h symmetry for the molecule as a whole. The level of the first excited state Q₁ of this structure is substantially shifted (δ ≅ +4000 cm⁻¹) relative to the Q_x level of porphin (H₂P) toward shorter waves, which is in contradiction with the experimental data, according to which this shift is long-wave and is equal to δ = −400 to −550 cm⁻¹. The optimization of the geometry of H₂Ch by the UHF method has shown that it has a structure with an 18-member azacyclopolyene with bonds of equal lengths and a D_2h symmetry. For this geometry of H₂Ch the calculated shift of the Q_x level, equal to δ = −70 cm⁻¹, is bathochromic and the position of the Q_y level is practically exactly coincident with the experimental one. For the geometry calculated by the RHF method with restrictions on the D_2h symmetry of the 18-member azacyclopolyene δ = +180 cm⁻¹, and for the geometry calculated with restrictions on the highest C_2v symmetry of the H₂Ch molecule δ = +620 cm⁻¹. The latter result shows that the “natural” requirement for the C_2v symmetry of the H₂Ch macrocycle, which is frequently used in various calculations, is inadequate to achieve a quantitative agreement between the calculation and experimental data and, in this case, the lengths of the bonds along the 18-member azacyclopolyene are not equal. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 3, pp. 339–347, May–June, 2005.     

High-precision laser spectroscopy of antiprotonic helium atomcules and effects of collisions at high-density conditions

We have performed laser spectroscpy of metastable antiprotonic helium atoms (or “atomcules”) ( He⁺) and have observed a density dependence of the resonance vacuum wavelengths for the known transitions (n,l)=(39,35)→(38,34) and (37,34)→(36,33). They showed linear red-shifts of 0.61±0.01 GHz and 0.22±0.02 GHz per 1 g℞, respectively. With the shift parameters above, the transition vacuum wavelengths were extrapolated to zero-density limits, yielding λ₀ = 597.2570± 0.0003 nm and λ₀ = 470.7220±0.0006 nm, respectively. These values were compared with the result of recent theoretical calculations on the energy of the Coulombic three-body system, including relativistic corrections and the Lamb shift. The agreements between our experimental values and the calculations have become as good as 2×10^-6. This sets a severe constraint on the antiproton charge ( ) and mass ( ) with |Q _p - |/e < 5 × 10^-7 and |M _p - |/M _p < 5 × 10^-7, under a more precisely known constraint on the charge-to-mass ratio. Thus we have opened a new possibility of measuring fundamental constants of the antiproton. This revised version was published online in August 2006 with corrections to the Cover Date.     

Image states on beryllium surfaces with low indices

Using the self-consistent pseudopotential method, we have calculated the binding energy of the image states for the (0001) , and surfaces of beryllium. It is shown for the (0001) face that there exists a pronounced resonance image state with n=1 and energy −0.95 eV at the point of the surface Brillouin zone. In the surface, which has a wide band gap in the vicinity of the vacuum level, the calculated image state with n=1 at the point has energy −1.2 eV and is a surface state of gap type. For the face in the vicinity of the point band gaps are absent. However, the symmetry of the bulk states near the vacuum level enables the existence of a resonance image state with n=1 and energy −0.6 eV. Fiz. Tverd. Tela (St. Petersburg) 41, 935–940 (June 1999)     

Effect of a magnetic field on the yield point of NaCl crystals

A constant magnetic field is found to have a substantial effect on the macroplasticity of NaCl crystals when they are being actively strained at a constant rate during magnetic treatment. We have measured the dependence of the yield point σ _y on the magnetic induction B=0–0.48 T and the strain rate . It is shown that this magnetic effect has a threshold character and is observed only for B>B _c , where B _c grows with increasing as . The lower the strain rate , the larger the relative decrease in the yield point σ _y (B)/σ _y (0) at fixed field B>B _c . At small enough strain rates the threshold field B _c ceases to depend on and goes constant. A theoretical model is proposed which is in good agreement with the observed regularities. The model is based on the competition between thermally activated and magnetically stimulated depinning of dislocations from paramagnetic impurity centers. Zh. éksp. Teor. Fiz. 115, 951–958 (March 1999)     

Maximal Inequalities for CIR Processes

Let X be a Cox—Ingersoll—Ross (CIR) process given by

Observable N \overline N oscillation, high-scale see-saw and origin of matteroscillation, high-scale see-saw and origin of matter

See-saw mechanism has been a dominant paradigm in the discussion of neutrino masses. We discuss how this idea can be tested via a baryon number violating process such as N- oscillation. Since the expected see-saw scale is high and the N- amplitude goes like M _R ⁻⁵ , one might think that this process is not observable in realistic see-saw models for neutrino masses. In this talk I show that in supersymmetric models, the above conclusion is circumvented leading to an enhanced and observable rate for N oscillation. I also discuss a new mechanism for baryogenesis in generic models for neutron-anti-neutron oscillation.