Interaction of a diazoresin with sodium dodecyl sulfate in aqueous solution

The interaction between a diazoresin and sodium dodecyl sulfate (SDS) in aqueous solution was investigated. It was found that the diazoresin-SDS complex dissolves in water containing excessive SDS. The thermal stability and photo-sensitivity of the diazoresin-SDS complex was also studied. The results show that the complex possesses an increased thermal stability while preserving its high photo-sensitivity. An aqueous composition containing diazoresin and SDS was used directly to prepare a photosensitive coating.     

十二烷基硫酸钠与羟乙基纤维素的相互作用

本文用表面张力(γ)和电导率(κ)方法研究了阴离子表面活性剂十二烷基硫酸钠(SDS)与天然纤维素的水溶性改性物羟乙基纤维素(HEC)的相互作用.实验结果表明,SDS-HEC溶液的γ-lgcSDS曲线和κ～CSDS曲线均呈现双拐点特征,并且γ-lgcSDS曲线上两个SDS临界浓度值(c1 )γ及(c2)γ,与κ～CSDS...     

Interaction of trypsin with sodium dodecyl sulfate in aqueous medium: a conformational view

The conformational behavior of a globular protein, trypsin has been studied in presence of an anionic surfactant, sodium dodecyl sulfate (SDS) in aqueous medium by different techniques, such as, viscometry, circular dichroism, fluorimetry, Fourier transform infra-red, UV-vis absorption, dynamic light scattering and nuclear magnetic resonance. The results indicate that the viscosity of the mixture increases above the critical micelle concentration of SDS micelle supporting an expansion of a protein coil in the cluster. The spectroscopic techniques show the change of the conformation, i.e., the change of the values of alpha-helicity, beta-sheet, and random-coil of trypsin in the presence of SDS, and ultimately unfolding of trypsin occurs due to strong electrostatic repulsion of micellar clusters of the protein-surfactant complexes.     

Interaction of cationic monomer with sodium dodecyl sulfate in dilute aqueous solutions: ESR study

The effect of a cationic monomer (N,N,N,N-trimethyl[methacryloxyethyl]ammonium methyl sulfate) on the formation, structure, and local dynamics of associates resulted from the interaction of the monomer with sodium dodecyl sulfate in aqueous solutions was studied by ESR spectroscopy. In the presence of the monomer, micelles are formed at concentrations much lower than the CMC of the pure surfactant with the monomer molecules that form a condensed layer of counterions around a micelle of sodium dodecyl sulfate. The binding of surfactant micelles with the cationic monomer causes a significant decrease in the local molecular mobility of dodecyl sulfate ions.     

Thermodynamics of aqueous sodium sulfate

The activity coefficient of saturated aqueous Na₂SO₄ is calculated from the properties of the solid and the infinitely dilute solution as well as the solubility. These values are compared with those given by the equation of Rogers and Pitzer which is based on the measured dependence of heat capacity upon molality together with other solution properties at low temperature. Excellent agreement is found from 30 to 280°C. Consequently the equation of Rogers and Pitzer is given an extended range of validity to saturated molality and to 280°C. The trend of solubility with temperature is discussed in relation to the C_p of solution.     

Decomposition of sodium dodecyl sulfate with ozone in aqueous solution

Decomposition of sodium dodecyl sulfate with ozone in aqueous solution in the presence of high concentrations of sodium nitrate was studied. The factors affecting ozone interaction with a dissolved compound were determined.     

Aggregation of sodium dodecyl sulfate in aqueous sodium chloride solutions

Summary Aqueous solutions of sodium dodecyl sulfate with added sodium chloride (0–0.3 mol kg^–1) were studied at 298.2 K in order to calculate the molar standard free energy of micelle formationG _m . The following properties were measured: (i) aggregation number by membrane osmometry, (ii) counter-ion binding and sodium ion activities by electromotive force, (iii) critical micelle concentration by electromotive force and fluorescence spectrophotometry. The results indicate thatG _m . is independent of the NaCl concentration.     

The solubility of disperse dyes in an aqueous sodium dodecyl sulfate solution

Summary The solubilities of the following compounds in an aqueous sodium dodecyl sulfate solution were determined at 25°, 30°, 35° and 40°C: biphenyl, azobenzene, p-chloroazobenzene, p-aminoazobenzene, p-N,N-dimethylaminoazobenzene and p-nitroazobenzene. From the results the thermodynamic parameters for the transfer of the model compounds from water to SDS micellar environment were calculated. The resulting thermodynamic parameters were not so certain, but suggested that with biphenyl, azobenzene and p-chloroazobenzene which seem to be solubilized in the SDS micellar interior the solubilizing process is a result of a favourable increase in entropy, and that with p-aminoazobenzene, p-N, N-dimethylaminoazobenzene and p-nitroazobenzene which seem to be solubilized in the SDS micellar surface the solubilizing process is a result of a favourable decrease in enthalpy. The favourable increase in entropy was explained in terms of iceberg and the favourable decrease in enthalpy in terms of interfacial energy.     

Interaction between styrene–ethylene oxide block copolymers and sodium lauryl sulfate in aqueous solution

Interactions of water-soluble AB block copolymers of polystyrene and poly(ethylene oxide) with sodium lauryl sulfate (SLS) in aqueous solution were investigated by high-resolution proton magnetic resonance (NMR). The viscosity in aqueous SLS solution was also measured. From the NMR results in D₂O, it appears that molecular motions of the polystyrene blocks of the copolymer in aqueous solution are activated by interaction between the polystyrene blocks and the added SLS. From solution viscosity, on the other hand, it is apparent that a complex is formed between the copolymer and SLS and that it exhibits typical polyelectrolyte properties. The polyelectrolyte character is attributable largely to intrachain repulsions between like charges of the SLS anions adsorbed on the poly(ethylene oxide) blocks of the copolymers since the polystyrene blocks are insoluble in water and the styrene content is less than 10%.     

Interaction of sodium dodecyl sulfate with methacrylate-PEG comb copolymers

A series of sodium methacrylate and poly(ethylene glycol) (PEG) comb copolymers (MAA/PEG) with approximate PEG chain lengths of 7, 11, and 22 ethylene oxide units were synthesized by free radical polymerization. Their weight-average molecular mass was found to be approximately 66 000. A commercial sample of a PEG comb polymer with an acrylic backbone was also used in the studies (Sokalan HP 80). The interaction of the MAA/PEG comb polymers and pure sodium methacrylate (SPMA) with sodium dodecyl sulfate (SDS) was studied by ESR spectroscopy using 5-doxyl stearic acid (5-DSA) spin probe and by conductivity measurements. Surfactant aggregation in water occurred at SDS concentrations lower than the surfactant critical micelle concentration (cmc) and depended on the polymer concentration. The observations have been attributed to changes in the effective ionic strength of the systems due to the polymer itself, and it has been concluded that there is no interaction between the MAA/PEG comb copolymers or SPMA and SDS. This has been confirmed by the fact that the decrease in surfactant aggregation concentration is similar in magnitude to the decrease observed on adding NaCl when counterion ion condensation effects are taken into account. It is apparent that the electrostatic repulsions between the surfactant molecules and the methacrylate backbone of the MAA/PEG comb copolymers inhibit association of SDS with the PEG side chains.     

Interaction between casein and sodium dodecyl sulfate

The interaction of the anionic surfactant sodium dodecyl sulfate (SDS) with 2.0 mg/ml casein was first investigated using isothermal titration calorimetry (ITC), dynamic light scattering (DLS), and fluorescence spectra. ITC results show that individual SDS molecules first bind to casein micelles by the hydrophobic interaction. The micelle-like SDS aggregate is formed on the casein chains when SDS concentration reaches the critical aggregation concentration (c1), which is far below the critical micellar concentration (cmc) of SDS in the absence of casein. With the further increase of SDS concentration to the saturate binding concentration c2, SDS molecules no longer bind to the casein chains, and free SDS micelles coexist with casein micelles bound with SDS aggregates in the system. DLS results show that the addition of SDS leads to an increase in the hydrodynamic radius of casein micelles with bound surfactant at SDS concentration higher than 4 mM, and also an increase in the casein monomer molecule (or submicelles) at SDS concentration higher than 10 mM. Fluorometric results suggest the addition of SDS leads to some changes in the binding process of hydrophobic probes to casein micelles.     

Interaction between polyacrylamide and sodium dodecyl sulfate

Summary Some preliminar results about the interaction between -SDS and polyacrylamide reveal that without added salts, the two compounds mixt by keeping their own properties while, in salt presence, there is probably complex formation.

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Resumé Quelques résultats préliminaires de l'étude des interactions entre SDS et polyacrylamide montrent un comportement diffèrent en presence et en absence de sels; dans ce dernier cas seulement on peut s'attendre à la formation de complexes.

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With 3 figures     

Interaction of sulfate solutions of zinc with natural calcium carbonates

Precipitation of zinc from sulfate solutions onto carbonate rock was studied. The residual concentrations of zinc and the capacity of the precipitating agent were measured, and the mineral forms of zinc in the precipitate under various process conditions were determined.     

Photooxidative decomposition of sodium dodecyl sulfate in aqueous solutions

Kinetic features and the mechanism of photooxidative decomposition of sodium dodecyl sulfate in an aqueous solution under the action of pulsed short-wavelength UV light with a continuous spectrum upon introduction of hydrogen peroxide was studied.     

Amino acid hydration in aqueous magnesium and sodium sulfate solutions

We study the partial volumes of amino acids in aqueous magnesium and sodium sulfate solutions, which have a different effect on the structure of water, and calculate the structural parameters of hydrated complexes of NH ₃ ⁺ and COO^? groups: hydration numbers and water volumes inside and outside the hydration shell. The hydration numbers are given as a sum of the contributions of the interactions in the ternary (water-salt-amino acid) and binary (water-salt) systems.     

Enthalpies of reaction of calcium chloride and sodium oxalate in an aqueous NaCl solution

The heats of mixing of dilute aqueous solutions of calcium chloride and sodium oxalate with additions of 1–5 wt % NaCl at 298.15 K and the heats of dilution of calcium chloride solutions were measured. Increasing the sodium chloride content in a solution noticeably increases the time of precipitation of calcium oxalate. A fine precipitate of CaC₂O₄ formed in solutions containing 3 and 5 wt % NaCl is difficult to remove from the parts of a calorimeter cell. The enthalpies of precipitation of CaC₂O₄ depend slightly on the content of the “background electrolyte,” whereas the enthalpies of dilution, owing to ion association, significantly decrease in magnitude and become positive in a 5% NaCl solution. The “standard” enthalpy of precipitation in water, determined by extrapolation of the experimental values to the zero concentration of the background electrolyte, differs noticeably from the enthalpy of precipitation in water.     

Temperature-induced intermicellization and contraction in aqueous mixtures of sodium dodecyl sulfate and an amphiphilic diblock copolymer

Aqueous solutions of a thermoresponsive amphiphilic diblock copolymer, containing poly(N-isopropylacrylamide), in the presence of the anionic sodium dodecyl sulfate (SDS) surfactant can undergo a temperature-induced transition from loose intermicellar clusters to collapsed core–shell nanostructures. The polymer–surfactant mixtures have been characterized with the aid of turbidity, small-angle neutron scattering (SANS), intensity light scattering (ILS), dynamic light scattering (DLS), shear viscosity, and rheo-small angle light scattering (rheo-SALS). In the absence of SDS, compressed intermicellar structures are formed at intermediate temperatures, and at higher temperatures further aggregation is detected. The SANS results disclose a structure peak in the scattered intensity profile at the highest measured temperature. This peak is ascribed to the formation of ordered structures (crystallites). In the presence of a low amount of SDS, a strong collapse of the intermicellar clusters is observed at moderate temperatures, and only a slight renewed interpolymer association is found at higher temperatures because of repulsive electrostatic interactions. Finally, at moderate surfactant concentrations, temperature-induced loose intermicellar clusters are detected but no shrinking was registered in the considered temperature range. At a high level of SDS addition, large polymer–surfactant complexes appear at low temperatures, and these species are compressed at elevated temperatures. The rheo-SALS results show that the transition structures are rather fragile under the influence of shear flow.