SrCl2:Co++EPR谱电场效应的理论解释

本文从理论上研究了[111]方向电场对SrCl₂:Co⁺⁺的EPR谱的影响。结果表明:外电场使晶格发生畸变而偏离原来的O_h对称,成为C_3v。由此圆满地从理论上解释了零场分裂因子D随电场强度E线性变化的实验规律,并从理论上预言了晶格在平行电场方向的变化率为α=—8×10^-5α₀mm/kV,在垂直电场方向的变化率β=1.66×10^-4α₀关键词：     

Deuteron quadrupole coupling in formaldehyde

The hyperfine structure of the 1₁₀-1₁₁ rotational transition of D₂CO has been observed with a beam-maser spectrometer and the spin-rotation and electric quadrupole coupling constants have been determined. Using previously reported measurements on HDCO, the complete electric field gradient tensor at the position of the deuteron has been evaluated.     

Influence of a magnetic field on the mutual rectification of alternating currents induced by electromagnetic waves in graphene

The direct component of the electric current induced in graphene placed in a constant magnetic field has been found in the case where two electromagnetic waves with two mutually perpendicular planes of polarization are normally incident on the surface of the sample. It has been demonstrated that the direct component of the current along the direction of the electric field vector of the wave with the frequency ω₁ arises only when the ratio between the frequencies of the incident waves is ω₁/ω₂ = 2 or 1/2. In the latter case, the direct current component appears only in the presence of a magnetic field.     

Effect of electric field on the smeared phase transition in crystals PbIn1/2Nb1/2O3-28PbTiO3 and PbIn1/2Nb1/2O3-37PbTiO3

The effect of a direct-current electric field (0 < E < 3 kV/cm) on the smearing of the phase transition and the Curie-Weiss exponent (γ) for two PbIn_1/2Nb_1/2O₃-28PbTiO₃ and PbIn_1/2Nb_1/2O₃-37PbTiO₃ crystals lying at different distances from the morphotropic phase boundary has been investigated. The universal Curie-Weiss law has been used to approximate the temperature dependences of the dielectric permittivity. It has been shown that the more remote is the crystal from the morphotropic phase boundary, the larger is the exponent γ and, consequently, the more smeared is the phase transition (in the zero field, γ = 1.67 and 1.49 for PbIn_1/2Nb_1/2O₃-28PbTiO₃ and PbIn_1/2Nb_1/2O₃-37PbTiO₃, respectively). It has been found that a weak electric field (no greater than 2–3 kV/cm) in the case of the more smeared phase transition almost does not affect the Curie-Weiss exponent, whereas for the PbIn_1/2Nb_1/2O₃-37PbTiO₃ crystal, this exponent decreases with increasing electric field strength and approaches γ = 1, which is characteristic of the conventional ferroelectric.     

Energetic barrier reduction at the carbyne film interface

An abnormal injection current density through SiO₂ has been observed recently for both signs of charge carriers in experiments with an oriented carbyne film grown on a SiO₂ layer. The absence of a surface leakage current and the insulating property of SiO₂ were experimentally proved. The temperature dependence of the current through SiO₂ showed low activation energy and confirmed the model of thermally activated injection. A strong influence of the electric field applied transverse to the carbon chains on the current through SiO₂ was observed. A model of energetic barrier reduction at the carbyne interface based on the hypothesis of transverse inter-chain hopping in the electric field was proposed. It was shown that a transverse electric field can be induced in a carbyne film as in one-dimensional media. The first organic light emitting device with a carbyne-based effective injector was fabricated.     

Parametric instability in a two-hole species semiconductor-plasma

The parametric excitation of a low frequency wave has been investigated analytically in a two-hole species semiconductor-plasma in the region of kl ? 1 using the hydrodynamic model of the plasmas in the presence of a high frequency oscillatory electric field (E₀ cos ω₀t applied along the X-axis) and a d.c. magnetic field B₀ normal to the electric field (along the Z-axis), the low frequency wave propagating in the X–Z plane making a very small angle θ with the X-axis. The system supports a purely growing unstable mode. The variation of the growth rate of the unstable mode has been studied over a wide range of system parameters for the specific case of an intrinsic GaAs crystal at 300 K. The oscillatory electric field can be obtained by irradiating the crystal with a 119μm H₂O laser.     

Sulfur dioxide (SO2) gas transfer process enhanced by corona discharge

The sulfur dioxide (SO₂) gas transfer process in a corona discharge field has been studied. The experiments were conducted to investigate the effects of voltage, length, and height of the discharge area on the electric transfer of SO₂ as well as on the desulphurization efficiency. Experimental results show that corona discharge can facilitate the SO₂ gas transfer process. The rate and efficiency of desulphurization increase with increasing voltage, length of discharge area, and input power. The addition of a uniform electric field to the corona-discharge field improves the electronic transfer of SO₂. Measured desulphurization efficiency was as high as 95%, and the augmentation of desulphurization efficiency due to corona discharge was nearly 50% under the conditions tested.     

Measurement of electron energy and density in an H. F. electrodeless ring discharge

The electron temperatureT _e and the electron density were measured as functions of the radial distance in a 10 Mc/s electrodeless ring discharge in hydrogen in the pressure range 0.1–0.3 Torr. It was found thatT _e remains nearly constant along the radius of the cylindrical vessel. The measured values ofT _e have been compared with those observed by other workers and an estimate of the effective electric field in the discharge has been made. From this estimate it has been inferred that even after the first stage of the ring discharge is well established the longitudinal component of the electric field remains of considerable importance. The radial density distribution of the electrons was found to be different from those in an uniform electric field. This deviation in the radial density distribution has been attributed to the influence of the azimuthal electric field.     

Phase transitions and optical properties in 〈001〉 (1−<Emphasis Type="Italic">x</Emphasis>)PbZn<Subscript>1/3</Subscript>Nb<Subscript>2/3</Subscript>O<Subscript>3</Subscript>−<Emphasis Type="Italic">x</Emphasis>PbTiO<Subscript>3</Subscript> single crystals

The effect of a constant electric field (0 < E < 5 kV/cm) on the optical properties of PbZn_1/3Nb_2/3O₃?xPbTiO₃ (PZN-xPT) crystals with x = 7 and 9% has been analyzed. It has been shown that, at temperatures close to the temperature of the transition from the rhombohedral [R(X)] phase to the tetragonal (T) phase, two induced phase transitions are observed in the electric field, which are associated with the appearance of new intermediate phases M_a and M_c [R(X)-M_a-M_c-T]. Correlation between these two transitions and the PbTiO₃ content x has been found. The E-T phase diagrams have been obtained. The M_c phase in PZN-9PT crystals is found to remain the ground state after the removal of the electric field, whereas the M_c phase in PZN-7PT crystals is metastable and is transformed into the M_a phase after the removal of the electric field.     

Investigation of quadratic stark effect on Rb D<Subscript>2</Subscript> atomic line

Experimental study of the influence of an electric field on the atomic hfs levels of D₂ line of Rb atom, transitions 5S _1/2 ? 5P _3/2, has been performed. For this purpose a sapphire cell with internal electrodes used to produce a constant electric field was elaborated. By using the saturation absorption technique the frequency shifts of all 12 atomic D₂ line transitions were recorded. The results are compared with the theory.     

Transient energy transfer between writing beams during hologram formation in Bi12GeO20

A large transient energy transfer between writing beams during volume phase-hologram formation in Bi₁₂GeO₂₀ has been observed. The variation of the energy transfer by applying an external field and by changing the fringe spacing of the elementary holograms have been measured and described in the framework of Kukhtarevs nonlinear theory of transient self-diffraction. The results indicate that the transient energy transfer in Bi₁₂GeO₂₀ is due to a non-stationary phase mismatch between the intensity- and refractive index grating caused by photoconductivity and that the transient energy transfer increases with increasing fringe spacing and increasing applied electric field. Up to ten-fold amplification of coherent beams has been measured, corresponding to an exponential gain of Г = 2 cm^-1. A continuous energy transfer has been observed when the phase between recording beams was changed linearly with time during recording. It is shown that light is coherently amplified for electric field strengths larger than 2.3 kV/cm and that a peak amplification factor of Г₁ = 2 cm^-1 has been reached for E₀ = 11 kV/cm.     

外电场作用下Si_2O分子的激发特性

主要对2种Si2O分子异构体的激发特性进行研究,由计算结果可知,外电场对Si2O分子的激发能,振子强度,跃迁偶极矩及吸收光谱有着显著的影响.无外电场时三角型Si2O(C2v,1A1)分子在可见光区无吸收谱,外电场作用下其在可见光区(407.18—526.93nm)有比较弱的吸收谱.直线型Si-Si-O(C∞v,3Σ-)分子在有无外电场作用时在蓝光和紫光区均有一定的吸收谱,其中比较难得的是在蓝色光区(478.88—488.59nm)呈现较强的吸收谱.     

Parametric excitation of acoustohelicon waves in a piezoelectric semiconductor

The parametric excitation of acoustohelicon waves has been studied in a piezoelectric semiconductor in the presence of a strong high frequency oscillatory electric field. The threshold electric field amplitude and the growth rate of the unstable mode have been obtained analytically and for n-InSb at 77 K the unstable mode is found to be propagating with a growth rate ～10³ s^?1 when the crystal is irradiated with a 10.6 μm CO₂ laser.     

Temperature defendence of the hyperfine interaction in (NH4)2ZrF6

The thermal evolution of the hyperfine quadrupole interaction in (NH₄)₂ZrF₆ has been investigated via TDPAC from 14 to 400 K. A phase transition is detected near 370 K. The low-temperature phase exhibits two sites equally populated for¹⁸¹Ta probes. The associated electric field gradients are described by both high asymmetry parameters and high interaction frequencies. On the other hand, the high-temperature phase corresponds to an unique axially symmetric and more intense electric field gradient.     

Optical and acoustic properties of 33PbIn1/2Nb1/2O3-35PbMg1/3Nb2/3O3-32PbTiO3 single crystals in an electric field

The influence of different conditions of applying a dc electric field (0 < E < 4 kV/cm) on the behavior of optical transmission and on the acoustic parameters (sound velocity and attenuation) in the [001]- and [011]-oriented single crystals 33Pb(In_1/2Nb_1/2)O₃-35PbMg_1/3Nb_2/3O₃-32PbTiO₃ existing near the morphotropic phase boundary has been investigated. It has been found that the optical transmission, sound velocity, and attenuation sharply change near the phase transition in a narrow range of electric fields for any method of their applying. In the field applied along [001], the change in the sound velocity due to the phase transition is 1.5 times greater than that in the field applied along [011]. This is caused by a larger contribution of the piezoelectric effect to the elastic modulus determining the sound velocity along [001] as compared to [011]. It has been shown that the number, symmetry, and stability of the phases formed in the field depend on the conditions of applying the field.     

Hole-stimulated transfer of traps in dielectrics

The transport of traps in a dielectric after capture of holes in an electric field is considered with the inclusion of the two-band conduction. The distance covered by a trap with a trapped hole decreases exponentially with an increase in the electric field. A value of 3 × 10^–15 cm²/(V s) has been determined for the mobility of traps with trapped holes in Si₃N₄.     

PAC study of CdFe2O4 and ZnFe2O4

The time-differential perturbed angular correlation technique has been used to study the temperature dependence of the electric-field gradient at ¹¹¹Cd nuclei in the spinels CdFe₂O₄ and ZnFe₂O₄. The samples were doped with radioactive ¹¹¹In tracers which decay to ¹¹¹Cd by electron capture. For both compounds the results of the measurements show the presence of two electric quadrupole interactions. One is well defined and corresponds to a fairly symmetrical electric field gradient. The other is broadly distributed and corresponds to electric field gradients with lower symmetry. The fractions of probes associated with these interactions are temperature dependent. The interactions are analysed taking into account the possible sites in the spinel structure for In occupation. The results are compared with those obtained with other spinels. The electric field gradient associated with the octahedral site is compared with the predictions of point charge model and with Mössbauer spectroscopy results at iron site.

     

静电场中Ca原子里德堡态的能级结构

用两步激发和光电离方法,在0—8kV/cm电场范围内,测定了Ca原子n=10至n=13附近m=0的Stark光谱。实验结果显示,3d²³P₀及3d²³P₂价态受到n=12Stark簇的排斥。观察到与价态有关的干涉现象及其随电场大小的改变。讨论了零场非简并态、价态及Stark簇之间的能级交叉和抗交叉结构。     

Optical and dielectric anomalies in PbIn1/2Nb1/2O3-xPbTiO3 crystals in an electric field

A study is reported of the effect produced by application of a dc electric field (0 < E < 5 kV/cm) in different regimes on structural phase transformations and behavior of the phase boundary in [001]-oriented PbIn_1/2Nb_1/2O₃-37PbTiO₃ single crystals (starting composition) near the morphotropic phase boundary. The dielectric methods have been complemented for the first time by optical probing. It has been demonstrated that the content of PbTiO₃ in the samples under study is less than that in the starting composition. A suggestion is advanced that, in the samples studied, the stable room-temperature state with no electric field applied is that formed in the mixture of the rhombohedral R and monoclinic M _a phases. It has been found that the number, symmetry, and stability of the phases formed in a field depend on the regime of field application. The E-T phase diagrams have been constructed for different field application regimes. Phase diagrams obtained for the same crystal have been shown to differ for different regimes of field application.     

Effect of the la concentration on the dielectric and optical properties of the transparent ferroelectric ceramics 75PbMg<Subscript>1/3</Subscript>Nb<Subscript>2/3</Subscript>O<Subscript>3</Subscript>-25PbTiO<Subscript>3</Subscript>

The dielectric, optical, and electro-optical properties of transparent ferroelectric ceramics 75PbMg_1/3Nb_2/3O₃-25PbTiO₃ (75PMN-25PT) with different La concentrations (2, 3, and 4 at %) have been studied. It has been shown that all the samples under study undergo a diffuse phase transition, and the degree of diffuseness increases with an increase in the La concentration. The temperature dependences of the optical transmission in different regimes of applying an electric field and the quadratic electro-optical effect have been investigated. It has been found that, at room temperature, the maximum electro-optical effect is observed in the ceramics with a La concentration of 3 at %. This is explained by the fact that the measurement temperature is close to the Vogel-Fulcher temperature at which the minimum electric field is required to induce ferroelectric states from the relaxor phase.