Measurements of the intermediate field magnetization of a random exchange heisenberg antiferromagnetic chain,quinolinium(TCNQ)2

Measurements of the relative magnetization (M) and linewidth (ΔH$\text{1}\text{2}$) of quinolinium(TCNQ)₂ are reported using ESR at 9.5 GHz over the temperature range 0.054–4.2 K. The experiment was performed in a dilution refrigerator using an unconventional microwave technique. Throughout the entire temperature range, M fits the behavior expected of a random exchange Heisenberg antiferromagnetic chain on the basis of the ECP or Bulaevskii models using an exponent α = 0.81 ± .03. The linewidth has a slow, logarithmic divergence with decreasing temperature similar to that reported earlier for low frequency measurements.     

The renormalization of the string operator in QCD

We shall observe that the renormalization of the string operator U(x₁, x₂; C) = Pexp{ig∫_x1^x2dx_μA^μ(x)} with an open path C (smooth and non-intersecting) is path-independently performed in any order of perturbation. To demonstrate this, the renormalization constants will be calculated up to order g⁴. Next the renormalization effect on the algebraic identity $\text{U(x}{}_1\text{, x}{}_2\text{;}\text{C}\text{)U(x}{}_2\text{, x}{}_3\text{;}\text{C}\text{) = U(x}{}_1\text{, x}{}_3\text{;}\text{C}\text{∪}\text{C}\text{)}$ will be discussed and it will be proved that the renormalization preserves the algebraic identity in any order of perturbation if the paths C and $\text{C}$ are smoothly connected at x₂. Finally, the string operator renormalization is extended to the case when the path C is smoothly closed (the Wilson loop operator). It is then shown that the renormalization factor which multiplicatively renormalizes the string operator in the case of the open path, is cancelled in any order of perturbation by the divergence appearing in the coincidence of the end points. As a results, the Wilson loop operator can be renormalized by the coupling constant renormalization alone.     

One-dimensional magnetism in N2H6FeF5,

A new Fe(III) fluoride N₂H₆FeF₅ has been investigated by magnetic susceptibility measurements and Mössbauer resonance. It has a one-dimensional magnetic behaviour. The intrachain exchange integral ($\text{J}\text{k}\text{= -10.2}\text{K}$) has been determined by fitting the χ^-1 = f(T) curve and the ratio between the inter- and intrachain exchange integrals evaluated with Oguchi's formula. Below T_N = 9 K, N₂H₆FeF₅ shows a long range three-dimensional anti-ferromagnetic ordering.     

Neutral heavy lepton candidate in e+e− interactions

An event of the form e⁺e^? → μ⁺μ^? + (2 jets) recently observed at √s = 43.45 GeV is interpreted as production of a pair of neutral heavy leptons N, each with mass 20.5 ± 1.0 Gev/c². Two possibilities are explored: (i) the lepton is a wak isodoublet neutrino, produced in pairs by virtual Z⁰ decay. In this case, one expects $\text{B(}\text{Z}{}^0\text{→}\text{N}\text{N}\text{) ≈ 5\%}$; (ii) the lepton is a “right-handed neutrino”, produced in pairs via a new vector boson Z_χ. In this case, in one model, the Z_χ must lie between about 50 and 67 GeV/c². More generally, it must be very weakly coupled to ordinary quarks and leptons in order not to conflict with low-q² neutral-current data. Suggestions are made for further observation of N$\text{N}$ pairs and other effects of Z_χ in forthcoming e⁺e^? and p$\text{p}$ collisions.     

A semiclassical formula for the topological susceptibility in a finite space-time volume

The volume dependence of the topological susceptibility (Q: topological charge, V: space-time volume in four-dimensional non-abelian gauge theories is studied. For small volumes, χ_t^V is shown to be dominated by the one-instanton contribution and is therefore analytically calculable. It turns out that χ_t^V increases monotonically with V. If this property continues to hold beyond the small volume range, a lower bound on χ_t = lim_V→∞χ_t^V can be obtained. For an SU(3) gauge group it reads χ_t?5Λ_MS⁴.     

Anomalous optical response with variation in band filling in linear chain conductors

We report the polarized infrared reflectance of ($\text{N}$-methylphenazinium)_x (phenazine)_1-x(tetracyanoquinodimethanide), (NMP)_x(Phen)_1-x(TCNQ) for 0.5≤x≤1.0. We demonstrate that the “Drude edge” in TCNQ salts is related to the conduction electron charge density. An anomalous rapid red shift of the plasma frequency, observed for $\text{x ～}\text{2}\text{3}$, may signal the emptying of the conduction electrons from half of the chains and/or a crossover from small U/W (coulomb repulsion/bandwidth) to large U/W behavior.     

Anomalies in the elastic constants of antiferromagnetic uranium mononitride

Measured anomalies in the elastic constants of a single crystal of cubic anti-ferromagnetic uranium mononitride are reported. A dip of about 10% occurs in C₁₁ at 6 K below the Néel point $\text{T}{}_{\mathrm{<mtext>N</mtext>}}\text{?53}\text{K}$. Starting at T_N a renormalization in C₄₄ which is proportional to the square of the sublattice ,magnetization also occurs. The results are in general agreement with model calculations of the sound velocity renormalization due to spin-phonon interactions.     

Magnetization process and principal magnetic susceptibilities in RbMnF3

The temperature dependence of χ_⊥, initialχ_p (powder), and evaluated χ_∥ for RbMnF₃ are reported for the temperature range of 4.2–106 K. A shallow minimum at $\text{T}\text{T}{}_{\mathrm{N}}\text{? 0.72}$ is observed in χ_⊥. The field dependence of the magnetization shows a smooth rotation of the spins to a normal direction above H_c ? 2.43 kOe at 4.2 K.     

Measurement of hadronic production of the χ1++(3507) and the χ2++(3553) through their radiative decay to Jϕ

The _χ1⁺⁺(3507) and the _χ2⁺⁺(3553) states have been observed in the Goliath spectrometer at the CERN SPS in 185 GeV/cπ^?-Be collisions. Their radiative decays contribute 27.7% (for the χ₁⁺⁺) and 12.8% (for the χ₂⁺⁺) to $\text{J}\text{?}$ production. At this energy, their cross sections are 65±19 nb and 96±29 nb, respectively     

Electronic-excitation transfer collisions in flames—V. Cross sections for quenching and doublet-mixing of K(42P)-doublet by N2, O2, H2 and H2O

Weighted average cross sections for quenching of the K(4²P)-doublet by N₂, H₂, O₂ and H₂O, measured in flames, show no significant temperature dependence in the range from 1500 to 2500K. Doublet mixing cross sections for K(4²P$\text{3}\text{2}$?4²P$\text{1}\text{2}$) transitions were measured at 1720K for N₂, O₂, H₂O. The ratios of both mixing cross sections were measured independently and were found to agree with the detailed balance condition within 2 per cent. It is shown that an ionic intermediate-state model cannot explain the large magnitude of N_2? mixing cross sections.     

Displacive surface phases formed by hydrogen chemisorption on W {001}

A detailed LEED study is reported of the surface phases stabilised by hydrogen chemisorption on W {001}, over the temperature range 170 to 400 K, correlated with absolute determinations of surface coverages and sticking probabilities. The saturation coverage at 300 K is 19(± 3) × 10¹⁴ atoms cm^?2, corresponding to a surface stoichiometry of WH₂, and the initial sticking probability for both H₂ and D₂ is 0.60 ± 0.03, independent of substrate temperature down to 170 K. Over the range 170 to 300 K six coverage-dependent temperature-independent phases are identified, and the transition coverages determined. As with the clean surface $\text{(}\text{2}\text{×}\text{2}\text{)R45°}$ displacive phase, the c(2 × 2)-H phase is inhibited by the presence of steps and impurities over large distances (～20 Å), again strongly indicative of CDW-PLD mechanisms for the formation of the H-stabilised phases. These phases are significantly more temperature stable than the clean $\text{(}\text{2}\text{×}\text{2}\text{)R45°}$, the most stable being a c(2 × 2)-H split half-order phase which is formed at domain stoichiometries between WH_0.3 and WH_0.5. LEED symmetry analysis, the dependence of half-order intensity and half-width on coverage, and I-V spectra indicate that the c(2 × 2)-H phase is a different displacive structure from that determined by Debe and King for the clean $\text{(}\text{2}\text{×}\text{2}\text{)R45°}$. LEED I-V spectra are consistent with an expansion of the surface-bulk interlayer spacing from 1.48 to 1.51 Å as the hydrogen coverage increases to ～4 × 10¹⁴ atoms cm^?2. The transition from the split half-order to a streaked half-order phase is found to be correlated with changes in a range of other physical properties previously reported for this system. As the surface stoichiometry increases from WH to WH₂ a gradual transition occurs between a phase devoid of long-range order to well-ordered (1 × 1)-H. Displacive structures are proposed for the various phases formed, based on the hypothesis that at any coverage the most stable phase is determined by the gain in stability produced by a combination of chemical bonding to form a local surface complex and electron-phonon coupling to produce a periodic lattice distortion. The sequence of commensurate, incommensurate and disordered structures are consistent with the wealth of data now available for this system. Finally, a simple structural model is suggested for the peak-splitting observed in desorption spectra.     

Microwave spectrum of dimethyldichlorosilane

The microwave spectrum of dimethyldichlorosilane has been observed and the rotational constants and centrifugal distortion constants have been determined for ³⁵Cl₂ and ³⁵Cl³⁷Cl species. From these constants, the molecular structure is determined as $\text{r(}\text{SiCl}\text{) = 2.055 ± 0.003}\text{A}\text{?}$, $\text{r(}\text{SiC}\text{) = 1.845 ± 0.005}\text{A}\text{?}$, ∠ClSiCl = 107.2 ± 0.3°, ∠CSiC = 114.7 ± 0.3°. An analysis of the ³⁵Cl₂ quadrupole splittings leads to quadrupole coupling constants of χ_aa = ?19.6 ± 0.3 MHz, χ_bb = ?3.7 ± 1.4 MHz, χ_cc = 23.3 ± 1.4 MHz, χ_bond = ?38.0 ± 1.6 MHz, and η_bond = 0.22 ± 0.08.     

Exact Fermi energy,susceptibilities, and their singularities for an electron gas in a uniform magnetic field at T = 0 °K

Exact analysis is presented to derive the magnetic response functions and their singularities of free-electron gas in a uniform magnetic field of arbitrary strength at T = 0 °K. The newly defined functions, Λ_μ(s) = ∑₀^[s])(s ? n)^μ of $\text{μ =}\text{?1}\text{2}\text{,}\text{1}\text{2}\text{,}\text{3}\text{2}$, are employed to obtain the Fermi energy, magnetization, and susceptibility as functions of B. It is revealed that the spin susceptibility is composed of two parts, χ_s1 and χ_s2, where χ_s2 is purely oscillatory diamagnetic. A graphical method of finding the Fermi energy ?_F(B) as a function of B has been obtained. The system is shown to become totally one-dimensional electron gas in the field B greater than $\text{B}{}_{\mathrm{\downarrow }}\text{= (2ηn)}{}^{\mathrm{<mtext>2</mtext><mtext>3</mtext>}}$ and the total energy satisfies $\text{E}{}_{\mathrm{t}}\text{=}\text{1}\text{3}\text{?}{}_{\mathrm{F}}\text{(B)N}$. The obvious extension of the present theory to the Bloch electrons on the ellipsoidal constant energy surface is also discussed.     

The paramagnetic susceptability of neutron irradiated V3Ge single crystals

The paramagnetic susceptibility χ of V₃Ge single crystals was measured in the temperature range from 10 K to 350 K after irradiation with neutron fluences of $\text{(0.3?20) × 10}{}^{18}\text{n}\text{cm}{}^2\text{(E>1}\text{MeV}\text{)}$. Unirradiated crystals show a flat maximum at T=65±6 K, which disappears at high neutron doses. The temperature dependence and the absolute values of χ are continuously reduced by increasing neutron doses. This behaviour can be understood by the models of high density of states (DOS) proposed for A15 materials confirming the assumption that a sharp peak in the electronic density of states exists which is lowered and broadened by irradiation induced defects.     

NMR study of one-dimensional ionic conductor with hollandite-type structure. II. Frequency dependence of spin-lattice relaxation time of 27Al

Frequency dependence of spin-lattice relaxation time T₁ of ²⁷Al in one-dimensional K⁺ ion conductor, K-Al-priderite, was measured at 45 K in the frequency range from 10.1 MHz to 55 MHz. It is found that T₁ is proportional to ω^1.49±0.05 and agrres well with the $\text{ω}{}^{\mathrm{<mtext>3</mtext><mtext>4</mtext>}}$ dependence derived by the continuum diffusion model. The intrinsic activation energy is determined to be 0.058 eV by doubling the slope E_NMR=0.029 eV of the d(ln T₁)/dT curve in the low temperature region. The frequency dependence of T₁ in the high temperature region measured in the frequency range from 11.5 MHz to 20.8 MHz shows a tendency that the frequency dependence becomes smaller than the $\text{ω}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ dependence as temperature is raised above 450 K.     

Peierls transitions in semimetallic one dimensional charge transfer salts

Peierls transitions in one dimensional charge transfer salts in which both donor and acceptor molecules have even valency such as TTF-TCNQ have been studied. Transitions involving macroscopic occupation of phonon states of wavevector $\text{k}{}_{\mathrm{<mtext>F</mtext>}}\text{(TTF)}\text{+ k}{}_{\mathrm{<mtext>F</mtext>}}\text{(TCNQ)}\text{=}\text{1}\text{2}\text{G}$ and |k_F(TTF) ? k_F (TCNQ)| can occur as well as transitions of wavevector 2k_F(TTF) [and 2k_F(TCNQ)].     

Thermodynamics of ternary Fe-Ni-N-austenites

Measurements, in the range 1140–1548 K, of the temperature variation of the solubility of nitrogen at constant pressure (1.04 × 10⁵ Pa) in Fe-Ni fee solid solutions in equilibrium with N₂ gas, show that the partial molar enthalpy $\text{H}$_i of the nitrogen atoms is invariant to the nickel concentration up to 15 atm % Ni. In the same temperature range the partial molar excess entropy $\text{S}$^xs_i exhibits a slight decrease with increasing nickel concentration.The thermodynamic data are consistent with the cell model for ternary solid solutions in which the nickel atoms create shallow trapping sites for N-atoms, deeper by only 4.9 kJ/mol than interstitial sites in binary Fe-N solutions.The variation in H_i with nickel content due to the distribution of N atoms in energetically differing cells is of about the same size, but opposite in sign, to the contribution to $\text{H}$_i ascribable to the change in specific density of the substitutional lattice with varying Ni content.     

2kF and 4kF charge-density waves in TTF0.4TSeF0.6-TCNQ — An X-ray study

In the quasi one-dimensional conductor TTF_0.4TSeF_0.6-TCNQ, it is found that the 2k_F CDW has three-dimensional correlations of relatively long range below the metal-insulator transition temperature ～40K, although the 4k_F CDWs are only one-dimensional in character at all temperatures. This result supports the speculation that the 2k_F CDWs and the 4k_F CDWs are present predominantly on the TCNQ and the fulvalene stacks, respectively. The 2k_F-value of the present material is similar to that of TTF-TCNQ but far from that of TSeF-TCNQ. The change of the value with the concentration of TSeF (or TTF) is nonlinear. The transverse period of the ordered 2k_F CDW along the a-axis is $\text{a}$ just below the transition temperature and becomes 4$\text{a}$ below 34.5K. A discussion is given based on the two-chain model.     

Electrical conduction and 1ƒ noise in Li-DOPED MnO

Electrical resistivity, thermoelectric power and current noise were measured on Li-doped MnO single crystals in the temperature range from 300 to 1000 K. Below 700 K the crystals are p-type and the activation energy of the resistivity is 0.75 eV. Around 700 K the activation energy changes from 0.75 to 1.25 eV owing to a change from p- to n-type conduction. The depth of the Li acceptor is found to be 0.65 eV. From resistivity and thermoelectric power data it is concluded that the bandgap in first approximation can be written as E_s(T) = E_o ? γT between 750 and 1000 K, with E_o = 1.9 eV and γ = 6 × 10^?4 eV/K. The current noise spectra show $\text{1}\text{?}$ noise. The magnitude of the $\text{1}\text{?}$ noise is strongly temperature dependent. From the noise data it is deduced that E_o = 2.2 eV and γ = 10^?3 eV/K in the temperature range 430–700 K.