Solubility of Na2Co3 in NaCl:CaCl2 crystals

Measurements of electrical conductivity of NaCl 10^–5 molar fr. CaCl2 (1–80)×10^–5 molar fr. Na₂CO₃ crystals have been used to determine the temperature dependence of the solubility of CO₃-ions over the temperature range from 75 to 530 °C. The total solubility of CO₃-ions and that of [CO ₃ ^2– -vacancy] complexes may be expressed by simple relationships andc _ka=3·19× 10^–2 exp (–0·25 eV/kT), resp. The heat of solution of complexes is equal to 0·25 eV and that of free CO ₃ ^2– ions is higher than 1·2 eV. Under conditions of the thermal equilibrium between the solid solution and precipitate, the ratio of Na₂CO₃ and CaCO₃ components in the precipitate has been calculated at various temperatures and CO₃ concentrations.     

Decay of Hf172

The internal conversion spectrum of Hf¹⁷² was examined with an intermediate image magnetic spectrometer. The gamma-ray spectrum and gamma-gamma coincidence spectrum were studied by means of scintillation spectrometers. The half-life of the 65·9 keV excited level in Lu¹⁷² was found to beT _1/2 = (3·32±0·20) × 10^–7 sec. The proposed decay scheme is discussed.On the same apparatus the half-life of the 206·25 keV excited level in Re¹⁸⁷ was measured and the result isT _1/2 = (5·05±0·13) × 10^–7 sec.The authors wish to thank to Ing. Vobecký and Ing. Matalka for the separation of Hf and Z. Praáková for assistance in the numerical calculation.     

Magnetic properties of amorphous Bi2DyFe5O12

Amorphous Bi₂DyFe₅O₁₂ films have been prepared by rf sputtering technique. The magnetic properties, structure and effect of annealing have been investigated. The magnetization increases with increasing magnetic field and is not saturated at a high magnetic field of 65 kOe. In the temperature range 20 K<T<200 K the susceptibility can be described by a Curie-Weiss law with a Weiss constant of =–15 K. The effective paramagnetic moment for the iron ion (4.1 _B ) is much smaller than the theoretical moment (5.9 _B ). Above 200 K the slope in ^–1 vsT curve changes. The Weiss constant and effective paramagnetic moment for the iron ion increase. After annealing above 600°C the amorphous samples crystallize to a single garnet phase with the magnetization of 21 emu/g at 1.5 K and 7.2 emu/g at 300 K, which are the same as those of the bulk Bi₂DyFe₅O₁₂ garnet ferrites.     

Inclusive production of φ-mesons in neutron-proton interaction at 30–70 GeV/c

A signal of the-K⁺K^– decays has been observed in neutron-hydrogen interactions at energies of 30–70 GeV in an experiment using the BIS-2 spectrometer. The longitudinal momentum spectrum in the forward region,x _F<0·1 atp _T<1 GeV/c, can be well described by a power law dependence (1–x _F)^N withN=4·28±0·42. Thep _T ² -spectrum has been parametrized by the exp(–Bp _T ² ) law with the exponentB=(3·02±0·55) (GeV/c)^–2. The extrapolation of the measured cross section to the full kinematic region yields a value of (220±85) b in agreement with measurements from the proton beams.     

High-resolution measurements of thermal expansion along the uniqueb-axis of squaric acid

The thermal expansion of squaric acid along the uniqueb-axis was measured between 323 K and 418 K with a resolution of 2·10^–7 in strain and 5·10^–4 K in temperature using a capacitance dilatometer. The anomaly associated with the antiferro-electric phase transition occuring atT _c=373.5 K was observed over the rangeT _c–50 K<T<T _c+7 K. The regular lattice expansion follows a generalized Grüneisen's law with a Debye-temperature _D =660 K and a uniaxial pressure-dependence of _D /p _b . The critical behaviour close toT _c was studied with a sweep rate of 36 mK/h. A hyteresis loop of width 23 mK was observed in the strain curve, indicating a 1st order transition. However, no discontinuity in dilatation was observed, and therefore the transition is close to a multicritical point. The anomalous increase in the expansion coefficient can be described with critical exponents ==0.56 in the interval 0.4 K<|T–T _c|<12 K. Closer toT _c the divergence is stronger. A generalized Pippard relation between the expansion coefficient and specific heat holds to within 1 K from the transition point. The inconsistencies apparent closer toT _c are interpreted as a consequence of a weak 1st order transition.     

Electromagnetic decay of the 6+ isomer of102Rh

Conversion electrons, and X rays from¹⁰²Rh^m (6⁺,T _1/2=1057 d) have been studied. An electromagnetic branch (2.3±0.3) ·10^–3 feeding the¹⁰²Rh first excited state has been observed in the 6⁺ isomeric decay. The excitation energy of the 6⁺ isomer turns out to be 140.7 keV above the 2^– ground state.We wish to thank P. Del Carmine, M. Ottanelli, and A. Pecchioli for their skillful collaboration during the measurements and the Technical Staffs of LNS and LNL for operation of the Tandem Accelerators.     

The effect of low-temperature electron irradiation on the transition temperature of YBa2Cu3O7−δ superconductors

Measurements of the complex susceptibility =–i of electron-irradiated YBa₂Cu₃O_7– show a strong influence of the electron irradiation dose, ·t on the transition temperatureT _c . For irradiation doses of ·t=2.2·10¹⁹ e^–/cm² we find a damage rate of T _c /(·t)=–1.6·10^–19 K/(e^–/cm²). It is assumed that the decrease ofT _c is mainly a bulk effect due to the production of atomic defects like vacancies and interstitials in the Cu–O–Cu chains and in the basal planes of the unit cells.     

Decay of Cs134m

The decay of the isomeric state of Cs¹³⁴ was studied. The decay half-timeT _1/2=2·93±0·05 hours was determined. From measurements carried out by means of a spectrometer with short lens, scintillation measurements and chemical separations, the non-existence of the weak decay of this state was proved, contrary to statements found previously in the literature (maximum possible intensity 0·02%, compared to the value of 1% found in the literature). The spectrum of conversion electrons was measured by a double-focusing spectrometer, and the following transition energies were determined: 127·3±0·3 keV (E3) and 138·4±0·4 keV (M4) (K:L:M+N is 92 100 27 for the 127·3 keV transition, and 206 100 31 for the 138·4 keV transition). The conversion coefficient of the 127 keV transition was measured, resulting in a value of _k =2·55±±0·4. The ratio of transition intensities isI ₁₃₈ I ₁₂₇=5·7 1000.     

Anomalous internal conversion ofE1 transitions in outer atomic shells

The experimentalN andO shell conversion coefficients of highly hinderedE1 transitions were found to be anomalous. The discrepancies as well as those for theL andM shells were removed by using the following values of the nuclear current parameter: 9·2±0·1 for the 6·21 keV transition in¹⁸¹Ta, 8·5±0·5 or –7·5±0·5 for the 84·20 keV transition in²³¹Pa and 1·9±0·2 for the 26·38 keV one in²³⁷Np.     

The dependence of the neutron temperature on the geometric parameter for water and loose diphenyl

The dependence of the neutron temperatureT _n on the geometric parameterB ² was measured by the pulse method in water and loose diphenyl. The measurements were made on a moderator poisoned by cadmium sulphate, a substance whose absorption cross-section is non 1/v.The following results were obtained: For waterT _n [eV]=–(0·00391±0·00045)B ² [cm^–2]+(0·02537±0·00035) for loose diphenyl:T _n [eV]=–(0·01014±0·00152)B ² [cm^–2]+(0·02518±0·00054).We are indebted to J. Jirou and J. Jadavan for their assistance in the measurements, the accelerator operation and electronic apparatus maintenance.     

Heterodiffusion of Cr in molten Fe in the temperature range 1800 to 1970 K

Heterodiffusion of Cr has been studied using the method of thin layer and the radionuclide⁵¹Cr. The diffusion characteristics determined from the experimental results in the temperature range 1800 KT1970 K areD _o=1·59×10^–2 cm²/s andE=22·3±1·6 kcal/mol. The experimental method is discussed in detail and the results are compared with those of other authors.     

The183Re ground state dipole moment and nuclear spin-lattice relaxation of Re in Fe

The hyperfine interaction of the system¹⁸³Re(70d)Fe has been investigated with the NMR/ON technique. With the hyperfine field valueB _hf(ReFe)=–76.0(1.5) T the ground state magnetic moment was determined as: (5/2⁺,¹⁸³Re)=+3.12(6) _N. The field dependent nuclear spin-lattice relaxation time has been measured. The result for the high-field relaxation rateR _exp=1.65(5)·10^–15 T ²s K^–1 is explained in terms of indirect spin-wave interaction.     

Some physical properties of KCl+Pb2+ crystals

This paper presents the results of measurements of the mechanical and electrical properties of as-received pure and lead-doped crystals of potassium chloride. The critical resolved shear stress of the crystals obeys the Franks relationship in the whole concentration range. In addition, the correlation between ₀ and the Vickers hardness numberH was found and the equation is of the form ₀=k (H–H ₀). The solubility of Pb²⁺ in as-received KCl crystals was observed, from measurements of the electrical conductivity, to be low—the successive saturation of the solid solution started already in an environment of 5 mole ppm in agreement with data from the mechanical measurements. The density of cation vacancies and their mobility were represented by the following euqations ₁ T=6·25×10⁴ exp(–·75/kT) cm² K/volt. sec,n ₁=6·95×10²³ exp(–2·12/kT) vacancies/cm³ The value of 0sd46±0·02 eV was found as a rough estimate of the association energy.The authors wish to express their thanks to Professor Dr. J. Z.Damm and Ing. E.Mariani for their stimulating interest in the present work.     

Electrical properties of p-type ZnGeP2 irradiated by H+ ions

The properties of p-type ZnGeP₂ [p₀=(5–10)·10¹⁰ cm^–3, ₀=(2–5)·10^–7 (·cm)^–1], irradiated with H⁺ ions [E=5 MeV, T_irr=300 K, D=(1·10¹²–1.7·10¹⁶) cm^–2] are studied. An increase in the resistivity (to gr_max - 5·10¹¹ ·cm) and subsequent reduction in for large currents of H⁺ ions ( - 9·10⁸ ·cm for D - 1.7·10¹⁶ cm^–2), is observed in irradiated crystals. The resistivity of irradiated p-type ZnGeP₂ is found to be very sensitive to hydrostatic pressure [(4–5)·10^–5 bar^–1]. The annealing of radiation defects in the temperature interval (20–600) °C is examined.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 91–93, October, 1991.     

The hall effect in PdSi-based amorphous alloys containing Co.

The Hall effect in amorphous Pd₈₀Si₂₀ and Pd_80–x Si₂₀Co _x , wherex=2, 4, 6 (at.% are implied throughout) alloys was investigated. Measurements were carried out at r.t. in fields up to 17·5 kG. Also the electrical conductivity was measured. The Hall effect was found negative in all alloys of the above composition. Observedx-dependence of the Hall constantR _H tends to change the sign of the effect and is interpreted on the assumption that an extraordinary Hall effect manifests itself besides the ordinary one in Co-containing alloys. The value ofR _H for the basal alloy should be looked upon as an evidence of electron transfer from glass-former (Si) to transition metal (Pd) empty d-states. The values ofR _H obtained for the alloys withx=0, 2, 4, 6 are respectively, –7·8; –8·7; –8·3; –5·2 (×10^–5 cm³/A. sec throughout).     

VUV emission model of REB-heated plasma

VUV emission model of a hygrogen plasma with oxygen impurity (T _e=tens of eV,n _e 10¹⁴–10¹⁶ cm^–3,ⁿimp=1–3 % n_e) is constructed in order to judge different possibilities of plasma diagnostics (especiallyT _e measurements) in the REBEX experiments. Two sets of calculations based on the nonstationary corona model are performed: time dependent continuous and line spectra in the range 5 eV—5 keV in the constantT _e approximation (discussion ofT _e measurements by the filter-method) and time dependent intensities of selected spectral lines (2s-2p type) of ionsO ²⁺–O⁵⁺ at variableT _e (including plasma heating by REB and radiative cooling). A possibility of plasma energy content determination from radiation losses is shown.We would like to acknowledge many helpful discussions with dr. P. unka; we thank also dr. J. Ullschmied for comparing our results with diamagnetic measurements.     

Nuclear orientation studies of the 51·5 min167Lu decay

Anisotropies of rays emitted in the decay of¹⁶⁷Lu,T _1/2=51·5 min, were measured. The¹⁶⁷Lu was oriented by the hyperfine interaction when the lutetium activity was included in a gadolinium host which was cooled to 15 mK temperature. A top-loading³He⁴He dilution refrigerator capable of quickly cooling a short-lived sample was used. Multipole mixing ratios have been evaluated for many transitions. The spin assignments have been made for a number of levels in¹⁶⁷Yb and their parities have been deduced. In particular, an unambiguous 11/2^– assignment was made for the 571·5 keV level which was identified as the band head of the 11/2^– [505] band observed by Lindblad. The rotational bands in¹⁶⁷Yb are discussed.Dedicated to the 25th anniversary of the Joint Institute for Nuclear Research.     

Pitfalls in the Use of Common Luminescent Probes for Oxidative and Nitrosative Stress

Lucigenin (LC²⁺, bis-N-methylacridinium) and 2,7-dichlorofluorescin (DCFH₂) are widely used as chemiluminescent or fluorescent probes for cellular oxidative stress, to reflect levels of superoxide (O₂ ^·–) and hydrogen peroxide, respectively. We report mechanistic studies that add to the growing evidence for the unsuitability of either probe except in very well-defined circumstances. The ability for lucigenin to generate superoxide via reduction of LC²⁺ to LC^·+ and redox cycling with oxygen depends on the reduction potential of the LC²⁺/LC^·+ couple. Redox equilibrium between LC^·+ and the redox indicator benzyl viologen is established in microseconds after generation of the radicals by pulse radiolysis and indicated E(LC²⁺/LC^·+) –0.28 V vs. NHE. Reaction of LC^·+ with O₂ to generate O₂ ^·– was also observed directly similarly, occurring in milliseconds, with a rate constant k 3 × 10⁶ M ^–1 s^–1. Quinones act as redox mediators in LC^·+/O₂ redox cycling. Oxidation of DCFH₂ to fluorescent DCF is not achieved by O₂ ^·– or H₂O₂, but NO₂ ^·) reacts rapidly: k 1 × 10⁷ M ^–1 s^–1. Oxidation by H₂O₂ requires a catalyst: cytochrome c (released into the cytosol in apoptosis) is very effective (even 10 nM). Fluorescence reflects catalyst level as much as O₂ ^·–) production.     

Observation of variable range hopping at “natural” phonon frequencies

Hill's analysis of hopping conductivity data has been applied to ion-bombarded amorphous-silicon samples. The apparent hopping conductivity parameters derived from a standardT ^–0.25 plot undergo changes by several orders of magnitude when plotted with the exact scaling of the abscissa. A typical example is characterized by a temperature dependence ofdc conductivity according to= ₀ exp (—(T ₀/T) ^m ), withm=0.45,T ₀ =6.410⁴K and ₀=6.610^{1 –1} cm^–1. From ₀ a phonon frequency of about 3–1510¹² s^–1 is derived.     

Isomeric transitions between shape coexisting states in iodine isotopes withA=115, 119 and 121

Applying delayed- r.f. coincidences and generalized centroid-shift analysis, nanosecond isomers in some odd-A iodine isotopes are studied in-beam. The reactions¹⁰⁶Cd(¹²C,p2n) and^116,118Sn(⁶Li,3n) have been used. The following half-lives were determined:T _1/2(565 keV)=0.50±0.10 ns andT _1/2(837 keV) =0.90±0.20 ns in¹¹⁵I,T _1/2(687 keV)=5.50±0.50 ns andT _1/2(2418 keV)=4.0±0.50 ns in¹¹⁹I as well asT _1/2(812 keV)=0.35±0.20 ns andT _1/2(445 keV)<0.10 ns=">¹²¹I. A systematics of the absolute probabilities for the transitions deexciting theg _9/2 9/2⁺ and _11/2 11/2 ₁ ^– band heads in^115–125I is presented and discussed.Partly supported by the Bulgarian National Research Foundation under contracts PH14, and PH31 and Kernforschungszentrum Karlsruhe, Stabsabteilung Internationale Beziehungen