共查询到17条相似文献,搜索用时 140 毫秒
1.
2.
3.
4.
5.
6.
简要叙述了自悬浮定向流方法制备铜纳米粉末的原理和包覆层薄膜的生长机理,采用空心阴极辉光放电对铜纳米粉末进行有机包覆,实验中CH4和H2的流量分别为6 ml/min和12 ml/min,工作电压为450 V,衬底与空心阴极的底端距离为2 cm,背景真空和工作气压分别为6 Pa和100 Pa,沉积速率为7.5 nm/min。用透射电镜(TEM)对铜纳米粉末进行了观察和分析,结果表明:铜纳米粉末呈球状,其粒径分布在10~100 nm之间, 平均粒径大小为50 nm;其包覆层的厚度大约为15 nm,而且该厚度可以通过调节空心阴极辉光放电的参数来控制。 相似文献
7.
采用自悬浮定向流法制备出Ag2Al复合金属间化合物的纳米微粉,通过透射电子显微镜、X射线衍射仪和X射线能谱仪对纳米微粉的显微结构、粒度、相组成和成分构成进行研究。结果表明:所制备出的复合金属间化合物纳米颗粒呈规则球形,粒径分布在20~110 nm之间;纳米合金颗粒的主要组成相为Ag2Al,并伴有少量的Al;样品中的Ag,Al原子数比约为66.5∶33.5,金属间化合物纳米颗粒中Ag2Al晶粒尺寸约为33 nm,Al的约为21 nm。 相似文献
8.
采用自悬浮定向流法制备出Ag2Al复合金属间化合物的纳米微粉,通过透射电子显微镜、X射线衍射仪和X射线能谱仪对纳米微粉的显微结构、粒度、相组成和成分构成进行研究。结果表明:所制备出的复合金属间化合物纳米颗粒呈规则球形,粒径分布在20~110 nm之间;纳米合金颗粒的主要组成相为Ag2Al,并伴有少量的Al;样品中的Ag,Al原子数比约为66.5∶33.5,金属间化合物纳米颗粒中Ag2Al晶粒尺寸约为33 nm,Al的约为21 nm。 相似文献
9.
10.
简要叙述了自悬浮定向流方法制备铜纳米粉末的原理和包覆层薄膜的生长机理,采用空心阴极辉光放电对铜纳米粉末进行有机包覆,实验中CH4和H2的流量分别为6 ml/min和12 ml/min,工作电压为450 V,衬底与空心阴极的底端距离为2 cm,背景真空和工作气压分别为6 Pa和100 Pa,沉积速率为7.5 nm/min。用透射电镜(TEM)对铜纳米粉末进行了观察和分析,结果表明:铜纳米粉末呈球状,其粒径分布在10~100 nm之间, 平均粒径大小为50 nm;其包覆层的厚度大约为15 nm,而且该厚度可以通过调节空心阴极辉光放电的参数来控制。 相似文献
11.
12.
彩色负片的颗粒性能是一个重要的质量指标。以往颗粒性能的度量采用均方根颗粒度的方法。均方根颗粒度建立在只对彩色负片进行灰密度(白光调制)采样的基础之上,难以保证所测数值与实际扩印照片效果相符合。采用对彩色负片进行红、绿、蓝三色光调制密度采样的方法,从三色均方根颗粒度出发,结合扩印过程中颗粒性能的传递特性以及观察照片时人眼的视觉生理和心理特性等诸多因素,形成一个代表最终照片颗粒效果的知觉颗粒度,称为彩色负片的印片颗粒指数(PGI)。实际测试和观测比较表明,所测彩色负片印片颗粒指数数值与其扩印效果相符合,印片颗粒指数方法能够反应彩色负片颗粒性的实用效果。 相似文献
13.
《X射线光谱测定》2005,34(3):245-252
An alternative preparation method for samples containing high levels of biogenic and organic matter with respect to automated electron probe microanalysis (EPMA) measurements was investigated. The organic and biogenic particles were impregnated with a heavy metal (Ru), causing an increase in the average atomic number of the particle. After impregnation, biogenic and organic particles give better contrast in backscattered electron images and can be traced by automated EPMA. During the interpretation of the results, attention was focused on the differences in the detected abundances of organic and biogenic particles and the relative importance of different particles types in the impregnated and non‐impregnated samples. The results obtained for particle diameters larger than 0.7 µm show that the method could be successfully applied to samples with a high contribution of coarse biogenic and organic particles. The impregnation of the particles with a heavy metal results in more efficient detection of smaller particles, which implies that the particle size distribution can be obtained more correctly. A second benefit of the impregnation method is the detection of a larger number of particles, which has an important influence on the calculation of the absolute abundances. The apparent abundance of the biogenic and organic particles was clearly higher in the treated samples. Moreover, in the case when only the conventional EPMA technique with a Be detector window is available, this method can be applied for the identification of organic and inorganic agglomerates. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
14.
植物样品消解后残留颗粒物元素组成研究 总被引:8,自引:0,他引:8
分别采用干灰化法和湿消化法处理植物标准参考物质灌木枝叶组合样(杨树叶和茶叶),用扫描电镜(SEM)对消解液中残留的不溶性颗粒物微观形貌进行了观察,并用SEM附属的X能谱仪研究了颗粒物的主要元素组成。另外,还用BCR法对茶叶残留颗粒物进行了分级萃取, 相关元素在四种存在形态中的含量分布状况由AAS和ICP-AES给出。研究结果表明:不同消解方法对颗粒物微观形貌有较大影响,其中植物样品经干灰化法处理后残留的颗粒物多呈灰黑色,表面疏松多孔;经湿消化法处理后残留的颗粒物均呈白色,多数结构紧密,数量也相对较少。不同植物样品残留的颗粒物元素组成均大同小异,主要为Si和Al,此外还有少量的Ca, Fe, K, Ti等。这些元素在颗粒物中存在形态不一,致使在进行植物样品分析时某些元素含量测定结果大为偏低。 相似文献
15.
采用化学气相沉积技术,利用旋转涂膜法制备催化剂基底材料,通过对涂膜过程中的角速度、旋转时间以及基底还原过程中温度的控制改变催化剂颗粒的分布状态,获得了粒径均匀分布的催化剂基底,该基底上催化剂颗粒集中分布在47~62 nm区间,再利用该基底生长出定向碳纳米管阵列。运用扫描电镜、透射电镜、拉曼光谱仪对样品进行了表征。结果表明旋转涂膜法制备的基底平整性好于普通的滴膜法,且较其它基底制备方法具有简单易控、可使催化剂均匀分散等特点。利用该基底制备的碳纳米管阵列定向性良好。 相似文献
16.
Fabrication and characterization of drug particles produced by electrospraying into reduced pressure
In the present study, electrospraying was used in drug particle-production. The objective of the research was to establish whether electrospraying can be carried out in reduced pressure in order to improve the drying process of the droplets. By this method, it is possible to produce drug particles relatively uniform in size, crystallinity and porosity. Drying the droplets in a reduced pressure is a more sensitive way to remove the solvent from the particles than, for example, the addition of heat. The efficiency of this drying method and particle morphology were studied using SEM, DSC, and XRD. Another objective was to workout whether the size of the produced particles can be estimated by a simple method. The maximum particle size was defined theoretically and compared to experimental results with good agreement. 相似文献
17.
Shigehisa Endoh Yoshikazu Kuga Hitoshi Ohya Chihiro Ikeda Hiroyuki Iwata 《Particle & Particle Systems Characterization》1998,15(3):145-149
This study was conducted to establish a simple method for evaluating the morphology of fine anisometric particles using size measurement techniques. The size distributions of mica particles and carbon fibers classified into narrower size ranges were measured by gravitational sedimentation and laser diffraction techniques. The ratio of mean diameters determined for flaky particles strongly depended on the aspect ratio, i.e. flatness. The relationship between particle shape and diameter is discussed theoretically. The experimental results were similar to those predicted. The flatness of fine particles can be evaluated by the ratio of the median diameter determined by laser diffraction to that determined by sedimentation. 相似文献