Determination of cadmium by precipitation of cadmium molybdate from homogeneous solution

A quantitative method has been developed for the determination of cadmium as cadmium molybdate by PFHS method using the technique of volatalisation of ammonia. The pH range for complete precipitation is found to be 6·0–7·6. Presence of 20–50 mmoles acetate is necessary for obtaining quantitative results. From 20–200 mg of cadmium could be conveniently determined using this method. Zinc, magnesium and nickel do not interfere. The anions such as sulphate, acetate, nitrate and chloride can be tolerated up to 50 mmoles. The precipitate has constant weight upto 750°.     

Spectrophotometric studies of copper (II)—bis-2-pyridyl glycol complex

An aqueous solution ofbis-2-pyridyl glycol forms a deep blue water-soluble complex with an aqueous solution of copper (II) salts. The complex has an absorption maximum at 600–650 mµ between pH range 3·0–8·7. The complex is stable for four days and obeys Lambert-Beer’s law in the concentration range of 5·08–50·80 ppm. of copper (II) in solution. The optical density of the complex remains constant between pH 3·8–5·9. The molar composition as determined by the method of continuous variation and by the slope ratio method has been found to be 1:1. The limits of interference due to some foreign ions during the estimation of copper (II) have been determined.     

Volumetric determination of copper by precipitation with ammonium thiocyanate

Potassium dichromate was employed for the determination of copper by precipitation as cuprous thiocyanate. 1·0–10·0 mg of copper was accurately determined by this procedure. The method was applied for the analysis of copper in Devarda’s alloy and chalcopyrites.     

Studies in the separation and determination of zirconium using vanillin as an analytical reagent

Vanillin, quantitatively precipitates zirconium between pH 5·0–6·5, as insoluble complex. This complex on ignition gives ZrO₂ which can be weighed. Zirconium can be readily separated and determined in the presence of varying quantities of chromium (III), cobalt (II), copper (II), manganese (II), molybdenum (VI), nickel (II), titanium (IV), tungsten (VI), uranium (VI), vanadium (V), zinc (II) and trivalent rare earths.     

Periodicities in the series of cyclonic disturbances over India

The time series of yearly occurrence frequency of cyclonic disturbances over the Indian region for 1891–1970 is subjected to power spectrum analysis by the maximum entropy method (MEM) of Burg. Earlier analyses by the conventional Blackman-Tukey method had indicated periodicities atT= 2·3-2·5, 5 and 30–45 years at about 90–95% significance level. The present analysis shows peaks atT = 1·2, 2·4, 2·9, 3·7, 4·7, 6·4, 7·4, 9·2, 10·5, 20 and 40–60 years but the significance level may not be better than the earlier method. When data are analysed separately for first half and latter half, periodicities observed are quite different, the earlier half revealingT= 1· 2, 2·3, 2·9, 4·7, 9·0 and 23 years and the latter half revealingT= 1·2, 2·1, 2·4, 3·8, 6·7 and 21 years. Thus, a change of pattern before and after about 1920 is indicated. However, the power in the various peaks is small and a random origin cannot be ruled out. An analysis of several artificially produced samples of pseudo-Gaussian random white noise of the same mean, standard deviation and length (80 values) as the above physical samples indicated that similar peaks could occur by pure chance also. Physically, T=l·2 years corresponds to the Chandler’s wobble and other peaks could be harmonics of the sunspot cycleT= 11 years or double sunspot cycleT = 22 years. However, no peak is noticed at or nearT= 11 years whereasT near 22 years is noticed.     

The new physiology of vision

α-Nitroso-β-naphthol was successfully employed for the gravimetric determination of Mercury (ii) (as nitrate) and in its separation from copper (ii). The former was percipitated at pH 1·9 and the latter at pH 11·00. The precipitate could be dried to constant weight at 110° C. The composition of the complex was established by analysis to be Hg (C₁₀H₆NO₂)₂ 20 mg. of mercury could be estimated with an error of ± 0·3% in pure solutions. Appreciable amounts of copper could be removed in alkaline medium without co-precipitation of mercury. The error was ±0·5%.     

Investigations on the multiply charged nuclei of the primary cosmic radiation near the geomagnetic equator using nuclear emulsion

A nuclear emulsion stack was exposed over Hyderabad, India (geomagnetic latitudeλ=7·6° N) under a mean atmospheric depth of 6·8 g./cm.², on 24 March 1960. The relative and absolute intensities of Be and B nuclei and nuclei of charge Z?6 (the S-nuclei) have been determined in this stack. The intensities were extrapolated to the top of the atmosphere using measured fragmentation parameters involved in collisions of cosmic ray nuclei in graphite. The flux values of Be, B and S nuclei at the top of the atmosphere have been determined to be 0·025±0·011, 0·101±0·023 and 1·12±0·10 particles/m.² sec. sr. respectively. The ratios of intensities B/S, Be/S and Be/B have been found to be 0·09±0·02, 0·022±0·008 and 0·25±0·11 respectively. These ratios of intensities have been used (a) to compute the amount of matter traversed by the radiation before reaching the vicinity of the earth as 2·6±0·6 g./cm.², (b) to show that the Fermi mechanism of acceleration of particles is not efficient at these energies (1–10 GeV/n.) in interstellar space and (c) to show that preferential acceleration of H₁-nuclei (Z?20) is not of overwhelming importance. The derived source composition of nuclei of energy ?7·5 GeV/n suggests that N, O, F and H₃-nuclei (Z=10–15) have similar abundances in the universe and in cosmic rays, and that C and H₁-nuclei are overabundant in cosmic rays.     

Spins of the first two excited states in27Mg by an angular correlation technique in the reaction26Mg (d,pγ)27Mg

Proton-gamma-ray angular correlation measurements, employing the ‘method II’ of Litherland and Ferguson, have been made in the reaction²⁶Mg (d, pγ)²⁷Mg, using 1·80 MeV deuteron beam and detecting the outgoing protons at 0° with respect to the beam. Analysis of these measurements leads to spin assignments of 3/2 and 5/2 for the 0·98 and 1·69 MeV excited states of²⁷Mg. The 1·69 MeV second excited state is found to decay almost completely to the ground state.     

He3 nuclei in the low energy primary cosmic radiation

The flux of He³ nuclei and the ratio He³/(He³+He⁴) in the low energy primary cosmic radiation have been determined using a stack of nuclear emulsions exposed at 3·1 g. cm.^?2 of atmospheric depth from Fort Churchill, Canada, in June 1963. The grain-densityversus residual range method was used to determine the masses of the helium nuclei. Using a sample of 146 helium nuclei whose masses could be identified, the ratio He³/(He³+He⁴) is obtained as 0·14±0·04 for the kinetic energy interval 115–210 MeV per nucleon and 0·43±0·11 for the rigidity interval 0·85–1·05 BV. The differential fluxes of He³ nuclei are determined as 0·017±0·006, 0·045±0·015, and 0·054±0·017 particles/M². Sr. Sec. MeV/nucleon, in the kinetic energy intervals of 117–183, 183–217, and 217–250 MeV/nucleon respectively. These results are compared with those of other investigators. From the results of the present work the amount of matter traversed in space by the primary cosmic ray helium nuclei of energy 115–210 MeV/nucleon is obtained as 4·7±1·8 gm. cm.^?2 of hydrogen.     

Spectrophotometric studies of 6-methyl pyridine-2-aldoxime-iron (II) complex

6-Methyl pyridine-2-aldoxime produces with iron (II) solution a deep red complex soluble in 50% (by volume) aqueous acetone. The complex is stable at 10–45°C. and its colour intensity does not vary between pH 7·3 and 10·0. The complex obeys Lambert-Beer’s law at 520 mµ in the concentration range of 1·12 to 28·0 p.p.m. of iron.     

Cosmic ray nuclei of chargeZ⩾3 during the period of low solar activity

A detailed study of the composition and energy spectra of heavy nuclei of charge Z?3 in the primary cosmic rays has been made during the period of low solar activity, using two stacks of nuclear emulsions exposed in balloon flights from Fort Churchill, Canada, in June 1963. Each of the stacks was composed of 120 nuclear emulsions of three different sensitivities and was exposed at about 3·5 g. cm.^?2 of residual air for about 11.1 hr. Reliable resolution of charges of nuclei from lithium to oxygen was obtained; for heavier nuclei, charge groups were determined. From the analysis of 793 tracks of nuclei with Z?3, results on the following aspects were obtained:

1. The differential energy spectra of L (Z=3–5), M (Z=6–9) and H (Z=10–28) nuclei were measured in the energy intervel 150–600 MeV/nucleon; integral fluxes were obtained for energy >600 MeV/nucleon;
2. The energy dependence of the L/M ratio at the top of the atmosphere was determined; the ratios were obtained as 0·45 ± 0·06 and 0·29 ± 0·03 in the energy intervals of 200–575, and >575 MeV/nucleon respectively;
3. Relative abundances of individual nuclei of Li, Be, B, C, N and O at the top of the atmosphere were determined as 36, 29, 55, 100, 60 and 106 respectively in the energy interval 150–600 MeV/nucleon; corresponding values were also obtained for energy >600 MeV/nucleon.
4. The differential fluxes of multiply charged nuclei measured by us and by other investigators were used to determine the solar modulation between solar maximum to solar minimum. It was found that solar modulation of the fluxes of M and He nuclei were consistent with Rβ dependence and that the modulation parameter Δη between 1965 and 1957 was about 1·1.

The implications of these results are discussed.     

Emission spectrum of chlorine excited in the presence of argon

The spectrum of chlorine excited in the presence of argon has been photographed with a 21-ft. grating spectrograph in the first order. Two band systems in the region 2600–2390 Å and 2365–2239 Å are observed which appear to be respectively analogous to the 2950–2670 Å and 2660–2590 Å systems of bromine reported earlier by Venkateswarlu and Verma. The wavelengths and the wavenumbers of all the bands in the system 2600–2390 Å are given. The vibrational scheme along with the corresponding Franck-Condon parabola is also given. The analysis suggests that the lower state of the system is the 3π(O _u ⁺_ state established by Elliott at 17658 cm.^?1 and that the upper state is at 67773 cm.^?1 The vibrational constants obtained arew ₀′ = 246·6 cm.^?1,w ₀′x ₀′ = 0·615 cm.^?1,w ₀″ = 255·2 cm.^?1,w ₀″x ₀″ = 5·5 cm.^?1,w ₀″y ₀″ = ?0·0155 cm.^?1 andw ₀″z ₀″ = 0·00115 cm.^?1     

Applications of the purely imaginary powers of operators in Hilbert spaces

In C. R. Acad. Sci. Paris299 (1984), 173–176, we discussed purely imaginary powers A^iy(−∞ < y < + ∞) of linear operators A in Hilbert spaces. Here we utilize the results to consider the various problems: generation of cosine families in Hilbert spaces, coincidence of the definition domains of the fractional powers of operators, differentiability of the functions of the form A(·)⁰ (0 < θ < 1) where A(·) is an operator valued function defined on an interval [0, T], and so forth.     

Amperometric determination of copper with resacetophenone-phenylhydrazone

An amperometric method for determination of copper (II) with resacetophenone-phenylhydrazone is described. The method is useful to determine the metal in amounts ranging from 1·0–16·0 mg with an accuracy of ±1 per cent. Ten-fold excess of zinc, cadmium and nickel did not interfere. Iron which interefered both polarographically and chemically was complexed with sodium fluoride and the determination was successfully carried out. The method was applied for the determination of the metal in german silver.     

Ratio of pions to protons and ratio of neutral to charged interacting particles at mountain altitude of 800 gm/cm2

Using a combined set-up of a multiplate cloud chamber, an air Cerenkov counter and a total absorption spectrometer, the ratio of pions to protons not associated with large air showers has been determined to be 0·50 ± ·07 in the energy region 20–40 GeV at an altitude of 800 gm/cm². In the same energy region the ratio of neutral to charged particles is found to be 0·66 ± ·07. From the ratio of neutrons to protons deduced from these measurements (i.e., 0·99 ± ·11), it is concluded that most of the charge excess of nuclear active particles of energies > 20 GeV at mountain altitudes and sea-level is due to pions.     

Asymptotic behavior of solutions of the functional differential equation x′(t) = Ax(λt) + Bx(t), λ>0

The author discusses the asymptotic behavior of the solutions of the functional differential equation x′(t) = Ax(λt) + Bx(t), λ>0 (1) where x(t) is an n-dimensional column vector and A, B are n × n matrices with complex constant entries. He obtains the following results for the case 0 < λ < 1: (i) If B is diagonalizable with eigenvalues b_i such that Re b_i < 0 for all i, then there is a constant α such that every solution of (1) is O(t^α) as t → ∞. (ii) If B is diagonalizable with eigenvalues b_i such that 0 < Re b₁ ? Re b₂ ? ··· ? Re b_n and λ times Re b_n < Re b₁, then every solution of (1) is O(e^bn^t) as t → ∞. For the case λ>1, he has the following results: (i) If B is diagonalizable with eigenvalues b_i such that Re b_i>0 for all i, then there is a constant α such that no solution x(t) of (1), except the identically zero solution, is 0(t^α) as t → ∞. (ii) If B is diagonalizable with eigenvalues b_i such that Re b₁ ? Re b₂ ? ··· ? Re b_n < 0 and λ Re b_n < Re b₁, then no solution x(t) of (1), except the identically zero solution, is 0(e^b1^t) as t → ∞.     

The emission spectrum of iodine bromide excited in the presence of Argon

IBr vapour was excited in the presence of argon by an uncondensed transformer discharge. Four band systems were obtained in the regions 5425–5360 Å, 4520–4415 Å, 4120–4010 Å and 3915–3540 Å of which the first three are discussed in this paper. The wavelengths and wavenumbers of the band heads in three systems as measured from the plates obtained with a 3-prism Steinheil glass spectrograph are given along with their visually estimated relative intensities. The three band systems, which are new, are analysed and the following vibrational constants expressed in cm.^?1 are obtained:

Band system	v e	w e ″	w e ″x e ″	w e ″y e ″	w e ′	w e ′x e ′
5425-5360 Å	18613	65·5	0·24	?0·01	43·0	0·026
4520-4415 Å	22312	65·5	0·24	?0·01	77·0	0·5
4120-4010 Å	24540	160·6	1·125	..	128·4	0·1

     

On the univalence of functions defined by certain integral transforms

The integral transform $\text{F(z) = ∝}{}_0{}^{\mathrm{z}}\text{(f′(t))}{}^{\mathrm{\alpha }}\text{(}\text{g(t)}\text{t}\text{)}{}^{\mathrm{\beta }}\text{dt}$, where α and β are real, of pairs of special analytic functions f(z) = z + ···, g(z) = z + ···, univalent in the open unit disc Δ is studied. The transform and our results extend some recent results due to Shirakova.     

Microwave spectrum of pentafluorobenzonitrile

The absorption spectrum of pentafluorobenzonitrile has been investigated in the frequency range of 18–26·5 GHz using a 100 KHz stark modulated microwave spectrometer. The analysis of the spectrum is based on the rigid asymmetric rotor theory. The rotational constants obtained are A=1026·82±0·3 MHz, B=776·34±0·1 MHz, C=442·06±0·1 MHz and the asymmetry parameterχ=+0·1433. The inertial defect is I _o ?I _a ?I _b =0·081 amu Ų. The bond distances ared _CF=1·328 Å andd _CN=1·157 Å. The results are in good agreement with the assumed planarity of the molecule and the normal values of bond distances.     

Numerical studies of slow viscous rotating fluid past a sphere

Navier-Stokes equations for steady, viscous rotating fluid, rotating about the zaxis with angular velocity ω are linearized using Stokes approximation. The linearized Navier-Stokes equations governing the axisymmetric flow can be written as three coupled partial differential equations for the stream function, vorticity and rotational velocity component. Only one parameterR _eω =2ωa ²/v enters the resulting equations. Even the linearized equations are difficult to solve analytically and the method of matched asymptotic expansions is to be applied. Central differences are applied to the two-dimensional partial differential equations and are solved by the Peaceman-Rachford ADI method. The resulting algebraic equations are solved by successive over relaxation method. Streamlines are plotted for Ψ=0·01, 0·05, and 0·25 andR _eω =0·1, 0·3, 0·5.