Simulation of viscoelasticity for one case of material testing

Conclusions Similariry conditions have been established on the basis of which the viscosity can be simulated in testing viscoelastic materials for tension (compression) under hydrostatic pressure. It has been shown that criteria and account for the effect of viscosity, while the II number accounts for the effect of pressure. The criterion is, in form, identical to the analogous parameter in the theory of non-Newtonian fluid flow. It has been shown, furthermore, that criterion is the monodromic version of criterion (the similarity number). When P=0 or P is very small and the II number degenerates, then only criterion or criterion should be used.Institute of Problems in Mechanics, Academy of Sciences of the USSR, Moscow. Translated from Prikladnaya Mekhanika, Vol. 11, No. 6, pp. 109–114, June, 1975.     

Rheology of concentrated disperse systems III. General features of the proposed non-newtonian model. Comparison with experimental data

Summary A non-newtonian viscosity equation where is the volume concentration and is an intrinsic viscosity, function of a relative shear rate and being structural parameters, has been proposed in a previous paper (1). From empirical grounds, the valuep = 1/2 holds for a large class of systems, like suspensions of rodand disc-shaped particles. In the high shear rate limit, aCasson law-type is recovered and discussed, especially the concentration dependence of the yield stress. However, the latter disappears in the low shear limit, and must be considered as a pseudo-yield stress. Good agreement is found in this low shear limit with some theoretical results ofBueche for polymers. More generally, the viscosity equation displays pseudo-plastic behaviour and fitting it on experimental data allows the determination of the structural parameters. Some examples (especially Red Blood Cell suspensions and Blood) are studied and support the model. Nevertheless, for spherical particle suspensions, the best fitting is reached forp = 1. Accurate values of particle diameters can be deduced from the structural parameter , in this case.

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Zusammenfassung In einer vorangegangenen Arbeit (1) wurde eine Viskositätsgleichung für eine nicht-newtonsche Flüssigkeit von der Form vorgeschlagen, worin die Volumenkonzentration und eine Grenzviskosität bedeutet; die letztere stellt eine Funktion der relativen Schergeschwindigkeit dar, die Konstantenk ₀,k und bezeichnen Strukturparameter. Empirisch wird gefunden, daß für eine große Klasse von Systemen, wie z. B. stäbchen- und scheibchenförmigen Teilchen,p = 1/2 gilt. In der Grenze hoher Schergeschwindigkeiten wird ein Verlauf gemäß einer Casson-Gleichung gefunden und diskutiert, insbesondere bezüglich der Konzentrationsabhängigkeit der Fließspannung. Allerdings verschwindet diese in der Grenze niedriger Schergeschwindigkeiten und muß daher als Pseudo-Fließspannung betrachtet werden. In diesem Grenzfall wird eine gute Übereinstimmung mit theoretischen Voraussagen vonBueche an Polymeren gefunden. Ganz allgemein beschreibt die obige Viskositätsgleichung ein pseudoplastisches Verhalten, und ihre Anpassung an experimentelle Werte erlaubt die Bestimmung der Strukturparameter. Einige Beispiele, insbesondere Suspensionen von roten Blutkörperchen und Blut, werden untersucht und bestätigen das Modell. Allerdings erhält man bei Suspensionen kugelförmiger Teilchen die beste Anpassung fürp = 1. In diesem Fall kann man mit Hilfe des Strukturparameters genaue Werte der Teilchendurchmesser bestimmen.

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With 5 figures and 3 tables     

Effects of couple-stresses on the dispersion of a soluble matter in a pipe flow of blood

Summary An analysis of the effects of couple-stresses on the effective Taylor diffusion coefficient has been carried out with the help of two non-dimensional parameters based on the concentration of suspensions and , a constant associated with the couple-stresses. It is observed that the concentration distribution increases with increasing or The effective Taylor diffusion coefficient falls rapidly with increasing when is negative.

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Zusammenfassung Der Einfluß der Momentenspannungen auf den effektiven Taylorschen Diffusionskoeffizienten wird untersucht. Dabei treten zwei dimensionslose Parameter and auf: Der erste bezieht sich auf die Suspensionskonzentration, der zweite kennzeichnet die Momentenspannungen. Man findet, daß die Verteilungsgeschwindigkeit mit wachsendem oder zunimmt. Dagegen fällt der Taylorsche Diffusionskoeffizient bei wachsendem stark ab, wenn negativ ist.

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a Tube radius - C Concentration - C _i Body moment vector - C ₀ Concentration at the axis of the tube - C _m Mean concentration - D Molecular diffusion coefficient - d _ij Symmetric part of velocity gradient - F Function of and characterising effective Taylor diffusion coefficient - f _i Body force vector - H A function of and - K ₂ Integration constant - K ^* Effective Taylor diffusion coefficient - k Radius of gyration of a unit cuboid with its sides normal to the spatial axes - I _n Modified Bessel's function ofnth order - L Length of the tube over which the concentration is spread - M Function ofH and - M _ij Couple stress tensor - P Function of - p Fluid pressure - Q Volume rate of the transport of the solute across a section of the tube - r Radial distance from the axis of the tube - T _ij Stress tensor - t Time coordinate - T _ij ^A Antisymmetric part of the stress tensor - u Relative fluid velocity - Average velocity - v _i Velocity vector - Fluid velocity at any point of the tube - v ₀ ⁿ Velocity of Newtonian fluid at the axis of the tube - _i Vorticity vector - x Axial coordinate - x ₁ Relative axial coordinate - z Non-Dimensional radial coordinate - Density - _ij Symmetric part of the stress tensor - µ Viscosity of the fluid - µ _ij Deviatoric part ofM _ij - , Constants associated with couple-stress With 3 figures     

Optimal cupolas of uniform strength: Spherical M-shells and axisymmetric T-shells

Summary The first part of this paper is concerned with the optimal design of spherical cupolas obeying the von Mises yield condition. Five different load combinations, which all include selfweight, are investigated. The second part of the paper deals with the optimal quadratic meridional shape of cupolas obeying the Tresca yield condition, considering selfweight plus the weight of a non-carrying uniform cover. It is established that at long spans some non-spherical Tresca cupolas are much more economical than spherical ones.

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Optimale Kuppeln gleicher Festigkeit: Kugelschalen und axialsymmetrische Schalen

Übersicht Im ersten Teil dieser Arbeit wird der optimale Entwurf sphärischer Kuppeln behandelt, wobei die von Misessche Fließbewegung zugrunde gelegt wird. Fünf verschiedene Lastkombinationen werden untersucht. Der zweite Teil befaßt sich mit der optimalen quadratischen Form des Meridians von Kuppeln, die der Fließbedingung von Tresca folgen.

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List of Symbols a_k, b_k, c_k, A_k, B_k, C_k coefficients used in series solutions - A, B constants in the nondimensional equation of the meridional curve - normal component of the load per unit area of the middle surface - meridional and circumferential forces per unit width - radial pressure per unit area of the middle surface, - skin weight per unit area of the middle surface, - vertical external load per unit horizontal area, - base radius, - R radius of convergence - s - cupola thickness, - u, w subsidiary functions for quadratic cupolas - vertical component of the load per unit area of middle surface - resultant vertical force on a cupola segment - structural weight of cupola, - combined weight of cupola and skin, - distance from the axis of rotation, - vertical distance from the shell apex, - z auxiliary variable in series solutions - specific weight of structural material of cupola - radius of the middle surface, - uniaxial yield stress - meridional stress, - circumferential stress, - _a, _b, _c, _d, _e subsidiary variables used in evaluating the meridional stress - auxiliary function used in series solutions This paper constitutes the third part of a study of shell optimization which was initiated and planned by the late Prof. W. Prager     

On the dynamic behaviour of an elastically supported beam of infinite length, loaded by a concentrated force

Summary An elastically supported beam of infinite length, initially at rest, carries a variable concentrated force at a prescribed point A. General expressions are given for the deflection and the bending moment at A (6.3 and 6.4). Three special cases are considered; the first one is defined by =0 for and =K=const. for ; the second one by =0 for 0 > > , given function of for 0 ; the third one applies to problems in which, during the period of impact, itself is an unknown. The results given here may be of use in those railway-engineering problems in which a rail can be considered as a beam of infinite length, and in which the supporting ground has the required properties.     

Interval stochastic matrices: A combinatorial lemma and the computation of invariant measures of dynamical systems

The concept of an interval stochastic matrix is introduced. We prove a combinatorial theorem which describes the network flow associated with an interval matrix. The semi-invariant vectors of are characterized in terms of eigenvectors with unit eigenvalue of stochastic matrices . These results are then applied to the approximation and machine computation of invariant measures of dynamical systems.Funded under Australian Research Council Grant A 8913 2609.     

Unsteady flow in an annulus between two concentric rotating spheres

An analysis is presented for the unsteady laminar flow of an incompressible Newtonian fluid in an annulus between two concentric spheres rotating about a common axis of symmetry. A solution of the Navier-Stokes equations is obtained by employing an iterative technique. The solution is valid for small values of Reynolds numbers and acceleration parameters of the spheres. In applying the results of this analysis to a rotationally accelerating sphere, a virtual moment of intertia is introduced to account for the local inertia of the fluid.Nomenclature R _i radius of the inner sphere - R _o radius of the outer sphere - radial coordinate - r dimensionless radial coordinate, - meridional coordinate - azimuthal coordinate - time - t dimensionless time, - Re _i instantaneous Reynolds number of the inner sphere, _i R _k ² / - Re _o instantaneous Reynolds number of the outer sphere, _o R _o ² / - radial velocity component - V _r dimensionless radial velocity component, - meridional velocity component - V dimensionless meridional velocity component, - azimuthal velocity component - V dimensionless azimuthal velocity component, - viscous torque - T dimensionless viscous torque, - viscous torque at surface of inner sphere - T _i dimensionless viscous torque at surface of inner sphere, - viscous torque at surface of outer sphere - T _o dimensionless viscous torque at surface of outer sphere, - externally applied torque on inner sphere - T _p,i dimensionless applied torque on inner sphere, - moment of inertia of inner sphere - Z _i dimensionless moment of inertia of inner sphere, - virtual moment of inertia of inner sphere - Z _i,v dimensionless virtual moment of inertia of inner sphere, - virtual moment of inertia of outer sphere - _i instantaneous angular velocity of the inner sphere - _o instantaneous angular velocity of the outer sphere - density of fluid - viscosity of fluid - kinematic viscosity of fluid,/ - radius ratio,R _i/R _o - swirl function, - dimensionless swirl function, - stream function - dimensionless stream function, - _i acceleration parameter for the inner sphere, - _o acceleration parameter for the outer sphere, - shear stress - _r dimensionless shear stress,      

Nonlinear rheology of a concentrated spherical silica suspension:

Time-dependent nonlinear flow behavior was investigated for a model hard-sphere suspension, a 50 wt% suspension of spherical silica particles (radius = 40 nm; effective volume fraction = 0.53) in a 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The suspension had two stress components, the Brownian stress ^B and the hydrodynamic stress ^H After start-up of flow at various shear rates , the viscosity growth function ₊ (t, ) was measured with time t until it reached the steady state. The viscosity decay function _– (t, ) was measured after cessation of flow from the steady as well as transient states. At low where the steady state viscosity ( ) exhibited the shear-thinning, the _– (t, ) and ⁺ (t, ) data were quantitatively described with a BKZ constitutive equation utilizing data for nonlinear relaxation moduli G (t, ). This result enabled us to attribute the thinning behavior to the decrease of the Brownian contribution ^B = ^B / (considered in the BKZ equation through damping of G (t, )). On the other hand, at high where ( ) exhibited the thickening, the BKZ prediction largely deviated from the ₊ (t, ) and ₊ (t, ) data, the latter obtained after cessation of steady flow. This result suggested that the thickening was due to an enhancement of the hydrodynamic contribution ^H = ^H / (not considered in the BKZ equation). However, when the flow was stopped at the transient state and only a small strain (<0.2) was applied, ^H was hardly enhanced and the _– (t, ) data agreed with the BKZ prediction. Correspondingly, the onset of thickening of ₊ (t, ) was characterized with a -insensitive strain ( 0.2). On the basis of these results, the enhancement of ^H (thickening mechanism) was related to dynamic clustering of the particles that took place only when the strain applied through the fast flow was larger than a characteristic strain necessary for close approach/collision of the particles.     

Apparent thickening behavior of dilute polystyrene solutions in extensional flows

An experimental investigation was undertaken to study the apparent thickening behavior of dilute polystyrene solutions in extensional flow. Among the parameters investigated were molecular weight, molecular weight distribution, concentration, thermodynamic solvent quality, and solvent viscosity. Apparent relative viscosity was measured as a function of wall shear rate for solutions flowing from a reservoir through a 0.1 mm I.D. tube. As increased, slight shear thinning behavior was observed up until a critical wall shear rate was exceeded, whereupon either a large increase in or small-scale thickening was observed depending on the particular solution under study. As molecular weight or concentration increased, decreased and, the jump in above , increased. increased as thermodynamic solvent quality improved. These results have been interpreted in terms of the polymer chains undergoing a coil-stretch transition at . The observation of a drop-off in at high (above ) was shown to be associated with inertial effects and not with chain fracture due to high extensional rates.     

The mathematically linear analysis of strain in continua

Summary One-one correspondence is postulated for two coordinate continua. One continuum is regarded as the initially undeformed state of a currently deformed continuum. The two continua are orthogonal trasformations each to the other. The square root of the quadratic metric, when the appropriate self-conjugate stretch dyadic is expressed in its principal form, gives the mathematically linear form to the analysis. The self-conjugate dyadic is expressed as =grad grad P in terms of a scalar potential function P. The physical and mathematical continuity of the strain dyadic is ensured by curl =0.A 4-vector analysis is evolved from a 4-vector quinternion analysis. The 4-vector analysis is of the same form as the usual 3-vector analysis that evolved from Hamilton's quaternion analysis.

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Sommario Si postula una corrispondenza biunivoca per due continui coordinati. Un continuo viene considerato come lo stato inizialmente non deformato di un continuo attualmente deformato.I due continui sono trasformazioni ortogonali uno dell'altro. La radice quadrata della metrica quadratica, quando la relativa diade di dilatazione autoconiugata venga espressa nella sua forma principale dà la forma matematicamente lineare alla analisi.La diade coniugata viene espresse come =grad grad P in termini di una funzione potenziale scalare P. La continuità fisica e matematica della diade di deformazione è assicurata da rot =0.Una analisi tetravettoriale viene sviluppata da analisi di quinternioni tetravettoriali. L'analisi tetravettoriale è della stessa forma dell'analisi trivettoriale che viene vsiluppata dalla analisi quaternionica trivettoriale di Hamilton.

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A generalisation that, when particularised, applies to the finite or infinitesimal straining of elastic bodies, incremental straining of plastic or fluidic bodies in 3-dimensional continua and to the space-time continuum as a 4-dimensional continuum.     

Mathematical model of the entry length in the flow of suspensions of solid particles in a gas

A mathematical model consisting of equations of mass and momentum and for the velocity field has been used for computing the entry length of the flow of non-Newtonian fluids in laminar, transition and turbulent regions. Experimental data measured in a vertical flow of a suspension of solid particles in air have been used for verifying the predictions. n flow index for laminar flow - Re Reynolds number defined for the flow of the carrier medium - q exponent for turbulent flow - ratio of core radius with a flat velocity profile to pipe radius - _c ratio of the axial component of local velocity in the core to mean velocity - w mean flow velocity - ratio of axial distance from the pipe entrance to the pipe radius - ratio of the entrance length to the pipe radius - relative mass fraction of particles - ratio of the distance from the pipe wall to the pipe radius - coefficient of pressure loss due to friction     

Slip flow of non-plasticized PVC compounds

Measurements on seven rigid PVC compounds were carried out with a slit rheometer working in combination with an injection moulding machine. Plastication of the compounds occurred in the screw of the plastication unit, which also forced the melt through the die with a controlled forward velocity. The rectangular slit had a length of 90 mm and a widthB of 20 mm. The heightH could be varied between 0.8 and 3.3 mm. Pressures and temperatures were recorded at several positions in and before the die. Measurements were carried out at shear rates from 10 to 2000 s^–1.When the reduced volume output was plotted against the wall shear stress _W , only four compounds showed master curves independent ofH, which is indicative of wall adhesion. In the other cases this plot did not produce such a master curve, but the plot of the mean velocity against _W was independent ofH (slip curve). This indicated that slip flow prevailed with a slip velocityv _G When, in the case of wall slip, the smooth inner surfaces of the die were replaced by surfaces with grooves perpendicular to the direction of flow, slip flow was prevented and the flow curves were shifted to much higher values of _Wc Above a critical value of the wall shear stress ( _Wc ) at which slip flow began, the output became nearly independent of _W . From the measurements made below _Wc a vs. relation for the shear flow could be derived, which was used to calculate the superimposed shear flow . Exact values of the slip velocity were then given by . Wall slip only occurred for compounds with a high shear viscosity, which corresponds to a high molecular weight (K-value).Dedicated to Professor H. Janeschitz-Kriegl on the occasion of his 60th birthday.     

Heat conduction in a semi-infinite solid subject to time-dependent surface heat fluxes: an analytical study

A closed-form model for the computation of the transient temperature and heat flux distribution in the case of a semi-infinite solid of constant properties is investigated. The temperature and heat flux solutions are presented for time-dependent, surface-heat flux of the forms: (i) , (ii) , and (iii) , where is a real number and is a positive real number. The dimensionless (or reduced) temperature and heat flux solutions are presented in terms of the Whittaker function, the generalized representation of an incomplete Gamma functionI (b, x) which can also be expressed by the complementary error functions. It is also demonstrated that the present analysis covers some well known (classical) solutions as well as a family of new solutions for the heat transfer through a semi-infinite solid.

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Wärmeleitung in einem halbunendlichen Festkörper bei zeitveränderlichem Randwärmefluß: Eine analytische Untersuchung

Zusammenfassung Es wird ein geschlossenes Modell zur Berechnung der nichtstationären Temperatur- and Wärmestromverteilung für einen halbunendlichen Festkörper mit konstanten Stoffwerten untersucht. Die Lösungen für das Temperatur- und Wärmeflußfeld basieren auf folgenden Zeitgesetzen für den Randwärmefluß: (i) , (ii) , und (iii) wobei eine reelle Zahl und eine positive reelle Zahl ist. Die dimensionslosen Lösungen für das Temperatur- und Wärmflußfeld lassen sich in Form der Whittaker- Funktionen, der verallgemeinerten Darstellung einer unvollständigen Gamma-FunktionI (b, x) angeben, welche auch durch das komplementäre Fehlerintegral ausgedrückt werden kann. Es wird ferner gezeigt, daß die hier durchgeführte Untersuchung sowohl einige bekannte (klassische) Lösungen für die Wärmeleitung im halbunendlichen Festkörper liefert, wie auch eine Familie von neuen Lösungen.

     

Zur analytischen Beschreibung des Füllstoffeinflusses auf das Fließverhalten von Kunststoff-Schmelzen

From literature some representative equations have been compiled describing the influence of filler on the viscosity of polymer melts. By application of these on the experimental results obtained from GF-SAN it was found that the relative viscosity _R , i.e. the ratio of the viscosities of the filled and unfilled melt, shows a pronounced dependence on the shear rate but not on the shear stress. Defining _R with constant and not with constant (as it is usually done), an analytical approach is possible independent of Further the influence of pressure, temperature and filler content on the zero-shear viscosity of filled polymer melts may be expressed by a modified Arrhenius equation.

     

High Reynolds Number Flow past a Plate Mounted at a Small Angle of Attack

A plane incompressible fluid flow past a plate mounted in a homogeneous stream at a small angle of attack ^* is investigated on the basis of an asymptotic analysis of the Navier-Stokes equations at high Reynolds numbers (Re). In the neighborhood of the leading edge the flow structure is studied in detail. It is found that separation is initiated in a small vicinity of the leading edge at and the length of the slow reverse stream zone is of the order O(1) at . The nonuniqueness of the solution is detected at and the hysteresis phenomenon is explained. It is shown that under certain conditions the solutions obtained also hold for flows past bodies of small thickness.     

Yield stress: A time-dependent property and how to measure it

This paper reviews the different aspects of the yield stress phenomenon and attempts a synthesis of knowledge. Yield stress can be probed using constant shear stress or shear rate. The magnitude of the result depends on the time allowed to determine whether the sample has developed continuous flow or has ceased flowing. It is closely associated with creep, stress growth and thixotropic breakdown and recovery, and the characteristic times of these transient responses play a part in yield stress measurement. In thixotropic fluids, yield stress is a function of structure and hence of time. In simple thixotropy, the yield stress derived from the equilibrium flow curve is the same as that for the fully built-up structure. But in many materials, the static yield stress obtained after prolonged rest is much higher than the dynamic yield stress from the equilibrium flow curve. This is associated with the phenomenon in which the equilibrium flow curve bends upwards as the shear rate is reduced to very low values. The paper also reviews the many methods that can be used to measure yield stress. It is pointed out that the choice of observation time or shear rate to use should be related to the characteristic time of the flow process to which the result is to be applied. Examples discussed are solids suspension capability of fluids, levelling and sagging, pipeline flow and start-up power requirement of mixers. CS constant structure - D diameter of Gun Rheometer tube - EFC equilibrium flow curve - G measured torque - L length of Gun Rheometer tube - P _min minimum pressure to cause flow - t time - form factor for shear stress - - _y - shear rate - a particular value of shear rate - reference shear rate - test shear rate - shear stress - _y yield stress - _yd dynamic yield stress - _ys static yield stress - 0 initial value after speed change - e equilibrium Paper presented at the British Society of Rheology Conference on New Techniques in Experimental Rheology, University of Reading, 9–11 September 1985.     

Fluage de la glace polycristalline

Summary Creep tests have been performed at temperatures above –10°C. The secondary creep behaviour can be described by a relation of the type where is the effective shear strain rate, the effective shear stress andB andn are constants. n has a value close to 3 for stresses ranging from 0,8 kgf/cm² to 5 kgf/cm². Oscillatory creep rates have been observed during the tertiary creep, resulting from periodic processes of recrystallisation.

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Avec 6 figures et 1 tableau     

A study of the shear viscosity of human whole saliva

Summary A model R-18 Weissenberg Rheogoniometer operating in the continuous shear mode was used to generate shear viscosity vs. shear rate data on male and female human whole saliva. These data were found to accurately follow the Sisko model, , whereµ is the shear viscosity at shear rate is the asymptotic shear viscosity at infinite shear rate, andK andn are constants. Data were collected on the effects of food, coffee, caffeine, and aspirin as functions of time. Studies were also made on the effects of emotional stress, donor sex and age.The saliva viscosity increased with time and then decreased to the basal value for most ingested materials. Emotional stress was found to elevate the saliva viscosity. On the other hand, no significant difference was found between the average saliva viscosities of male and female groups. Also, no significant effect of donor age was detected.

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Zusammenfassung Mit Hilfe eines Weissenberg-Rheogoniometers (Typ R-18) wurden bei stationärem Betrieb Scherviskositätskurven in Abhängigkeit von der Schergeschwindigkeit für den Speichel von Männern und Frauen gemessen. Man fand, daß sich die Meßwerte hinreichend genau durch ein Sisko-Modell, , beschreiben lassen, woµ die Scherviskosität bei der Schergeschwindigkeit die asymptotische Scherviskosität bei unendlich großer Schergeschwindigkeit sowieK undn weitere Konstanten bedeuten. Diese Messungen verfolgten die Wirkung von Nahrung, Kaffee, Coffein und Aspirin als Funktion der Zeit. Untersucht wurde weiterhin der Einfluß von emotionaler Spannung, sowie Geschlecht und Alter der Spender.Die Speichelviskosität stieg bei den meisten eingenommenen Stoffen mit der Zeit zuerst an, um danach wieder auf den Normalwert abzusinken. Ebenso fand man, daß emotionale Spannung eine Viskositätserhöhung hervorruft. Dagegen wurden bei Gruppen von Männern und Frauen keine signifikanten Unterschiede gefunden, und ebenso wurde kein gesicherter Einfluß des Alters festgestellt.

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With 4 figures and 6 tables     

Das Dispersionsmodell

Zusammenfassung Ein Vergleich im Frequenzbereich zeigt, daß bei der Berechnung der Verweilzeitverteilung mit dem Dispersionsmodell das endlich begrenzte System für Péclet-Zahlen Pe > 10 mit guter Näherung durch ein einseitig unbegrenztes System und für Pe > 50 durch ein beidseitig unbegrenztes System ersetzt werden kann.

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The dispersion model. A comparison of approximations

A comparison in the frequency domain shows that for the determination of the residence time distribution with the dispersion model the finitely restricted system may be substituted with good approximation for Peclet numbers Pe > 10 by a one-side unrestricted system and for Pe > 50 by a both-side unrestricted system.

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Bezeichnungen A Rohrquerschnitt - A=A mittlerer Strömungsquerschnitt in der Schüttschicht - Konzentration (Partialdichte) der Bezugskomponente i - Bezugskonzentration nach Gl. (5) - c_i Konzentration (Dichte) der reinen Bezugskomponente i - D axialer Dispersionskoeffizient - E Fehler im Frequenzbereich nach Gl. (36) - G(,) Übertragungsfunktion - G(,i) Frequenzgang - L Länge der Schüttschicht - m Masse - Massenstrom - Péclet-Zahl - s Laplace-Variable - t Zeit - t Impulsbreite - v Strömungsgeschwindigkeit im leeren Rohr - mittlere axiale Strömungsgeschwin digkeit in der Schüttschicht - V=AL Zwischenraumvolumen der Schüttschicht - x Ortskoordinate - (t) Dirac-Stoss - Porosität - dimensionslose Zeit - dimensionslose Konzentration - Laplace-Transformierte der Konzentration - Fourier-Transformierte der Konzentration - dimensionslose Ortskoordinate - =s dimensionslose Laplace-Variable - mittlere Verweilzeit - Kreisfrequenz - = dimensionslose Kreisfrequenz Indices A Ausgang - D Dispersion - E Eingang - i Bezugskomponente - K Konvektion Mitteilung Nr. 44 des Institutes für Mess-und Regel-technik der Eidgenössischen Technischen Hochschule Zürich (Vorsteher: Prof. Dr. P. Profos)     

Influence of the formation of associations of macromolecules on the rheo-optical properties of their dilute solutions. I. Theory

Assuming the formation of doublets in the flow according to a mass action law, the shear rate and the concentration dependence of the extinction angle, of the birefringence, and of the average coil expansion are calculated for dilute solutions of flexible macromolecules. It is shown that this reversible association process has a strong influence on the measurable parameters in a flow birefringence experiment. c concentration (g/cm³) - h ² mean square end-to-end distance at shear rate - h ₀ ² mean-square end-to-end distance at zero-shear rate - n refractive index of the solution (not very different from the solvent for a very dilute solution) - E mean coil expansion - K ₀,K constant of the mass action law - M molecular weight - R _G gas constant - T absolute temperature - ₁ – ₂ optical anisotropy of the segment - ₀ Deborah number: - Deborah number: - shear rate - ₀, reduced concentration - _s viscosity of the solvent - [] ₀ intrinsic viscosity at zero-shear rate - [] intrinsic viscosity at shear rate - extinction angle - N _a Avodagro's number - _n magnitude of the birefringence