共查询到20条相似文献,搜索用时 15 毫秒
1.
S. V. Antonenko O. S. Malinovskaya S. N. Mal’tsev 《Journal of Experimental and Theoretical Physics》2007,105(1):201-202
The multiwalled carbon nanotube films examined in this study are produced by two methods: current annealing of carbon paper and dc magnetron sputtering. The conductivity and the temperature dependence of resistance of the samples are measured. The thermal conductivity of the film-substrate system is evaluated. 相似文献
2.
I. Echeverría A. Urbina 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(3):491-496
We have prepared solutions of multiwalled carbon nanotubes in very low
vapour pressure solvents (a mixture of chlorinated biphenyls). The solutions
are stable and show no sign of precipitation for six months. Rheological
measurements using a modified Birnboim apparatus with annular and Sogel-Pochetino geometries have been performed.
Using time-temperature superposition we obtained the real and imaginary part of the complex viscosity coefficient in
a frequency range covering eight orders of magnitude and a temperature range
from 5 to 50 ○C. The data shows unexpected changes in the solution with
temperature: for T below 30 ○C there appears to be some
reorganization or clustering. This self-organization could result in
a useful technique to improve the electronic properties of polymer/carbon
nanotubes composites used in organic electronic devices. 相似文献
3.
4.
We have investigated electrical transport in a diffusive multiwalled carbon nanotube contacted using superconducting leads made of an Al/Ti sandwich structure. We find proximity-induced superconductivity with measured critical currents up to I(cm)=1.3 nA, tunable by the gate voltage down to 10 pA. The supercurrent branch displays a finite zero bias resistance which varies as R(0) proportional to I(cm){-alpha} with alpha=0.74. Using IV characteristics of junctions with phase diffusion, a good agreement is obtained with the Josephson coupling energy in the long, diffusive junction model of A. D. Zaikin and G. F. Zharkov [Sov. J. Low Temp. Phys. 7, 184 (1981)]. 相似文献
5.
Atomic force microscopy (AFM) was employed for the morphology measurements of bamboo-shaped multiwalled carbon nanotubes (BS-MWNTs) grown by thermal chemical vapor deposition on Fe catalyst deposited SiO2/Ti substrates. Greater diameters and compartment distances of the bamboo structures were observed for the BS-MWNTs grown at 950 °C than for those grown at 850 °C. 相似文献
6.
Jesionek M Nowak M Szperlich P Stróż D Szala J Jesionek K Rzychoń T 《Ultrasonics sonochemistry》2012,19(1):179-185
This paper presents, for the first time, the nanocrystalline, semiconducting antimony selenoiodide (SbSeI) grown in multi-walled carbon nanotubes (CNTs). It was prepared sonochemically using elemental Sb, Se, and I in the presence of ethanol under ultrasonic irradiation (35 kHz, 2.6 W/cm2) at 323 K for 3 h. The CNTs filled with SbSeI were characterized by using techniques such as powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, high-resolution transmission electron microscopy, selected area electron diffraction, and optical diffuse reflection spectroscopy. These investigations exhibit that the SbSeI filling the CNTs is single crystalline in nature and in the form of nanowires. It has indirect allowed energy band gap EgIf = 1.61(6) eV. 相似文献
7.
M. Nowak M. Jesionek P. Szperlich J. Szala T. Rzycho D. Str 《Ultrasonics sonochemistry》2009,16(6):800-804
This paper presents for the first time the nanocrystalline, semiconducting ferroelectrics antimony sulfoiodide (SbSI) grown in multiwalled carbon nanotubes (CNTs). It was prepared sonochemically using elemental Sb, S and I in the presence of methanol under ultrasonic irradiation (35 kHz, 2.6 W/cm2) at 323 K for 3 h. The CNTs filled with SbSI were characterized by using techniques such as powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, high-resolution transmission electron microscopy, selected area electron diffraction, and optical diffuse reflection spectroscopy. These investigations exhibit that the SbSI filling the CNTs is single crystalline in nature and in the form of nanowires. It has indirect forbidden energy band gap EgIf = 1.871(1) eV. 相似文献
8.
In this article, we have decorated multiwalled carbon nanotubes (MWCNTs) scaffold with ZnO quantum dots (QDs, size in the range of 2.9–4.5 nm) and investigated their prospects for photovoltaic applications. ZnO QDs, in the present study, work as photosensitizer instead of electron transporting media as used in recent conventional strategic solar cells. ZnO QDs/MWCNTs composite shows an increased visible absorbance and quenching of the broad visible emission at around ~560 nm, while only ZnO QDs exhibit a strong visible emission. An efficient electron–hole separation facilitates an increase in the short-circuit current. These results show a possibility of developing a nontoxic, ZnO QDs sensitized MWCNTs composite-based photovoltaic solar cell. 相似文献
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10.
A new type of one-dimensional (1D) carbon structure, carbon nanowires (CNWs), was discovered in the cathode deposits prepared by hydrogen arc discharge evaporation of carbon rods. Observation of high-resolution transmission electron microscopy (HRTEM) indicates that a CNW consists of a multiwalled carbon nanotube (MWNT) with a long 1D linear carbon chain (C chain) inserted into its innermost tube of 0.7 nm in diameter. The characteristic Raman peaks of CNWs appeared at around 1850 cm(-1). Raman scattering and HRTEM studies show the formation of a long linear C chain involving more than 100 carbon atoms inside a MWNT. This novel 1D carbon allotrope has potential applications in nanoelectronics, nanomechanics, and nanomaterials. 相似文献
11.
用Pt细丝代替已有3ω方法中的薄膜热线,并设计了基于Labview程序的虚拟测量系统,准确、方便地测量了聚丙烯复合材料的热导率. 测量结果发现,多壁碳纳米管/丁苯橡胶/聚丙烯三元复合材料的热导率随着多壁碳纳米管/丁苯橡胶粉末含量的增加变化不大;多壁碳纳米管/聚丙烯复合材料的热导率随着多壁碳纳米管含量增加而增大;复合材料热导率远小于简单混合规则预测的结果,而与有效介质理论符合很好.
关键词:
ω法')" href="#">3ω法
多壁碳纳米管
聚丙烯复合材料
热导率 相似文献
12.
采用X射线吸收精细结构光谱探索性地研究了多壁碳纳米管束.在多壁碳纳米管束不同入射角的X射线吸收精细结构光谱中,观察到C—H σ*共振峰强度随入射角的变化而发生变化.在常温常压下出现C—H键可能与多壁碳纳米管束中存在缺陷有关,缺陷数量越大C—H σ*共振峰的强度越大.光谱中C—C π*和C—C σ*共振峰强度的变化趋势都不同于C—H σ*共振峰,这有力地证明了在常温常压条件下氢原子是吸附在多壁碳纳米
关键词:
X射线吸收精细结构光谱
碳纳米管
储氢
化学吸附 相似文献
13.
We have measured the size of the localized electron emission sites on multiwalled carbon nanotubes (MWNTs) with caps closed by a fullerenelike structure. MWNTs were individually mounted on tungsten support tips and imaged with a field emission microscope (FEM). The magnification of the FEM was calibrated using electron ray tracing and verified by comparing transmission electron microscope images. The FEM image was also tested for effects of the lateral energy spread. We found ring-shaped emission areas with three flattened sides, of a radius of 1.7±0.3 nm, and separated by 5±1 nm. 相似文献
14.
Hongyu Sun Yan Chen Xiaohong Li Wei Li Yanwu Xie Baoting Liu Xiangyi Zhang 《Solid State Communications》2010,150(17-18):820-823
Multiwalled carbon nanotube (MWCNT)/CdS core/shell heterostructures have been successfully synthesized via a simple solution-phase method. The thickness of CdS shells can be facilely tuned by either the reaction temperature or time. The CdS nanoparticles are first formed directly on the surface of MWCNT, and then a uniform CdS sheath is yielded via orientated aggregation processes. The present work provides a simple route to obtain MWCNT-based core/shell heterostructures and thus is of wide interest for the studies of nanomaterials and nanodevices. 相似文献
15.
We report the temperature and magnetic field dependence of the conductivity of multiwall carbon nanotube mat in the temperature range 1.4-150 K and in magnetic fields up to 10 T. It is observed that charge transport in this system is governed by Mott’s variable-range hopping of three-dimensional type in the higher temperature range and two-dimensional type in the lower temperature range. Mott’s various parameters, such as localization length, hopping length, hopping energy and density of states at the Fermi level are deduced from the variable-range hopping fit. The resistance of the sample decreases with the magnetic field applied in the direction of tube axis of the nanotubes. The magnetic field gives rise to delocalization of states with the well-known consequence of a decrease in Mott’s T0 parameter in variable-range hopping. The application of magnetic field lowers the crossover temperature at which three-dimensional variable-range hopping turns to two-dimensional variable-range hopping. The conductivity on the lower temperature side is governed by the weak localization giving rise to positive magnetoconductance. Finally, a magnetic field-temperature diagram is proposed showing different regions for different kinds of transport mechanism. 相似文献
16.
An attempt has been made to prepare and characterise ammonium thiocyanate (NH4SCN) salt and a multiwall carbon nanotube (MWNT)-doped polyvinyl alcohol-based nanofibre mats using an electrospinning process. The X-ray diffraction result shows an improvement in the amorphous nature of composite electrolyte fibre mats with increasing concentrations of the MWNT filler. The DSC behaviour of these nanofibre mat exhibits better thermal response upon dispersal of the filler. Composite electrolyte nanofibre mat doped with 6 wt% MWNT shows optimum conductivity, viz., 5.8?×?10?4 Scm?1. The temperature dependence of the bulk electrical conductivity displays a combination of Arrhenius and Vogel–Tammam–Fulcher nature. Dielectric loss studies have also been used to understand the conduction process in the system. Jonscher power law seems to be obeyed during ac conductivity measurements of the fibre mats. 相似文献
17.
F. Estaline Amitha A. Leela Mohana Reddy S. Ramaprabhu 《Journal of nanoparticle research》2009,11(3):725-729
A supercapacitor using non-aqueous electrolyte and multiwalled carbon nanotube (MWNTs) nanocomposite electrodes has been designed
with polymer and metal oxide loaded carbon nanotubes as electrodes. These nanocomposites were coated on the carbon paper with
Nafion solution to obtain the flexible electrodes. Carbon paper with the nanocomposite coating was pressed on either sides
of the Nafion membrane, which acts both as a separator and as an electrolyte. The performance of asymmetric assembly of electrochemical
double layer capacitor with polymer- and metal oxide-dispersed MWNTs composite materials with non-aqueous Nafion electrolyte
is compared with symmetric assemblies, and the results are discussed. 相似文献
18.
Multiwalled carbon nanotubes (MWCNTs) were homogeneously dispersed in pure acrylic emulsion by ultrasonication to prepare MWCNT/polyacrylate composites applied on building interior wall for electromagnetic interference (EMI) shielding applications. The structure and surface morphology of the MWCNTs and MWCNT/polyacrylate composites were studied by field emission scanning microscopy (FESEM) and transmission electron microscopy (TEM). The electrical conductivity at room temperature and EMI shielding effectiveness (SE) of the composite films on concrete substrate with different MWCNT loadings were investigated and the measurement of EMI SE was carried out in two different frequency ranges of 100-1000 MHz (radio frequency range) and 8.2-12.4 GHz (X-band). The experimental results show that a low mass concentration of MWCNTs could achieve a high conductivity and the EMI SE of the MWCNT/polyacrylate composite films has a strong dependence on MWCNTs content in both two frequency ranges. The SE is higher in X-band than that in radio frequency range. For the composite films with 10 wt.% MWCNTs, the EMI SE of experiment agrees well with that of theoretical prediction in far field. 相似文献
19.
We have studied the radiation of a double-walled carbon nanotube
(DWNT) filament with a length of 4.5\,mm and a diameter of
10\,$\mu$m by applying an electric current through the filament. The
DWNT filament starts emitting incandescent light at voltage
$U=6$\,V. Emission spectra of the DWNT below temperature 1250\,K can
well be fitted to those of the blackbody radiation. The intensity of
the incandescent light shows an exponential dependence on the
voltage applied on the DWNT filaments. The resistance of the DWNT
filaments is very stable at high temperatures between 900 and
1250\,K during the emission of light in the experiments. 相似文献
20.
In this paper, we describe a statistical method of quantification of the number of functional groups at the contact area of a probe tip for atomic force microscopy from the result of repetitive pull-off force measurements. We have investigated laboratory-made carbon nanotube (CNT) probe tips to apply them for chemical force microscopy because limited number of functional groups at the tip-end is expected. Using a CNT tip, we conducted repetitive pull-off force measurements against a self-assembled monolayer terminated with carboxyl group and analyzed them in terms of the number of hydrogen bond groups at the CNT tip. The elementary hydrogen bond rupture force quantum in n-decane medium was estimated to be 84.2 ± 0.5 pN in the present system. Thus it was revealed that only a couple of hydrogen bond groups of the CNT tip were participating in hydrogen bonding with the sample on an average in this experimental system. 相似文献