Enhanced light confinement in a near-field optical probe with a triangular aperture

We present a probe concept for scanning near-field optical microscopy combining the excellent background suppression of aperture probes with the superior light confinement of apertureless probes. A triangular aperture at the tip of a tetrahedral waveguide (full taper angle approximately 90 degrees ) shows a strong field enhancement at only one rim when illuminated with light of suitable polarization. Compared to a circular aperture of equivalent size, the resolution capability is doubled without loss of brightness. For a approximately 60 nm sized triangular aperture, we measured an optical resolution <40 nm and a transmission of approximately 10(-4).     

Apertureless near-field laser nanotechnology

We consider apertureless near-field optics that provides subwavelength resolution. We study the enhancement of the electromagnetic field near nanospheres and under the tip of a scanning probe microscope using the finite difference time-domain (FDTD) method. We discuss the mechanisms of field enhancement connected with the system geometry (“lightning rod effect”) and resonance excitation of local plasmon eigenmodes for different materials of the tip and various geometrical parameters of the system. We describe the possible applications in nano-optics and nanotechnology. We present the experimental achievements in apertureless near-field nanolithography.     

Near-Field Fluorescence and Topography Characterization of a Single Nanometre Fluorophore by Apertureless Tip-Enhanced Scanning Near-Field Microscopy

Tip-enhanced near-field fluorescence and topography characterization of a single nanometre fluorophore is conducted by using an apertureless scanning near-field microscopy system. A fluorophore with size 80hm is mapped with a spatial resolution of 10hm. The corresponding near-field fluorescence data shows significant signal enhancement due to the apertureless tip-enhanced effect. With the nanometre spatial resolution capability and nanometre local tip-enhanced effect, the apertureless tip-enhanced scanning near-field microscopy may be further used to characterize a single molecule by realizing the local near-field spectrum assignment corresponding to topography at nanometre scale.     

反射式无孔径近场Raman研究(英文)

近场扫描光学显微技术与Raman光谱技术的结合能够在纳米尺度下提供化学 /结构信息 ,这对很多应用都是至关重要的 ,比如硅器件 ,纳米器件 ,量子点及生物样品单分子研究。本文报导了采用无孔径探针的近场Raman研究。我们的系统有两大特征 :1 近场Raman的增强是通过金属探针上的银镀层实现的 ,无需样品准备 ;2 系统在反射模式下工作 ,适用于任何样品。这两点对实际应用是至关重要的。我们首次在实际硅器件上用 1秒积分时间获得了 1维近场Raman映射和 2维近场Raman图象。我们首次展示了由于积分时间短 ,该技术可用于成象用途。因此 ,这是近场扫描Raman研究中的一次巨大进步。此外 ,我们系统中采用的金属探针可同时用于AFM及电学特性成象 ,比如电阻 ,电容 ,这些是器件应用中的重要参数。     

Fluorescence near-field microscopy of DNA at sub-10 nm resolution

We demonstrate apertureless near-field microscopy of single molecules at sub-10 nm resolution. With a novel phase filter, near-field images of single organic fluorophores were obtained with approximately sixfold improvement in the signal-to-noise ratio. The improvement allowed pairs of molecules separated by approximately 15 nm to be reliably and repeatedly resolved, thus demonstrating the first true Rayleigh resolution test for near-field images of single molecules. The potential of this technique for biological applications was demonstrated with an experiment that measured the helical rise of A-form DNA.     

Amplitude- and phase-resolved optical near fields of split-ring-resonator-based metamaterials

We investigate the local optical response of split-ring resonator-(SRR)-based metamaterials with an apertureless scanning near-field optical microscope. By mapping the near fields of suitably resonant micrometer-sized SRRs in the near-infrared spectral region with an uncoated silicon tip, we obtain a spatial resolution of better than lambda/50. The experimental results confirm numerical predictions of the near-field excitations of SRRs. Combining experimental near-field optical studies with near- and far-field optical simulations provides a detailed understanding of resonance mechanisms in subwavelength structures and will facilitate an efficient approach to improved designs.     

Near-field optical microscope with a multiheight scanning imaging mode

A near-field scanning optical microscope has been developed to yield optical images with various gap distances between the probe and the sample surface. The microscope uses an apertureless metallic probe, the position of which is controlled by regulation of the tunneling-electron current from the probe to the sample and by computer-generated bias voltage. Experimental results of near-field optical imaging with the developed microscope at different gap distances are shown. Thirteen images at gap distances of 0 to 500nm demonstrate that the near-field image depends strongly on the gap distance. The imaging characteristics of a near-field imaging system are shown with the spatial-frequency spectra of images. Future investigation of the developed microscope is also discussed.     

Single-metal-cluster local imaging: polarized scattered electric field calculation compared to the field’s modulus and phase observed in the optical near-field

Simultaneous topographical and near-field optical imaging have been performed on single gold particles of diameters close to 12 nm. The optical source is a linearly polarized laser diode operating at λ=780 nm away from the plasmon resonance of the particles. The experimental optical image is recorded with an apertureless scanning near-field optical microscope (ASNOM) operating in transmission mode. It is compared to the components of the polarized scattered electric field around a single cluster calculated using Mie formalism. We show that the tip used in the experiments is sensitive to the axial component of the scattered field, thus allowing us to obtain the amplitude and the phase of the local field. Our derivation brings out new information, usually shaded when applied to an ensemble of particles. In particular, the dipole model widely used to describe the scattered field by a spherical particle is not suitable to describe the three components of the scattered field in the near zone. Our results are of interest for fundamental studies of the optical properties of single metal clusters and the control of local phenomena such as enhancement, extinction, etc. PACS 07.79.Fc; 78.67.Bf; 78.35.+c     

Spaser spectroscopy with subwavelength spatial resolution

We propose a method for high-sensitivity subwavelength spectromicroscopy based on the usage of a spaser (plasmonic nanolaser) in the form of a scanning probe microscope tip. The high spatial resolution is defined by plasmon localization at the tip, as is the case for apertureless scanning near-field optical microscopy. In contrast to the latter method, we suggest using radiationless plasmon pumping with quantum dots instead of irradiation with an external laser beam. Due to absorption at the transition frequencies of neighboring nano-objects (molecules or clusters), dips appear in the plasmon generation spectrum. The highest sensitivity is achieved near the generation threshold.     

Nanometer-scale probing of optical and thermal near-fields with an apertureless NSOM

We have used a home-made apertureless near-field scanning optical microscope (ANSOM) for mapping nanometric steps between SiC and gold regions under visible (λ=655 nm) and infrared (λ=10.6 μm) illumination. The images, obtained with a signal demodulation at the tip oscillation frequency and at higher harmonics, clearly show optical contrasts with a subwavelength resolution of about 30 nm. Other images recorded in the visible on a YBa₂Cu₃O₇ crystal indicate that the tip used in our experiments is able to reveal polarization effects. We also present a near-field thermal optical microscope (NTOM) which operates without any external illumination. In this new kind of microscope, the laser source which is usually used to excite the evanescent waves, is replaced by a simple heating of the sample. The electromagnetic radiation locally scattered by the tip comes from the thermal radiation. Our results with this new technique prove a 200 nm lateral resolution.     

Cloaking apertureless near-field scanning optical microscopy tips

We numerically demonstrate that properly designed plasmonic covers can be used to enhance the performance of near-field scanning optical microscopy (NSOM) systems based on the employment of apertureless metallic tip probes. The covering material, exhibiting a near-zero value of the real permittivity at the working frequency, is designed in such a way to dramatically reduce the undesired scattering due to the strongly plasmonic behavior of the tip. Though the light scattering by the tip end is necessary for the correct operation of NSOMs, the additional scattering due to the whole probe affects the signal-to-noise ratio and thus the resolution of the acquired image. By covering the whole probe but not the very tip, we show that unwanted scattering can be effectively reduced. A realistic setup, working at mid-IR frequencies and employing silicon carbide covers, has been designed and simulated to confirm the effectiveness of the proposed approach.     

25 nm resolution single molecular fluorescence imaging by scanning near-field optical/atomic force microscopy

High-resolution single molecular near-field fluorescence images were observed by scanning near-field optical/atomic force microscopy (SNOM/AFM). We modified the SNOM/AFM for both high-resolution fluorescence imaging and high-resolution topographic imaging. The imaged fluorophore, Alexa 532, is prepared with a poly-methyl-methacrylate (PMMA) film coating. A fluorescence resolution of 25 nm was obtained with a simultaneous topographic image of a flat surface. A sample prepared with a lower PMMA concentration exhibited a rough surface in the micro area. The results for the flat surface indicated that the fluorescence resolution is worst in the rough surface sample, that the maximum fluorescence intensities for the individual fluorophore are similar, and that the decay rate is faster. Thus, we concluded that the morphological effect is an important factor in fluorescence image resolution and the apparent lifetimes of the fluorescence molecules.     

Simulated Output Images of Near-Field Optics by Volume Integral Equation: Object Placed on the Dielectric Substrate

We investigated near-field optical (NFO) imaging characteristics of a small object placed on a dielectric slab by a computer-code using a three-dimensional volume integral equation with an effective iteration technique called the generalized minimal residual method. A simplified three-dimensional NFO microscope that consists of a small dielectric object placed on the dielectric substrate and a small dielectric sphere as a scanning probe-tip was considered. Calculating two-dimensional output images obtained from scattered far fields, we studied the effect of the substrate on NFO output images, the comparison of NFO output images with electrostatic field around the small object, the dependence of output image characteristics on the wavelength and the difference of imaging characteristics between incident plane waves and incident evanescent waves.     

Near-field scanning optical microscopy of single molecules by femtosecond two-photon excitation

We present a demonstration of near-field scanning optical microscopy of single molecules based on ultrafast two-photon-induced fluorescence. Measurements were performed by use of 100-fs pulses at 800 nm from a Ti:sapphire laser to excite the two-photon transition in Rhodamine B molecules. Although near-field probes are normally metal coated to achieve superresolution, we used uncoated tips to achieve sufficiently high optical powers to generate acceptable fluorescence emission rates. Images of single molecules demonstrate a resolution of ~175nm(< lambda/4) on a topographically smooth surface, which surpasses the apparent lambda/2 resolution limit for uncoated tips operating in the linear response regime.     

10 nm Spatial Resolution Fluorescence Imaging of Single Molecules by Near-Field Scanning Optical Microscopy Using a Tiny Aperture Probe

We demonstrate high-resolution fluorescence imaging of single molecules using near-field scanning optical microscopy (NSOM) with a tiny aperture probe for two different wavelengths in visible range in the illumination mode of operation. The spatial resolutions obtained at both excitation wavelengths were almost the same and the highest resolution realized was about 10 nm. To discuss the achievable resolution in aperture NSOM, we also employed a computer simulation by the finite-difference time-domain method for various aperture sizes and wavelengths. The resolution of 10 nm is predicted to be contributed by the single peak of localized near-field light around the rim of the aperture.     

Ultraviolet tip‐enhanced nanoscale Raman imaging

We have constructed an ultraviolet (UV)‐apertureless near‐field scanning optical microscope‐Raman spectroscopy system by using an aluminum tip for the simultaneous measurement of topography and Raman scattering of nanomaterials with high spatial resolution. The topography, Rayleigh scattering image, and tip‐enhanced Raman scattering image of the carbon nanotube film showed that a spatial resolution of around 19 nm was achieved. This spatial resolution of UV‐Raman mapping image exceeds that of previous approaches, which have several hundred nanometers of spatial resolution. Copyright © 2012 John Wiley & Sons, Ltd.     

Electroless nickel plating on optical fiber probe

As a component of near-field scanning optical microscope （NSOM）, optical fiber probe is an important factor influncing the equipment resolution. Electroless nickel plating is introduced to metallize the optical fiber probe. The optical fibers are etched by 40% HF with Turner etching method. Through pretreatment, the optical fiber probe is coated with Ni-P film by electroless plating in a constant temperature water tank. Atomic absorption spectrometry （AAS）, scanning electron microscopy （SEM）, and energy dispersive X-ray spectrometry （EDXS） are carried out to characterize the deposition on fiber probe. We have reproducibly fabricated two kinds of fiber probes with a Ni-P film： aperture probe and apertureless probe. In addition, reductive particle transportation on the surface of fiber probe is proposed to explain the cause of these probes.     

Characterization of strong electromagnetic field confinement on gold nanostructures by apertureless scanning near-field optical microscopy

We report on the detection of the optical near field of a 1D gold particle array by using an apertureless scanning near-field optical microscope. The strong near-field confinement measured above the grating proves unambiguously the near-field origin of the detected optical signal. Comparing the experiment with theory leads us to assign the optical near field to the first diffracted order of the grating, which is evanescent.     

Reducing Background Light Interaction in Near-Field Optical Microscopy Using Lateral and Vertical Probe-Dithering

We investigate the effectiveness of differential detection, which is a combination of probe-dithering and synchronous detection, in discriminating near-field light interaction from background light interaction in apertureless near-field optical microscopy (NSOM). The lateral differential NSOM with a photocantilever is more effective than the vertical differential detection, which does not always provide sufficient discrimination. The V-dithering-based lateral differential detection provides apertureless NSOM that can image the optical coupling between sample and probe dipoles, which is an interaction through near-field light.This paper was originally presented at the 5th International Conference on NEAR FIELD OPTICS and RELATED TECHNOLOGIES (NFO-5), which was held on December 6–10, 1998 at Coganoi Bay Hotel, Shirahama, Japan, in cooperation with the Japan Society of Applied Physics and Mombusho Grant-in Aid for Scientific Research on Priority Areas “Near-field Nano-optics” Project, sponsored by Japan Society for the Promotion of Science.     

Near-field magneto-optics and microscopy in resonant scattering of light from a linear nanoprobe

A theory is presented for the polar near-field magneto-optical Kerr effect in scattering of light from a linear nanoprobe. In the framework of Green’s function technique, a solution is obtained for the problem of near-field magneto-optics and apertureless scanning microscopy of lateral magnetic inhomogeneities (domains) with nanometer scale. The probe in the form of a nanowire and the sample with a near-surface magnetic nanolayer are considered to support surface plasmons. Electromagnetic coupling between a nanow-ire and a sample surface (polarizability of the complex “probe plus image charges”) is taken into account self-consistently. Magneto-induced polarization of an ultrathin near-surface layer is treated within linear approximation in magnetization which is perpendicular to the layer. The polarization, spectral and angular characteristics of light scattering modulated by magnetization and resonantly enhanced by surface plasmons are examined. Dependence of the near-field magneto-optical response on the probe-domain distance along the sample surface is obtained. The resolution power of scanning near-field microscopy is estimated and the factors to influence it are pointed out.