共查询到20条相似文献,搜索用时 31 毫秒
1.
V.K. Sharma P.S. Singh S. Gautam P. Maheshwari D. Dutta R. Mukhopadhyay 《Journal of membrane science》2009
Dynamical motion of water sorbed in reverse osmosis polyamide membrane (ROPM) material is reported as studied by quasielastic neutron scattering (QENS) technique. The ROPM studied here has pore size of 4.4 Å as determined by positron annihilation lifetime spectroscopy. Analysis of the QENS data showed that diffusion behavior of the water within the membrane is describable by random jump diffusion model. A much longer residence time is found as compared to bulk water. Positive shift of the freezing point as observed in differential scanning calorimetry indicates presence of strong attractive interaction corroborating the slower diffusivity as observed in QENS. 相似文献
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《Radiation Physics and Chemistry》2007,76(2):142-145
An experimental positron annihilation lifetime spectroscopy (PALS), differential scanning calorimetry (DSC) and small angle X-ray scattering (SAXS) study of the effect of the advance of the crosslinking reaction on the free volume in a copolymer of styrene–butadiene and natural rubbers was carried out. The crosslink density developed in SBR specimens with different sulfur contents and cure temperatures was studied. SAXS technique was applied to study the process of crosslinking in NR as a function of the cure temperature. Finally, a study of different SBR/NR blends is presented using PALS and DSC. 相似文献
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D. Samios S. Castiglia N. Pesce Da Silveira H. Stassen 《Journal of Polymer Science.Polymer Physics》1995,33(13):1857-1866
The network formation process of the triethylamine-initiated reaction of 1,4-butanediol diglycidyl ether with cis-1,2-cyclohexanedicarboxylic anhydride has been investigated by conventional differential scanning calorimetry and temperature scanning Brillouin light scattering as a new experimental method for the estimation of the reaction's conversion factor. The time-temperature evolution of the observed quantities (reaction enthalpy in the calorimetric measurements and hypersound velocity in the light scattering) reflects in both sets of experimental data, but results in different kinetic parameters obtained by the assumption of an Arrhenius behavior. These differences are ascribed to the relation of the observed properties with respect to the evolution of the reaction. The enthalpy production of the system observed in the calorimetric experiment is shown to be connected directly to the chemical reaction, whereas the change in the hypersound velocity measured by the light scattering method is sensitive to the solidification of the system. © 1995 John Wiley & Sons, Inc. 相似文献
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A series of 3-n-alkyl substituted poly(4-hydroxybenzoates) were prepared by melt-polycondensation of the corresponding monomers. The length of the alkyl side chains was varied in the range of 3 to 18 carbon atoms. The average degree of polymerisation (DP) was determined by 1H NMR end-group analysis. The thermal behavior of the polymers was studied by differential scanning calorimetry (DSC) and polarising microscopy (PM). Structural investigations of oriented and not oriented samples were performed by means of wide angle X-ray scattering (WAXS). The density of the polymers was measured by gradient column technique. 相似文献
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M. Garcia-Ramirez J. Y. Cavaill D. Dupeyre A. Pguy 《Journal of Polymer Science.Polymer Physics》1994,32(8):1437-1448
Each homopolymer, cellulose and polyamide 66 (PA66), was separately dissolved in a mixture of N-methyl morpholine N-oxide and phenol (80/20 w/w). Then, the two solutions were mixed together. This step leads to the crystallization of PA66 in small aggregates (about 1 μ) regularly dispersed in the cellulose solution. It appeared that this morphology remains independent of further processing such as spinning or casting. Finally, fibers or films were precipitated in methanol. The entire preparation technique used here results mainly in two-phase systems in which PA66 domains are embedded in an amorphous cellulose matrix. The specimens obtained were at first characterized by differential scanning calorimetry, scanning electron microscopy, and wide angle x-ray scattering. © 1994 John Wiley & Sons, Inc. 相似文献
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Nonaethylene glycol and pentadecaethylene glycol and their dimethyl ethers have been prepared and characterized, with respect to crystallinity by wide- and small-angle X-ray scattering, Raman scattering, i.r. spectroscopy and differential scanning calorimetry. Wide-angle X-ray scattering is similar to that from high molecular weight poly(ethylene oxide). The crystal habit is lamella. The lamellae are highly crystalline and the surface layers are ordered. Comparison with crystalline poly(ethylene oxide) prepared conventionally, and having a distribution of chain lengths, shows that such samples crystallize into lamellae with disordered surface layers. 相似文献
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A. V. Anshakova E. V. Vinogradov N. G. Sedush T. S. Kurtikyan S. S. Zhokhov V. I. Polshakov Yu. V. Ermolenko V. Yu. Konyukhov O. O. Maksimenko S. E. Gelperin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(5):983-989
The formulations of rifabutin (RB) and 2-hydroxypropyl-β-cyclodextrin (HP-β-CD), obtained using different preparation techniques, are studied by means of differential scanning calorimetry and molecular spectroscopy (FTIR, NMR, Raman scattering, and photon correlation light scattering). It is established that molecules of RB do not form inclusion complexes with the molecules of HP-β-CD, and an increase in the solubility of RB determined earlier is caused by the formation of weak intermolecular associates. 相似文献
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L. I. Makarova L. V. Filimonova L. V. Dubrovina M. I. Buzin G. G. Nikiforova B. G. Zavin V. S. Papkov 《Polymer Science Series B》2010,52(5-6):346-352
A new approach to the synthesis of hydrolytically stable dimethylsiloxane-ethylene oxide polyblock copolymers is described, in which ethylene oxide and siloxane blocks are linked by urethane groups. The molecular-mass parameters of block copolymers of different compositions are determined by capillary viscometry, light scattering, and gel-permeation chromatography. The temperature transitions in copolymers are characterized by differential scanning calorimetry. 相似文献
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COMPATIBILITY IN POLYMER BLENDS OF POLY (VINYL ACETATE) AND POLY (METHYL METHACRYLATE)STUDIED BY NMR
Compatibility of poly (vinyl acetate) (PVAc) with poly (methyl methacrylate) (PMMA) mixtures has been studied by using nuclear magnetic relaxation, differential scanning calorimeter and small-angle X-ray scattering techniques. The nuclear magnetic relaxation time T_1's were measured as a function of composition in blends of PMMA and PVAc prepared from chloroform solution. The results show that the system is miscible for casting from chloroform solution. 相似文献
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T. W. Warmerdam R. J. M. Nolte W. Drenth J. C. Van Miltenburg D. Frenkel R. J. J. Zijlstra 《Liquid crystals》1988,3(8):1087-1104
The synthesis of a new discotic mesogen, 2,3,7,8,12,13-hexa(octadecanoyloxy)-truxene is reported. This new compound has been studied using polarization microscopy, differential scanning calorimetry, small angle X-ray scattering and adiabatic calorimetry. The results are compared with those of two other truxene derivatives from the same series: 2,3,7,8,12,13-hexa(decanoyloxy)truxene and 2,3,7,8,12,13-hexa(tetradecanoyloxy)truxene. Refractive index measurements have been performed on these three truxene derivatives as a function of temperature. A re-entrant isotropic phase has been observed in 2,3,7,8,12,13-hexa(octadecanoyloxy)truxene. This is the first report of such a phase in a pure mesogen. We also report measurements of the ratio of the Frank constants for splay and bend in the nematic regime of this new mesogen as a function of temperature using the magnetic Frederiks transition technique. 相似文献
13.
Avendaño-Gómez JR Balmori-Ramírez H Durán-Páramo E 《Journal of colloid and interface science》2012,380(1):75-82
The aim of this works is to study an oil-in-water emulsion stabilized with a triblock copolymer Synperonic F127 which presents a double size distribution of oil droplets. The emulsions were studied experimentally by means of differential scanning calorimetry (DSC) and dynamic light scattering (DLS). The DSC analysis was carried out focusing on the cooling behavior of the emulsion. The cooling thermograms of the oil-in-water emulsion revealed two crystallization peaks with Gaussian profile; the interesting characteristic is that both peaks are separated in temperature. In accordance to previous works for a single oil dispersed within an aqueous phase, the DSC technique must show a single Gaussian peak of crystallization attributable to a size distribution of droplets. In the present case of emulsions stabilized with 1 g/L of Synperonic F127, the aggregation behavior of triblock as a function of temperature allows to produce an emulsion with a double size droplet distribution. Comparison with emulsions stabilized with 2 and 4 wt% of non-ionic Tween 20 are also presented. 相似文献
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A. P. Korobko S. N. Drozd S. V. Krasheninnikov I. V. Levakova S. N. Chvalun Yu. M. Milekhin N. I. Shishov T. A. Bestuzheva 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(10):1726-1732
The thermophysical properties and surface structure of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (TNCO) particles before and after their contact with liquid nitro esters were studied by differential scanning calorimetry and small-angle X-ray scattering. The thermophysical properties of TNCO changed after contact with nitro esters, and the temperature range of the transition from the β to δ polymorph broadened. This peculiarity was explained in terms of the fracton theory by changes in the heat capacity of particles related to the formation of nanoscale roughness with a fractal (scale-invariant) organization as a result of surface etching by solvents such as nitro esters, which are thermodynamically “bad” with respect to TNCO. The volume properties of particles did not change. The possibility of determining the fractal dimension of the surface of TNCO particles by differential scanning calorimetry was demonstrated. The rate of heating was then used as a “scale ruler” (“yardstick”), and the temperature range of the transition from the β to δ polymorph, as a measured parameter. The dimension of the surface fractal was also determined by an independent method (small-angle X-ray scattering). The results obtained by the two methods were closely similar. 相似文献
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Marcel Ruppert Katharina Landfester Ulrich Ziener 《Journal of polymer science. Part A, Polymer chemistry》2010,48(22):4929-4937
For the first time, poly(ε‐caprolactone) and poly(ε‐caprolactone‐co‐ε‐caprolactam) nanoparticles were successfully obtained by anionic polymerization of ε‐caprolactone and anionic copolymerization of ε‐caprolactone with ε‐caprolactam, respectively, in heterophase by the miniemulsion technique. After polymerization the resulting dispersions are stable for hours in case of the pure polyester and days for the copolymer. The syntheses were carried out with different continuous phases, amounts of surfactant, initiator, and monomers. The influence of the reaction parameters on the molecular weight of the polymers and on colloidal characteristics like size and morphology of the nanoparticles were studied by dynamic light scattering, gel permeation chromatography, differential scanning calorimetry, nuclear magnetic resonance, and Fourier transform infrared spectroscopy. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
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Through differential scanning calorimetry and wide angle x-ray scattering, the room-temperature transitions of native (never melted) polytetrafluoroethylene have been investigated. The independence of the transitions, and in particular of the lowest one, on the heating kinetics, seems to suggest that also this transition is a true crystal-crystal transition. 相似文献
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Gunn E Sours R Benedict JB Kaminsky W Kahr B 《Journal of the American Chemical Society》2006,128(44):14234-14235
Rhythmic precipitates of centrosymmetric phthalic acid were analyzed by a square-wave mechanically modulated circular extinction imaging microscope. Spherulites were bisected into square-millimeter sized heterochiral domains that are a consequence of circular intensity differential scattering of left and right circularly polarized light. The dissymmetry and chiral amplification indicated optically was confirmed in the microtexture established by atomic force and scanning electron microscopies. 相似文献