锰原子的二步多光子与三步三光子共振电离研究

激光共振电离技术是痕量分析中的重要手段之一。文章以速率方程理论为基础,对锰原子的激光共振电离过程进行了分析,讨论了电离过程中各级激发光功率密度及激光作用时间对电离效率的影响;提出了根据所要求的电离效率和激光作用时间计算所需要的各激发光或电离激光的功率密度的方法;得到了饱和激发或饱和电离的规律及阈值条件。研究发现,在激光作用时间为10 ns时,锰原子饱和电离的激光强度阈值基本都在108 W·cm-2的量级,只有“1+1”双色双共振低三个量级;而“1+1”和“1+1+1”饱和激发的激光强度阈值则在102～103 W·cm-2量级;并且随着激光作用时间的增加,各过程的饱和激发和饱和电离的激光强度阈值将单调减少。     

Structure of the (1 1 1) hydrogen platelet in silicon

The stability of hydrogen complexes aligned in a (1 1 1) plane of silicon is studied theoretically. Pairs of hydrogen atoms saturating broken bonds between adjacent planes are found to be the most stable arrangement with the heat of formation increasing as the platelet grows. The related stress is estimated and electronic effects are discussed.     

Al(111)/Al_3Li(111)的界面性质

运用基于第一性原理的平面波贋势法,计算研究了Al (111)/Al_3Li (111)的界面性质.结果表明:Al (111)/Al_3Li (111)的界面具有三种原子配位关系结构,其中界面处仍保持与基体Al一致的三明治堆垛构型的界面稳定性最好.计算表明,该结构界面最薄弱层,位于Al_3Li (111)内,其分离功最小(约1.53 J/m~2),强度最弱,而基体Al和Al_3Li内部的强度随着到界面距离的增大而逐渐增强.     

Relativistic one-step photoemission calculations for Pt(1 1 1)

A fully relativistic one-step theory of photoemission has been applied to normal emission from Pt(1 1 1) induced by circularly polarized ultraviolet radiation. The calculated spin polarization and intensity spectra are in quantitative agreement with experimental data. Individual features are identified as bulk interband transitions and one-dimensional density of state involving initial states of specified symmetries.     

Diffusions of small clusters on Pt(1 1 1) and Cu(1 1 1) surfaces

Diffusions of small cluster Pt₆ on Pt(1 1 1) surface and Cu₆ on Cu(1 1 1) are studied by molecular dynamics simulation, respectively. The atomic interaction is modeled by the semiempirical potential. The results show that the diffusion processes in the two systems are far different. For example, on Pt(1 1 1) surface, the hopping of single atom and the shearing of two atoms of hexamer only occur on the adatom(s) adsorbed at B-step, while on Cu(1 1 1) surface they can appear on the adatom(s) either at A-step or B-step. To the concerted translation of the parallelogram hexamer, the anisotropy in the diffusion path is observed in the two systems, the mechanisms and then the preferential paths, however, are completely different. The reasons for these diffusion characteristics and differences are discussed.     

Theoretical analysis of reactivity on Pt(1 1 1) and Pt-Pd(1 1 1) alloys

The reactivity of Pt-Pd alloy surfaces towards the oxygen reduction reaction is studied as a function of the alloy overall composition and surface atomic distribution and compared to that on pure Pt surfaces. The systems include Pd and Pt monolayers on various substrates and Pt₃Pd, PtPd and PtPd₃ surfaces of ordered alloys. Reactivity is evaluated on the basis of the adsorption strength of oxygenated compounds which are intermediate species of the four-electron oxygen reduction reaction, separating the effect of the first electron-proton transfer from that of the three last electron-proton transfer steps. None of the alloys are found to provide better sites than those of pure Pt both for O₂ dissociation and for the reduction of O and OH to water; with the skin surfaces being the closest to pure Pt. The results are discussed in relation to those found in 10-atom clusters of similar compositions and to experiments.     

Precise semiconductor nanotubes and nanoshells fabricated on (1 1 0) and (1 1 1) Si and GaAs

In our previous works, we showed that ultrathin epitaxial heterofilms (down to two monolayers for the case of InGaAs/GaAs) can be controllably detatched from substrates and rolled, under the action of internal stresses, into various cylindrical micro- and nanoshells (tubes, scrolls, rings, spirals, etc.). The present review outlines the cornerstone stages in the development of this fabrication technology for semiconductor and metal nanoobjects, including: (1) directional rolling of films yielding 3D micro- and nanoshells of various shapes; (2) assembling of micro- and nanoshells in more complex architectures; (3) super-critical drying of nanoshells, and (4) formation of nanoshells whose sizes can be precisely controlled in three dimensions.With this technology new possibilities that open up for the use of strained films, selectively, grown on uncommonly used (1 1 0) and (1 1 1) surfaces, are presented. The role of mechanical anisotropy in the formation of the 3D nanoshells and the electrical and mechanical properties of formed nanotubes are discussed.     

Two-photon E1M1 and E1E2 transitions between 2p and 1s levels in hydrogen

Two-photon transitions in the hydrogen atom are analytically evaluated within the nonrelativistic limit utilizing the Coulomb Green function method. The two-photon emission probability for the transition process 2s→2γ(E1)+1s serves as a test for the other calculations and was compared with the results of previous analytical and numerical calculations. The two-photon emission probabilities for the processes 2p→ γ(E1)+γ(M1)+1s and 2p→γ(E1)+γ(E2)+1s are also evaluated and compared with previous numerical calculations. Different nonrelativistic “forms" for the decay probabilities in combination with different gauge choices are considered.     

Non-abelian Cheshire cat bag models in 1+1 dimensions

Non-abelian Cheshire cat models are investigated in their lagrangian and hamiltonian formulations. The lagrangian bag boundary conditions are used to derive the form of non-abelian soliton operators, through which fermions are represented in bosonic language. These soliton operators are then used to construct the boundary interaction in the hamiltonian picture, wherein the bosonic sector is formulated by means of a current algebra involving anomalous commutators. The hamiltonian and the momentum operator are shown to commute, thus implying that the Cheshire cat criterion — the independence of the energy spectrum on the bag wall position — is fulfilled by the system.     

Schwinger terms in 1+1 dimensions

Two different approaches — Källen’s and Brandt’s methods — for calculation of the Schwinger terms in the 1+1 dimensional Abelian and non-Abelian free current algebras are discussed. These methods are applied to calculation of the single and double commutators. The validity of the Jacobi identities is examined in 1+1 and 3+1 dimensions and in this way is given natural restriction on the regularization. It is shown that the Jacobi identity cannot be broken in 1+1 dimensions even using the regularization which fails in the 3+1 dimensional case. A connection between the Schwinger term and anomaly is shown in the simplest case of the Schwinger model.     

Scalars coupled to fermions in 1+1 dimensions

Using a method introduced in an earlier paper, we study a Bose field coupled to a Fermi field in 1+1 space-time dimensions. We employ the standard Hamiltonian formalism in which one computes the eigenvalues and eigenvectors of the Hamiltonian matrix. The matrix elements are computed using states defined on a lattice in momentum space. The results are compared with known strong and weak coupling limits. Bound states and renormalization effects are studied. We find that the choice of bare masses which give specified physical masses can be non-unique once a critical couplingλ _μ has been exceeded.     

Simulations of V-I characteristics in a plasmafocus fun

The voltage and current characteristics in a plasma focus gun are simulated to yield the current efficiency and the rundown velocity of the current sheath. Since the discharge circuit is strongly influenced by the rundown dynamics of the current sheath, the simple snowplow model, which is modified to include the time-varying current and mass efficiencies, us used. The computer simulations are carried out for two separate experiments using deuterium and argon gas. A steady state of constant rundown velocity and saturated sheath current for both gases is correlated to the maximum holding voltage of the glass insulator. As much as 27% of the total discharge current for the deuterium gas and 33% for argon gas stay behind as leakage currents around the glass insulator when the radial compression phase begins     

3-三苯基锗基-1,1-二苯基-1-丙烯及其同系物的拉曼光谱和红外光谱

我们合成了一类多苯基取代的烯丙基锗烷类化合物,并测量了这三种化合物的拉曼光谱和红外光谱。经光谱分析,指认了主要波数所对应的分子振动。在这三种化合物的拉曼光谱中,Ge-Ph均在1000cm-1附近出现非常强的振动峰;烯丙基中的C=C键在1615 cm-1和1595 cm-1附近出现强的振动峰;在1585 cm-1附近出现芳香环的多重振动峰;在3050 cm-1(m)1、025 cm-1(m)、615 cm-1(m)附近出现芳香环的C-H伸缩振动,C-H面内弯曲振动和C-H面外弯曲振动峰;与饱和碳原子相连接的Ge-C振动峰分别出现在595 cm-1、592 cm-1和597 cm-1。在红外光谱中,这类化合物的Ge-C振动和饱和Ge-C振动较为明显,分别出现在1090 cm-1(s)附近和625 cm-1~577 cm-1(w)之间。     

1+1 dimensional compactifications of string theory

We argue that stable, maximally symmetric compactifications of string theory to 1+1 dimensions are in conflict with holography. In particular, the finite horizon entropies of the Rindler wedge in 1+1 dimensional Minkowski and anti-de Sitter space, and of the de Sitter horizon in any dimension, are inconsistent with the symmetries of these spaces. The argument parallels one made recently by the same authors, in which we demonstrated the incompatibility of the finiteness of the entropy and the symmetries of de Sitter space in any dimension. If the horizon entropy is either infinite or zero, the conflict is resolved.     

Sn/Ge(1 1 1) α-phase: characterization of image resonances by specular electron reflection and selective electron scattering

Image potential resonances on the Sn/Ge(1 1 1) α-phase are investigated by two closely related methods: specular electron reflection and so-called selective electron scattering. Electrons from image resonances are detected on this surface at 120 and 300 K, i.e. below and above the phase transition at about 200 K. The dispersion of the image resonances reveals at these two temperatures equivalent effective electron masses, which are characteristic for this type of electronic surface states. The results of the two methods are consistent according to the similarity of the scattering processes. Changes in the loss peak intensity with the annealing temperature are assigned to the surface quality and are reflected by characteristic photoemission intensities.     

Water adsorption on hydrogenated Si(1 1 1) surfaces

The adsorption of water on the hydrogen terminated Si(1 1 1) surface is studied by means of first-principles calculations as well as contact angle measurements. Possible initial adsorption configurations for single water molecules and the potential energy surface are calculated. Only small adsorption energies of the order of meV are predicted. Calculations for higher coverage show that the water-water interactions are stronger than the water-surface bonding. The contact angle formed between a water droplet on the surface approximated from the total-energy calculations amounts to 88°, while our measured value is 91°.     

(1 + 1) dimensional hydrodynamics for high-energy heavy-ion collisions

A (1 + 1)-dimensional hydrodynamical model in the light-cone coordinates is used to describe central heavy-ion collisions at ultrarelativistic bombarding energies. Deviations from Bjorken scaling are taken into account by choosing finite-size profiles for the initial energy density. The sensitivity of fluid-dynamical evolution to the equation of state and the parameters of initial state are investigated. Experimental constraints on the total energy of produced particles are used to reduce the number of model parameters. Spectra of secondary particles are calculated under the assumption that the transition from the hydrodynamical stage to the collisionless expansion of matter occurs at a certain freeze-out temperature. An important role of resonances in the formation of observed hadronic spectra is demonstrated. The calculated rapidity distributions of pions, kaons, and antiprotons in central Au + Au collisions at √^s NN = 200 GeV are compared with experimental data of the BRAHMS Collaboration. Parameters of the initial state are reconstructed for different choices of the equation of state. The best fit of these data is obtained for a soft equation of state and Gaussian-like initial profiles of the energy density, intermediate between the Landau and Bjorken limits. The text was submitted by the authors in English.     

Hanle lifetime measurements of SrI 1P1 and CaI 1P1 levels excited by a neutral beam of 1 1S0 helium atoms

A 0.8 keV He(1 ¹S₀) beam was used to coherently excite the ¹P₁ levels of Sr and Ca targets. The coherence appears as an alignment of the excited state with respect to the beam axis. We report here the results of a Hanle measurement, or a zero-field level-crossing experiment, performed on these coherently excited levels. The radiative lifetimes of the SrI ¹P₁ and CaI ¹P₁ levels were measured to be 4.7 ns and 5.3 ns, respectively. These values are in good agreement with conventional Hanle measurements.     

A note on supersymmetry breaking in 1+1 dimensions

The spontaneous breakdown of supersymmetry for a single chiral superfield in 1+1 dimensions is investigated and a number of puzzling features are resolved by noting that the loop expansion is not always valid. It is found that both broken and unbroken supersymmetry are stable with respect to radiative corrections.     

Structures of CoAl(1 1 1) surface: A first principles study

The structures of the CoAl(1 1 1) surface are studied by first principles calculations. Our calculations show that the surface layer is always occupied by pure Al for all concentrations studied here, which indicates the dominant role of the Al segregation tendency. This is different from the CoAl(0 0 1) surface, where a number of Co anti-sites are found on the top most layer. The calculated surface phase diagram of ground states shows that there are three stable structures. The diffusion barriers of the metastable structure evolving to the stable structure are also calculated. The high diffusion barrier can explain the appearance of metastable structures at low temperature in experiment.