麦克斯韦分子速率分布律与扩散方程、扩散系数的初浅推导

从演示统计规律的装置－伽耳顿板实验出发，用初等微积分方法推导高斯误差函数，麦氏速率分布律，扩散方程，扩散系数。     

Fractional nonlinear diffusion equation,solutions and anomalous diffusion

We devote this work to investigate the solutions of a generalized diffusion equation which contains spatial fractional derivatives and nonlinear terms. The presence of external forces and absorbent terms is also considered. The solutions found here can have a compact or long tail behavior and, in particular, for the last case in the asymptotic limit, we relate these solutions to the Lévy or Tsallis distributions. In addition, from the results presented here a rich class of diffusive processes, including normal and anomalous ones, can be obtained.     

On the diffusion of a fast molecule

We consider the motion of a heavy particle in interaction with an infinite ideal gas of slow atoms. We prove that the velocity of the heavy particle is, in a suitable limit, modeled by a deterministic process. We also treat the process of rescaled velocity fluctuations around a certain deterministic motion and show that this is appropriately modeled by a nonhomogeneous diffusion process.Supported in part by NSF grants PHY-8201708 and DMR81-14726.Supported in part by NSF grant PHY-8003298 and the Seton Hall University, Research and Faculty Development Council.     

The diffusion constant for two-state brownons

We calculate the diffusion constant for two-state brownons when the change of state is not, as usually assumed, Markovian. The correction to the non-interchanging species result is found to be exactly expressible in terms of the Laplace transforms of the sojourn time densities.     

Chapman-Enskog velocity distribution for tracer diffusion

The Chapman-Enskog method is used to obtain an approximate velocity distribution function for tracer diffusion in dilute hard-sphere mixtures. Different ratios of the mass of the tracer to that of the excess component (including the well-known limiting cases of the Lorentz and the Rayleigh models) are considered and the corresponding diffusion coefficients are also evaluated. A comparison with the recent results of Tompson and Loyalka for both the diffusion coefficients and the distribution functions provides a perspective on the usefulness and nature of the approximate method.     

局域浓度调控扩散系数的次氯酸-碘离子-丙二酸系统图灵斑图形成中的反常扩散

通过数值模拟及振幅方程解析解方法,从实空间和倒空间分析了受局域浓度扩散系数调控下次氯酸-碘离子-丙二酸反应扩散系统图灵斑图形成的扩散机理.在零扩散系数调节下,斑图形成为典型的菲克扩散;而在负向正向扩散系数调节下,斑图的形成依赖欠扩散和超扩散.图灵系统的浓度稳态振幅对随机初始条件敏感性随局域浓度扩散调控系数k的增大而增加.     

Computer simulation of shock waves in the completely asymmetric simple exclusion process

We study the evolution of the completely asymmetric simple exclusion process in one dimension, with particles moving only to the right, for initial configurations corresponding to average density _– ( ₊) left (right) of the origin, _{– +}. The microscopic shock position is identified by introducing a second-class particle. Results indicate that the shock profile is stable, and that the distribution as seen from the shock positionN(t) tends, as time increases, to a limiting distribution, which is locally close to an equilibrium distribution far from the shock. Moreover , withV=1– _–– ₊, as predicted, and the dispersion ofN(t), ²(t), behaves linearly, for not too small values of ₊– _–, i.e., , whereS is equal, up to a scaling factor, to the valueS _WA predicted in the weakly asymmetric case. For ₊= _– we find agreement with the conjecture .Dedicated to the memory of Paola Calderoni.     

Apparent diffusion coefficient of line scan diffusion image in normal prostate and prostate cancer—comparison with single-shot echo planner image

Purpose

This retrospective study was designed to evaluate the apparent diffusion coefficient (ADC) of line scan diffusion images (LSDI) in normal prostate and prostate cancer. Single-shot echo planner images (SS-EPI) were used for comparison.

Materials and Methods

Twenty prostate tumors were examined by conventional MRI in 14 patients prior to radical prostatectomy. All patients were examined with a 1.5-T MR imager (Signa CV/i ver. 9.1 GE Medical System Milwaukee, WI, USA). Diffusion-weighted MR imaging (DWI) using LSDI was performed with a pelvic phased-array coil, with b values of 5 and 800 s/mm². DWI using SS-EPI was performed with a body coil, with b values of 0 and 800 s/mm². The ADCs of each sequence for 14 normal prostate and 20 prostate cancers were histopathologically assessed. Signal-to-noise ratio (SNR) on DWI was estimated and compared for each sequence.

Results

The mean ADCs (±S.D.) of normal peripheral zones (PZ), transition zones (TZ) and cancer (in 10⁻³ mm²/s) that used LSDI were 1.42±0.12, 1.23±0.10 and 0.79±0.19, respectively. Those that used SS-EPI were 1.76±0.26, 1.38±0.20 and 1.05±0.27, respectively. Using unpaired t test (P<.05), we found a significant difference in each sequence between normal tissue (both PZ and TZ) and the cancer. Paired t test (P<.05) also registered a significant difference between LSDI and SS-EPI. Mean SNR for DWI using LSDI was 16.49±5.03, while the DWI using SS-EPI was 18.85±9.26. The difference between the SNR of each sequence was not statistically significant by paired t test.

Conclusion

We found that ADCs using LSDI and SS-EPI showed similar tendencies in the same patients. However, in all regions, LSDI ADCs had smaller standard deviations than SS-EPI ADCs.     

基于信息分配和扩散理论的东北地区干旱脆弱性特征分析

基于信息分配和扩散理论, 结合标准化降水指数和东北三省(黑龙江、吉林、辽宁)旱灾灾损指数, 综合考虑了气象因子与社会因子, 分析了我国东北三省1971–2012年的干旱脆弱性特征, 并进一步计算了我国东北三省的干旱风险. 使用信息分配方法估计干旱强度概率分布, 采用二维正态信息扩散方法构造了干旱强度与旱灾灾损的脆弱性关系, 将干旱强度的概率分布与脆弱性折线相乘求和(离散分布)或积分(连续分布)即可得到多年平均风险. 研究表明, 针对灾损的小样本事件引入信息分配和扩散方法对小样本数据进行分析, 获取的干旱强度概率分布比简单直方图法所得更加平滑, 而以事件为因、灾损为果得到干旱强度-旱灾灾损的脆弱性关系, 物理意义明确, 所得脆弱性关系折线也比较符合实际情况, 并且不同样本长度所得结果相近, 对样本长度不敏感, 较好地克服了小样本分析的不稳定性.关键词：信息分配和扩散理论标准化降水指数脆弱性风险     

反常扩散与分数阶对流-扩散方程

反常扩散现象在自然界和社会系统中广泛存在.考虑了扩散过程的时间相关和时空相关性，用非局域性的处理方法，在传统的二阶对流 扩散方程基础上，得到了分数阶对流 扩散方程，以此方程来描述反常扩散.在此方程中，弥散项和对时间的导数为分数阶导数所代替.由此分数阶对流 扩散方程，对传统的费克扩散定律进行推广，得到了广义的分数费克扩散定律，分数费克扩散定律说明某时刻空间中某点的流量不仅与其领域内的浓度梯度有关，而且与整个空间中其他不同点的粒子浓度、浓度变化的历史，甚至初始时刻的浓度有关.讨论了方程的解——分数稳定分布，并由此说明了扩散运动的平均平方位移是运移时间的非线性函数. 关键词： 扩散 分数阶微积分 稳定分布（Lévy分布） 费克扩散定律     

Simultaneous tracer diffusion and interdiffusion in a sandwich-type configuration to provide the composition dependence of the tracer diffusion coefficients

In this paper, a new formalism of a combined tracer and interdiffusion experiment for a binary interdiffusion couple is developed. The analysis requires an interdiffusion couple that initially contains a thin layer of tracers of one or both of the constituent elements at the original interface of the couple (sandwich interdiffusion experiment). This type of interdiffusion experiment was first performed in 1958 by J.R. Manning. The theoretical analysis presented in this paper is based on a newly developed phenomenological theory of isotopic interdiffusion combined with the Boltzmann–Matano formalism. This new analysis now provides the means to obtain the composition dependent interdiffusion coefficient and tracer diffusion coefficients simultaneously from analysis of the interdiffusion and tracer profiles in a single sandwich interdiffusion experiment. The new analysis is successfully applied to the results of Manning’s original ‘sandwich interdiffusion’ experiment in the Ag–Cd system (six couples in total) and is validated with an independent determination of the Ag and Cd tracer diffusion coefficients by Schoen using the conventional thin film technique. Suggestions for further development of the sandwich interdiffusion experiment and analysis to the case of multicomponent alloys are provided.     

A note on confined diffusion

The random motion of a Brownian particle confined in some finite domain is considered. Quite generally, the relevant statistical properties involve infinite series, whose coefficients are related to the eigenvalues of the diffusion operator. Because the latter depend on space dimensionality and on the particular shape of the domain, an analytical expression is in most circumstances not available. In this article, it is shown that the series may in some circumstances sum up exactly. Explicit calculations are performed for 2D diffusion restricted to a circular domain and 3D diffusion inside a sphere. In both cases, the short-time behaviour of the mean square displacement is obtained.     

Influence of isotopic substitution on the diffusion and thermal diffusion coefficient of binary liquids

The mutual mass diffusion coefficient (D) and the thermal diffusion coefficient ( D _T) of the liquids acetone, benzene, benzene-d ₁, benzene-d ₃, benzene-d ₅, benzene-d ₆, benzene- ¹³C₆, n-hexane, toluene, 1, 2, 3, 4-tetrahydronaphtalene, isobutylbenzene, and 1, 6-dibromohexane in protonated and perdeuterated cyclohexane have been measured with a transient holographic grating technique at a temperature of 25 ^°C. The mass diffusion coefficient shows a pronounced concentration dependence. Perdeuteration of cyclohexane only leads to marginal changes of the mass diffusion coefficient. The Stokes-Einstein equation describes the limiting tracer diffusion coefficients well if the solute molecule is smaller than the solvent. It is not capable to describe the small isotope effect of a few percent. On the other hand, the isotope effect, which is independent of concentration, is in agreement with the Enskog theory, that does not provide the absolute value of the mass diffusion coefficient of the liquid mixtures. The thermal diffusion coefficient of all the binary mixtures shows a moderate and almost linear concentration dependence. Its isotope effect, which is the change of D _T upon deuteration of cyclohexane, varies with mole fraction. The thermophoretic force acting on any tracer molecule in cyclohexane changes by the same amount when cyclohexane is perdeuterated, irrespective of the magnitude of the thermophoretic force before deuteration. This change of the thermophoretic force is equal but of opposite sign to the difference between the thermophoretic forces acting on cyclohexane and perdeuterated cyclohexane as tracers in any of the above liquids.     

A model of modulated diffusion. II. Numerical results on statistical properties

We investigate numerically the statistical properties of a model of modulated diffusion for which we have already computed analytically the diffusion coefficientD. Our model is constructed by adding a deterministic or random noise to the frequency of an integrable isochronous system. We consider in particular the central limit theorem and the invariance principle and we show that they follow wheneverD is positive and for any magnitude of the noise; we also investigate the asymptotic distribution in a case whenD=0.     

表面Cu原子间相互作用对Cu(001)表面跳跃扩散行为的影响

采用嵌入原子方法的原子间相互作用势，利用准静态分子动力学模拟研究了Cu原子在Cu(001)表面吸附所导致的基体晶格畸变以及对其附近的另一个吸附原子自扩散行为的影响.研究结果表明，吸附原子的存在可以导致多达10层的Cu基体晶格产生畸变.两个吸附原子所产生的晶格畸变应力场之间的相互作用，可以导致吸附原子运动活性的增加.通过比较同一路径上往返跳跃扩散势垒的差异发现，在原子间相互作用势的有效距离之外，两个吸附原子的扩散行为可以认为是存在晶格畸变应力场相互作用的两个独立吸附原子的扩散；在原子间相互作用势的有效距离之 关键词： 表面吸附原子 晶格畸变 表面二聚体 扩散     

Study on the Performance of the nonlinear Joint Transform Correlator

l.IntroductionJointtransformcorrelation[1]hasbeeninvestigatedwidelyinrecentyears[2~4]be-causeitsreferenceimagesandobjectimagescanbeuPdatedinreal-time[5J.Nonlinearjointtransformcorre1ationtheoretica1ana1ysis[']showsthatcomparedwiththelinearjointtransformcorrelation,non1inearjointtransformcorrelationcanproducemorehighautcacorre1ationPeakintensity,andthelargerPeaktosideloberatiothataregoodforelectronicdevicestodetectandana]yze.Onthebasisofthemodu1ationprincipleana1ysisoftheliq-uidcrysta11ightva…     

Anomalous diffusion and continuum percolation

Anomalous diffusion for continuum percolation is simulated by considering systems of randomly distributed circles and spheres. Universal behavior is obtained for the case of equal local conductances and nonuniversal behavior for diverging distributions of the local conductances. Diffusion in the continuum has a behavior consistent with that of other transport properties in the continuum. In addition, the results suggest that different algorithms for diffusion, which differ only in the random walker sitting times, are equivalent.     

Computational analysis of the roles of biochemical reactions in anomalous diffusion dynamics

Most biochemical processes in cells are usually modeled by reaction–diffusion(RD) equations. In these RD models,the diffusive process is assumed to be Gaussian. However, a growing number of studies have noted that intracellular diffusion is anomalous at some or all times, which may result from a crowded environment and chemical kinetics. This work aims to computationally study the effects of chemical reactions on the diffusive dynamics of RD systems by using both stochastic and deterministic algorithms. Numerical method to estimate the mean-square displacement(MSD) from a deterministic algorithm is also investigated. Our computational results show that anomalous diffusion can be solely due to chemical reactions. The chemical reactions alone can cause anomalous sub-diffusion in the RD system at some or all times.The time-dependent anomalous diffusion exponent is found to depend on many parameters, including chemical reaction rates, reaction orders, and chemical concentrations.