Enhancement of photoluminescence of the CdSe/CdS quantum dots on quartz substrates in the presence of silver nanoparticles

Multilayer systems consisting of layers of hybrid quantum dots are fabricated. The quantum dots with the CdSe/CdS core/shell structure are chemically synthesized and deposited on the surface of quartz glass that contains ion-synthesized silver nanoparticles in the near-surface region. Silver nanoparticles exhibit optical absorption owing to the localized surface plasmon resonance. Variations in the photoluminescence intensity of the layer related to an increase in the distance from the quartz surface with metal nanoparticles are studied. An increase in the photoluminescence intensity is observed under excitation in the spectral region of the plasmon absorption of silver nanoparticles. An optimal distance between the layers is determined to maximize the enhancement of the photoluminescence of quantum dots in the presence of the near field of metal nanoparticles.     

巯基丙酸分子对CdSe核壳量子点和 ZnO纳米粒子薄膜之间电荷转移的影响

通过稳态光谱和时间分辨荧光光谱研究了巯基丙酸(MPA)分子对由量子点到ZnO纳米粒子薄膜的电荷转移过程的影响。研究发现,相对于CdSe纳米粒子薄膜样品,没有MPA分子参与作用的CdSe/ZnO薄膜样品和有MPA分子连接的CdSe/MPA/ZnO薄膜样品中都存在从CdSe量子点到ZnO纳米粒子薄膜的有效电荷分离过程,但是相对于CdSe/ZnO样品, CdSe/MPA/ZnO样品中电荷转移速率明显变小。这表明MPA分子本身它并不能促进CdSe到ZnO电荷分离过程,因此可以认为用金属氧化物薄膜直接吸附量子点吸收材料,将能获得高功率转换效率的量子点敏化太阳能电池。     

胶质红外量子点薄膜入射角对荧光特性的影响分析

胶质红外量子点优异的光学性能使其荧光特性具有广泛的应用前景,在实际应用中通常需要封装成薄膜形态以保持稳定的荧光特性。然而,分散形式的改变可能会导致量子点荧光效率降低以及荧光角度特性变化。因此,建立了红外量子点荧光强度探测系统,对胶质红外量子点薄膜在不同角度激发光入射时产生的荧光分布情况进行研究。实验及分析结果表明,激发光与样品表面夹角大小在10°～170°之间的较大范围内入射时,在反射及透射荧光区域均可探测到荧光峰值强度70%～80%以上的荧光出射,在这一范围内的反射荧光与透射荧光强度差异和荧光强度随激发光入射角度的变化规律分别与样品中量子点的浓度以及分布形态有关。同时,随着入射激光能量的增强,样品出射荧光强度对于入射角度变化的“平坦”范围进一步扩大。     

Mid-infrared optical resonances in quantum dot photodetectors coupled with metallic gratings with different aperture diameters

The paper is devoted to optical testing of mid-infrared Ge/Si photodetectors obtained by stacking of self-assembled Ge quantum dots in multilayer structures, which are near-field coupled to the adjacent nanoplasmonic arrays of subwavelength holes in metallic films. It is shown that photocurrent and near-field spectra consist of several sets of peaks, which are attributted to surface plasmon waves, localized surface plasmon modes or diffractive Rayleigh anomaly depending on the hole diameter and the angle of incidence θ. We find that for small holes the greatest contribution to the photocurrent enhancement is due to the excitation of the surface plasmon-polariton waves for all θ. As the hole diameter is increased and becomes comparable with the array periodicity, the normal-incident photoresponse improvement is provided by the Rayleigh anomaly. With the increase of incident angle, the photocurrent enhancement is supposed to arise from coupling of the localized shape resonance and propagating plasmon modes.     

基于表面等离子体共振增强的硅基锗金属-半导体-金属光电探测器的设计研究

金属-半导体-金属光电探测器的光栅结构可激发表面等离子体, 有效增强探测器的吸收. 为深入研究器件结构对于表面等离子体的激发及共振增强的影响, 本文提出了一种具有超薄有源层的硅基锗金属-半导体-金属光电探测器的设计方法. 采用时域有限差分的方法详细分析了光栅周期、光栅厚度、 光栅间距及有源层厚度对于表面等离子体共振增强器件性能的影响, 通过仿真模拟获得了器件的最佳结构, 详细地分析了各个界面激发的表面等离子体及其共振模式对于光谱吸收增强的机理. 仿真结果表明, 有源层锗的厚度为400nm的超薄器件在通信波段具有较高的吸收, 尤其在1550nm波长处器件的归一化的光谱吸收率可以高达53.77%, 增强因子达7.22倍. 利用共振效应能够极大地提高高速器件的光电响应, 为解决光电探测器响应度与响应速度之间的相互制约关系提供了有效途径. 关键词： 表面等离子体 锗探测器 时域有限差分仿真     

CdSe量子点滤光片尺寸、温度依赖的光学特性

为了缩小光谱仪体积使之适用于军事卫星等领域,本文将胶体量子点作为滤光材料,研究了CdSe胶体量子点滤光片的光学特性.本文采用热注入法合成出了高质量的CdSe胶体量子点,经过对苯二胺消光处理制备成CdSe胶体量子点滤光片.利用透射电子显微镜(TEM)进行样品形貌结构的表征及粒径尺寸的测量,并分别在不同温度下进行了紫外.可...     

Selective enhancement of the hole photocurrent by surface plasmon–polaritons in layers of Ge/Si quantum dots

It is found that the integration of Ge/Si heterostructures containing layers of Ge quantum dots with twodimensional regular lattices of subwave holes in a gold film on the surface of a semiconductor leads to the multiple (to 20 times) enhancement of the hole photocurrent in narrow wavelength regions of the mid-infrared range. The results are explained by the light wave excitation of the surface plasmon–polaritons at the metal–semiconductor interface effectively interacting with intraband transitions of holes in quantum dots.     

Surface enhanced Raman scattering by CdS quantum dots

Surface enhanced Raman scattering is studied in nanostructures with CdS quantum dots formed using the Langmuir-Blodgett technology. Features due to quantum dot longitudinal optical phonons are observed in the Raman spectra of both free CdS quantum dots and such dots distributed in an organic matrix. The surface enhanced Raman scattering by nanostructures with CdS quantum dots covered by an Ag cluster film is observed experimentally. Applying Ag clusters onto the nanostructure surfaces results in a sharp (40-fold) increase in the intensity of Raman scattering by optical phonons in the quantum dots. It is shown that the dependence of surface enhanced Raman scattering on the excitation energy is resonant with a maximum at the energy corresponding to the maximum absorption coefficient of Ag clusters.     

Resonant photocurrent-spectroscopy of individual CdSe quantum dots

Here we report on investigations on CdSe quantum dots incorporated in ZnSe based Schottky photodiodes with near-field shadow masks. Photoluminescence and photocurrent of individual quantum dots were studied as a function of the applied bias voltage. The exciton energy of the quantum dot ground state transition was shifted to the excitation energy by using the Stark effect tuning via an external bias voltage. Under the condition of resonance with the laser excitation energy we observed a resonant photocurrent signal due to the tunnelling of carriers out of the quantum dots at electric fields above 500 kV/cm.     

Localization of Surface Plasmon Waves in Hybrid Photodetectors with Subwavelength Metallic Arrays

The spectral characteristics of the hole photocurrent in plasmon photodetectors based on Ge/Si heterostructures with Ge quantum dots combined with regular arrays of subwavelength apertures of various shapes in a gold film on the semiconductor surface are investigated. Dispersion relations characterizing the propagation of surface plasmon waves along the metal–semiconductor interface are determined from the dependences of the photocurrent on the angle of incidence of light. It is established that the plasmonic enhancement of the photocurrent in rectangular aperture array is suppressed as compared to that in circular and square aperture arrays. It is found that, in hybrid structures with rectangular apertures, there exists a range of wave vectors where the energy of surface plasmons is independent of the wave vector of incident radiation. The results are explained by the excitation of dipole modes localized at rectangular apertures with a large aspect ratio by light waves.     

Enhanced photoluminescence of CdSe quantum dots by the coupling of Ag nanocube and Ag film

The coupling of local surface plasmon(LSP) of nanoparticle and surface plasmon(SP) mode produced by metal film can lead to the enhanced electromagnetic field, which has an important application in enhancing the fluorescence of quantum dots(QDs). Herein, the Ag nanocube and Ag film are used to enhance the fluorescence of CdSe QDs. The enhancement is found to relate to the sizes of the Ag nanocube and the thickness of the Ag film. Moreover, we also present the fluorescence enhancement caused by only SP. The result shows that the coupling between metal nanoparticles and metal film can realize larger field enhancement. Numerical simulation verifies that a nanocube can localize a strong electric field around its corner. All the results indicate that the fluorescence of QDs can be efficiently improved by optimizing the parameters of Ag film and Ag cubes.     

Resonance energy transfer in a dense array of II–VI quantum dots

Förster resonance energy transfer in inhomogeneous dense arrays of epitaxial CdSe/ZnSe quantum dots is demonstrated by time- and space-resolved photoluminescence spectroscopy. The specific feature of this process is the dipole–dipole interaction between the ground exciton levels of small quantum dots and the excited levels of large dots. This interaction brings efficient energy collection and spectral selection of a limited number of emitters. Results of theoretical modeling of optical transitions in spheroidal quantum dots with a Gaussian potential profile agree with the observed features of optical spectra induced by the change of the dominant energy transfer mechanism.     

五边形截面的Ag纳米线局域表面等离子体共振模式

五边形截面的单晶Ag纳米线对ZnO量子点荧光具有增强的现象. 为解释这一现象, 利用时域有限差分法对五边形截面的Ag纳米线的局域表面等离子体共振模式进行了理论模拟. 结果表明, 五边形截面的Ag纳米线在紫外区域存在两个消光峰, 分别由Ag纳米线的横向偶极共振(340 nm)和四极共振(375 nm)引起; 这两个消光峰与ZnO量子点荧光增强峰相一致, 而且随着Ag纳米线的半径增大而红移; 消光峰对应的共振模式取决于Ag纳米线的截面形状; 根据Ag纳米线电场增强倍数与激发光波长变化关系曲线可知, 最大增强电场位于五边形截面的顶点处, 而边线处电场增强较小. 理论模拟的结果较好地解释了Ag纳米线/ZnO量子点体系的荧光增强现象, 也为Ag纳米线在提高半导体材料发光效率、生物探测等方面的应用提供有益的参考.     

利用重离子径迹模版法制备出的钯纳米线阵列的表面等离激元共振现象研究(英文)

利用电化学沉积在重离子径迹模版中制备出了不同直径的一维钯纳米线。利用扫描电子显微镜、透射电子显微镜和X射线衍射等多多种手段对制得的钯纳米线进行了形貌和结构表征。利用紫外可见光谱仪分析了钯纳米线的光学响应,发现钯纳米线存在表面等离子体共振现象。随着纳米线直径和长度的增加,其表面等离子体共振峰位发生红移;通过改变光谱测试中激发光的入射角度,其表面等离激元共振模式会随着角度的增大而变多,这可能是在横向振动模式的基础上激发了沿纳米线长度方向振动的纵向模式。与此同时,基于时域有限差分法对钯纳米线的表面等离子体共振特性进行数值模拟,结果与实验符合较好。Palladium nanowires with varied diameters were fabricated using ion-track templates coupled with electrochemical deposition. The morphology and crystallographic structure were characterized with Scanning Electron Microscopy, Transmission Electron Microscopy, X-ray diffraction (XRD). The plasmonic responses of the as-prepared nanowires were investigated by UV-Vis-NIR spectroscopy and the simulations based on the finite-difference time-domain algorithm. The results demonstrate that the surface plasmon resonances of Pd nanowire are sensitive to the wire geometry, but also influenced by the incidence angle of light. The frequency of the transverse dipolar plasmon resonance of nanowire arrays shifts within a wide range from visible to near infrared. With increasing of wires' diameter or length, the resonance peak shifts to the red. With increasing of incident angle, a new peak appears, which is possibly assigned to the excitation of the longitudinal resonance. In addition, numerical simulations disclose that propagating surface plasmon polaritons can be excited on the palladium nanowires and the wavelength of the resonance peak is in good agreement with the experimental results.     

Modification of spontaneous emission from CdSe/CdS quantum dots in the presence of a semiconductor interface

The spontaneous-emission lifetime of CdSe/CdS core-shell quantum dots was studied as a function of the distance between the dots and a polished Si surface. The experimental results reveal a significant modification of the spontaneous-emission rate of the quantum dots by the Si surface.     

Fano resonance and magneto-optical Kerr rotaion in periodic Co/Ni complex plasmonic nanostructure

we report a pure rerromagneuc metallic magnetopiasmonic structure consisting or two-dimensional oraerea Ni nanodisks array on Co film.With a sufficient height of the nanodisks,a steep and asymmetric Fano resonance can be excited in this structure.We attribute the fascinating spectral lineshape to the strong coupling between the excitation of surface plasmon polaritons at the interface and the localized surface plasmon resonance of nanodisks.The conclusion is fully confirmed by spectrum measurements in nanostructures with different heights.Furthermore,the enhancement and sign of the magneto-optical Kerr rotation in this structure are significantly modified by the Fano resonance.     

Tunable grating-assisted surface plasmon resonance by use of nano-polymer dispersed liquid crystal electro-optical material

This paper reports on the experimental observation of the displacement of a surface plasmon resonance (SPR) excited by a metallic diffraction grating. This effect is achieved by the use of an electro-optical material composed of nano-sized droplets of liquid crystals dispersed in a host polymer. The average refractive index of this material in the form of a thin film on the undulated metal surface can be modified with the application of an external electric field and to tune the wavelength at which the SPR excitation leads to a reflection minimum. The theoretical design and experimental demonstration of the principle of this component are described.     

Encapsulation of highly confined CdSe quantum dots for defect free luminescence and improved stability

This is the first report on the generation of trap states and their effective elimination in highly confined CdSe quantum dots in order to obtain enhanced and stable optical properties prepared by aqueous route. Surface plays an important role in optical properties of quantum dots (QDs) and surface modification of quantum dots can improve optical properties. In present work luminescent CdSe QDs were prepared using 2-Mercaptoethanol (2-ME) as stabilizing agent and encapsulated by polymer. Different concentrations of 2-ME were used to tune the emission spectra with respect to their reduced size. Addition of 2-ME to CdSe QDs enhances the trap emission and quenching band edge emission due to (i) increased surface to volume ratio and; (ii) presence of high concentration of sulfide ions as confirmed from EDX analysis as sulfide ions possesses the hole scavenging characteristics. Polymer encapsulation of QDs was carried out to make them stable and to improve their optical properties. Even though there are previous reports addressing the improved optical properties by polymer encapsulation and silica encapsulation but experimentally it has not been reported yet experimentally. In this work we have synthesized and characterized water soluble polymer encapsulated QDs and proved the facts experimentally. Photoluminescence spectroscopy clearly reveals the role of polymer encapsulation in boosting the optical properties of CdSe QDs. FTIR spectra validate the presence of biocompatible functional groups on CdSe4/PEG (Polymer encapsulated QDs).     

Photoluminescence from single silicon quantum dots excited via surface plasmon polaritons

Single dot spectroscopy of Si quantum dots (QDs) was performed by using surface plasmon polariton (SPP)-mediated excitation in the attenuated total reflection geometry with a MgF₂/Ag film on the base of a prism. Thanks to the 16 times enhancement of the incident electric field and very small background signal, PL from single Si QDs was observed clearly. This proves the usefulness of the technique for the detection of inherently weak emission of Si QDs.     

Direct observation of optical excitation transfer based on resonant optical near-field interaction

This article reports the direct observation of long-distance optical excitation transfer based on resonant optical near-field interactions in randomly distributed quantum dots (QDs). We fabricated optical excitation transfer paths based on randomly distributed QDs by using CdSe/ZnS core?Cshell QDs and succeeded for the first time in obtaining output signals resulting from a unidirectional optical excitation transfer length of 2.4???m. Furthermore, we demonstrate that the optical excitation transfer occurs via the resonant excited levels of the QDs with a comparative experiment using non-resonant QDs. This excitation-transfer mechanism allows for intersecting, non-interacting nano-optical wires.