共查询到19条相似文献,搜索用时 109 毫秒
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用化学方法对碳纳米管进行表面处理,用红外谱对处理后的碳纳米管进行表征,处理后的碳纳米管表面出现了活性功能团羧基.用这些碳纳米管制成电极,对Cd离子在硫酸钠中的电化学行为进行了分析.结果表明,从碳纳米管电极上可以观察到很好的、准可逆循环伏安图;在扫描速度为100 mV*s-1时,氧化还原峰电位分别出现在-0.65 V和 -0.95 V 对照饱和甘汞电极(SCE).峰电流与扫描速度的平方根成良好的线性关系,说明反应过程是由镉离子的扩散控制的.由循环伏安图相关的电位与扫描速度关系,我们导出了电子转移动力学速度参数.由于碳纳米管电极有很好的电化学活性和可重复性,它可以成为一种新型的分析电极材料. 相似文献
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用化学方法对碳纳米管进行表面处理,用红外谱对处理后的碳纳米管进行表征,处理后的碳纳米管表面出现了活性功能团羧基.用这些碳纳米管制成电极,对Cd离子在硫酸钠中的电化学行为进行了分析.结果表明,从碳纳米管电极上可以观察到很好的、准可逆循环伏安图;在扫描速度为100 mV*s-1时,氧化还原峰电位分别出现在-0.65 V和 -0.95 V 对照饱和甘汞电极(SCE).峰电流与扫描速度的平方根成良好的线性关系,说明反应过程是由镉离子的扩散控制的.由循环伏安图相关的电位与扫描速度关系,我们导出了电子转移动力学速度参数.由于碳纳米管电极有很好的电化学活性和可重复性,它可以成为一种新型的分析电极材料. 相似文献
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介绍了利用简单有效的电泳沉积工艺制备新型碳纳米管薄膜材料,并应用于染料敏化太阳电池。通过场发射扫描电子显微镜(FESEM)和透射电子显微镜(TEM)等表征手段发现,制备的新型碳纳米管薄膜材料直径均匀分布,且形成一种均匀的网状结构,这种均匀的网状结构有利于电子的传输。循环伏安法测试其电化学性能,并且对制备的染料敏化太阳电池的光电性能进行测试。实验结果表明,电泳沉积制备的碳纳米管薄膜具有良好的导电和催化性能,作为对电极组装的染料敏化太阳电池光电转换效率达到6.54%,有希望替代传统的铂对电极。 相似文献
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F. E. Jones A. A. Talin F. Léonard P. M. Dentinger W. M. Clift 《Journal of Electronic Materials》2006,35(8):1641-1646
In this paper, we report on the electrical transport characteristics and sensitivity to chemical exposure of single wall carbon
nanotube devices fabricated on Pd, plasma-oxidized Pd, and Au electrodes. When the devices are exposed to vapors from ammonia,
ethanol, and water, the response of current to each chemical is unique. However, there is essentially no difference in response
between devices with different electrode materials. This finding suggests that for the chemical species tested in this study,
the main interaction is on the nanotube or nanotube junction, and not on the effect stemming from electrode adsorption and
the change in electrode work function. 相似文献
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V. Lemos S. Guerini S.M. Lala L.A. Montoro J.M. Rosolen 《Microelectronics Journal》2005,36(11):1020-1022
The possibility of inserting lithium into single wall carbon nanotube bundles during the growth process is analyzed in this work by using the Raman technique as probe. The nanotubes were prepared by the arc discharge method by using catalysts prepared by mixing compounds containing lithium and as their counterpart, a similar mixture without this alkali-metal. The two pair of samples studied in this work were obtained with the following catalysts: (i) Li2CO3/NiO/CoO and NiO/CoO; or (ii) LiCo0.5Ni0.5O2 and Ni/Co. Raman spectra reveal that the tangential bands profiles of the samples prepared with the catalyst containing lithium is considerably modified in both cases. In the case of the carbon nanotubes obtained using the LiCo0.5Ni0.5O2 catalyst a down shift and severe broadening are observed in addition. Comparison of our results with those published previously for alkali-metals doped single wall carbon nanotubes allowed to conclude that lithium incorporation, actually, occurs during the growth process. 相似文献
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A new technique to fabricate nylon-6/carbon nanotube (PA6/CNT) composites is presented. The method involves a pretreatment
of carbon nanotubes synthesized by catalytic pyrolysis of hydrocarbon and an improved in-situ process for mixing nanotubes
with the nylon 6 matrix. A good bond between carbon nanotubes and the nylon-6 matrix is obtained. Mechanical property measurements
indicate that the tensile strength of PA6/CNT composites is improved significantly while the toughness and elongation are
somewhat compromised. Scanning electron microscopy (SEM) analysis of the fractured tensile specimens reveals cracking initiated
at the wrapping of the CNTs PA6 layer/PA6 matrix interface rather than at the PA6/CNT interface. 相似文献
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A procedure for producing arrays of self-aligned carbon nanotubes (CNTs) using standard chemical vapor deposition (CVD) is
reported. Using UV photolithography, silicon substrates are patterned with a thin layer of thermally evaporated iron as a
CNT catalyst. The CVD synthesis was carried out over a small temperature range (700°C–800°C) using acetylene and methane gasses,
producing aligned CNT towers. Scanning electron microscopy (SEM) analysis shows a relationship between CNT tower height and
synthesis time. Additionally, results show that impurity particles dramatically effect CNT tower growth. These results indicate
that aligned CNTs can be produced in a desired pattern with height control. 相似文献
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为发展场致发射冷阴极毫米波电真空辐射源器件, 对利用大面积碳纳米管冷阴极产生大电流、高电流密度电子注的电子光学系统进行了研究.通过在Pierce电子枪阴极表面引入栅网结构, 解决了碳纳米管冷阴极场致发射所需的强电场和电子聚束问题.在碳纳米管冷阴极实验测试数据的基础上, 采用粒子模拟软件对上述电子光学系统进行了仿真.研究了栅网对注电流、注腰半径和电子注散射的影响, 分析了阳极电压和外加轴向磁场对电子注的聚束作用.优化后的仿真结果表明在阴极发射面为3.03 cm2时, 该电子光学系统能够产生210 mA、60 kV, 电流密度为6.7 A/cm2, 最大注半径为1mm的电子注. 相似文献
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为了研究碳纳米管悬浮液的光限幅机理,测量了碳纳米管悬浮液的散射能量和透射能量随入射激光能量密度的变化曲线,得到了不同入射激光能量密度下,散射光能量在平行于入射线偏振光偏振方向的散射面内的角度分布,并对碳纳米管悬浮液进行了探针光实验。根据米氏散射理论,计算了在不同大小的散射中心下,碳纳米管悬浮液的散射光能量在平行于入射线偏振光偏振方向的散射面内的角度分布,以及散射截面随散射中心半径大小的变化。结果表明,碳纳米管悬浮液光限幅可能源于碳纳米管吸收激光能量汽化形成的碳气泡引起的非线性散射。 相似文献
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A novel capacitance-type relative humidity (RH) sensor based on multi-wall carbon nanotubc/SiO2 (MWCNTs/SiO2) composite film is reported.Details of the fabrication process,possible sensing mechanism and sensing characteristics,such as linearity and sensitivity,are described.The capacitance of the MWCNTs/SiO2 composite film shows typical concentration percolation behavior with increasing MWCNT loading.At loadings below the percolation threshold (1.842wt%),the sensor capacitance increases obviously with increasing MWCNTs.The water condensed in the MWCNTs/SiO2 layer can lower the percolation threshold and increase the sensor capacitance.The sensor with MWCNT concentration of 1 wt% has the best properties.The sensor has a humidity sensitivity of about 673 pF/% RH and a linearity correlation of 0.98428.The response time of the sensor to RH is about 40 s and the recovery time is about 2 s. 相似文献