电解等离子体法制备Al2O3陶瓷层及其特性研究

利用电弧喷铝并重熔后进行电解等离子体处理(EPP)的方法在Q235钢基体上制备出呈冶金结 合的Al₂O₃陶瓷层.利用XRD，SEM和EDS等手段对陶瓷层的成分和显 微组织进行了分析， 测定了陶瓷层的耐蚀性能和耐磨性能.实验结果表明，陶瓷层主要由α-Al₂O3，γ-Al₂O₃，θ-Al₂O₃以及一 些非晶相组成，组织致密，耐蚀性能和耐磨性能良好. 关键词： 电解等离子体处理 陶瓷层 复合技术 生长机理     

掺杂As2S8非晶态薄膜波导的光阻断效应

实验研究了未掺杂和低浓度掺锡和掺磷的As₂S₈薄膜波导的光阻断效应,提供了三种样品的光阻断响应曲线、室温退激实验数据和光谱测试数据. 结果表明,掺锡样品可以明显提升毫秒级响应的快过程恢复作用,同时还具有减少残留传输损耗的效果,掺磷的效果则相反. 结合实验结果给出了分析讨论. 关键词： 光波导技术 硫属化合物玻璃 光阻断效应 掺杂     

Ground state rotational spectrum of nitrogen trifluoride: The K = 3 splittings of NF3 and NF3

The ground state rotational spectrum of the ¹⁴NF₃ and ¹⁵NF₃ isotopic species of nitrogen fluoride has been observed in the ∼450-810 GHz frequency range. This investigation allowed us to improve the rotational parameters for both isotopologues. In particular, for the first time the K = 3 line splitting parameter and the sextic centrifugal distortion constants have been determined for ¹⁵NF₃.     

Study of PbO-SrO-TiO2-B2O3 glass and glass ceramics

The glasses with composition (50−X)PbO–XSrO-25TiO₂-25B₂O₃ (where X=0, 5, 10 and 15 mol%) were prepared using conventional quenching technique. The T_g, T_c, density and CTE of the glass samples were measured. The T_g observed to increase with increasing concentration of SrO, while the T_c first decreased and then increased. The glass samples were converted to glass ceramics by following two stage heat treatment schedule. The glass ceramic samples were characterized by XRD, SEM and dielectric measurements. The XRD results revealed the formation of ferroelectric lead titanate as a major crystalline phase in glass ceramics. Additional phases observed include Sr₂B₂O₅ and PbB₂O₄. The room temperature (RT) dielectric constant of glass and glass ceramics are in the range of 100–120 which is promising for capacitor application.     

用激光分子束外延在玻璃衬底上生长La0.67Sr0.33MnO3薄膜

采用激光分子束外延技术,在玻璃衬底上制备了La_067Sr_033MnO₃ （LSMO） 薄膜,X射线衍射测量结果表明在玻璃衬底上生长的LSMO薄膜沿c轴择优取向生长.在外磁场3 T和88, 220, 300 K条件下,LSMO薄膜的磁电阻变化率分别达到-378%, -268%和-607%.实验结果表明,在廉价的玻璃衬底上制备大面积和具有应用价值的锰氧化物薄膜是可行的. 关键词： 锰氧化物薄膜 玻璃衬底 外延生长     

Al2O3对氟氧化物玻璃微结构和析晶的影响

采用红外, Raman, X射线衍射测试分析方法, 研究了Al₂O₃对氟氧化物玻璃微结构和析晶的影响.结果表明, Al³⁺主要以[AlO₄]的形式与[SiO₄]以顶角相连的方式构成基本网络骨架, Al₂O₃含量的增加, 使氧化物玻璃基质的网络向单体和二聚体结构转变, 并使氟化物微晶尺寸有一个先变小后增大的趋势, 但不影响微晶结构.     

高气压直流辉光CH4/H2等离子体的气相过程诊断

对高气压(约100 Torr) 直流辉光碳氢等离子体的气相过程进行了光谱和质谱原位诊断. 在高气压下, 等离子体不同区域光发射特性存在明显差异. 正柱区存在着以C₂和CH为主的多个带状谱和分立谱线, 阳极区粒子发射谱线明显减少, 而在阴极区则出现大量复杂的光谱成分, 表明高气压情形下等离子体与阴极间强烈的相互作用将导致复杂的原子分子过程. 从低气压到高气压演变过程中, 电子激发温度降低而气体分子转动温度升高. 在高气压下, 高甲烷浓度导致C₂, C₂H₂及C₂H₄增多而C₂H₆减少. 表明在高气压条件下, 气体温度对气相过程的影响作用显著增强. 关键词： 高气压直流等离子体 光发射谱 质谱     

Thermoluminescent properties of a Li2O-B2O3-Al2O3 glass system doped with CaF2 and Mn

A Li₂O-B₂O₃-Al₂O₃ glass system doped with CaF₂ and Mn was synthesized by fusion and its physical properties were investigated using thermoluminescence (TL) and differential thermal analysis (DTA) techniques. The TL glow curve peaks, resulting from this analysis, are characteristic of metastable levels intrinsic to CaF₂ crystals that have undergone γ-ray irradiation from a colbalt-60 (⁶⁰Co) source. This provides evidence of CaF₂ crystal formation in the glass system. Furthermore, the TL glow peak at about 480 K was stable at room temperature, sensitive to ⁶⁰Co γ-rays and showed good linearity with doses ranging from 3 Gy to approximately 100 Gy, and consequently could be used to quantify radiation doses. High quality synthesis of these crystals permits control of their thermoluminescent properties.     

Comparative study of spectroscopic properties of Er^3＋／Yb^3＋-codoped tellurite glass and fibres under 980nm excitation＊

A tellurite fibre of TeO_{2}－ZnO－La_{2}O_{3}－Li_{2}O glass codoped with 20000 ppm ytterbium and 5000 ppm erbium was fabricated by the suction casting and rod-in-tube technologies. The absorption spectrum of Er^{3+}/Yb^{3+} -codoped bulk glass has been measured. From the Judd－Ofelt intensity parameters, the spontaneous emission probability and radiative lifetime τ_{rad} of Er^{3+}:{}^{4}I_{13/2}→{}^{4}I_{15/2} transition for the bulk glass have been calculated. The emission fluorescence spectra and lifetimes around 1.5μm, and subsequent upconversion fluorescence in the range of 500－700nm were measured in fibres and compared with those in bulk glass. The changes in amplified spontaneous emission with fibre length and pumping power was also measured. It was found that the emission spectrum from erbium in fibres is almost twice as broad as the corresponding spectrum in bulk glass when pumped at 980nm.     

OH-1 absorption bands of LiNbO3 with varying composition

This paper reports that OHabsorption bands of lithium niobate crystal have been measured at room temperature, and the band shape depending on the crystal composition has been observed. The OHabsorption bands are fitted with three Lorentzian peaks by varying position, halfwidth, and height. Nearly constant peak positions (3468, 3481 and 3490 cm-1) are obtained for all samples. It shows that the height and area of the decomposed peaks vary with the Li composition in a complex way. However, the combinations of these fitting parameters show a linear dependence on the composition up to nearly 50 mol%, which is very useful for the composition determination in a wide range. The linear relationships between the parameter combinations and Li composition are also presented quantitatively. In addition, the explanations were given for the excellent composition linearity of parameter combinations.     

基于熔融玻璃的预沉积法生长毫米级单晶MoS2及WS2-MoS2异质结

MoS₂是一种具有优异光电性能和奇特物理性质的二维材料,在电子器件领域具有巨大的应用潜力.高效可控生长出大尺寸单晶MoS₂是该材料进入产业应用所必须克服的重大难关,而化学气相沉积技术被认为是工业化生产二维材料的最有效手段.本文介绍了一种利用磁控溅射预沉积钼源至熔融玻璃上,通过快速升温的化学气相沉积技术生长出尺寸达1 mm的单晶MoS₂的方法,并通过引入WO₃粉末生长出了二硫化钼与二硫化钨的横向异质结(WS₂-MoS₂).拉曼和荧光光谱仪测试表明所生长的样品具有较好的晶体质量.利用转移电极技术制备出了背栅器件样品并对其进行了电学测试,在室温常压下开关比可达10~5,迁移率可达4.53 cm~2/(V·s).这种低成本高质量的大尺寸材料生长方法为二维材料电子器件的大规模应用找到了出路.     

使用发射光谱对感应耦合CF4/CH4等离子体中C2基团形成机理的研究

利用强度标定的发射光谱法，研究了感应耦合CF4₄/CH4₄等离 子体中空间基团的 相对密度随宏观条件（射频输入功率、气压和流量比）的变化情况. 研究表明：在所研究的 碳氟/碳氢混合气体放电等离子体中除了具有丰富的CF，CF2₂，CH，H和F等活 性基团外 ，还同时存在着C2₂基团，其相对密度随着放电功率的提高而增加；随着气压 的上升呈 现倒“U”型的变化. C2₂随流量比R（R=［CH4 _{关键词： 发射光谱 感应耦合等离子体 2}基团')" href="#">C2₂基团     

Influence of processing variables on the formation of La2Zr2O7 in transferred arc plasma torch processing

The transferred arc plasma (TAP) torch process has various noteworthy features such as extremely high temperatures, low environmental impact and short processing time which makes it the most suitable technique for synthesizing ceramic composite materials. Furthermore, it is a direct two-step technique which by its virtue of high temperature and power density paves way for high production rate. Hence in this study, an effort has been made to utilize the TAP torch processing technique for the bulk production of La₂Zr₂O₇ with time effectiveness from the mixture of La₂O₃ and ZrO₂ powders (1:2 mol ratios) which were ball milled for 4 h. For this purpose, transferred arc plasma torch was specially designed in laboratory scale level and the operating parameters were optimized in order to achieve maximum La₂Zr₂O₇ formation efficiency. In this study, the phase and microstructure formation of the processed samples was analyzed via X-ray diffraction (XRD) and scanning electron microscope (SEM) images respectively. Moreover, EDX analysis was incorporated to highlight the superior influence of the longer processing time on the stoichiometric ratio of ZrO₂/La₂O₃ in the processed sample as against input power and the gas flow rate.     

Ce3+掺杂SiO2-Al2O3-Gd2O3玻璃的闪烁性能

通常, Ce离子掺杂的低密度玻璃有较高的发光效率, 而高密度的Ce离子掺杂玻璃其发光效率很低. 为了解释这一现象, 采用高温熔融法获得了SiO₂-Al₂O₃-Gd₂O₃三元系统的玻璃形成区, 并在还原气氛下制备了Ce³⁺掺杂SiO₂-Al₂O₃-Gd₂O₃以及SiO₂-Al₂O₃-Gd₂O₃-Ln₂O₃ (Ln=Y, La, Lu)闪烁玻璃, 研究了其光谱和闪烁性能. 测试结果显示: 随着Gd₂O₃含量增加, 玻璃紫外截止波长发生红移, 荧光强度降低, 衰减时间缩短; 加入Lu₂O₃, La₂O₃, Y₂O₃后, 紫外截止波长发生红移, 荧光强度降低, 衰减时间变短; 当Gd₂O₃超过10% mol时, X射线荧光积分光产额从相当于锗酸铋 晶体的61%降低到13%. 荧光强度降低、衰减时间缩短的原因是随着玻璃的紫外截止波长红移玻璃的能带宽度变窄, 使得Ce³⁺离子的d电子轨道开始接近玻璃的导带, Ce³⁺离子受辐射后跃迁到d电子轨道的电子会通过导带与玻璃中的空穴复合, 产生电荷迁移猝灭效应.     

Effect of neutron-irradiation on optical properties of SiO2-Na2O-MgO-Al2O3 glasses

Silica based glasses are used as nuclear shielding materials. The effect of radiation on these glasses varies as per the constituents used in these glasses. Glasses of different composition of SiO₂-Na₂OMgO-Al₂O₃ were made by melt casting techniques. These glasses were irradiated with neutrons of different fluences. Optical absorption measurements of neutron-irradiated silica based glasses were performed at room temperature (RT) to detect and characterize the induced radiation damage in these materials. The absorption band found for neutron-irradiated glasses are induced by hole type color centers related to non-bridging oxygen ions (NBO) located in different surroundings of glass matrix. Decrease in the transmittance indicates the formation of color-center defects. Values for band gap energy and the width of the energy tail above the mobility gap have been measured before and after irradiation. The band gap energy has been found to decrease with increasing fluence while the Urbach energy shows an increase. The effects of the composition of the glasses on these parameters have been discussed in detail in this paper.      

Thermoluminescence, structural and magnetic properties of a Li2O-B2O3-Al2O3 glass system doped with LiF and TiO2

A Li₂O-B₂O₃-Al₂O₃ glass system, un-doped and doped with LiF, and/or TiO₂ was synthesized by the fusion method and its physical properties were investigated by thermoluminescence (TL), X-ray diffraction (XRD), electron paramagnetic resonance (EPR), atomic force microscopy (AFM) and differential thermal analysis (DTA). The samples were subjected to γ-rays from a colbalt-60 (⁶⁰Co) source. These techniques provided evidence of LiF and LiF doped with Ti crystal formation in the glass system. A TL glow peak at about 433 K was sensitive to ⁶⁰Co γ-rays and showed good linearity with doses and consequently could be used to quantify radiation doses.     

1at％ Ag替代Zr57Cu20Al10Ni8Ti5金属玻璃中各组元对玻璃形成能力及热稳定性的作用分析

以1at％ Ag元素分别等量替代Zr57Cu20Al10Ni8Ti5金属玻璃的各个组元,利用差示扫描量热升温分析获得不同试样的热力学参数,并结合不同尺寸(Φ8,Φ10,Φ12)吸铸试样的X-射线衍射分析结果,考察、验证元素替代后合金的实际玻璃形成能力及热稳定性的变化规律.经比较发现,Ag替代Ti元素,其玻璃形成能力显著提高(直径实际增大4 mm),同时热稳定性也明显改善,且临界冷却速率也明显降低,而Ag替代其他组元却无明显规律.针对玻璃形成能力的相关数据比较分析表明,本文结果未显示符合其Inoue的尺寸准则,混合焓判据也未显示出明显符合的现象.通过对堆垛密度的计算发现,1 at％ Ag替代Ti元素后使金属玻璃体系内部的堆垛密度增加.通过动力学分析,从晶化激活能、晶化反应速率常数两方面探讨了元素替代对玻璃形成能力和热稳定性的作用机理.     

GeO2-Sb22O3-K22O玻璃空芯光纤材料的光学特性研究

系统地研究了传输CO2激光用的新型光纤材料GeO2-Sb2O3-K2O玻璃空芯光纤的光学特性。通过理论计算,得到了该材料nr＜1的波长范围,消光系数Ｋ和损耗系数a,通过工艺和材料的选择,使a理论值达到0.05 dB/m。同时讨论了HE11,TM01,TE01模式损耗和频率的关系。     

SrHfO3和SrTiO3光学特性的第一性原理研究

用全电势线性缀加平面波法(FLAPW)计算了SrTiO₃和SrHfO₃的光学特性，即介电函数虚部ε₂(ω)、光学吸收系数I(ω)和反射率R(ω).对它们光学特性进行了对比分析，给出了它们光学特性的差别，并进行了解释.计算的SrTiO₃光学谱分别在4.4，7.4，8.3和23.6eV处出现峰值，且其在4.4eV处的峰值比较高而尖.计算结果与实验值符合得很好. 关键词： 平面波法计算 光学常量和参数 铁电体     

H2 分子在Li3N(110)表面吸附的第一性原理研究

采用第一性原理方法研究了H₂分子在Li₃N(110)晶面的表面吸附. 通过研究H₂/Li₃N(110)体系的吸附位置、吸附能和电子结构发现: H₂分子吸附在N桥位要比吸附在其他位置稳定,此时在Li₃N(110)面形成两个-NH基,其吸附能为1.909 eV,属于强化学吸附;H₂与Li₃N(110)面的相互作用主要是H 1s轨道与N 关键词： 第一性原理 3N(110)')" href="#">Li₃N(110) 2')" href="#">H₂ 吸附和解离