共查询到18条相似文献,搜索用时 140 毫秒
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本文用改进PT方程对22种常见低温流体的汽化潜热进行了计算.计算结果与原始PT方程、原始PR方程和改进PR方程计算结果的比较表明,用改进型PT方程所得的结果与实验值的偏差明显小于原始PT方程、PR方程和改进PR方程,特别是该方程对强极性物质、低温流体的汽化潜热计算,优越性更为显著. 相似文献
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液氮中的水滴凝固后为何自炸曾朝阳(南京工程兵工程学院210007)在利用液氮进行的实验中,常常遇到一个有趣的现象:将水滴入液氮,水滴即成球状,在液氮表面上不停滚动并快速地游荡,同时引起液氮剧烈汽化.过几秒钟后,液滴凝固成冰粒,在液氮面上缓慢游动,同时... 相似文献
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瞬态高热流加热下饱和液氮会发生爆发沸腾,而对于该过程的特殊传热机理因素,目前还没有相关的深入研究和分析。本文基于实验,在总结沸腾传热机理研究成果的基础上,重点分析了饱和液氮爆发沸腾过程中以汽泡群形态实现热量传递的特殊之处,并进行了理论模拟验证。结果表明,汽泡群内部众多汽泡所发生的破裂收缩行为,会释放潜热并形成热流,成为爆发沸腾独特的传热机理影响因素。 相似文献
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基于焦-汤节流原理,针对航天领域常用气体在高压节流过程出现的温变现象,分析了高压气体节流温变过程及规律,开展了不同种类气体的节流温变对气体设备的影响研究。研究表明,对于预先压气的高压气瓶供气模式,氮气设备受节流降温影响较小,氧气设备则需关注节流元件及其下游设备对节流过程强烈降温效应的适应性;对于航天常用的液氮高压空浴汽化后在线压供气模式,为减少节流降温对下游设备的影响,需在高压空浴汽化器出口设置加温设施;对于高压氦气节流减压后的显著升温效应,为减少对下游设备的影响,采用液氮汽化对氦气进行降温是一种较为理想的技术路线。 相似文献
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D.J. Adams 《Molecular physics》2013,111(3):647-657
A combination of canonical and grand-canonical ensemble Monte Carlo calculations, together with the virial expansion, have been used to calculate the thermodynamic properties of the liquid/vapour co-existence curve of the (6 : 12) Lennard-Jones fluid for reduced temperatures, [Ttilde] ? 1·1. The results for the liquid density and energy and the latent heat of vaporization are believed to be precise, with the exception of the point at [Ttilde]=1·1 which may lie outside the range of the function fitting the liquid phase Monte Carlo data. The liquid density and the saturated vapour pressure are in very good agreement with the results of perturbation theory. The latent heat of vaporization does not agree well with the experimental data for argon though the fit to liquid density and internal energy is good. 相似文献
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In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film. 相似文献
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《Combustion Theory and Modelling》2013,17(1):163-174
Experimental evidence seems to indicate that the life of a laminar spherical flame front propagating through a fresh mixture of air and liquid fuel droplets can be roughly split into three stages: (1) ignition, (2) radial propagation with a smooth flame front and (3) propagation with flame front cellularization and/or pulsation. In this work, the second stage is analysed using the slowly varying flame approach, for a fuel rich flame. The droplets are presumed to vaporize in a sharp front ahead of the reaction front. Evolution equations for the flame and evaporation fronts are derived. For the former the combined effect of heat loss due to droplet vaporization and radiation plays a dominant explicit role. In addition, the structure of the evaporation front is deduced using asymptotics based on a large parameter associated with spray vaporization. Numerical calculations based on the analysis point to the way in which the spray modifies conditions for flame front extinction. Within the framework of the present simplified model the main relevant parameters turn out to be the initial liquid fuel load in the fresh mixture and/or the latent heat of vaporization of the fuel. 相似文献
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汽化器是LNG汽车燃料系统的重要设备。本文提出将汽化器换热过程分为过冷段、沸腾段与过热段的简化方法,并进行了LNG汽车起步阶段与正常行驶阶段汽化器性能模拟实验研究。 相似文献
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水和氢气、氧气在同等条件下(一个大气压,温度为25度)互相转变时自由能是相同的;同等条件下水变水蒸气时的汽化潜热和水蒸气变为水时的凝结热是相同的。利用一个刚性的绝热的容器,在海拔零米处电解水,利用氢气和氧气的混合密度小于空气密度的特点,携带一定质量的物体到数千米的高空。点燃混合气体,生成高温水蒸气。通过这个过程分析,将发现两部分能量多出。 相似文献
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CS Tripathi P Losada-Pérez J Leys G Cordoyiannis C Glorieux J Thoen 《The European physical journal. E, Soft matter》2012,35(7):54-7
The high-resolution adiabatic scanning calorimetric technique has been used to investigate the nematic-smectic A transition (N-SmA in binary mixtures of the non-smectogenic liquid crystal heptyloxycyanobiphenyl (7OCB) and heptane, exhibiting a so-called injected smectic A phase. With the exception of a mixture with the lowest heptane mole fraction for which only an upper limit of 0.2 ± 0.2 J kg(-1) for a possible latent heat could be obtained, for all other mixtures finite latent heats were obtained. The mole fraction dependence of the latent heat could be well fitted with a crossover function consistent with a mean-field free energy expression with a non-zero cubic term arising from the Halperin-Lubensky-Ma (HLM) coupling between the SmA order parameter and the orientational director fluctuations. The mole fraction dependence of the heat capacity effective critical exponents is similar to that observed in mixtures of the two liquid crystals octyloxycyanobiphenyl (8OCB) and nonylcyanobiphenyl (9OCB). The thermal behavior observed along the N-SmA phase transition line yields further strong evidence for the HLM coupling effect. 相似文献