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1.
The thermal conductivity, λ, and the specific heat capacity per unit volume, ρC p, of cyclopentane were determined in the range 100–300 K and up to 2·1 GPa. The transient hot-wire technique was used, and the experiments were carried out in a piston-cylinder apparatus. The λ values for the liquid and the two plastic crystalline phases are quite similar, while there is a strong increase corresponding to the plastic →normal crystal transition. In the normal crystal phase a T -1 dependence is observed, in contrast to the small variations of λ with temperature in the other phases. The pressure dependence of λ for the two plastic crystal phases shows a behaviour similar to that of the compressed liquid. Approximate ρC p data are reported. An extended phase diagram for cyclopentane is given.  相似文献   

2.
Sodium fullerides Na n C60 (n = 2, 3) have been synthesized by a liquid phase reaction and investigated with X-ray diffraction (XRD), nuclear magnetic resonance (NMR), electron paramagnetic resonance, and differential thermal analysis. XRD data indicate that the crystal structure of Na2C60 at 300 K is face centered cubic (FCC). A phase transition from primitive cubic to FCC crystal structure has been observed in this work in Na2C60 fulleride at 290 K. The transition is accompanied by the step-like change of paramagnetic susceptibility. The crystal structure of Na3C60 is more complicated than, and different from, what has been reported in the literature. A nearly seven-fold increase of paramagnetic susceptibility with increasing temperature has been observed in the Na3C60 fulleride at 240–260 K. In the same temperature range, a new line at about 255 ppm appears in the 23Na NMR spectrum, indicating a significant increase of electron density near the Na nucleus. The observed effect can be explained by a metal-insulator transition caused by a structural transition.  相似文献   

3.
Single crystal Brillouin and Raman scattering measurements on NH3 in a diamond anvil cell have been performed under pressures up to 26 GPa at room temperature. The pressure dependencies of acoustic velocity, adiabatic elastic constants, and bulk moduli of ammonia from liquid to solid III and solid IV phase have been determined. All the nine elastic constants in orthorhombic structure phase IV were presented for the first time, each elastic constant grows monotonously with pressure and a crossover of the off‐diagonal moduli C12 and C13 was observed at around 12 GPa because of their different pressure derivative values. We also performed ab initio simulations to calculate the bulk elastic moduli for orthorhombic ammonia, the calculated bulk moduli agree well with experimental results. In Raman spectra the very weak bending modes ν2 and ν4 for orthorhombic ammonia are both observed at room temperature, a transition point near 12 GPa is also found from the pressure evolution of the Raman bands. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

4.
The crystal structure and Raman spectra of Pr0.7Ca0.3MnO3 manganite at high pressures of up to 30 GPa and the magnetic structure at pressures of up to 1 GPa have been studied. A structural phase transition from the orthorhombic phase of the Pnma symmetry to the high-pressure orthorhombic phase of the Imma symmetry has been observed at P ∼ 15 GPa and room temperature. Anomalies of the pressure dependences of the bending and stretching vibrational modes have been observed in the region of the phase transition. A magnetic phase transition from the initial ferromagnetic ground state (T C = 120 K) to the A-type antiferromagnetic state (T N = 140 K) takes place at a relatively low pressure of P = 1 GPa in the low-temperature region. The structural mechanisms of the change of the character of the magnetic ordering have been discussed.  相似文献   

5.

We have used the real-space Migdal-Kadanoff renormalization group technique on d-dimensional hypercubic lattice to study the mixed spin-1/2 and spin-2 Blume-Capel model. First, we indicate a critical dimension dC ≈?2.05, above and below which different topologies of phase diagrams occur. The phase diagrams have been plotted in the (crystal field, temperature) plane around dC, in which there is a second-order phase transition. Moreover, using the variation of the free energy at low temperatures, we have established the ground-state phase diagrams in the (?/J, C/J) plane for d?<?dC and d?≥?dC. In particular, we have seen the appearance of two first-order transitions at very low temperatures by the use of the free energy and its isotherm derivative. A detailed analysis of fixed points and flow diagrams indicates that there is no tricritical point.

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6.
A model of a crystal with a strong electron-phonon interaction that initiates a second-order phase transition has been considered. The purpose of the study is to determine the temperature dependence of the thermodynamic potential of the symmetric phase in the temperature range in the immediate vicinity of the transition temperature T C for this model. The problem has been solved using the quantum Matsubara Green’s function approach, which takes into account the influence of both thermal and quantum fluctuations. It has been demonstrated that fluctuation coherent deformations of the crystal lattice with the same symmetry as in the ordered phase appear to be energetically favorable at T > T C due to the interaction with the electronic subsystem. The results obtained have made it possible to construct the model of the second-order phase transition near the Curie point T C.  相似文献   

7.

Magnetisation and magnetic susceptibility of a Lu2Fe17 single crystal have been studied under hydrostatic pressure up to 1.2 GPa at temperatures down to 5 K using a SQUID magnetometer. The ferromagnetic phase of Lu2Fe17 is suppressed rapidly above a critical pressure P C = 0.4 GPa in the whole temperature range below the critical temperature T C . A magnetic phase diagram of Lu2Fe17 has been constructed using results of the magnetic susceptibility measurements under pressure. A pressure induced incommensurate antiferromagnetic phase exhibits metamagnetic transitions with the increasing critical magnetic field H C under pressure. Taking into account recent neutron diffraction data, the pressure induced anisotropic changes of the lattice parameters of the Lu2Fe17 are discussed.  相似文献   

8.
MnGeO3 single‐crystal samples have been synthesized by optical zonal melting and spontaneous crystallization. X‐ray crystal analysis showed the first sample to be a two‐phase one with phase ratio as follows: 17% – monoclinic C2/c, and 83% – orthorhombic Pbca; the phase ratio of the second sample was unknown. Raman spectra have been produced for these samples. Lattice dynamics has been simulated and polarization dependencies of lines' intensities have been analyzed to interpret experimental Raman spectra and to attribute lines to the spectra of monoclinic and orthorhombic phases. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

9.
Infrared spectra of 1,2‐bis(trifluorosilyl)ethane (SiF3CH2CH2SiF3) were obtained in the vapour and liquid phases, in argon matrices and in the solid phase. Raman spectra of the compound as a liquid were recorded at various temperatures between 293 and 270 K and spectra of an apparently crystalline solid were observed. The spectra revealed the existence of two conformers (anti and gauche) in the vapour, liquid and in the matrix. When the vapour was chock‐frozen on a cold finger at 78 K and annealed to 150 K, certain weak Raman bands vanished in the crystal. The vibrational spectra of the crystal demonstrated mutual exclusion between IR and Raman bands in accordance with C2h symmetry. Intensity variations between 293 and 270 K of pairs of various Raman bands gave ΔH(gauche—anti) = 5.6 ± 0.5 kJ mol−1 in the liquid, suggesting 85% anti and 15% gauche in equilibrium at room temperature. Annealing experiments indicate that the anti conformer also has a lower energy in the argon matrices, is the low‐energy conformer in the liquid and is also present in the crystal. The spectra of both conformers have been interpreted, and 34 anti and 17 gauche bands were tentatively identified. Ab initio and density functional theory (DFT) calculations were performed giving optimized geometries, infrared and Raman intensities and anharmonic vibrational frequencies for both conformers. The conformational energy difference derived in CBS‐QB3 and in G3 calculations was 5 kJ mol−1. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

10.
The crystal and magnetic structures of manganite Pr0.7Ba0.3MnO3 have been studied at high pressures of up to 5.1 GPa and temperatures from 10 to 300 K by means of the neutron diffraction. At normal pressure and a temperature T C = 200 K, a ferromagnetic state forms in Pr0.7Ba0.3MnO3. At high pressures P ≥ 1.9 GPa and T < T N ≈ 153 K, a new antiferromagnetic state of A-type have been observed. Under high pressure, the Curie temperature T C increases with the characteristic quantity dT C/dP ≈ 2.4 K/GPa. A possible reason for the appearance of an A-type antiferromagnetic phase in Pr0.7Ba0.3MnO3 at high pressures may be anisotropic uniaxial compression of oxygen octahedra along the b axis of the orthorhombic structure.  相似文献   

11.
The effect of an external magnetic field with a strength up to 140 kOe on the phase transitions in manganese arsenide single crystals has been investigated. The existence of unstable magnetic and crystal structures at temperatures above the Curie temperature T C = 308 K has been established. The displacements of manganese and arsenic atoms during the magnetostructural phase transition and the shift in the temperature of the first-order magnetostructural phase transition in a magnetic field have been determined. It has been shown that the magnetocaloric effect in a magnetic field of 140 kOe near the Curie temperature T C is equal to ??T ?? 13 K. A model of the superparamagnetic state in MnAs above the temperature T C has been proposed using the data on the magnetic properties and structural transformation in the region of the first-order magnetostructural phase transition. It has been demonstrated that, at temperatures close to T C, apart from the contribution to the change in the entropy from the change in the magnetization there is a significant contribution from the transformation of the crystal lattice due to the magnetostructural phase transition.  相似文献   

12.
Electrical properties of SrTiO3 single crystal samples treated by an anisotropic surface annealing technique under reducing conditions have been investigated in the temperature range of 35 K–300 K. Optical and atomic force microscopy show that annealing gives rise to polycrystallization and the formation of colored dendritic structures. Carrier concentrations and mobilities determined by Hall measurements as well as resistivities detected by van der Pauw measurements show the expected metallic behavior due to oxygen vacancy doping. Moreover, the temperature dependent resistivities indicate a cubic-to-tetragonal phase transition, which to our knowledge has not been reported before. Additionally, the transition occurred up to 53 K above the known bulk transition temperature T C at 105 K with a hysteresis up to a temperature of 220 K. Both phenomena possibly arise from dislocations and associated strain fields introduced by surface annealing that are assumed to lower the free energy of the tetragonal phase and simultaneously pin tetragonal domains. Thus, microregions of the tetragonal phase persist above T C causing the hysteresis in resistivity up to ∼12%. This effect possibly provides new chances for future oxide based non-volatile data-storage devices.  相似文献   

13.
Abstract

A Series of dialkyldimethylammonium bromides (DDAB), (C n H2n+1)zN+(CH3)2Br?with n = 10, 12, 14, 16 and 18 were investigated using X-ray diffraction. Measurements were performed by the photographic Guinier method as well as by diffractometer on samples aligned on a glass substrate. For a sample with n=12, X-ray high-pressure measurements were also performed which allowed us to confirm the destabilization under pressure of the phase existing on heating above the first transition point. For all the studied compounds, except for that with n =16, strong hysteresis and rich polymorphism were observed. A smectic T phase - high-temperature liquid crystal was confirmed for compounds with n= 16 and 18. All the remaining alkylammonium salts have smectic an E high-temperature liquid crystal phase.  相似文献   

14.
Diffusion of lithium cations in C60 single crystals driven by electric field has been detected and studied. A novel technique for fullerene crystal doping based on injection of ions through a “superionic crystal/C60 single crystal” heterojunction has been suggested. It has been found that lithium doping of C60 single crystals brings about an ESR signal, and this signal as a function of time has been investigated. The electronic conductivity in LixC60 crystals has a nonmetallic nature. Reflection spectra measured in the IR band have shown that the reflectivity due to free electrons gradually decreases with time, which correlates with the evolution of signals due to ESR and microwave conductivity. Lithium doping of crystals increases the oscillator strength of the T 1u (4) vibrational mode and shifts it to lower frequencies (from 1429 cm−1 to 1413 cm−1), which indicates that one electron is present at the C60 molecule, and this fact may be treated as evidence that the LiC60 phase is generated in a C60 crystal. Zh. éksp. Teor. Fiz. 116, 1706–1722 (November 1999)  相似文献   

15.
The organic compound 1-chlorooctane exists in liquid state at ambient temperatures and has numerous synthetic applications. Fourier transform infrared and Raman spectra of this molecule have been recorded in the range of 4000−400 cm−1 and 3500−200 cm−1, respectively. A detailed vibrational analysis in terms of assignment of the observed frequencies of this molecule for its four most probable conformations in liquid phase, having symmetries C s and C l , has been done using normal co-ordinate calculations. The force-field transferred from already studied lower chain chloro-alkanes is subjected to refinement so as to fit the observed infrared and Raman frequencies with those of calculated ones. The potential energy distribution has also been calculated for each mode of vibration of the molecule for the most probable conformations present in its liquid phase.  相似文献   

16.
The mesophasic properties of S-alkylthiohexonolactones (d-galactono- and d-mannono-) and the corresponding itol derivatives with general formula Su-SR (R = C11H23) have been investigated. The observation that the synthesized compounds of this series has been studied using crossed polarized optical microscopy. This study involves the discovery of new chiral Smectic A liquid crystal phase through direct comparison with the defective texture of known Smectic A phase of available commercially biphenyls 8CB and 10CB.  相似文献   

17.
The organic compound 1,8-dibromooctane (1,8-DBO) exists in liquid phase at ambient temperatures and has versatile synthetic applications. In its liquid phase 1,8-DBO has been expected to exist in four most probable conformations, with all its carbon atoms in the same plane, having symmetries C 2h , C i , C 2 and C 1 . In the present study a detailed vibrational analysis in terms of assignment of Fourier transform infrared (FT-IR) and Raman bands of this molecule using normal co-ordinate calculations has been done. A systematic set of symmetry co-ordinates has been constructed for this molecule and normal co-ordinate analysis is carried out using the computer program MOLVIB. The force-field transferred from already studied lower chain bromo-alkanes is subjected to refinement so as to fit the observed infrared and Raman frequencies with those of calculated ones. The potential energy distribution (PED) has also been calculated for each mode of vibration of the molecule for the assumed conformations.  相似文献   

18.
The crystal structure of lead titanate PbTiO3 was investigated by energy dispersive X-ray diffraction at high pressures up to 4 GPa in a temperature range of 300–950 K. At the ambient conditions, the PbTiO3 structure is tetragonal with the space group P4mm (ferroelectric phase). A structural phase transition into the cubic phase with a space group Pm[`3]mPm\bar 3m is observed at T = 747 K. It was found that the phase transition temperature decreases upon applying the high pressure with the coefficient dT C /dP = -65 K/GPa. Dependences of parameters and volume of the unit cell on the pressure and temperature was found, and the bulk modulus and thermal expansion coefficients for the tetragonal and cubic phases of lead titanate have been calculated.  相似文献   

19.
In the lithium-caesium sulphate crystal in the temperature range of ferroelastic phase transition, the uniaxial stress σ X induced changes in velocity and attenuation of the longitudinal ultrasonic wave propagating in the direction [010] are studied. The phase transition is close to the three-critical point and the critical exponent is κ = 0.27 ± 0.02. The stress applied drastically decreases the stepwise change in the wave velocity at T C up to its disappearance at 2 MPa. In the temperature range between T C and T C − 6 K, the stress leads to an increase in the wave velocity and a decrease in its attenuation. This range was interpreted as that of co-existence of ferroelastic and incommensurate ordering, in which the stress influences the density of solitons leading to stiffening of the crystal lattice.  相似文献   

20.
We have performed thermal conductivity measurements on C60 and C70 crystals grown by sublimation. For single crystal C60, the thermal conductivity k is 0.4 W/m K at room temperature and is nearly temperature independent down to 260K. We observed a sharp orientational phase transition at 260K, indicated by a 25% jump in k. Below 90K, k is time dependent, which manifests itself as a shoulder-like structure at 85K. The temperature and time dependence of k below 260K can be described by a simple model which accounts for the thermally activated hopping of C60 molecules between two nearly degenerate orientations, separated by an energy barrier of 240 meV. It is found that solvents have a strong influence on the physical properties of C70 crystals. For solvent-free C70 crystal, k is about constant above 300K. There is a broad first-order phase transition in k at 300K with a 25% jump. We associate this transition with the aligning of the fivefold axes of the C70 molecules along the c-axis of the hexagonal lattice. Upon further cooling, k increases and is time independent.  相似文献   

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