Group duality and the Kubo-Martin-Schwinger condition

We consider clusteringG-invariant states of aC*-algebraU endowed with an action of a locally compact abelian groupG. Denoting as usual byF _AB,G _AB, the corresponding two-point functions, we give criteria for the fulfillment of the KMS condition (w.r.t. some one-parameter subgroup ofG) based upon the existence of a closable mapT such thatTF _AB =G _AB for allA,BU. Closability is either inL (G),B(G), orC (G), according to clustering assumptions. Our criteria originate from the combination of duality results for the groupG (phrased in terms of functions systems), with density results for the two-point functions.Supported in part by the National Science Foundation     

A new approach to calculate the gluon polarization

We derive the Leading-Order (LO) master equation to extract the polarized gluon distribution G(x,Q ²)=xδg(x,Q ²) from polarized proton structure function, g^p₁(x,Q²)g^{p}_{1}(x,Q^{2}). By using a Laplace-transform technique, we solve the master equation and derive the polarized gluon distribution inside the proton. The test of accuracy which is based in our calculations on two different methods, confirms that we achieve to the correct solution for the polarized gluon distribution. To determine the polarized gluon distribution xδg(x,Q ²) more accurately, we only need to have more experimental data on the polarized structure functions, g₁^p(x,Q²)g_{1}^{p}(x,Q^{2}). Our result for polarized gluon distribution is in good agreement with some phenomenological models.     

The 2‐matrix of the spin‐polarized electron gas: contraction sum rules and spectral resolutions

The spin‐polarized homogeneous electron gas with densities ρ_↑ and ρ_↓ for electrons with spin ‘up’ (↑) and spin ‘down’ (↓), respectively, is systematically analyzed with respect to its lowest‐order reduced densities and density matrices and their mutual relations. The three 2‐body reduced density matrices γ_↑↑, γ_↓↓, γ_a are 4‐point functions for electron pairs with spins ↑↑, ↓↓, and antiparallel, respectively. From them, three functions G_↑↑(x,y), G_↓↓(x,y), G_a(x,y), depending on only two variables, are derived. These functions contain not only the pair densities according to g_↑↑(r) = G_↑uarr;(0,r), g_↓↓(r) = G_↓↓(0,r), g_a(r) = G_a(0,r) with r = | r ₁ ‐ r ₂|, but also the 1‐body reduced density matrices γ_↑ and γ_↓ being 2‐point functions according to γ_s = ρ_sf_s and f_s(r) = G_ss(r, ∞) with s = ↑,↓ and r = | r ₁ ‐ r ^′₁|. The contraction properties of the 2‐body reduced density matrices lead to three sum rules to be obeyed by the three key functions G_ss, G_a. These contraction sum rules contain corresponding normalization sum rules as special cases. The momentum distributions n_↑(k) and n_↓(k), following from f_↑(r) and f_↓(r) by Fourier transform, are correctly normalized through f_s(0) = 1. In addition to the non‐negativity conditions n_s(k),g_ss(r),g_a(r) ≥ 0 [these quantities are probabilities], it holds n_s(k) ≤ 1 and g_ss(0) = 0 due to the Pauli principle and g_a(0) ≤ 1 due to the Coulomb repulsion. Recent parametrizations of the pair densities of the spin‐unpolarized homogeneous electron gas in terms of 2‐body wave functions (geminals) and corresponding occupancies are generalized (i) to the spin‐polarized case and (ii) to the 2‐body reduced density matrix giving thus its spectral resolutions.     

Ab initio study of the Ar–CS2(V1B2) intermolecular potential surface: effect of van der Waals interaction on the emission of CS2 molecule

In this work, the excited state intermolecular potential energy surface of the Ar–CS₂(V¹B₂) van der Waals complex was evaluated for the first time. The calculation of more than 4000 single-point interaction energies for the complex using an equation-of-motion coupled-cluster model with single and double substitutions level of theory with extended basis set involving bond functions has been performed. After fitting the interaction energies to analytical functions, the emission spectra of the Ar–CS₂(V¹B₂) complex related to the different stationary points on the potential energy surface were calculated. It was seen that the intensity and the position of the emission spectra are dependent on the orientation of the Ar atom around the bent excited CS₂ and the distance between two components. The information about the structural parameters of the complex related to the global minimum was obtained under the pseudodiatomic approximation with assistance of ab initio potential. The presented investigation could be useful for further theoretical and experimental studies of Ar–CS₂(V¹B₂) complex.     

Electromagnetic form factors of nucleons in a relativistic square-root potential model of independent quarks

The nucleon electromagnetic form factorsG _E ^P (q²),G _M ^P (q²) and the axial-vector form factor G_A(q²) are studied in a relativistic model of independent quarks confined by an equally mixed scalar-vector square root potentialV _q(r)=1/2(1+γ ⁰)(ar ^1/2+ν ₀) taking into account the appropriate centre-of-mass corrections. The respective root-mean-square radii associated withG _E ^P (q²) and G _A (q²) come out as [〈r ²〉 _E ^P ]^1/2=0.86 fm and 〈r _A ² 〉^1/2=0.88 fm. Restoration of chiral symmetry in this model is discussed to derive the pion-nucleon form factorG _πNN(q²) and consequently the pion-nucleon coupling constant is obtained asg _πNN(q²)=12.81 as compared tog _πNN(q²)_exp⋍13.     

New explicit nonperiodic solutions of the homogeneous wave equation

We exhibit a newansatz for the solution of the homogeneous three-dimensional time-dependent wave equation in spherical coordinates of the form Φ(r,t)=Y(θ, φ)(I(r)+G(g)), whereg ≡ct/r. FunctionG(g) has explicit solution in terms of three independent nonperiodic functionss _ℓ,t _ℓ,u _ℓ (s _ℓ andt _ℓ are related to the associated Legendre functions of the first and second kinds).G(g) is nonperiodic and may be cast as a superposition of incoming and outgoing waves. To obtainG(g), we solved a nonhomogeneous associated Legendre equation (this solution, to our knowledge, is also new).G(g) may prove useful in many microscopic and macroscopic problems, representable by homogeneous wave equations.     

Study of nucleon spin-dependent properties in the resonance region

In this paper, the spin-dependent structure functions of nucleon g ₁, and photoabsorption cross sections σ_1/2, σ_3/2 and σ_T in the resonance region are estimated based on the constituent quark model and the properties of the five phenomenological Breit-Wigner resonances P ₃₃(1232), S ₁₁(1535), D ₁₃(1520), P ₁₁(1440), and F ₁₅(1680). Our results are compared to the recent E143 data of the polarized structure functions g ₁(W ², Q ²) at points Q ²=0.5 GeV² and Q ²=1.2 GeV² and the data of the total inclusive photoabsorption cross sections. Received: 7 October 1997     

The gluonic condensate from the hyperfine splitting M cog(XcJ) — M(h c) in charmonium

The precision measurement of the hyperfine splitting, Δ_HF(1P, c-c) = M _cog(xcJ) — M(h _c), in the Fermilab-E835 and CLEO experiments allows one to determine the gluonic condensate G ₂ with high accuracy if the gluonic correlation length T _g is fixed. In our calculations, the negative value of Δ_HF = −0.5 ± 0.4 MeV, as in the E835 experiment, is obtained only if the relatively small T _g = 0.16 im and G ₂ = 0.060(3) GeV⁴ are taken. For T _g ≥ 0.2 fm, the hyperfine splitting is positive and grows for increasing T _g. In particular, for T _g = 0.2 fm and G ₂ = 0.045(2) GeV⁴, the splitting Δ_HF = 1.0(5) MeV is just in accordance with the recent CLEO result. The values of G ₂ taken correspond to the “physical” string tension σ ≈ 0.18 GeV². The text was submitted by the authors in English.     

Quantum Yang-Mills on a Riemann surface

We obtain the quantum expectations of gauge-invariant functions of the connection on aG=SU(N) product bundle over a Riemann surface of genusg. We show that the spaceA/G _m of connections modulo those gauge transformations which are the identity at one point is itself a principal bundle with affine linear fiber. The base space Path^2g G consists of 2g-tuples of paths inG subject to a relation on their endpoint values. Quantum expectations are iterated path integrals over first the fiber then over Path^2g G, each with respect to the push-forward toA/G _m of the measuree ^–S(A) D A. Here,S(A) denotes the Yang-Mills action onA. We exhibit a global section ofA/G _m to define a choice of origin in each fiber, relative to which the measure on the fiber is Gaussian. The induced measure on Path^2g G is the product of Wiener measures on the component paths, conditioned to preserve the endopoint relation. Conformal transformations of the metric onM act by reparametrizing these paths. We explicitly compute the partition function in the general case and the expectations of functions of certain products of Wilson loops in the caseg=1.Research supported in part by DOE grant DE-FGO2-88ER25066     

Threshold energy electron impact excitation of carbon dioxide and carbon disulphide

The threshold energy electron impact excitation spectra of CO₂ and CS₂ have been studied using the sulfur hexafluoride scavenger technique. The main results are triplet state excitation and autoionisation of negative ions associated with resonant excited states of the molecules. This confirms previous data concerning diatomic molecules. Furthermore, transitions such as ¹Π_g?X¹Σ_g⁺ and ¹Π_u?X ¹Σ_g⁺ are only weakly induced by low energy electrons, while the corresponding triplet excitations are probably more easily produced. Structures at 5.6, 6.1 and 6.6 eV observed in CS₂ are due to negative ions and/or to ³Π_u, ³Π_g excitation.The autoionisation of CO₂^?(X²Π_u) proceeds also by ejection of a thermal energy electron and leads to highly excited vibrational levels (3–5 eV) of the ground electronic state of CO₂.     

A ligand field theory analysis of the spectra of the t 2g 3 levels of IrF6

Calculations and experimental data are presented for the t _2g ³ molecular levels of IrF₆ which imply that a substantial interaction takes place between these 5d³-configuration states and charge transfer states at ca. 20 000 cm^-1. This t _2g ³-charge transfer state configuration interaction is so extensive that the five t _2g ³ levels can only be fit with physically unreasonable values of the Racah (electrostatic) parameters and a spin orbit coupling parameter that is not consistent with expectations for 5d-series transition metal hexafluorides. Parameter values presented for IrF₆ are thus determined from the lowest three levels only, as these should experience the smallest relative shift due to configuration interaction: B = 297 cm^-1, C = 1167 cm^-1, ζ_5d = 4182 cm^-1, and 10Dq = 35 000 cm^-1. In order to corroborate the assertion that t _2g ³-charge transfer configuration interaction is an important factor for the determination of IrF₆ crystal and molecular properties, a number of t _2g ³ spectroscopic properties, which turn out to be quite sensitive to charge transfer state admixture, were studied theoretically and experimentally. These include gas-to-crystal shifts, site splittings, and Jahn-Teller interactions; comparison of calculated and experimental values clearly substantiate the conclusion that there is a strong influence of charge transfer states on the nature of the 5d³-t _2g ³ manifold. Finally, new data for the Γ_8g (² E_g ) and Γ_6g (² T _1g ) states at 1·2 μm are given, completing the data set for the t _2g ³ transitions of IrF₆.     

Amplitude of Aharonov-Bohm oscillations in a small semiconductor ring interferometer in the tunneling regime

The amplitude g_AB of Aharonov-Bohm oscillations in a small semiconductor ring interferometer is studied as a function of the average conductance G_AV. Experimentally, it is found that, in the tunneling regime, the relative amplitude g_AB/G_AV of h/e oscillations is constant in the rings under investigation and smaller than unity. The small value of g_AB/G_AV in ring interferometers in the tunneling regime at low temperatures is explained by the difference in the amplitudes of the interfering electron waves.     

Nucleon form factors of the isovector axial-vector current

The theoretical and experimental status of the isovector axial-vector current form factors G _A(q ²) and G _P(q ²) of the nucleon is reviewed. We also describe a new calculation of these form factors in manifestly Lorentz-invariant chiral perturbation theory (ChPT) with the inclusion of axial-vector mesons as explicit degrees of freedom.     

Unpolarized structure functions and the parton distributions for nucleon in an independent quark model

Considering the nucleon as consisting entirely of its valence quarks confined independently in a scalar-vector harmonic potential; unpolarized structure functions F ₁(x, μ ²) and F ₂(x, μ ²) are derived in the Bjorken limit under certain simplifying assumptions; from which valence quark distribution functions u _v(x, μ ²) and d _v(x, μ ²) are appropriately extracted satisfying the normalization constraints. QCD-evolution of these input distributions from a model scale of μ ²=0.07 GeV² to a higher Q ² scale of Q ₀ ² =15 GeV² yields xu _v(x, Q ₀ ² ) and xd _v(x, Q ₀ ² ) in good agreement with experimental data. The gluon and sea-quark distributions such as G(x, Q ₀ ² ) and q _s(x, Q ₀ ² ) are dynamically generated with a reasonable qualitative agreement with the available data; using the leading order renormalization group equations with appropriate valence-quark distributions as the input.     

Attempts to understand g1(x) and g2(x)

The present theoretical understanding of the polarized nucleon structure functions is reviewed. The results of the European Muon Collaboration forg ₁ ^p (x) have generated an enormous theoretical activity, resulting in a large number of possible explanations. The presently available data are not sufficient to decide between them, but much improved experiments are planned for the next years. The possibility of an anomalous gluon contribution is most interesting on theoretical grounds. Finally we discussg ₂(x) which is extremely model dependent and thus could allow a clear decision between the various models proposed. Its measurement requires, however a much improved experimental precision.     

Group duality and the Kubo-Martin Schwinger condition. II

Let be an invariant state of theC*-system { ,G, } on a locally compact noncommutative groupG. Assume further that is extremal -invariant for an action of an amenable groupH which is -asymptotically abelian and commutes with . Denoting byF _AB,G _AB the corresponding two point functions, we give criteria for the fulfillment of the KMS condition with respect to some one parameter subgroup of the center ofG based on the existence of a closable mapT such thatTF _AB=G _AB for allA,B . Closability is either inL (G),B(G) orC (G), according to clustering properties for . The basic mathematical technique is the duality theory for noncompact, noncommutative locally compact groups.This work is supported in part by the National Science Foundation, Grant MCS 79-03041     

Method of Quantum Characters in Equivariant Quantization

 Let G be a reductive Lie group, g its Lie algebra, and M a G-manifold. Suppose 𝔸 _h (M) is a 𝕌 _h (g)-equivariant quantization of the function algebra 𝔸(M) on M. We develop a method of building 𝕌 _h (g)-equivariant quantization on G-orbits in M as quotients of 𝔸 _h (M). We are concerned with those quantizations that may be simultaneously represented as subalgebras in 𝕌^* _h (g) and quotients of 𝔸 _h (M). It turns out that they are in one-to-one correspondence with characters of the algebra 𝔸 _h (M). We specialize our approach to the situation g=gl(n,ℂ), M=End(ℂ ⁿ ), and 𝔸 _h (M) the so-called reflection equation algebra associated with the representation of 𝕌 _h (g) on ℂ ⁿ . For this particular case, we present in an explicit form all possible quantizations of this type; they cover symmetric and bisymmetric orbits. We build a two-parameter deformation family and obtain, as a limit case, the 𝕌(g)-equivariant quantization of the Kirillov-Kostant-Souriau bracket on symmetric orbits. Received: 28 April 2002 / Accepted: 3 October 2002 Published online: 24 January 2003 RID="*" ID="*" This research is partially supported by the Israel Academy of Sciences grant no. 8007/99-01. Communicated by L. Takhtajan     

Investigations on the g factors of the ground and excited states for Cu2+ ions in ZnO crystal

The g factors g _// and g _⊥ of the ground Γ₆(² T ₂) and excited Γ_4,5(² E), Γ₆(² E) states for trigonal Cu²⁺ centres in ZnO crystals are calculated from three theoretical methods, the complete diagonalization (of the energy matrix) method, the second-order perturbation method (PTM-I) and the simplified second-order perturbation method (PTM-II, this method was described in an earlier paper). These methods are based on the cluster approach in which the spin-orbit coupling parameters ζ, ζ′ and the orbital reduction factors k, k′ are calculated from a semi-empirical molecular orbital method. The crystal-field parameters used in the calculations are obtained from the superposition model and so the defect structure of Cu²⁺ centres in ZnO can be acquired. The calculated g factors from the three methods are in reasonable agreement with the experimental values and the defect structure of Cu²⁺ centres in ZnO is acquired. It appears that in some cases the approximate PTM can be applied in the studies of g factors of various states. The conditions that the PTM are ineffective are discussed.     

Studies of molecular motions and interactions in acetonitrile

Microwave and far-infrared absorption coefficients are reported for acetonitrile over the whole concentration range in carbon tetrachloride solution. The data have been used to compute dipole reorientational correlation functions and relaxation times as a function of concentration. These show that τ_1R ^T increases non-linearly as the acetonitrile concentration increases (in contrast to the values of τ_2R ^T obtained from light scattering measurements) and as the viscosity decreases. This behaviour is examined in terms of intermolecular correlations between rotating dipoles. Intensity data are used to provide a check on the importance of induced dipole absorption in the far-infrared spectra and to calculate ‘static’ correlation factors g ⁽¹⁾. Both g ⁽¹⁾ and the dynamic correlation factor f ⁽¹⁾ reflect the effects of strong molecular interactions in these solutions.     

Axial form-factor and induced pseudoscalar form-factor of the nucleons

We calculate the axial and the induced pseudoscalar form-factors G_A(t=-Q²) and G_P(t=-Q²) of the nucleons in the framework of the light-cone QCD sum-rules approach up to twist-6 three valence quark light-cone distribution amplitudes, and observe that the form-factors G_A(t=-Q²) and G_P(t=-Q²) at intermediate and large momentum transfers with Q²>2 GeV² have significant contributions from the end-point (soft) terms. The numerical values for the axial form-factor G_A(t=-Q²) are compatible with the experimental data and theoretical calculations; for example, the chiral quark models and lattice QCD. The numerical values for the induced pseudoscalar form-factor G_P(t=-Q²) are compatible with the calculation from the Bethe–Salpeter equation. PACS 12.38.Aw; 12.38.-t; 14.20.Dh