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1.
Polycondensation of the diacid chloride of 2-(3-carboxy vinyl)phenyl-1,3-dioxoisoindoline-5-carboxylic acid with m-phenylenediamine and the diacid chloride of 2-(4-carboxy phenyl)-1,3-dioxoisoindoline-5-carboxylic acid with 1,5-bis(3-aminophenyl)1,4-pentadien-3-one was carried out in polar solvents to produce new unsaturated polyamide–imides. The solution and the thermal, electrical, and a few other properties of the polymers were studies. The polymers were soluble in highly polar solvents. The solubility parameter of the polymers was calculated from the Small's group contribution. The polymers were fairly thermostable and underwent crosslinking creaction when heated, preferably in the presence of a suitable catalyst. The crosslinked polymers were in soluble even in highly polar solvents and possessed higher thermal stability. The swelling behavior of the polymers was studied and the molecular weight between two consecutive crosslinks was determined. X-ray diffraction and the dielectric properties of the polymers and their crosslinked products were also studied. 相似文献
2.
Ekaterine Chkhaidze David Tugushi Darejan Kharadze Zaza Gomurashvili Chih-Chang Chu Ramaz Katsarava 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(7):544-555
The synthesis of α-amino acid L-leucine (Leu) based high-molecular-weight and biodegradable unsaturated poly(ester-amide)s (PEAs) was reported. Amino acid L-phenylalanine (Phe) was used to synthesize some copolymers for a comparative study. The syntheses of three types of new unsaturated PEA polymers were explored – (i) Unsaturated PEA homopolymers (UPEAs) composed of fumaric acid, aliphatic diol and one alpha-amino acid: L-Leu or L-Phe; (ii) L-Leu-based unsaturated-saturated copolymers (USPEAs) composed of aliphatic diol, fumaric and saturated fatty diacid, and (iii) L-Leu- and L-Phe-based copolymers (co-UPEAs) composed of 100% fumaric acid, aliphatic diol and combinations of both amino acids. Many of the targeted unsaturated polymers were soluble in common organic solvents and showed good film-forming property. The unsaturated PEA polymers were further chemically modified into functional derivatives and subjected to thermal and photochemical transformations (curing) that substantially expand material properties and, hence, the scopes of potential applications as absorbable surgical devices and drug carriers. 相似文献
3.
Synthesis of ethylene/vinyl ester copolymers with pendent linear branches via ring‐opening metathesis polymerization of fatty acid‐derived cyclooctenes
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Yuchen Feng Suyun Jie Bo‐Geng Li 《Journal of polymer science. Part A, Polymer chemistry》2017,55(13):2211-2220
Fatty acid‐derived cyclooctenes, including n‐hexanoic acid ( M1 ), n‐octanoic acid ( M2 ), lauric acid ( M3 ), and palmitic acid ( M4 ), were prepared as monomers and polymerized by ring‐opening metathesis polymerization (ROMP) using Grubbs second‐generation catalyst ( G2 ). In all the cases, the regio‐irregular unsaturated polymers with pendent linear branches were obtained, which could be saturated by chemical hydrogenation with TSH/TPA in high conversion, yielding ethylene/vinyl ester copolymers with pendent linear branches on precisely every eighth backbone carbon. Both unsaturated and saturated polymers were amorphous, and their structures were characterized by FTIR, 1H and 13C NMR spectra, and elemental analysis. Differential scanning calorimetry (DSC) and thermo‐gravimetric analysis (TGA) were used to study their thermal properties. The chain length of branches greatly affected the thermal properties of polymers. After hydrogenation, the thermal degradation stability of polymers was relatively improved. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2211–2220 相似文献
4.
G. F. D'Alelio T. R. Hoffend 《Journal of polymer science. Part A, Polymer chemistry》1967,5(6):1245-1264
The synthesis and the anionic polymerization of representative substituted styrenes, CH2?CH? C6H4R′, where R′ is an ethylenic or acetylenic group attached directly or indirectly to the benzene ring, to linear polymers is described. In contrast, crosslinked polymers were obtained when radical and cationic initiators were used. The unpolymerized, unsaturated bonds in R′ in the resulting linear polymers were shown to be present by infrared spectroscopic methods and by the following post-reactions of these bonds: (1) the thermal- and radical-initiated crosslinking of the linear polymers through the unsaturated bonds in R′; (2) the post-bromination of these unsaturated bonds; (3) the post-copolymerization of these unsaturated bonds with vinyl monomers; and (4) the reaction of decaborane with the acetylenic bonds. The anionic copolymerizations of methyl methacrylate, acrylonitrile, and styrene with these monomers were performed and confirmed their behavior as substituted styrenes. Block copolymerizations with styrene and methyl methacrylate were also performed and the expected results obtained. Post-bromination of the linear polymers afforded self-extinguishing polymers. The linear polymers and copolymers may be classified as “self-reactive” polymers which yield thermosetting polystyrenes. 相似文献
5.
Three kinds of low molecular weight unsaturated polyesters containing carbon-carbon double bonds were synthesized by the reaction of poly (ε-caprolactone) diol or D,L-lactide and glycolic acid with maleic anhydride or fumaric acid. These functionalized polymers were thermally crosslinked in the presence of radical initiator to prepare the crosslinked polymers available as a matrix resin for biomedical composites. Hydrolysis of the crosslinked polyesters was investigated in buffer solution at 37°C. 相似文献
6.
Lidia Jasinska Cor E. Koning 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):2885-2895
Biobased, unsaturated polyesters derived from isosorbide, maleic anhydride, and succinic acid were synthesized and characterized. The presence of maleic anhydride units in the structure of the polyesters allowed converting them into cured coatings by radical copolymerization with crosslinking agents such as 2‐hydroxyethyl methacrylate, N‐vinyl‐2‐pyrrolidinone, acrylic acid or methacrylamide. The investigated polyesters were obtained via bulk polycondensation, catalyzed by titanium(IV) n‐butoxide. 2D NMR and MALDI‐Tof‐MS spectroscopy proved that this polymerization resulted in isomerization of maleic acid units into fumaric ones and in the formation of slightly branched structures by the reaction of isosorbide (end) groups with main chain unsaturated bonds. Moreover, some double bonds proved to have reacted with the condensation by‐product water. The resulting polyesters displayed the expected correlation between variables such as molecular weight and content of unsaturated bonds and their Tg values. Since the thermal properties of the obtained polyesters were appropriate for coating applications, the polymers were crosslinked with unsaturated monomers by radical copolymerization. The crosslinking process was studied using FTIR spectroscopy and by measurements of the soluble part of the cured coatings. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2885–2895, 2010 相似文献
7.
Efimenko I. A. Efimov N. N. Erofeeva O. S. Demina L. I. Simonenko N. P. Churakov A. V. Minin V. V. 《Russian Journal of Coordination Chemistry》2021,47(10):707-716
Russian Journal of Coordination Chemistry - Palladium(I) coordination polymers with unsaturated dicarboxylic acids, {[cis-Pd(C4H2O4)(H2O)]·(H2O)}n (I) (maleic acid),... 相似文献
8.
Ring Opening Metathesis Polymerization of Bicyclic α,β‐Unsaturated Anhydrides for Ready‐to‐be‐grafted Polymers Having Tailored pH‐Responsive Degradability
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Heejin Kim Sungwhan Kim Sunyoung Kang Youngjun Song Dr. Suyong Shin Dr. Seonju Lee Minji Kang Dr. So Hee Nam Prof. Dr. Yan Lee 《Angewandte Chemie (International ed. in English)》2018,57(38):12468-12472
Polymers having α,β‐unsaturated anhydrides as repeating units were synthesized by ring opening metathesis polymerization (ROMP). The anhydride moieties were ready‐to‐be‐grafted with amines to form acid‐labile cis‐α,β‐unsaturated acid amide linkages. The pH‐responsive reversible de‐grafting can be controlled by changing the intramolecular accessibility between acid and amide groups. The alendronate‐grafted ROMP polymers showed distinct pH‐dependent cytotoxicity according to the anhydride structures. 相似文献
9.
New types of polyanhydrides with advantageous properties with respect to biomedical use were synthesized. The first are aliphatic-aromatic homopolyanhydrides of the structure: -(OOC-C6H4-O(CH2)x- CO-)n (=1−10). These polymers display a zero-order hydrolytic degradation profile for two to ten weeks, the time period of degradation is a function of the length of the aliphatic chain. Stability studies under anhydrous conditions showed that these polymers underwent reversible self-depolymerization in chloroform but were stable in solid state for over 6 months at 25°C. The second type of polymer, unsaturated polyanhydride of the structure: [-(OOC-CH=CH-CO)x-(OOC-R-CO)y-]n, have the advantage of secondary polymerization of double bonds to create a crosslinked matrix. These polymers were prepared from the corresponding diacids polymerized by melt condensation or in solution. Molecular weights of up to 44 000 and 30 000 were achieved for polyanhydrides of p-carboxyphenoxyalkanoic acid and fumaric acid, respectively. 相似文献
10.
Liquid chromatographic assay for constituent disaccharides of hyaluronic acid and chondroitin sulphate isomers 总被引:1,自引:0,他引:1
An improved high-performance liquid chromatographic (HPLC) method for unsaturated disaccharides prepared from hyaluronic acid and various chondroitin sulphate and dermatan sulphate isomers was developed, which involves an ion-exchange resin prepared from a sulphonated styrene-divinylbenzene copolymer. The retention times of the individual unsaturated disaccharides were unique and reproducible, the disaccharides appearing in the following order: unsaturated non-sulphated disaccharide derived from hyaluronic acid, then unsaturated 6-sulphated, non-sulphated and 4-sulphated disaccharides from chondroitin sulphate isomers. Unsaturated disulphated disaccharide G had a much shorter retention time than the unsaturated non-sulphated disaccharide derived from hyaluronic acid. The contents of these individual unsaturated disaccharides could be determined with similar sensitivities on the basis of their ultraviolet absorbance. Selective and unique retention times and good resolutions were found for various unsaturated disulphated and trisulphated disaccharides. The proposed method can be used to determine various chondroitin sulphate and dermatan sulphate isomers in addition to hyaluronic acid in amounts as small as 100 ng to 8 micrograms. The practicality of this method was verified by its application to the separation and determination of the different types of chondroitin sulphate and dermatan sulphate isomers derived from human arteries in the presence of appreciable amounts of hyaluronic acid. 相似文献
11.
Patrick J. HeaphyJustin R. Griffiths Christopher J. DietzG. Paul Savage Ronny Priefer 《Tetrahedron letters》2011,52(48):6359-6362
Cubane is a highly strained unsaturated molecule that was first synthesized in 1964 by Philip E. Eaton. Since cubane’s discovery, it has been researched in pharmaceuticals, explosives, and polymers. Due to its range of uses, we have explored the thermo-stability of a number of cubane derivatives. Some derivatives have revealed its propensity to undergo cage opening/rearrangement. In examining 1-iodocubane-4-carboxaldehyde, we observed that benzoic acid, benzaldehyde, benzyl alcohol, and benzyl benzoate were surprisingly formed in this thermo-decay. 相似文献
12.
Boris A. Zaitsev Raisa F. Kiseleva Irina O. Gusarova 《Journal of polymer science. Part A, Polymer chemistry》1996,34(7):1165-1181
A peculiar step-growth (cationic) polymerization of bis(p-vinylphenyl) ether (BVPE) in nonpolar or slightly polar aromatic solvents in the temperature range from 70 to 150°C in the presence of 2.5–5.0 mmol/L of p-toluenesulfonic acid has been studied. Optimum polymerization conditions were found. New linear unsaturated polymers of BVPE with terminal vinyl groups and weight-average molecular weight from 1500 to 10,000 were obtained. The structure and the formation mechanism of these oligomers and polymers were established, and the accompanying side reactions were considered. The rate constants were measured for eight temperatures, and the activation energy was found to be −42 kJ/mol. The optimum polymerization temperature was about 80°C. © 1996 John Wiley & Sons, Inc. 相似文献
13.
Dhruba Jyoti Sarkar Jitendra Kumar N. A. Shakil Totan Adak A. C. Watterson 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(6):455-465
Twelve amphiphilic polymers were synthesized using poly(ethylene glycols) (PEGs) of different molecular weights, viz. 1000, 2000 and 4000 as hydrophilic block and linkers namely azelaic acid, sebacic acid, dimethyl isophthalate acid and dimethyl terephthalate as hydrophobic block in the presence of catalyst Conc. H2SO4. Synthesized polymers were characterized by using 1H-NMR, 13C-NMR and IR spectroscopy. Micellar sizes of the polymers were determined using Dynamic Light Scattering (DLS) which ranged from 51.6–174 nm for aliphatic polymers and 135.5–371 nm for aromatic polymers. Transmission Electron Microscope (TEM) results confirm the findings of DLS. Critical Micelle Concentrations (CMC) of the synthesized polymers were determined using electrical conductivity meter which ranged from 95 to 130 mg L?1 for aliphatic polymers and 420–1500 mg L?1 for aromatic polymers. 相似文献
14.
Jia Chen Yuan Liang Wang Mei Na Huang 《中国化学快报》2007,18(5):613-616
The novel biodegradable copolymer PDLLA-(MAH-Diol)_n-PDLLAwith unsaturated bond was synthesized by copolymerizing lactide and prepolymer, which was prepared by the polycondensation of maleic anhydride and poly(ethylene glycol), using p- toluene sulphonic acid as catalyst. The new copolymer has improved hydrophilicity and fexibility. The structure and properties of the novel polymers were studied by FTIR, NMR, GPC-MALLS and DSC. 相似文献
15.
Masao Kato Taro Ichijo Keizo Ishii Masaki Hasegawa 《Journal of polymer science. Part A, Polymer chemistry》1971,9(8):2109-2128
A new preparative route to photocrosslinkable polymers in which the polymers are produced directly from the polymerization of vinyl monomers having photocrosslinkable groups has been investigated. The photosensitive resins thus produced have higher sensitivity and resolution than conventional photosensitive resins. The monomers were synthesized from the esterification of vinylphenols or vinyl β-chloroethyl ether with cinnamic acid, β-styrylacrylic acid, and their homologs, and from the etherification of vinyl β-chloroethyl ether with hydroxychalcones. Homopolymerizations of these monomers and their copolymerizations with other comonomers were investigated with the use of both radical and ionic initiators. It is shown that radical polymerization of the monomers gave soluble polymers only at low conversion. Anionic initiators did not initiate polymerization. Cationic polymerization imparted soluble polymers in high yield, except for the monomers bearing cyano groups, which generally gave insoluble polymers. Infrared and NMR spectroscopic investigation of the cationically obtained soluble polymers and comparative investigation by cationic polymerization of model compounds indicated that polymerization of the monomers proceeds through the vinyl double bond without affecting the photosensitive unsaturated bond. Thus, linear photocrosslinkable polymers with an intact photoreactive group may be produced by cationic polymerization. In general, these polymers have uniform structure and modifiable physical properties depending on the monomer used. The polymer thus obtained from β-vinyloxyethyl cinnamate has been shown to have excellent properties for use as a photo-resist. 相似文献
16.
Yoshio Imai Mitsuru Ueda Tatsuo Aizawa 《Journal of polymer science. Part A, Polymer chemistry》1976,14(11):2797-2805
A novel class of polypyridazinophthalazinediones has been synthesized by the solution cyclopolycondensation in m-cresol of dibenzoylphthalic acids with aromatic dihydrazines such as bis(4-hydrazinophenyl)methane and bis(4-hydrazinophenyl) sulfone. The polyheterocycles derived from 4,6-dibenzoylisophthalic acid, which had inherent viscosities of up to 0.5, were soluble in m-cresol and hot dichloroacetic acid, whereas the polymers from 2,5-dibenzoylterephthalic acid were practically insoluble in organic solvents. Thermogravimetric analyses showed that all the polymers underwent weight losses of 10% at 490–520°C in both air and nitrogen. 相似文献
17.
Daniel Santhanaraj Maria P. Ruiz Mallik R. Komarneni Tu Pham Gengnan Li Daniel E. Resasco Jimmy Faria 《Angewandte Chemie (International ed. in English)》2020,59(19):7456-7460
We report a reaction platform for the synthesis of three different high‐value specialty chemical building blocks starting from bio‐ethanol, which might have an important impact in the implementation of biorefineries. First, oxidative dehydrogenation of ethanol to acetaldehyde generates an aldehyde‐containing stream active for the production of C4 aldehydes via base‐catalyzed aldol‐condensation. Then, the resulting C4 adduct is selectively converted into crotonic acid via catalytic aerobic oxidation (62 % yield). Using a sequential epoxidation and hydrogenation of crotonic acid leads to 29 % yield of β‐hydroxy acid (3‐hydroxybutanoic acid). By controlling the pH of the reaction media, it is possible to hydrolyze the oxirane moiety leading to 21 % yield of α,β‐dihydroxy acid (2,3‐dihydroxybutanoic acid). Crotonic acid, 3‐hydroxybutanoic acid, and 2,3‐dihydroxybutanoic acid are archetypal specialty chemicals used in the synthesis of polyvinyl‐co‐unsaturated acids resins, pharmaceutics, and bio‐degradable/ ‐compatible polymers, respectively. 相似文献
18.
John A. Mikroyannidis 《Journal of polymer science. Part A, Polymer chemistry》1995,33(3):381-387
3,5-Dinitrobenzoyl chloide was condensed with malononitrile in the presence of sodium hydroxide under phase-transfer conditions to afford 1-(2,2-dicyano-1-hydroxyvinyl)-3,5-dinitrobenzene, sodium salt, which was catalytically hydrogenated to the corresponding diamine. The latter was used as starting material for the preparation of unsaturated cyanosubstituted polyamides and polyimides. The polymers were soluble in polar aprotic solvents, dilute sodium hydroxide, and certain strong inorganic and organic acids. Upon curing at 300°C for 65 h, crosslinked polymers were obtained that were stable up to 392–404°C in N2 or air and afforded an anaerobic char yield of 60–71% at 800°C. Their glass transition temperatures as determined by thermal mechanical analysis (TMA) were 221–275°C. © 1995 John Wiley & Sons, Inc. 相似文献
19.
A high-performance liquid chromatographic (HPLC) method for quantifying unsaturated hexasaccharide and tetrasaccharide from Streptomyces hyaluronidase enzyme digestion products of hyaluronic acid was developed using a gel-permeation column packed with a sulphated polystyrene-divinylbenzene gel. For the oligosaccharides, the separation was accomplished in less than 7 min with a detection limit of 65 ng. An unsaturated non-sulphated disaccharide prepared from hyaluronic acid (delta Di-HA) and an unsaturated sulphated disaccharide (delta Di-4S) were analyzed by a HPLC method using a combination of two different gel-permeation columns. The separation of the disaccharides required less than 17 min at a flow rate of 0.7 ml/min with detection limits of as little as 4 ng for delta Di-HA and 5 ng for delta Di-4S. Both chromatographic methods were used for assay of a major component of hyaluronic acid and trace amounts of chondroitin sulphates in rabbit synovial fluid. The resulting contents of hyaluronic acid were compared to the values of polymeric hyaluronic acid directly measured by a HPLC method using two gel-permeation columns packed with a poly(hydroxyalkyl methacrylate) gel and the amounts of hyaluronic acid converted from uronic acid content determined by a colorimetric method. 相似文献
20.
Tyrosine-derived polycarbonates having carboxylic acid pendant groups were characterized by water contact angle and X-ray photoelectron spectroscopy (XPS). A pronounce decrease of receding angle as well as contact angle hysteresis as a function of acid composition strongly indicated that the acid groups are more accessible at the water/polymer interface after hydration. pH dependent contact angle confirmed an existence of carboxylic acid groups in the surface region. The receding angle transition appearing in the pH range of 4-6 was a consequence of hydrophilicity change due to interconverting from carboxylic acid (-COOH) to carboxylate ion (-COO−). The surface compositions of imidazole-labeled polymers as analyzed by XPS were consistent with the bulk stoichiometry of the polymers. Reactivity of acid groups towards chemical reaction at the surface was also investigated. The acid groups at the surface of polymers were capable of adsorbing a significant amount of calcium ion from simulated body fluid and being activated by a reaction with N-hydroxysuccinimide. 相似文献