HBr分子的爱因斯坦自发辐射系数的计算

本文从第一性原理出发,计算了ＨＢｒ分子ｖ≤７,Ｊ≤１４,Δｖ＝１,Ｒ,Ｐ支谱线的爱因斯坦自发辐射系数Ａ＾ｖ‘Ｊ’ｖ＾ｎＪ＾ｎ。测量了ＨＢｒ红外发射的振转谱线强度,证实由理论计算获得的Ａ＾ｖＪ’Ｖ＾ｎＪ＾ｎ系数是可靠的。     

关于HBr分子爱因斯坦自发辐射系数的一种理论计算方法

 采用双原子分子光谱参数计算程序LEVEL,分别选用目前最好的解析势能函数之一的Murrell-Sorbie函数和精确的RKR势,数值求解径向薛定谔方程,得到振转能级的本征能量和本征波函数。选用公开发表的最新的电偶极矩函数,计算得到了HBr分子X1Σ+态振动能级低于7时R和P支基频跃迁谱线的爱因斯坦自发辐射系数。     

光子晶体激光器阈值特性的理论研究

针对光子晶体激光器的结构特点,并考虑到非辐射复合及增益饱和效应的影响,运用速率方程研究了光子晶体激光器的阈值特性。由爱因斯坦A、B系数的关系,得出了自发辐射耦合因子的变化并不独立于腔体积的结论,并给出其具体数学表达式。分析了自发辐射耦合因子、表面复合速率、有源区体积及品质因子对光子晶体激光器阈值电流的影响。结果表明,经过优化处理,可以较好地降低光子晶体激光器的阈值电流,为无阈值激光器的实现提供了理论依据。     

利用杜哈梅尔方法近似求解EDF的自发辐射特性

掺铒光纤(EDF)中的自发辐射噪声是影响掺铒光纤放大器(EDFA)工作性能和掺铒光纤激光器(EDFL)的起振特性的重要因素。自发辐射与泵浦方式紧密相关,研究脉冲泵浦下EDF的自发辐射具有重要的学术意义。从速率方程出发,建立了任意波形脉冲泵浦下EDF自发辐射的能级粒子数分布所满足的一元二阶变系数微分方程。由于没有封闭形式的解析解,采用杜哈梅尔方法,将泵浦脉冲波形进行分时段描述,每个小时段都有解析解,从而得到了自发辐射的平均功率表达式。分析结果表明,随着泵浦功率的增大,ASE的输出波形更接近泵浦光的波形,且泵浦光的毛刺对于ASE噪声的影响较小。     

原子自发辐射的非马尔科夫理论

韦斯可夫-维格勒的自发辐射理论存在两个问题: 1.假定了每个时刻上能级布居数N2的衰减率与该时刻的N2值成正比,与它过去的值无关.这并非是理所当然的,而是马尔科夫近似下的结果.2.该理论中的比例常数取为爱因斯坦A系数,而A系数是在忽略了原子的有限大小条件下求出的结果.     

Er_xY_(1-x)Al_3(BO_3)_4晶体的生长和光谱性质

采用助熔剂法生长出了掺杂均匀的Er_xY_(1-X)Al_3(BO_3)_4厘米级优质单晶.测定了晶体的吸收、激发光谱.用Judd_Ofelt理论计算了晶体中Er~(3+)的十一条谱带的振子强度(ρ_(ad)和ρ_(md)以及Er~(3+)的强度参数Q_λ(λ-2、4、6).并由此计算了Er~(3+)不同能级之间跃迁的爱因斯坦自发辐射系数A_r、辐射寿命r、荧光分支比β_3以及积分发射截面Σ.根据这些参数讨论了在EYAB晶体中可能实现激光输出的通道.     

SASE自由电子激光起振问题及统计特性的数值模拟

 介绍一种自放大自发辐射自由电子激光（SASE FEL）的自发辐射和电子束噪声的数学描述，运用修正的一维非定态程序，对SASE FEL 起振问题及光场统计特性进行了数值模拟，分析了自发辐射谱的发展过程及一定频带宽度内光场随机特性的统计规律，数值模拟结果与理论结果符合较好。     

掺铒光纤自发辐射特性研究

本文对掺铒光纤的自发辐射特性进行了研究,分析了掺杂铒离子光纤的吸收截面、辐射截面、自发辐射谱、净增益系数等的特性,以及在掺铒光纤中,泵浦功率、自发辐射功率、光纤长度、自发辐射谱之间的关系,并用单色仪和波长为1.48um的InGaAsP半导体激光器测试了国产掺铒光纤的吸收谱和它的自发辐射谱。     

激光器泵浦的波导染料放大器的研究

本文对波导染料自发辐射放大器进行了理论和实验研究。利用矩形波导模型求出波导模式、放大自发辐射阈值、放大自发辐射的近场及远场光强分布。实验获得放大自发辐射的远场光斑图样与理论计算比较基本一致,并对放大自发辐射输出特性进行研究。     

费米—狄拉克分布,玻色—爱因斯坦分布及光子与物质的相互作用

当光子与服从玻尔兹曼分布的原子发生相互作用时，爱因斯坦对受激辐射、自发辐射和吸收的处理就能导出光子的普朗克分布律．同样，当光子与遵守费米－狄拉克或玻色－爱因斯坦分布的物质相互作用时也能得到普朗克定律．     

Radiation Parameters for the Electronic Transition A2Π1/2–X2Σ+ of the Diatomic Exiplex CsXe

Journal of Applied Spectroscopy - The radiation parameters, e.g., Einstein coefficients, oscillator strengths, Frank–Condon factors, and wavenumbers of vibronic transitions in the system of...     

Diffusion Mechanism in Liquid MgO: Insights from Simulation

A molecular dynamics study of the microstructure and of diffusion in liquid MgO is reported. Models with 2,000 atoms were constructed in a wide temperature range, from 3,400 to 5,000 K, at ambient pressure. Analyses of the nearest-neighbor atomic exchange among coordination units, lifetime of the coordination units, temperature dependence of the velocity of the MgO _x ?→?MgO _x±1 transitions, and dependence of the mean-squared displacement on the number of transitions provide information on the structural dynamics and diffusion mechanism. A new method to calculate the diffusion coefficients is proposed, which yields coefficients in agreement with the Einstein equation, a result that sheds light on the mechanism of diffusion in liquid MgO. The dynamics is shown to be spatially heterogeneous and the origin of this heterogeneity is identified.     

Study of Rydberg transitions in NaHe

Einstein coefficients and oscillator strengths for electronic transitions in the Rydberg radical NaHe have been calculated with the molecular-adapted quantum defect orbital (MQDO) method. The correctness of our estimations has been established on the basis of their good agreement with the results of a reliable complex calculation available in the literature. Transition probability data involving Rydberg states lying higher in energy than those so far reported are supplied.     

125m Te (109.3 keV) stimulated emission and gamma lasers

Summary Proceeding from the drastic discrepancy between experimental data and theory, we show (contrary to other authors) that the relations between the Einstein's coefficients are true for transitions from any of the excited levels and theground state of the quantum system only. The relations connecting those coefficients are derived for transitions betweenany two states; the corresponding cross-sections are calculated and it is shown (contrary to other authors) that the stimulated emission cross-section may be large enough for the creation of gamma lasers. The new relation for Einstein's coefficients (and the corresponding cross-sections) are fundamentally different from those known so far (74 years after Einstein). The results are compared with experiment and the coincidence is very good. These investigations can lead to progress in the study of physical processes in star atmospheres. The author of this paper has agreed to not receive the proofs for correction.     

Vibrational-rotational Einstein coefficients for HF/DF and HCl/DCl

The RKR potential functions have been combined with the best experimentally based dipole functions to calculate the Einstein coefficients for HF/DF and HCl/DCl. Calculations were done for the Δν = 1,2,3 transitions for a wide range of ν′ (?15 for HF/DF and ?8 for HCl/ DCl) and J′ (?25). Experimental tests involving comparison of P- and R-branch line intensities for high-J′ transitions of the HF (ν₁ → ν₀, ν₂ → ν₁ and ν₃ → ν₂ bands) and the Δν = 2 and Δν = 1 transitions for HF/DF and HCl are done to examine the reliability of the Einstein coefficients for the rotational and vibrational levels, respectively. Good agreement is obtained for HF/DF even for the high-J′ R-branch intensities which vary markedly with J′. But the data suggest improvement is needed in the dipole functions for HCl (and DCl).     

Spectral line intensities of Yb3+ ion in LiNbO3 crystals

Optical spectra of absorption and luminescence of LiNbO₃:Yb³⁺ crystals are investigated experimentally and theoretically. Within the framework of the point charge approximation of crystal field, the Stark problem is solved: crystal field parameters and wave functions of Stark states are determined. Line strengths due to indirect electric-dipole and magnetic-dipole inter-Stark transitions are calculated and values of the Judd-Ofelt parameters are determined. Values of the branching ratios of luminescence. Einstein coefficients and, lifetime of the excited sublevel are calculated. A satisfactory agreement of calculated results with experimental data is obtained.     

Spectroscopic lineshape study of the self-perturbed oxygen A-band

This paper reports accurate line positions, intensities, self-broadening, -shift and -line mixing coefficients for 56 rotational transitions from multispectrum fits of low noise, high-resolution Fourier-transform spectra. The measured line intensities are within the statistical spread of the previous measurements available in the literature—thus contributing to the efforts to measure the oxygen A-band intensities with an accuracy better than 1%. We determined the integrated band strength and Einstein A coefficient. Using our spectrum calibration method we could clearly show for the first time that there is a meaningful statistical discrepancy in the frequency standards used in spectroscopic studies for the oxygen A-band. We were able to explain how this discrepancy leads to two different sets of shifts reported in the literature and demonstrate the need for precise frequency-type transition wavenumber measurements of the oxygen A-band transitions. We observed deviations from the conventional Voigt profile due to speed-dependent broadening and line mixing effects. Dicke narrowing was observed on a selected group of spectra recorded at pressures between 98 and 337 Torr. The Dicke narrowed lineshapes were best modeled using a Galatry profile implemented using a fixed value for the velocity-changing collision rate. The weak line mixing coefficients were determined from fits using the speed-dependent models. Exponential Power Gap (EPG) and Energy Corrected Sudden (ECS) scaling laws were used to calculate the self-broadening and self-line mixing coefficients.     

Population inversion induced by collisions in a two level system under nonresonance optical excitation

When the gas particles, which can be considered as a two level quantum system, are affected by frequent collisions with buffer gas particles (thermal reservoir), the spectral densities of the Einstein coefficients for absorption and induced emission are unequal to each other far from the absorption (emission) line. The relationship between the spectral densities at the specified condition reveals new physical phenomena. The mostly convincing example is the fact that population inversion is established in a two level system under nonresonance optical excitation. This effect is experimentally observed as a lasing on sodium resonance transitions.