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Oxidechlorides, -bromides, and -iodides of Niobium and Tantalum We report on oxidehalides of the 5- and 4-valent niobium and tantalum, the most of which are chemically transportable. A new class of compounds (mNb2O5 + NbOCl3) is indicated.  相似文献   

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DL -Threitol dicarbonate and erythritol dicarbonate were prepared by the reaction of butadiene dioxide (DL and meso) with carbon dioxide. Treated with aqueous ammonia the dicarbonates gave the corresponding dicarbamates.  相似文献   

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On the Mechanism of the Thermal Decomposition of Ammonium and Ammin Chloro Complexes of Ruthenium, Rhodium, Palladium and Platinum The thermolysis of noble metal compounds was investigated by a combination of independent physical (DTA/TG, high-temperature Guinier-Simon-technique) and preparative methods, characterization of the educts, intermediats and products by Guinier X-ray patterns and IR spectroscopy:
  • (a) (NH4)2[PtCl6], (NH4)2[PtCl4], [Pt(NH3)4][PtCl4], [Pt(NH3)4]Cl2, and trans-[Pt(NH3)2Cl2];
  • (b) (NH4)2[PdCl4], [Pd(NH3)4]Cl2, trans-[Pd(NH3)2Cl2], and [Pd(NH3)4][PdCl4];
  • (c) (NH4)2[RhCl5(H2O)], (NH4)3[Rh2Cl9], K2[RhCl5(H2O)], and K2[RhCl5(NH3)];
  • (d) (NH4)2[RuCl5(NH3)] and (NH4)4[Ru2Cl10O]
. The most important step of the mechanism of the thermal decomposition is the ?internal”? redox reaction between the noble metal cation and the nitrogen atom of the ammine ligand.  相似文献   

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Analytical and Bioanalytical Chemistry -  相似文献   

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