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Partha P. Bera Kurt W. Sattelmeyer Martin Saunders Henry F. III Schaefer Paul von Rague Schleyer 《ChemInform》2006,37(30):no-no
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. 相似文献
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Colin F. Poole 《Chromatographia》2015,78(15-16):1103-1104
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V. P. Khilya D. Litkei T. Patonai L. G. Grishko A. M. Kornilov A. Aitmambetov 《Chemistry of Heterocyclic Compounds》1989,25(3):263-267
Benzodioxane analogs of chalcones were isomerized to the corresponding flavanones and isoflavones. The PMR and IR spectra of these compounds were discussed.For Communication 11, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 319–323, March, 1989. 相似文献
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Simona Badilescu 《The Chemical Educator》2001,6(2):114-120
Before women could participate directly in the creation of scientific knowledge, they worked privately as translators, illustrators, and authors of science books. In the early nineteenth century, Jane Marcet in Britain, and later Almira Lincoln Phelps in the U.S., recognized the need for experimental training of beginners and, to compensate for the lack of experiments, produced meaningful drawings for their textbooks. By using a fresh narrative, a pleasing style, and beautiful drawings of their own, they wrote chemistries for the beginners that were both instructional and entertaining. Engraved in the tradition of the nineteenth century illustration, Jane Marcets Conversations on Chemistry and Almira Lincoln Phelps Chemistry for Beginners, originally written for the education of women, were immensely successful and lasted longer than many of the more specialized contemporary works. 相似文献
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Srinivasan A Kebede N Saavedra JE Nikolaitchik AV Brady DA Yourd E Davies KM Keefer LK Toscano JP 《Journal of the American Chemical Society》2001,123(23):5465-5472
We have found O(2)-substituted diazeniumdiolates, compounds of structure R(2)N-N(O)=NOR' that are under development for various possible pharmaceutical uses, to be rather photosensitive. With R = ethyl and R' = methyl, benzyl, or 2-nitrobenzyl, the observed product distributions suggest that two primary pathways are operative. A minor pathway involves the extrusion of nitrous oxide (N(2)O) with simultaneous generation of R(2)N(*) and R'O(*), which may then form amines, aldehydes, and alcohols. The major reaction pathway is an interesting photochemical cleavage of the N=N bond to form a nitrosamine (R(2)NN=O) and an oxygen-substituted nitrene (R'ON). The intermediacy of the O-nitrene was inferred from the production of abundant oxime, via rearrangement of the O-nitrene to a C-nitroso compound (R'ON --> O=NR'), and subsequent tautomerization to the more stable oxime. Involvement of the O-nitrene was confirmed by trapping with 2,3-dimethyl-2-butene to form the aziridine and with oxygen to generate the nitrate ester. 2-Nitro substitution on the benzyl derivative had surprisingly little effect on the reaction course. For each compound examined, minor amounts of nitric oxide (NO), presumably produced by secondary photolysis of the nitrosamine, were observed. Time-resolved infrared experiments provided additional support for the above reaction pathways and confirmed that the nitrosamine is a primary photoproduct. We have also found that the relative contributions of the reaction pathways can be altered in certain derivatives. For example, when R' = 2,4-dinitrophenyl, the contribution of the nitrosamine/O-nitrene-forming pathway was diminished. Pharmacological implications of these results are discussed. 相似文献
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