Self-segregation in chemical reactions,diffusion in a catalytic environment and an ideal polymer near a defect

We study a family of equivalent continuum models in one dimension. All these models map onto a single equation and include simple chemical reactions, diffusion in presence of a trap or a source and an ideal polymer chain near an attractive or repulsive site. We have obtained analytical results for the survival probability, total growth rate, statistical properties of nearest-neighbour distribution between a trap and unreacted particle and mean-squared displacement of the polymer chain. Our results are compared with the known asymptotic results in the theory of discrete random walks on a lattice in presence of a defect.     

Fully nonlocal, monogamous, and random genuinely multipartite quantum correlations

Local measurements on bipartite maximally entangled states can yield correlations that are maximally nonlocal, monogamous, and with fully random outcomes. This makes these states ideal for bipartite cryptographic tasks. Genuine-multipartite nonlocality constitutes a stronger notion of nonlocality in the multipartite case. Maximal genuine-multipartite nonlocality, monogamy, and random outcomes are thus highly desired properties for genuine-multipartite cryptographic scenarios. We prove that local measurements on any Greenberger-Horne-Zeilinger state can produce correlations that are fully genuine-multipartite nonlocal, monogamous, and with fully random outcomes. A key ingredient in our proof is a multipartite chained Bell inequality detecting genuine-multipartite nonlocality, which we introduce. Finally, we discuss applications to device-independent secret sharing.     

Diffusion and reaction in random media and models of evolution processes

A diffusion equation including source terms, representing randomly distributed sources and sinks is considered. For quasilinear growth rates the eigenvalue problem is equivalent to that of the quantum mechanical motion of electrons in random fields. Correspondingly there exist localized and extended density distributions dependent on the statistics of the random field and on the dimension of the space. Besides applications in physics (nonequilibrium processes in pumped disordered solid materials) a new evolution model is discussed which considers evolution as hill climbing in a random landscape.We dedicate this work to the memory of Ilya M. Lifshitz.     

Pairwise correlations in a three-partite quantum system from a prequantum random field

Prequantum classical statistical field theory (PCSFT) is a model that provides the possibility to represent the averages of quantum observables (including correlations of observables on subsystems of a composite system) as averages with respect to fluctuations of classical random fields. In view of the PCSFT terminology, quantum states are classical random fields. The aim of our approach is to represent all quantum probabilistic quantities by means of classical random fields. We obtain the classical-random-field representation for pairwise correlations in three-partite quantum systems. The three-partite case (surprisingly) differs substantially from the bipartite case. As an important first step, we generalized the theory developed for pure quantum states of bipartite systems to the states given by density operators.     

Models of Local Relativistic Quantum Fields with Indefinite Metric (in All Dimensions)

A condition on a set of truncated Wightman functions is formulated and shown to permit the construction of the Hilbert space structure included in the Morchio--Strocchi modified Wightman axioms. The truncated Wightman functions which are obtained by analytic continuation of the (truncated) Schwinger functions of Euclidean scalar random fields and covariant vector (quaternionic) random fields constructed via convoluted generalized white noise, are then shown to satisfy this condition. As a consequence such random fields provide relativistic models for indefinite metric quantum field theory, in dimension 4 (vector case), respectively in all dimensions (scalar case). Received: 25 April 1996 / Accepted: 29 July 1996     

Fractal aggregates evolution of methyl red in liquid crystal

The spontaneous formation of dendritic aggregates is observed in a two-dimensional confined layered system consisting of a film composed of liquid crystal, dye and solvent cast above a polymer substrate. The observed aggregates are promoted by phase separation processes induced by dye diffusion and solvent evaporation. The growth properties of the aggregates are studied through the temporal evolution of their topological properties (surface, perimeter, fractal dimension). The fractal dimension of the completely formed structures, when they are coexistent with different types of structures, is consistent with theoretical and experimental values obtained for Diffusion-Limited Aggregates. Under different experimental conditions (temperature and local dye concentration) the structure forms without interactions with other kinds of structures, and its equilibrium fractal dimension is smaller. The fractal dimension is thus not a universal property of the observed structures, but rather depends on the experimental conditions.     

Bosonization and quantum hydrodynamics

It is shown that it is possible to bosonize fermions in any number of dimensions using the hydrodynamic variables, namely the velocity potential and density. The slow part of the Fermi field is defined irrespective of dimensionality and the commutators of this field with currents and densities are exponentiated using the velocity potential as conjugate to the density. An action in terms of these canonical bosonic variables is proposed that reproduces the correct current and density correlations. This formalism in one dimension is shown to be equivalent to the Tomonaga-Luttinger approach as it leads to the same propagator and exponents. We compute the one-particle properties of a spinless homogeneous Fermi system in two spatial dimensions with long-range gauge interactions and highlight the metal-insulator transition in the system. A general formula for the generating function of density correlations is derived that is valid beyond the random phase approximation. Finally, we write down a formula for the annihilation operator in momentum space directly in terms of number conserving products of Fermi fields.     

Diffusion with restrictions

A nonlinear diffusion equation is derived by taking into account hopping rates depending on the occupation of next neighbouring sites. There appears additional repulsive and attractive forces leading to a changed local mobility. The stationary and the time dependent behaviour of the system are studied based upon the master equation approach. Different to conventional diffusion it results in a time dependent bump the position of which increases with time described by an anomalous diffusion exponent. The fractal dimension of this random walk is exclusively determined by the space dimension. The applicability of the model to describe glasses is discussed.     

Analytic study of the effect of persistence on a one-dimensional biased random walk

An analytic study of a one-dimensional biased random walk with correlations between nearest-neighbour steps is presented, both in a lattice model and in its continuous version. First, the treatment of the unbiased problem is recalled and the effect of correlations on the diffusion coefficient is discussed. Then the study is extended to the biased case. The problem is then completely determined by two independent parameters, the degree of correlations in the motion on the one hand and the value of the bias on the other. Both the velocity of the particle and its diffusion coefficient are computed. As a result, the velocity as well as the diffusion coefficient are enhanced when there are positive correlations (qualified as persistence) in the motion, and reduced in the opposite case.     

Localization and the integer-quantized Hall effect: Diffusion constant for high Landau levels and white noise potential

The diffusion constant and the diagonal conductivity for non-interacting electrons in a two-dimensional, disordered system are studied. A homogeneous magnetic field perpendicular to the electron system is assumed. For weak short-range random potentials and high fields the Landau quantum numbern can be used as expansion parameter. In the limit of high Landau levels the system shows metallic behaviour. Corrections for finiten decrease the conductivity and indicate localized states in the whole energy band. A breakdown of the expansion and stronger localization are observed only for the lowest Landau levels if the typical experimental length scale of the quantized Hall effect is used.     

Transport by Time Dependent Stationary Flow

We consider transport properties for Gaussian, stationary, divergence free, random velocity fields in ², which are Markov in time. We prove the existence of effective diffusivity. We also obtain its full asymptotics in the case of short time correlations, on a fully rigorous level. The main regularity assumption is that almost every realization of the random velocity field should be continuous in space and time, and Lipschitz continuous in space.     

Anomalous diffusion and continuum percolation

Anomalous diffusion for continuum percolation is simulated by considering systems of randomly distributed circles and spheres. Universal behavior is obtained for the case of equal local conductances and nonuniversal behavior for diverging distributions of the local conductances. Diffusion in the continuum has a behavior consistent with that of other transport properties in the continuum. In addition, the results suggest that different algorithms for diffusion, which differ only in the random walker sitting times, are equivalent.     

Transport in a disordered tight-binding chain with dephasing

We studied transport properties of a disordered tight-binding model (XX spin chain) in the presence of dephasing. Focusing on diffusive behaviour in the thermodynamic limit at high energies, we analytically derived the dependence of conductivity on dephasing and disorder strengths. As a function of dephasing, conductivity exhibits a single maximum at the optimal dephasing strength. The scaling of the position of this maximum with disorder strength is different for small and large disorders. In addition, we studied periodic disorder for which we found a resonance phenomenon, with conductivity having two maxima as a function of dephasing strength. If the disorder is non-zero only at a random fraction of all sites, conductivity is approximately the same as in the case of a disorder on all sites but with a rescaled disorder strength.     

Universal properties of relaxation and diffusion in condensed matter

By and large the research communities today are not fully aware of the remarkable universality in the dynamic properties of many-body relaxation/diffusion processes manifested in experiments and simulations on condensed matter with diverse chemical compositions and physical structures. I shall demonstrate the universality first from the dynamic processes in glass-forming systems. This is reinforced by strikingly similar properties of different processes in contrasting interacting systems all having nothing to do with glass transition. The examples given here include glass-forming systems of diverse chemical compositions and physical structures, conductivity relaxation of ionic conductors(liquid, glassy, and crystalline),translation and orientation ordered phase of rigid molecule, and polymer chain dynamics. Universality is also found in the change of dynamics when dimension is reduced to nanometer size in widely different systems. The remarkable universality indicates that many-body relaxation/diffusion is governed by fundamental physics to be unveiled. One candidate is classical chaos on which the coupling model is based, Universal properties predicted by this model are in accord with diverse experiments and simulations.     

Effect of the nanofilm thickness on the properties of the two-dimensional electron gas at the interface between two dielectrics

The mechanism of formation of the two-dimensional conductivity along the interface between two polymer dielectrics is experimentally studied. The idea of “polar catastrophe,” which was successfully used earlier to explain the electronic properties of the interface between two perovskites LaAlO₃/SrTiO₃, is chosen as a base hypothesis. Piezoelectric response microscopy is used to reveal the presence of spontaneous polarization on the surface of a polymer film, and the remanent polarization is found to decrease with increasing film thickness. As in the case of perovskites, the polymer film thickness is found to strongly affect the electrical conductivity along the interface. Substantial differences between these phenomena are detected. The change in the electrical conductivity is shown to be caused by a significant increase in the charge carrier mobility when the film thickness decreases below a certain critical value. The relation between the change in the carrier mobility and the change in the spontaneous surface polarization of the polymer film when its thickness decreases is discussed.     

Mean first passage time of active Brownian particle in one dimension

We investigate the mean first passage time of an active Brownian particle in one dimension using numerical simulations. The activity in one dimension is modelled as a two state model; the particle moves with a constant propulsion strength but its orientation switches from one state to other as in a random telegraphic process. We study the influence of a finite resetting rate r on the mean first passage time to a fixed target of a single free active Brownian particle and map this result using an effective diffusion process. As in the case of a passive Brownian particle, we can find an optimal resetting rate r* for an active Brownian particle for which the target is found with the minimum average time. In the case of the presence of an external potential, we find good agreement between the theory and numerical simulations using an effective potential approach.     

Laplace operator and random walk on one-dimensional nonhomogeneous lattice

A classical result of probability theory states that under suitable space and time renormalization, a random walk converges to Brownian motion. We prove an analogous result in the case of nonhomogeneous random walk on onedimensional lattice. Under suitable conditions on the nonhomogeneous medium, we prove convergence to Brownian motion and explicitly compute the diffusion coefficient. The proofs are based on the study of the spectrum of random matrices of increasing dimension.     

Lateral diffusion of the topological charge density in stochastic optical fields

Stochastic (i.e. random and quasi-random) optical fields may contain distributions of optical vortices that are represented by non-uniform topological charge densities. Numerical simulations are used to investigate the evolution under free-space propagation of topological charge densities that are inhomogeneous along one dimension. It is shown that this evolution is described by a diffusion process that has a diffusion parameter which depends on the propagation distance.     

Diffusion-induced growth of compositional heterogeneity in polymer blends containing random copolymers

The compositional relaxation in random copolymer systems on a macroscopic scale is considered in theory. A set of diffusion equations is derived that describes the motion of chains of different composition and then converted into coupled equations for statistical moments of the compositional distribution. Several ways to solve the closure problem for these equations are discussed. The simplest is the situation when the shape of the transient compositional distribution can be predicted a priori, for example, a bimodal distribution is kept during interdiffusion of two copolymers that are not very close in composition. For a general case, it is shown that the cumulant-neglect closure based on the truncation of high-order cumulants is an effective method to get an approximate solution in terms of the time-dependent local mean composition and its dispersion. This method is applied to non-homogeneous compatible polymer systems, such as a random copolymer AB of a composition varying in space, a bilayer of Bernoullian copolymers AB of different composition, and a bilayer of homopolymers A and B, in which an autocatalytic polymer-analogous reaction A → B takes place, with possibility of the neighbor group effect. It is found that the interdiffusion can lead to a substantial broadening of the local compositional distribution, which, in turn, accelerates the system dynamics and promotes chemical reactions.     

Monte Carlo methods for turbulent tracers with long range and fractal random velocity fields

Monte Carlo methods for computing various statistical aspects of turbulent diffusion with long range correlated and even fractal random velocity fields are described here. A simple explicit exactly solvable model with complex regimes of scaling behavior including trapping, subdiffusion, and superdiffusion is utilized to compare and contrast the capabilities of conventional Monte Carlo procedures such as the Fourier method and the moving average method; explicit numerical examples are presented which demonstrate the poor convergence of these conventional methods in various regimes with long range velocity correlations. A new method for computing fractal random fields involving wavelets and random plane waves developed recently by two of the authors [J. Comput. Phys. 117, 146 (1995)] is applied to compute pair dispersion over many decades for systematic families of anisotropic fractal velocity fields with the Kolmogorov spectrum. The important associated preconstant for pair dispersion in the Richardson law in these anisotropic settings is compared with the one obtained over many decades recently by two of the authors [Phys. Fluids 8, 1052 (1996)] for an isotropic fractal field with the Kolmogorov spectrum. (c) 1997 American Institute of Physics.