共查询到16条相似文献,搜索用时 156 毫秒
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利用群理论详细分析了磷酸二氢钾(KDP)晶体的拉曼振动模式,得出了其拉曼振动模的归类?并采用拉曼光谱仪测量了Z切退火KDP晶体X(ZZ)X,Z(XY)Z和Y(XY)X三种散射配置和未退火KDP晶体Z(XY)Z配置下的拉曼光谱?根据拉曼选择定则得出X(ZZ)X,Z(XY)Z和Y(XY)X散射配置下的拉曼峰分别对应A1,B2(LO)?B2(TO)对称类振动模,但在Z(XY)Z配置下的拉曼光谱中除了B2模,还观察到了A1模,而在Y(XY)X配置下的拉曼光谱中只有B2模,且退火和未退火晶体Z(XY)Z配置下的拉曼光谱无明显差别,此结果表明KDP晶体的对称性降低,在背向散射时A1模也具有角度特性,但与晶体的内应力无关,这是由KDP晶体内部结构决定的? 相似文献
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详细比较了磷酸二氢钾(KDP)晶体的自发拉曼散射和受激拉曼散射光谱,在受激拉曼散射(SRS)中观察到了自发拉曼散射中最强的振动模的三阶Stokes光(559.43,589.74,623.50nm),由于其他振动模的受激拉曼散射增益系数较小,其SRS光谱未观察到。另外,比较了传统生长的未退火和退火后的KDP晶体及快速生长的锥区和柱区KDP晶体的受激拉曼散射增益系数,结果表明生长方法和热退火对KDP晶体的受激拉曼散射增益系数无明显影响。 相似文献
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通过结合纳米压痕和偏振拉曼散射技术对压应力影响下ZnO单晶晶格出现的变化进行了研究。位错的滑移是导致ZnO单晶中出现多处塑性变形的原因而非相变。之后采用偏振拉曼Mapping成像技术以E2(high)模为对象, 监视其在整个压痕区内的强度变化分布。在压痕区中心累积的应力通过位错的滑移而释放, 同时导致压痕区中心处的晶格畸变程度最为严重。伴随着晶格失配的加剧, 拉曼选择定则放宽, 在Z(XX)配置下较弱的LO得到增强, 原本非拉曼活性的B1(high)模出现。此外, 在Z(XY)偏振下压痕区左侧的拉曼光谱中观察到位于130 cm-1处的拉曼异常振动模。此峰的出现可能与压痕区左侧由刃位错所形成的应力场吸引间隙离子导致的晶格畸变有关。 相似文献
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本文测量了不同氘含量K(H1-xDx)2PO4晶体(DKDP晶体)在Z(XX)Y散射配置下的自发拉曼散射光谱, 并详细分析了氘含量对与横向受激拉曼散射(TSRS)增益系数有关的拉曼频移、半峰宽和散射强度的影响. 然后通过与去离子水拉曼散射对比得出了不同氘含量DKDP晶体的TSRS增益系数. 结果表明随着氘含量的增加DKDP晶体的TSRS增益系数先减小至KDP晶体的40.1%, 后增大至68.9%; 本文认为掺氘后拉曼半峰宽的变化是引起TSRS增益系数随氘含量变化的主要原因. 相似文献
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掺镜钒酸钇晶体是一种很有应用前景的晶体材料,由于它适合于半导体激光器泵浦的全固态激光器的要求而受到人们的普遍关注。拉曼光谱是研究材料的声子能谱分布的方法。本文根据群论对称性分类,计算了掺镜钒酸钇晶体的拉曼和红外活性振动模。选择不同几何配置的拉曼光谱,获得了不同的晶格振动模并计算了不同晶格振动模的散射效率。实验证明最强的振动模来自钒氧四面体的振动。 相似文献
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将冲击受激拉曼散射应用于某些铁电体中 ,在时间域内分析物质晶格振动。τωα <2π是应用冲击受激拉曼散射的必要条件。使用钛宝石激光再生放大系统作为激发源 ,在LiTaO3 晶体内获得了声子电磁激元振荡模。将同种方法用于KDP ,在其铁电体相位转换点以上 5 0K的温度范围内 ,仅发现了波矢 q =6848cm- 1 ,弛豫时间常数τ0 =1 33× 10 - 1 3 s的弛豫振动软模 ,显示出KDP铁电体相位转换的弛豫特性。 相似文献
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从理论上讨论了一阶和二阶斯托克斯与反斯托克斯拉曼散射截面的温度依赖关系;在293K至401K的温度范围内,测量了BaTiO3单晶斯托克斯和反斯托克斯过程的偏振拉曼光谱;通过对BaTiO3单晶斯托克斯和反斯托克斯拉曼光谱的综合分析,证实在X(ZZ)Y几何配置下测量到的位于275和514cm-1处的强峰为一阶拉曼光谱。此结果支持了BaTiO3铁电相变机制的有序—无序模型。 相似文献
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Richard E. Wilde 《Journal of Raman spectroscopy : JRS》1991,22(6):321-325
The Raman spectra of a single crystal of strontium barium niobate were recorded in the temperature range–193 to 140°C. The configurations studied were X(ZZ)Y, X(YZ)Y, X(YX)Y, Z(XX)Y, Z(YZ)Y and Z(XZ)Y. The behavior of integrated reduced intensities, band widths and band centers with temperature indicated that the ferro-electric transition temperature was near 65°C. The Raman data were not consistent with a classical Landau transition. Disorder-induced first-order spectra were observed and attributed to the disordered nature of the crystal Evidence was found for a possible phase transition near 120°C. 相似文献
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We systematically investigate the optical properties of the InP_(1-x)Bi_x ternary alloys with 0≤x≤2.46%,by using high resolution polarized Raman scattering measurement.Both InP-like and InBi-like optical vibration modes(LO) are identified in all the samples,suggesting that most of the Bi-atoms are incorporated into the lattice sites to substitute Patoms.And the intensity of the InBi-like Raman mode is positively proportional to the Bi-content.Linear red-shift of the InP-like longitudinal optical vibration mode is observed to be 1.1 cm~(-1)/Bi%,while that of the InP-like optical vibration overtone(2LO) is nearly doubled.In addition,through comparing the(XX) and Z(XY) Raman spectra,longitudinaloptical-plasmon-coupled(LOPC) modes are identified in all the samples,and their intensities are found to be proportional to the electron concentrations. 相似文献
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Guy Lucazeau Olivier Le Bacq Alain Pasturel Pierre Bouvier Thierry Pagnier 《Journal of Raman spectroscopy : JRS》2011,42(3):452-460
Polarized Raman spectra of a single crystal of gadolinium molybdate [Gd2(MoO4)3] were obtained between 1 atm and 7 GPa. Using a mixture of alcohols as the pressure‐transmitting medium, YY, ZZ, XY components of scattering matrices were measured. The ZZ spectra were also obtained in argon. Five phase transitions and amorphization were identified. The first and second transitions are reversible, while amorphization is not. In alcohol, amorphization is observed above 6.5 GPa. With argon as the pressure‐transmitting medium, amorphization is progressive and begins above 3 GPa. The spectral changes with pressure affect the high wavenumber bands attributed to symmetric and antisymmetric MoO4 stretching modes as well as the very low wavenumber modes such as librations of the tetrahedra. This means that both short‐range and long‐range organizations of the tetrahedra are involved in these phase transitions. The amorphization mechanism and its dependence on the pressure‐transmitting medium are discussed, and the steric hindrance between polyhedra is believed to be the most relevant mechanism. The TO and LO low wavenumber modes of A1 symmetry, observed in the Y(ZZ)Y and Z(YY)Z geometries, respectively, below 50 cm−1, soften continuously through the first three phases when increasing pressure. The strong A2 mode observed in the Z(XY)Z spectra exhibits the same anomalous behavior by decreasing from 53 to 46 cm−1 at 2 GPa. The softening of these modes is related to the orientation change of tetrahedra observed by ab initio calculations when the volume of the cell is decreased. These orientation changes can explain the wavenumber decrease of the Mo O stretching modes above 2 GPa, which indicates an increase of Mo coordination. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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We report on the dependence of the pH value on the growth rates of KDP single crystals. Extensive experimental work has been carried out in order to find the optimum pH ranges for growing KDP single crystals with suitable sizes and high optical quality. Different techniques including micro‐Raman back‐scattering spectroscopy, UV/vis/IR transmission spectroscopy and X‐ray diffraction have been employed for this investigation. Deuterated substituted single crystals of KDP and DKDP also have been grown for the investigation of growth rates and Raman active mode identification purposes. The molecular vibration modes of the grown crystals, including internal modes of PO4 tetrahedrons molecular vibrations, external modes of optical phonons and hydrogen bonding modes have been determined exactly by micro‐Raman back‐scattering spectroscopy. The best pH values of the solution for the KDP crystal growth with reasonably higher growth rates from aqueous solutions that have been supersaturated ata temperature range of 30–50 °C have been found to be in the pH range of 3.2–5.4. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献