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1.
采用固相烧结法制备(Bi2O3)1-x(Sc2O3)x(x=0.01, 0.03, 0.05)粉末晶体,在室温下对几种样品分别进行了X射线衍射实验,并用RIETAN-2000程序中的Rietveld解析法以及VEND、PRIMA和VICS程序分别研究了几种样品的晶体结构、等高电子密度(2D和3D)、原子配位数及原子热振动各向同性因子B等. 结果表明,(Bi2O3)1-x(Sc2O3)x(x=0.01, 0.03, 0.05)的晶胞体积(分别为329.3399Å3、329.5016 Å3、329.3400 Å3、330.3658 Å3)比Bi2O3的晶胞体积(330.3658 Å3)小;(Bi2O3)1-x(Sc2O3)x(x=0.01, 0.03, 0.05)晶体的原子热振动各向同性温度因子B(Sc1)、B(Sc2)、B(Bi1)、B(Bi2)、B(O1)、B(O2)、B(O3)的大小分别为0.42883 Å2、0.54412 Å2、0.609364 Å2、0.502542 Å2、0.4034 Å2、0.61406 Å2、0.74259 Å2;0.43052 Å2、0.52778 Å2、0.51647 Å2、0.382431 Å2、0.320327 Å2、0.516762 Å2、0.76875 Å2和0.42347 Å2、0.61022 Å2、0.514476 Å2、0.302724 Å2、0.34725 Å2、0.56175 Å2、0.72125 Å2. 确定了(Bi2O3)1-x(Sc2O3)x(x=0.01, 0.03, 0.05)粉末晶体属于单斜晶系,实现了二维和三维等高电子密度分布的可视化,进一步确定了晶体结构和原子位置.  相似文献   

2.
Sm2O3, Gd2O3, Eu2O3 triple-doped Bi2O3 based quaternary solid solutions were synthesized as a candidate electrolyte material using the solid-state reaction technique. The structural, thermal and electrical conductivity features of the ceramic samples were examined and compared by using X-ray powder diffraction (XRD), thermal gravimetry/differantial thermal analysis (TG/DTA) and the four-point probe technique (4PPT). The result of XRD measurements indicated that the (Bi2O3)(1−xyz)(Gd2O3)x(Sm2O3)y(Eu2O3)z (x = 10/y = 10/z = 5, 15, 20 mol % and x = 10/y = 5, 10, 15, 20/z = 10 mol %) samples have a stable face-centered cubic δ-phase and mixed phase crystallographic structure. The phase stability was also checked by the DTA evaluations results. The temperature dependent electrical conductivity measurements showed that the highest electrical conductivity was observed for the sample of the (Bi2O3)0.75(Gd2O3)0.10(Sm2O3)0.05(Eu2O3)0.10 system which has a stable and δ-phase was found as 6.67 × 10−3 (Ω cm)−1 at 650 °C. This sample can be used as an electrolyte material in the solid oxide fuel cells (SOFCs) which is possible to operate at intermediate temperature ranges. The activation energy was also calculated at a low temperature range (350–650 °C) and high temperature range (above 650 °C). The values for the samples vary from 0.63 eV to 1.08 eV at low temperature and at high temperature they vary from 0.43 eV to 0.75 eV.  相似文献   

3.
We report on crystal growth, spectroscopic investigations, crystal field tuning, and laser experiments of neodymium doped mixed sesquioxides (Lu1?x Sc x )2O3. Crystals were grown by the Nacken?CKyropoulos and the Heat-Exchanger method. Emission spectra for several mixing ratios are presented. Cw laser experiments were carried out with a 0.35?at.%-doped Nd:Lu1.82Sc0.18O3 crystal by using a Ti:sapphire laser as pump source, achieving a maximum slope efficiency of 47?% with respect to the absorbed pump power and a maximum output power of 356?mW at a wavelength of 952.7?nm. To the best of our knowledge, this represents the first continous wave (cw) laser operation of a Nd-doped mixed sesquioxide.  相似文献   

4.
5.
The tunable growth of In-doped Ga2O3 (Ga2O3:In) and Ga-doped In2O3 (In2O3:Ga) nanowires (NWs) on Au-coated Si substrates was achieved by modulating the amount of water vapor in flowing Ar at 700–750 °C via carbothermal reduction of Ga2O3/In2O3 powders with a fixed weight ratio. In Ar, only the Ga2O3:In NWs were grown, while in wet Ar the In2O3:Ga NWs were synthesized instead. The Ga concentration in In2O3 NWs decreased with the increment of water vapor in flowing Ar. The growth of both Ga2O3:In and In2O3:Ga NWs followed the vapor–liquid–solid process. The In and Ga doping induced a redshift and a blueshift in the optical bandgaps of Ga2O3 NWs and In2O3 NWs, respectively. The growth mechanisms and optical properties of Ga2O3:In and In2O3:Ga NWs were discussed.  相似文献   

6.
High resolution electron energy loss Spectroscopy (HREELS), X-ray photoelectron Spectroscopy (XPS) and low energy electron diffraction (LEED) have been used to characterize initial stages of oxidation of Si(100)2x1 and Gex Si1−x (100)2x1 surfaces. Different oxidation stages of Si were identified by measuring Si 2p core level shifts and characteristic vibrations of Si-O-Si complexes. The latter may be described in the framework of continuous random network models.Then,from the experimentally determined frequencies, force constants,average bond angles and bond lengths are determined. Complementary,marker experiments with atomic hydrogen as a probe in conjunction with HREELS were used to determine the local, atomic structure for different stages of oxidation from chemical shifts of Si-H and Ge-H stretching mode intensities, respectively.  相似文献   

7.
为了确定ZrO2和(ZrO2)0.97(Bi2O3)0.03的晶体结构和原子热振动各向同性温度因子B,对该粉末晶体进行X射线衍射实验,建立了晶体结构模型,进行晶体结构分析。首先,采用共沉淀法和高温固相烧结法制备了纳米氧化锆ZrO2和(ZrO2)0.97(Bi2O3)0.03粉末晶体,接着,使用X射线测试仪对两种样品进行了衍射实验(XRD),利用Rietveld 精修方法的 RIETAN-2000程序对所得实验结果进行了晶体结构分析,获得了晶体结构参量和原子热振动各向同性温度因子B。通过Maximum Entropy Method(MEM)解析得到了粉末晶体(ZrO2)x(Bi2O3)1-x(x=1.0,0.97)的等高电子密度分布可视化图谱。结果表明,(ZrO2)0.97(Bi2O3)0.03的晶胞体积比ZrO2的晶胞体积大分别为140.6850 Å3和140.5637Å3;ZrO2晶体的原子热振动各向同性温度因子B(Zr)、BO(1)、BO(2)和 B(Bi)分别为0.690、0.269、 0.178 和 0 Å2,(ZrO2)0.97(Bi2O3)0.03晶体的分别为0.460 、0.583 、0.121 和0.581 Å2。 确定了(ZrO2)0.97(Bi2O3)0.03的晶体结构属于单斜晶系,实现了等高电子密度分布三维(3D)和二维(2D)的可视化,进一步确定了晶体结构和原子位置。  相似文献   

8.
Composition (100?x) ZrO2 (x) Bi2O3 (x?=?15, 20, 25) is synthesized by solid-state reaction method to study the effect of Bi2O3 doping on ZrO2. The as-prepared samples are characterized by various methods. The X-ray diffraction pattern of all these samples exhibits three phases, namely, m-ZrO2, ??III-Bi2O3, and ??-Bi2O3. The differential thermal analysis curves do not show any phase transition/decomposition, which clearly indicated the stabilization of ??-Bi2O3 phase. The conductivity changes in all the samples are discussed in terms of different phase formations and their volume fractions. The microstructural and energy dispersive analyses indicate the presence of different phases. A maximum conductivity at high temperature (800?°C) was observed for the x?=?25 composition, i.e., ???=?4.21?×?10?2 S/cm.  相似文献   

9.
The X-ray powder diffraction, dielectric and Raman studies of the (1???x) PbMg1/3Nb2/3O3xPbTiO3 (0?≤?x?≤?0.38) single crystals were performed in a wide temperature range. The results of these complementary studies revealed that with the increase in PT content, the relaxor behaviour transforms into the ferroelectric one and a sequence of different structural phase transitions occur. On the base of the structural and dielectric results the phase diagram was determined. In addition, these results were used as a base for the group theory analysis and interpretation of the observed Raman spectra. The Raman spectra were deconvoluted using the independent damped oscillator model. From this model the temperature dependencies of the wavenumbers, reduced intensities and line widths were determined.  相似文献   

10.
We first demonstrate the precise Einstein-Podolsky-Rosen entanglement, which is inherent in quantum mechanics, in the context of quantum theory of complex scalar fields. We explicitly derive the entangled common eigenstates of φ1(x) - φ2(x) and П1(x) + П2(x) φ1and φ2 are two real components of the complex scalar field, and П1 and П2 are the corresponding conjugate fields) in the Fock space. The entangled eigenstates span a complete and orthonormal representation.  相似文献   

11.
In this study, (Bi2O3)1?x?y(Sm2O3)x(CeO2)y ternary system was synthesized by using solid-state reaction method. Structural, morphological, thermal and electrical properties of the samples were evaluated by means of X-ray diffraction (XRD), scanning electron microscopy, thermo gravimetry/differential thermal analyzer and four-probe method. The XRD measurement results indicated that the samples (x = 10–15, y = 5–10–15–20) had cubic δ-phase crystallographic structure. The phase stability of the samples was checked by the differential thermal analyzer measurements, which indicates most of the samples have stable δ-Bi2O3 phase. The electrical conductivity measurement results showed that the electrical conductivity increased with mol% CeO2 molar ratio at a fixed molar ratio of Sm2O3. The highest electrical conductivity obtained for the (Bi2O3)0.65(Sm2O3)0.15(CeO2)0.20 system was 1.55 × 10?2 (Ω.cm)?1 at 600 °C. The activation energies were also calculated at low temperature range (350–650 °C) which vary from 1.1325 to 1.4460 eV and at high temperature (above 650 °C) which vary from 0.4813 to 1.1071 eV.  相似文献   

12.
We have prepared a series of bulk polycrystalline samples with the nominal compositions (YBa2Cu3O7)1?x(Nd0.7Sr0.3MnO3)x (x = 0–1) by a conventional solid-state reaction method using the larger difference in sintering temperature of the two constituent oxides and a well conceived sintering sequence. XRD patterns show that the samples are composites consisting of YBa2Cu3O7 and Nd0.7Sr0.3MnO3 particles with average grain size of ~65 nm. For x ? 0.55, with increasing x, the zero-resistance superconducting transition temperature, TC0, measured at zero magnetic field decreases and the normal state resistivity increases rapidly. The TC0 for the sample with x  0.48 is estimated to be 0 K. The MH hysteresis loops indicate the coexistence of ferromagnetism and superconductivity in the samples. The depression of TC0 can be attributed to the proximity effect between ferromagnetism and superconductivity.  相似文献   

13.
Point-contact spectra of YBa2(Cu1–x Zn x )3O7/Ag are studied at various temperatures. The differential resistance dV/dI of the point contacts shows gap-related structures belowT c which can be attributed to Andreev reflection. Evaluation of many spectra for each sample taken at 4.2 K yields a wide distribution of voltages /e at which these structures occur. The upper limit varies roughly as expected from the depression ofT c by Zn-doping from /e=29 mV (x=0) to 9 mV (x=0.05), while the lower limit decreases much faster and disappears forx=0.05. Hence, the Zn doped samples exhibit a tendency to gapless superconductivity as suggested earlier on the basis of specific-heat measurements.  相似文献   

14.
The correlation between the magnetic and electrical properties of the (VS)x(Fe2O3)2?x (0.9<x<1.25) oxysulfide solid solutions has been studied. The crossover of conductivity from the semimetallic to semiconducting type is accompanied by changes in the magnetic susceptibility, which are characteristic of the transition from delocalized to localized electrons. For x=1.25, a region of the ferromagnetic ordering has been established in the temperature range 90–120 K.  相似文献   

15.
A comparative analysis of the magnetic flux trapping in monocrystalline and polycrystalline HTSC samples is carried out, and the possibility of employing the dependence of the trapped magnetic flux on the external magnetic field for obtaining comparative estimates of the effect of pinning centers is determined.  相似文献   

16.
Model concepts of the interphase boundaries whose displacements are capable of substantially affecting the piezoelectric properties of xPbTiO3-(1?x)Pb(Zn1/3Nb2/3)O3 multidomain crystals in the R3m-P4mm morphotropic region are developed. The contributions of the interphase boundaries Δd 33 to the piezoelectric modulus d 33 are determined, and the factors responsible for the large ratios Δd 33/d 33≈0.5–0.9 are analyzed.  相似文献   

17.
通过调节基质组份比例,研究了SrAl2xO3x+1∶Eu2+,Dy3+(x=1~2)荧光粉晶体结构,发光性质及长余辉特性。选取硝酸锶和硝酸铝作为基质原材料,硼酸氨和氟化铝作为助溶剂,采用阳离子草酸盐共沉淀,湿法预先混合原材料及分步合成等方法,制备了亮度高、余辉长及良好粒径分布的系列长余辉发光材料。基于对样品X射线衍射(XRD)图谱,扫描电子显微镜(SEM)照片,激发、发射光谱及余辉衰减曲线分析,发现SrAl2xO3x+1∶Eu2+,Dy3+具有良好的结晶状态;随x增加,发射光谱峰值从520 nm蓝移至470 nm;衰减到可辨认发光强度0.32 mcd/m2,余辉时间可相应地从30 h延长到60 h以上。通过分析发现表现不同余辉特性的主要原因是Eu2+在基质中具有不同浓度、不同衰减寿命的蓝、绿两种发光中心造成的,其中蓝发光中心寿命明显高于绿发光中心。  相似文献   

18.
In present work, a simple longitudinal piezoelectric transformer with the size of 16-mm length, 2-mm width, and 2-mm thickness was designed and fabricated with relaxor ferroelectric single-crystal (1−x)Pb(Mg1/3Nb2/3)O3-xPbTiO3. Both the input and output parts utilized the ultrahigh longitudinal extensional electromechanical coupling coefficients. Compared to the Rosen-type transformer, this transformer has the advantages of smaller-size, simpler structure, no spurious vibration, and no acoustic mismatch between the input and output parts. The electrical measurement results indicated that under the resonance frequency of 114 kHz, a step-up voltage of about 30 can be obtained under a 10-MΩ load resistance, which agreed well with the calculated results. Besides, the frequency and load dependences of this transformer were also systematically studied and discussed. The results indicated that this transformer has potential applications in the small-size high-voltage amplifier and magnetoelectric/piezoelectric-transformer composite transducers.  相似文献   

19.
20.
The dielectric properties of (1 ? x)Na1/2Bi1/2TiO3-xLaMg1/2Ti1/2O3 solid solutions (0 ≤ x ≤ 0.4) were studied over the temperature range 650–1030 K by measuring the impedance spectra over the frequency range 25–106 Hz. The Curie temperature T C was determined as a function of the composition of the solid solutions. It is shown that T C decreases linearly with increasing x. The temperature dependences of the dc component (σdc) and the polarization component (σ′ac) of the real part of the conductivity are found. The activation energy for the conductivity σdc is shown to increase abruptly as the temperature increases above approximately 770 K for all solid solution compositions. Over the temperature range corresponding approximately to the region of existence of the tetragonal phase of Na1/2Bi1/2TiO3, the polarization component σ′ac of the solid solutions, as well as that of the pure compound, is anomalously high at low frequencies, which can be due to structural inhomogeneities.  相似文献   

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