Xe54+离子与Xe原子碰撞过程中的辐射电子俘获及退激发辐射的理论研究

基于多组态Dirac-Fock理论方法和冲量近似, 对Xe⁵⁴⁺与Xe在197 MeV/u碰撞能量下, 炮弹离子的俘获及退激发过程进行了理论研究. 计算了炮弹离子从中性靶原子俘获一个电子到nl (n=1, 2, 3, 4, 5; l=s, p, d) 轨道上的辐射电子俘获截面和相应的辐射光子能量, 以及俘获末态退激发辐射跃迁的能量和概率. 结合这些计算结果, 进一步模拟了碰撞产生的炮弹离子的退激发X射线谱的结构, 并与兰州重离子加速器装置上的最新实验观测结果进行了比较, 符合得很好.     

Xe~(53+)离子与Xe原子碰撞过程中的辐射电子俘获和辐射退激发光谱的理论研究

基于多组态Dirac-Fock方法和密度矩阵理论,系统地研究了在197 Me V/u的碰撞能量下,Xe~(53+)离子与Xe原子的辐射电子俘获过程(REC)以及电子被俘获到激发态后辐射退激发产生的特征谱线.计算了炮弹Xe~(53+)离子俘获电子到不同壳层np_(1/2,3/2)(n=2—5)的总截面与相应的REC光子能量和角分布,以及由激发组态1snp_(1/2,3/2)(n=2—5)J_f=1向基态1s~2Jd=0辐射退激发的跃迁能量、跃迁概率和特征光子的角分布和线性极化度.计算结果表明,辐射光子具有显著的角各向异性特征.此外,1snp_(3/2)J_f=1→1s~2J_d=0退激发特征光子也显示出很强的线性极化和角各向异性特征,而1snp_(1/2)J_f=1→1s~2J_d=0退激发特征光子的线性极化度趋于零并且角分布也趋于各向同性.     

基于联合分离原子模型的电离理论

采用微扰静态(PSS)模型近似处理极化和结合能效应，并引入了相对论效应、能量损失效应和库仑偏转效应修正的ECPSSR理论是描述直接库仑电离过程最成功的理论，但对于低能离子入射时， 其结果明显低于实验值. 采用联合分离原子(USA)模型替代ECPSSR中的PSS模型，考虑分子轨道效应得到了基于USA模型的电离理论——MECUSAR理论. 对部分碰撞系统进行了计算，得到的碰撞截面与实验结果基本符合. 结合OBKN(Oppenheimer-Brinkman-Kramers formulas of Nikolae 关键词： X射线产生截面 离子-原子碰撞 电子俘获     

类氢铀离子的辐射电子俘获角分布研究

分析了在重离子冷却储存环上测量的辐射电子俘获产生的X射线能谱,得出了K REC光子的相对微分角分布,通过与非相对论理论和全相对论理论的计算结果进行比较,从实验上证明了相对论重离子 原子碰撞中自旋翻转跃迁的存在,实验结果与全相对论理论计算结果一致.同时还证实,重离子体系本身的相对论性质对碰撞过程有重要影响. Radiative electron capture process occurring in high-Z ion-atom collisions studied on the heavy ion storage ring (ERS) is reviewed. The REC differential angular distributions are deduced from the X-ray spectra recorded at various observation angles for 310 and 88 MeV/u U 92+on N 2collisions, respectively. The experimental results are compared with non-relativistic and complete relativistic calculations. Deviations from sin 2θ lab are found in both cases. The contributions to near 0°observation...     

Cq+ 和Oq+与原子碰撞的电子俘获过程的理论研究

在ECPSSR理论的基础上， 利用OBKN近似描述电子俘获过程， 得到了包括电子俘获过程贡献的ECPSSR理论， 编写了相应的计算程序。 采用该程序计算了不同电荷态离子与多种靶原子碰撞的电子俘获截面和相应的X 射线产生截面， 将计算得到的包含电子俘获过程贡献的X 射线产生截面与实验结果进行了比较。 对于具有满K壳层的入射离子碰撞， X 射线产生截面与入射离子电荷态基本无关； 对于以直接电离为主导的碰撞过程， 计算得到的X 射线产生截面与实验数据符合得很好； 对于全裸和单K空穴入射离子的碰撞， 计算高估了X 射线产生截面。 Based on the ECPSSR theory, the contribution of the electron capture is described by the OBKN theory. The cross sections of electron capture and X ray production for the collision of different charge state projectiles with various targets are calculated, and compared with the available experimental data. It is found that the obtained X ray production cross sections are almost independent of the projectile charge states for projectiles without a K vacancy. For the collision processes of direct ionization, the present calculated results agree well with the experimental data. The calculations overestimate the X ray production cross sections for the projectiles with full and a K vacancy.     

P—He碰撞中1s—ns电子俘获截面计算

本文进一步发展了由我们提出的一种新的方法来计算离子－原子，离子－离子碰撞中１ｓ－ｎｓ电子俘获截面。在该方法中，我们用联合原子模型描述初态电子的导曲波函数及用氢原子模型的描述末态电子的波函数，在小几率及峰点近似条件下，其散射振幅为一简单的解析形式。在１０－２００ｋｅＶ能量范围，我们用此方法计算了Ｐ＋Ｈｅ碰撞中电子俘获到４ｓ态的截面。计算结果与实验结果在３０－２００ｋｅＶ能量很好地一致。特别是我们的结     

低能非裸核高离化态离子与氢原子碰撞的电子俘获

基于单通道ＬａｎｄａｕＺｅｎｅｒ模型给出的电子俘获的反应窗口，分析了低能裸核离子与氢原子碰撞和非裸核离子与氢原子碰撞的电子俘获过程。结果表明：如果初、末态间的非绝热势能曲线的交点落在相应的反应窗口内，则多通道ＬａｎｄａｕＺｅｎｅｒ方法仍然能够给出较好的结果。用该方法对低能Ｃ３＋＋Ｈ，Ｃ４＋＋Ｈ和Ｏ５＋＋Ｈ碰撞的电子俘获截面进行了计算，其结果与我们的分析是一致的。     

7.5—30keVC^＋,N^＋,O^＋与H2分子碰撞的单电子俘获截面测量

建立了一套用于研究单价正离子与气体分子碰撞的单电子俘获过程的装置，测量了７．５－３０ｋｅＶ能量范围的Ｃ＋、Ｎ＋、Ｏ＋离子与Ｈ２分子碰撞单电子俘获截面。对于３０ｋｅＶ能量点，我们的实验结果和文献推荐值符合较好，其它能量点尚未见报道     

高电荷态离子Arq+与不同金属靶作用产生的X射线

研究了高电荷态离子Arq+(q=16,17,18)入射金属Be,Al,Ni,Mo,Au靶表面产生的X射线谱.实验结果表明,Ar的Kα-X射线是离子在与固体表面相互作用过程中固体表面之下形成空心原子发射的.电子组态1s2的高电荷态Ar16+离子在金属表面中性化过程中,存在的多电子激发过程使Ar16+的K壳层电子激发产生空穴,级联退激发射Ar的Kα特征X射线.Ar17+离子在金属表面作用过程中产生的X射线谱形与靶材料没有明显的关联,入射离子的Kα-X射线产额与其最初的电子组态有关,靶原子的X射线产额与入射离子的动能有关.     

Xe~(26+)入射Au靶离子L壳层空穴的产生与退激辐射

基于两体碰撞过程的能量与角动量守恒,推导出Xe26+离子与Au原子碰撞过程,单离子的L壳层空穴产额与离子动能的理论关系.实验测定了动能2.4-3.6Me V的Xe26+离子入射Au靶,产生的Xe的L-X射线谱,获得了射线产额与离子入射动能的实验关系.结果表明,碰撞过程产生Xe L壳层空穴的同时,产生了一定数目的 M壳层空穴,导致L壳层空穴平均荧光产额显著变大,在实验能量范围,空穴产额的理论值与射线产额的实验值存在较好的一致性.     

产生惰性气体高价离子的新方法

此文介绍了一种产生惰性气体高价离子的新方法。在飞行时间质谱仪（ＴＯＦ－ＭＳ）上，把聚焦后的３０８ｎｍ激光掠射到不锈钢栅网上，产生超短脉冲的电子束，利用这种电子束来轰击惰性气体（Ｈｅ，Ｎｅ，Ａｒ，Ｋｒ，Ｘｅ），产生高价离子，并给出了这些离子的飞行时间质谱。这些高价离子可能是电子逐次电离气体原子产生的。这种方法可作为飞行时间质谱的一种理想的“软电离”的“点”离子源     

Differential cross sections for elastic scattering and positronium formation for positron collisions with Ne,Ar, Kr and Xe

Differential cross sections for elastic scattering and Ps(1s) formation are calculated in the truncated coupled-static (TCS) approximation. Comparison is made with the elastic scattering measurements of Dou et al. on Ar and Kr. There is no support from the TCS approximation for the view that structure seen in the experimental results for Ar in the energy range 55–60 eV may be due to a resonance associated with coupling to the positronium formation channel. Rather, we believe that Dou et al. are right in correlating this feature with the maximum in the ionization cross section. In the experiment on Kr structures are observed at 25 and 200 eV. It is tentatively suggested that the structure at 200 eV may be the resonance seen in the TCS calculation at 100 eV, but modified by polarization and absorption effects. It is also suggested that the feature at 25 eV could be associated with coupling to excited states of positronium. The TCS results for the Xe target predict some very pronounced behaviour which would be worth experimental investigation. TCS differential cross sections for Ps(1s) formation by capture of an electron from the outer p-shell of the atom are presented for impact energies up to 75 eV. A noticeable property of these cross sections is that they do not usually peak at the forward direction; this is consistent with an experimental observation by Laricchia et al. on He and Ar targets. The importance of also looking at electron capture from inner shells is emphasized and illustrated by the cross section for electron capture from the 3s shell of Ar.     

A theoretical and experimental investigation of long-pulse,electron-beam-produced rare gas plasmas

Visible emission spectroscopy (380-650 nm) has been performed on intense, electron beam (1 kA, 300 ns, 300 kV) produced Ar, Kr, and Xe plasmas at pressures ranging from 10 to 750 torr. Singly ionized and neutral lines dominated the spectra in all cases except argon, where only singly ionized lines occurred. The temperature of the plasma as determined by comparing line intensities was between 1 and 2 eV. A computer model for chemical kinetics of the electron-beam-produced plasmas in Ar, Kr, and Xe was formulated. The model predicts time, pressure, and temperature trends of the ions, neutrals, and electrons, which agree with trends found experimentally     

态选择电荷交换实验测量以及对天体物理软X射线发射模型的检验

在高温天体等离子体环境中,低能高电荷态离子与中性原子和分子之间的电荷交换是天体物理环境中软X射线发射的重要机制之一.电荷交换软X射线发射相关的天体物理建模需要大量的主量子数n和角量子数l分辨的态选择俘获截面数据,目前这类数据主要来自于经典或者半经典的原子碰撞理论模型.本文利用反应显微成像谱仪,系统测量了炮弹能量为1.6—20.0 keV/u Ne~(8+)与He的单电子俘获n分辨的态选择俘获截面.将测得的相对态选择截面与多通道Landau-Zener方法以及分子库仑过垒模型计算的结果进行比较,发现理论模型计算结果与实验测量结果在弱反应通道上存在显著差异.进一步结合天体物理中常用的l分布模型,计算了1.6和2.4 keV/u Ne~(8+)与He之间电荷交换中的软X射线发射谱,通过与近期实验测量的X射线谱比较,发现计算的软X射线谱强度明显偏离已有的测量值.这些研究表明,多通道Landau-Zener方法、分子库仑过垒模型以及l分布模型在定量描述电荷交换态选择截面时存在一定的不足,如果将这些理论模型应用于天体物理的X射线背景研究中,可能导致对天体等离子体参数的描述不够准确.     

Effect of the structure of the singly charged ion on the cross section for electron capture

The calculations of the cross section for single-electron capture by fast ions are carried out in the Oppenheimer-Brinkman-Kramers approximation. The dependences of the experimental and calculated cross sections for single-electron capture by fast singly charged ions on the collision energy coincide. This makes it possible to estimate the cross section for electron capture in the case of ion-atom collisions if experimental data are absent. The results of calculations for projectiles with filled s-type subshells show that the contribution of electron capture channels to the excited state of the scattered particle depends on the collision energy.     

Electron transfer in low energetic Ne2+/Ar,Kr collisions

Single electron capture processes in Ne²⁺/Ar, Kr collisions were studied by aid of the high-resolution translational spectroscopy. At low collision energies (<1 keV) the dominant contribution to the Ne⁺-spectrum arises from Ne²⁺ ions in the metastable¹ S ₀-state, although it is the weakest component of the primary Ne²⁺ beam. Ne²⁺(³ P) and Ne^2+*(¹ D) projectiles play no important role due to unfavourable energy defects. Target excitation processes as well as transfer ionisation are considered as a possible explanation for different structures in the measured Ne⁺ spectra.     

UV photoemission from physisorbed atoms and molecules: Electronic binding energies of valence levels in mono- and multilayers

Angle-resolved UV photoemission spectra were measured for Ar, Kr, Xe, CO, O₂ and N₂ adsorbed on a Ni(110) surface at 20 K. The different gases were adsorbed also on the Ni(110) surface which had been precovered by mono- and multilayers of the same gases. Upon physisorbing one of these species onto the bare and precovered Ni surface, binding energy shifts up to 3 eV were found. These shifts will be explained by work function changes of the substrate onto which the gas is physisorbed. It will be shown that for the investigated gases the binding energy referred to the vacuum level is an atomic or molecular property which is independent of the substrate, to a first approximation. By physisorption of a known gas the work function of any substrate can be evaluated by UPS. The density of valence states for bulk Ar, Kr and Xe will be discussed. There is evidence that the conduction band can be seen in the secondary electron background of the UP spectra.     

Excitation-autoionization cross-sections and rate coefficients for Ge-like ions

Results of cross-section and rate coefficient calculations for electron impact direct and indirect ionization of ions belonging to the GeI isoelectronic sequence (ground 3d104s24p2) are presented. The cross-sections are given at near threshold energies for the five ions Kr4+, Mo10+, Xe22+, Pr27+ and Dy34+. The rate coefficients are computed for all the ions from Kr4+ to U60+ in the GeI sequence at seven electron temperatures (kTe = 0.1EI, 0.3EI, 0.5EI, 0.7EI, EI, 2EI and 10EI, where EI is the first ionization energy). The calculations include the contribution of direct ionization (DI) calculated with the Lotz formula approximation and the contributions of excitation-autoionization (EA) calculated in the framework of the distorted wave (DW) approximation for the 4s-nl, 3d-nl and 3p-nl resonant inner-shell excitations. The ionization enhancement due to the EA channels is shown as a function of Z along the GeI isoelectronic sequence.     

Efficient fluorescence in solid noble gases excited by 10—30 kV electrons

Fluorescent spectra and efficiency of vacuum ultraviolet generation have been investigated for solid Ar, Kr and Xe excited by 10–30 kV electrons. Overall conversion efficiency of e-beam energy into a single 7 nm wide band centered near 175 nm for Xe was measured to be 30%, indicating high intrinsic efficiency when electron backscatter is taken into account. In Ar and Kr the presence of trace amounts of O₂was found to cause energy transfer from the excimer bands to longer wavelengths.