Noncommutative Cohomology and Electromagnetism on $$\mathbb{C}$$ q [SL2] at Roots of Unity

We compute the noncommutative de Rham cohomology for the finite dimensional q-deformed coordinate ring _q [SL₂] at odd roots of unity and with its standard four-dimensional differential structure. We find that H ⁱ is highly nontrivial compared to case of generic q and has as many modes 1 : 4 : 6 : 4 : 1 as the dimension of the exterior algebra. We solve the spin-0 and Maxwell theory on _q [SL₂], including a complete picture of the self-dual and anti-self dual solutions and of Lorentz and temporal gauge fixing. The system behaves in fact like a noncompact space with self-propagating modes (i.e., in the absence of sources). We also solve with examples of electric and magnetic sources including the biinvariant element H ¹ which we find can be viewed as a source in the local (Minkowski) time-direction (i.e. a uniform electric charge density).     

Measurement of Cross Sections for the Reactions $${}^{{232}}{\textrm{Th}}({{}^{3}}{\textrm{He}}{,p4n})^{{230}}$$ Pa, $${}^{{232}}{\textrm{Th}}({{}^{3}}{\textrm{He}}{,p2n})^{{232}}$$ Pa,and $${}^{{232}}{\textrm{Th}}({{}^{3}}{\textrm{He}}{,2p+pn})^{{233}}$$ Pa Induced by the Irradiation of a ThO $${}_{2}$$ Target with $${}^{3}$$ He Nuclei

Physics of Atomic Nuclei - The efficiency of employing a beam of intermediate-energy $${}^{3}$$ He particles for the production of the radionuclide $${}^{230}$$ Pa on natural-thorium targets, which...     

Regioselective and stereoselective synthesis of epithiomethanoiminoindeno[1,2-b]furan-3-carbonitrile: heterocyclic [3.3.3]propellanes

Molecular Diversity - Synthesis of heteropropellanes in one step: the reaction between dicyanomethylene-1,3-indanedione (CNIND) and N-substituted-2-(2,4-dinitrophenyl)hydrazinecarbothioamides,...     

吡啶并嘧啶类Wee1激酶衍生物的三维定量构效关系与分子对接

采用比较分子场分析方法(CoMFA)和比较分子相似性指数分析方法(CoMSIA)对一系列吡啶并嘧啶类衍生物进行了三维定量构效关系(3D-QSAR)研究,建立了CoMFA和CoMSIA两种模型. 所构建的最佳模型的交叉验证相关系数分别为0.707和0.645,非交叉验证系数分别是0.964和0.972,模型的一些外部验证表明两个模型合理、可靠,并具有良好的预报能力. 同时,用分子对接的方法分析了该类化合物与Wee1激酶结构的作用模式,结果进一步表明,在R1和R5取代基上引入正电性基团,R2为体积小的电负性基团,同时选择体积中等和强的推电子的R3但亲水性的X取代基,能有效改善这类化合物的抑制活性.     

Investigation of the Yield of the Nuclear Reaction $${}^{{11}}$$ B( $${p,3\alpha}$$ ) Initiated by Powerful Picosecond Laser Radiation

Physics of Atomic Nuclei - The results obtained by experimentally and theoretically studying the yield of the promising nuclear-fusion reaction $${}^{11}$$ B( $$p,3\alpha$$ ) initiated by powerful...     

Synthesis and optical properties of novel pyrido[1,2-a]benzimidazole-containing 1,3,4-oxadiazole derivatives

A series of novel substituted 1,3,4-oxadiazole derivatives containing pyrido[1,2-a]benzimidazole moiety were synthesized and characterized using FTIR, ¹H NMR, ¹³C NMR, and HRMS. An efficient tandem reaction was employed as a key step in constructing the pyrido[1,2-a]benzimidazole moiety under very mild condition. The structure of compound 4a was established by X-ray crystallography. The UV-vis absorption and fluorescence spectral characteristics of these compounds were investigated in several solvents. Compounds 4a-i display similar absorptions, with absorption peaks ranging from 330 to 339 nm in acetonitrile, while the absorption maxima of compound 4j bearing a diphenylamino group on the benzene ring is red-shifted distinctly to 377 nm due to the strong electron-donating property of its substituent and extended π-conjugated system. All these target heterocyclic compounds present blue-green emissions (461-487 nm) in dilute solutions and show high quantum yields of fluorescence (Ф_PL=0.65−0.99) in dichloromethane.     

N-2-萘并[1,2-d]噻唑基苯甲酰胺的合成与结构表征

1-苯甲酰基-3-萘基硫脲在醋酸锰作用下,自身发生关环反应成功获得目标产物N-2-萘并[1,2-d]噻唑基苯甲酰胺,其结构经红外光谱、氢谱和碳谱得到了确证.     

3D-QSAR Study of 7,8-Dialkyl-1,3-diaminopyrrolo-[3,2-f] Quinazolines with Anticancer Activity as DHFR Inhibitors

在对一系列抗癌性7,8-二烃基-1,3-二氨基吡咯-[3,2-f]喹唑啉类二氢叶酸还原酶抑制剂的二维定量构效关系(2D-QSAR)研究基础上,应用比较分子场分析法对该类配合物进行了三维定量构效关系(3D-QSAR)研究. 建立了具有良好的统计学性能及预报能力的3D-QSAR模型,非交叉验证相关系数为0.993,交叉验证相关系数为0.619,估算的标准误差0.208, 统计方差比193.4. 该模型表明立体场因素的影响比静电场因素大很多,此结果与我们已经报道的2D-QSAR模型结果相一致. 然而,3D-QS     

A green synthesis in water of novel (1,5,3-dithiazepan-3-yl)alkanoic acids by the multicomponent reaction of amino acids, $$\hbox {CH}_{2}$$O,and 1,2-ethanedithiol

A library of new (1,5,3-dithiazepan-3-yl)alkanoic acids was prepared by the multicomponent cyclocondensation of amino acids, formaldehyde, and 1,2-ethanedithiol in water at room temperature for 1 to 5 h in high yields. This green procedure offers several advantages such as an operational simplicity, no catalyst, and no production of hazardous materials.     

Effect of nonstoichiometry on the plastic behavior of Ni3Ge single crystals with the [$$ \bar 2 $$34] orientation of the deformation axes

The effect of nonstoichiometry on the mechanical properties of Ni₃Ge single crystals with the [\(\bar 2\)34] orientation of the deformation axis, which is suitable to cubic slip, has been investigated. The influence of change in the Ge concentration on the Ni₃Ge plastic properties under the conditions of cubic slip is established. The concentration dependence of the yield stress at different temperatures is obtained.     

$$\hbox {I}_{2}$$-medi ated amin ation/cycliz ation of ketones with 2- aminopyridines under high-speed b all milling: solvent- and met al-free synthesis of 2,3-substituted imid azo[1,2- a]pyridines and zolimidine

Under solvent-free high-speed ball milling, an I\(_{2}\)-promoted condensation/cyclization of easily available methyl ketones or 1,3-dicarbonyl compounds with 2-aminopyridines has been developed, which allows the quick assembly of 2,3-substituted imidazo[1,2-a]pyridines (IPs) with broad molecular diversity, including the antiulcer drug zolimidine. The advantages of high yields, good functional group compatibility, short reaction time (within 90 min), free use of heating, solvent and metal, employment of cheap starting materials, and simple work-up procedure make this protocol a very efficient alternative to traditional synthesis of IPs.     

An efficient three-component synthesis of highly functionalized tetrahydroacenaphtho[1,2-b]indolone derivatives catalyzed by L-proline

An efficient and diastereoselective synthetic procedure for highly functionalized tetrahydroacenaphtho[1,2- \(b\) ]indolone derivatives was successfully developed by the three-component reaction of acenaphthequinone, enaminones, and barbituric acid in the presence of a catalytic amount of L-proline. This method has the advantages of convenient operation, excellent yields, mild reaction conditions, and environmental friendliness.     

Synthesis of Co nanocapsules coated with BN layers by annealing of KBH4 and [Co(NH3)6]Cl3

Cobalt (Co) nanocapsules coated with boron nitride (BN) layers were synthesized by annealing of ammine complex. KBH₄ and [Co(NH₃)₆]Cl₃ were used as starting materials, and annealed these powders at 500–1000 °C with flowing nitrogen gas. Formation of fcc-Co nanocapsules coated with BN layers was observed from X-ray diffraction patterns and high-resolution electron microscopy. Particle size of fcc-Co prepared at 1000 °C with flowing 100 sccm N₂ gas was approximately 40 nm, and the values of saturation magnetization and coercivity were 74.5 emu/g and 88 Oe, respectively. Good oxidation- and wear-resistances were obtained by encapsulating Co nanoparticles with BN layers.