Discovery and frequency measurement of far-infrared laser emissions generated by optically pumped CH2DOH

A recently improved three-laser heterodyne system was used to frequency measure ten previously observed optically pumped far-infrared (FIR) laser emissions from the partially deuterated methanol isotopologue CH₂DOH. Also, a 64.0 μm FIR emission generated by the 9P32 line of the carbon dioxide (CO₂) laser was discovered and frequency measured. These newly measured frequencies have fractional uncertainties on the order of ±2×10^-7 and correspond to laser wavelengths ranging from 42.6 to 152.7 μm. The offset frequency for the CO₂ pump laser was measured for twenty-two CH₂DOH FIR laser emissions. PACS 07.57.Hm; 42.55Lt; 42.62.Eh     

Stimulated rotational Raman scattering at multiwavelength under tea CO2 laser pumping with a multiple-pass cell

Stimulated rotational Raman scattering (SRRS) at multiwavelength pumped by TEA CO₂ laser was demonstrated in this paper. Raman mediums were cooled by liquid-N₂ and a multiple-pass cell (MPC) with 25 passes was designed and used. When the para-H2 was pumped by single-longitudinal-mode (SLM) circular polarized TEA CO₂ laser on 10P(20), 9P(20), and 10R(20), 50 mJ 16.95 μm, 350 mJ 14.44 μm, and 536 mJ 16.9 μm radiations were obtained, corresponding to energy conversion efficiency of 1.2, 11.7, and 13.4%, respectively. When the ortho-D₂ was pumped by CO₂ laser on 10R(18), 108 mJ 12.57 μm Raman laser was obtained with energy conversion efficiency of 2.9%.     

The Muonic Hydrogen Lamb Shift Experiment at PSI

A measurement of the 2S Lamb shift in muonic hydrogen (μ⁻p) is being prepared at the Paul Scherrer Institute (PSI). The goal of the experiment is to measure the energy difference ΔE(2⁵ P _3/2−2³ S _1/2) by laser spectroscopy (λ≈6μm) to a precision of 30 ppm and to deduce the root mean square (rms) proton charge radius with 10⁻³ relative accuracy, 20 times more precise than presently known. An important prerequisite to this experiment is the availability of long-lived μp_2S -atoms. A 2S-lifetime of ∼1 μs – sufficiently long to perform the laser experiment – at H₂ gas pressures of 1–2 hPa was deduced from recent measurements of the collisional 2S-quenching rate. A new low-energy negative muon beam yields an order of magnitude more muon stops in a small low-density gas volume than a conventional cloud muon beam. A stack of ultra-thin carbon foils is the key element of a fast detector for keV-muons. The development of a 2 keV X-ray detector and a 3-stage laser system providing 0.5 mJ laser pulses at 6 μm is on the way. This revised version was published online in August 2006 with corrections to the Cover Date.     

High-efficiency,high-repetition-rate,temperature-tuning optical parametric oscillator based on periodically poled MgO-doped lithium niobate

We report a compact and viable source of high-efficiency, high-repetition-rate, temperature-tuning, mid-IR optical parametric oscillator (OPO) based on periodically poled MgO-doped lithium niobate (PPMgOLN) pumped by a homemade high power AOM Q-switched Nd:YVO₄ laser centered at 1.064 μm. With an optimal plane-concave resonator configuration, average output power of 5.7 W at 2.73 μm was obtained when the pump power was 25 W at the repetition rate of 80 kHz. The conversion efficiency from the 1.064 μm laser to the 2.73 μm laser was 22.8%. Temperature tuning of the OPO yielded a signal wavelength range from 1.67 to 1.75 μm and an idler wavelength in the range of 2.72 to 2.92 μm.     

Sub-wavelength micromachining of silica glass by irradiation of CO<Subscript>2</Subscript> laser with Fresnel diffraction

We investigated a simple and productive micromachining method of silica glass by ablation using a TEA CO₂ laser (10.6 μm) with a spatial resolution down to sub-wavelength scale. The silica glass was irradiated by the TEA CO₂ laser light through a copper grid mask with square apertures of 20×20 μm² attached to the silica glass surface. After the irradiation, circular holes with a diameter of several μm were formed on the silica glass surface at the centers of the apertures due to the Fresnel diffraction effect. The minimum diameter of the holes was 3.4 μm. The characteristics of the micromachining are discussed based on the electric field distributions of the CO₂ laser light under the mask using a three-dimensional full-wave electromagnetic field simulation.     

CW laser performance of Yb and Er,Yb doped tungstates

 Room temperature cw laser action of Yb³⁺-doped KY(WO₄)₂ and KGd(WO₄)₂ crystals at 1.025 μm and Er, Yb : KY(WO₄)₂ at 1.54 μm has been demonstrated under pumping by both Ti-sapphire laser and InGaAs laser diodes. A slope efficiency of Yb-lasers up to 78% has been obtained. Received: 19 June 1996     

New short-wavelength laser emissions from partially deuterated methanol isotopes

The partially deuterated isotopes of methanol, CH₂DOH and CHD₂OH, have been reinvestigated as sources of far-infrared (FIR) laser emissions using an optically pumped molecular laser (OPML) system recently designed for wavelengths below 150 μm. With this system, 10 new FIR laser emissions from these isotopes ranging from 32.8 to 174.6 μm have been discovered. This includes the shortest known OPML emission from CHD₂OH, at 32.8 μm. These lines are reported with their operating pressure, polarizations relative to the CO₂ pump laser and wavelengths, measured to ±0.5 μm. In addition, polarizations for three previously observed FIR laser lines from CHD₂OH were measured for the first time. This paper is dedicated to the memory of Dr. K.M. Evenson, a pioneer in the field for his role in the development of optically pumped molecular lasers and their use in laser frequency measurements and the laser magnetic resonance technique. His scientific expertise, guidance, mentoring and friendship will be greatly missed. Received: 27 March 2002 / Published online: 8 May 2002     

8.30 μm singly resonant ZnGeP2 optical parametric oscillators pumped by a Tm,Ho:GdVO4 laser

A single resonator 8.30 μm ZnGeP₂ (ZGP) optical parametric oscillators (OPO) was reported in the paper. The OPO was pumped by a 10.2-W Tm,Ho:GdVO₄ laser at 8 kHz in a Q-switch mode, a 170-mW idler was obtained at 8.30 μm, and the output power of the idler and signal wave was 1.0 W, corresponding to an optical-optical conversion efficiency of 10.3% and a slope efficiency of 20.9%. Tm,Ho:GdVO₄ laser was pumped by a 30-W fiber-coupled laser diode (LD) at the center wavelength of 801 nm. The output wavelength of Tm,Ho:GdVO₄ laser was at 2.05 μm, and the energy per pulse of 1.28 mJ in 18 ns was achieved at 8 kHz with the peak power of 71.1 kW.     

$90^{\circ}$ phase-matched parametric frequency conversion in AgGa1-xInxS2

AgGa_1-xIn_xS₂ with x=0.14±0.01 was found to be 90° phase-matchable for type-I difference-frequency generation (DFG) by mixing the dual-wavelength pulses emitted from an electronically tuned Ti:sapphire laser. Infrared radiation continuously tunable over the range of 4.80–6.98 μm was generated by independently varying the two wavelengths in the 705–932 nm spectral range, and 4.04 μm radiation by mixing a Nd:YAG laser with the Ti:sapphire laser. In addition, this material was found to be noncritically phase-matchable for the second harmonic generation (SHG) of CO₂ laser radiation at 10.591 μm at 203 °C. Sellmeier equations that reproduce well these experimental data are presented. PACS  42.65.-k; 42.65.ky     

Infrared laser emission in two-photon pumped sodium vapour

We report infrared laser emission in the region of 3 to 5 μm from sodium vapour optically pumped by a pulsed dye laser with wavelengths ranging from 585 to 610nm. Twophoton excitation processes are believed to be responsible for the primary excitation. Both molecular transitions (4 to 5 μm) between high lying states, and atomic transitions (5² S _1/2−4² P _3/2,1/2 at 3.41 μm) have been identified.     

Efficient generation of orange light in a quasi-periodically poled LiTaO3 crystal

We present an approach to generating a tunable orange laser from 0.601 to 0.604 μm based on a quasi-periodically poled superlattice in LiTaO₃ and a Q-switched 1.064 μm Nd:YVO₄ laser as pump. The orange laser was generated in a cavity by a parametric process cascaded by a frequency mixing with a maximum output of 310 mW using 15 W pump power.     

Steady state mode-locking of a 1.34 μm Nd:YVO<Subscript>4</Subscript> laser using a single-walled carbon nanotube saturable absorber

Steady state mode-locked operation of a neodymium laser operating on the ⁴F_3/2 → ⁴I_13/2 transition around 1.3 μm is achieved for the first time using transmitting single-walled carbon nanotube (SWCNT) saturable absorber. The Nd:YVO₄ laser cavity was optimized for large fundamental mode volume generating an average power of 0.8 W at a repetition rate of 127 MHz in a stable train of 16.5 ps long pulses.     

Stark effect on CH3OH and CH3F FIR lasers: Large frequency tuning and resolved structures

The operation of a cw FIR laser in the presence of a strong electric field is described. A hybrid metal-dielectric waveguide is used and the cavity length is scanned to study how the frequency and power of the laser depend on the field strength. The results have also been checked by heterodyning with a conventional reference laser. We report the results obtained for the 496 μm line of CH₃F and the 70.5 μm and 119 μm lines of CH₃OH. A large frequency tunability of almost ±40 MHz is obtained in the best case with power levels in the mW range. A very simple theoretical model accounts for the experimental results. We also report the appearance of a new FIR line at about 204 μm when CH₃OH is pumped by the 9 μmP(34) of CO₂ in the presence of an electric field larger than 1.2 KV/cm.     

Hard tissue ablation with a free running Er:YAG and a Q-switched CO2 laser: a comparative study

The Er:YAG and the CO₂ laser are competitors in the field of hard tissue ablation. The use of Er:YAG lasers (2.94 μm, pulse length _L of 100 to 200 μs) show smaller areas of thermal defects then ‘‘superpulsed’’ CO₂ lasers with pulse lengths of approximately 100 μs. Only the development of a Q-switched CO₂ laser (9.6 μm, τ_L=250 ns) allowed for similar results. In this paper new results for the Er:YAG and the Q-switched CO₂ laser under the influence of water spray will be presented. Several parameters are of special interest for these investigations: the specific ablation energy, which shows a minimum for the CO₂ laser at an energy density of 9 J/cm ² and a broad shallow minimum in the range of 10 to 70 J/cm² for the Er:YAG laser, and comparison of the cut-shape and depth. Surface effects and cutting velocity are discussed based on SEM pictures. Received: 19 July 2000 / Revised version: 1 November 2000 / Published online: 30 November 2000     

Research of Tm (5.5 at %), Ho (0.55 at %):GdVO<Subscript>4</Subscript> laser pumped by diode laser at 800 nm

In this paper, we report a Tm (5.5 at %), Ho (0.55 at %):GdVO₄ laser pumped by diode laser at 800 nm. To our best knowledge, it is the first time that the use of Tm (5.5 at %), Ho (0.55 at %):GdVO₄ crystal among the similar experiments. We observed the influences of LD working temperature i.e. pump wavelength to 2 μm laser conversion efficiency. In the conditions of the continuous wave and 10 kHz acousto-optic Q-switch, high efficiency output of 2.05 μm laser was obtained. With the maximum pump power of 34.6, 13.9, and 13.6 W at 2.05 μm laser output was achieved respectively. Single laser pulse width was 25.6 ns in 10 kHz acousto-optic Q-switched condition.     

Investigation of 13CH3OH methanol: new laser lines and assignments

We have reinvestigated ¹³CH₃OH as a source of far-infrared (FIR) laser emission using a CO₂ laser as a pumping source. Thirty new FIR laser lines in the range 36.5 μm to 202.6 μm were observed and characterized. Five of them have wavelengths between 36.5 and 75 μm and have sufficient intensity to be used in LMR spectroscopy. Using Fourier-transform spectroscopic data in the infrared (IR) and FIR regions we have determined the assignment for 10 FIR laser transitions and predict nine frequencies for laser lines which have yet to be observed. Received: 17 July 2000 / Published online: 6 December 2000     

Time evolution of emission by carbon nanoparticles generated with a laser furnace technique

Time evolution of emission by carbon nanoparticles generated with a laser furnace technique was investigated with a high-speed video camera. Assuming blackbody radiation formula for small spherical particle, the internal temperature of these carbon nanoparticles was determined as a function of time delay (Δt) after laser vaporization. It was found that the internal temperature of them drastically decreased at Δt < 400μs through collision with the surrounding rare gas inside the furnace. On the other hand, in particular laser vaporization condition where yields of C₆₀ and other higher fullerenes in the soot were found to be high, an increase in the blackbody emission intensity could be recognized for longer wavelength ( 660 < λ < 830 nm) at Δt > 400μs. This finding suggests that a certain exothermic process related to the formation of C₆₀ and other higher fullerenes should occur at Δt > 400μs inside the furnace.     

Laser diode spectroscopy of H2O at 2.63 μm for atmospheric applications

The 2.7 μm spectral range is highly suitable for the in situ monitoring of atmospheric H₂O using compact balloonborne laser diode spectrometers. Water vapour spectroscopic parameters of the 2₀₂   1₀₁ and the 4₁₃   4₁₄ transitions of the ν₃ band are revisited in this spectral region using a new distributed-feedback InGaAsSb laser diode emitting at 2.63 μm. Accurate line strengths are provided which are well adapted for the in situ probing of the middle atmosphere. Our measurements are thoroughly compared to an existing molecular database, laboratory measurements and ab-initio calculations. A laser hygrometer was developed for operation from small stratospheric balloons using this new laser diode technology, with emission at 2.6 μm. The realized sensor is described and results from a recent test-flight are reported. PACS 07.57.Ty; 92.60 Jq     

Frequencies of cw FIR laser lines for use in laser magnetic resonance spectroscopy

A transversely pumped far-infrared laser cavity has been used to discover two optically pumped laser lines: the 357.7 μm line from H₂C=CF₂ and the 242.3 μm line from CH₃OH. Using heterodyne techniques, the frequencies of fourteen far-infrared laser emissions have been measured, six for the first time. PACS  07.57.Hm; 42.55.Lt; 42.62.Eh     

2.2 μm InGaAsSb/AlGaAsSb laser diode under continuous wave operating at room temperature

2.2 μm InGaAsSb/AlGaAsSb Sb-based type-I laser diodes (LDs) were fabricated, with cavity lengths of 1000 μm and stripe width of 150 μm. The high output performance was achieved with the threshold current density of the device is as low as 187 A/cm², slope efficiency of 0.2 W/A, and vertical and parallel divergent angles ϑ_⊥ = 42° and ϑ_| = 10°, respectively. The continuous wave operating up to 320 mW at room temperature (RT) were achieved.