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1.
Effect of Fe3O4 segregation at grain boundaries on the electrical transport and magnetic properties of La0.67Ca0.33MnO3 is investigated. The experimental results show that the Fe3O4 segregation not only shifts the paramagnetic-ferromagnetic transition temperature of La0.6TCa0.33MnO3 to a lower temperature region but also induces a new transition in a lower temperature region. Meanwhile, the transition processes observed in both the resistivity and magnetization curves are obviously widened. Compared to pure La0.67Ca0.33MnO3, we assume that the Fe3O4 segregation level at the grain boundaries can modify the electrical transport and magnetic properties of La0.67Ca0.33MnO3. 相似文献
2.
Giant Magnetoresistance in La0.67Ca0.33MnO3/Alq3/Co Sandwiched-Structure Organic Spin Valves
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PANG Zhi-Yong CHEN Yan-Xue LIU Tian-Tian ZHANG Yun-Pang XIE Shi-Jie YAN Shi-Shen HAN Sheng-Hao 《中国物理快报》2006,23(6):1566-1569
La0.67Ca0.33MnO3/Alq3/Co sandwiched-structure organic spin valves are fabricated by vacuum thermal evaporation method. A giant magnetoresistance (GMR) of 14% is observed at low temperature 100K. At 30K, the magnetoresistance can increase to 50%. The large GMR of the device is attributed to the high spin polarization and low conductivity of the La0.67Ca0.33MnO3 contact. The magnetoresistance ΔR/R and the coercive field of the Co electrode depend strongly on temperature. The large high-field magnetoresistance reported on La0.67Sr0.33MnO3/Alq3/Co organic spin valves [Nature 427 (2004) 821] is not observed in our La0.67Ca0.33MnO3/Alq2/Co organic spin valves. 相似文献
3.
The resistivity of the heavy-doped La1/3Ca2/3MnO3 (LCMO) is simulated using a random resistor network model, based on a phase separation scenario. The simulated results agree well with the reported experimental data, showing a transition from a charge-disordered (CDO) state embedded with a few ferromagnetic (FM) metallic clusters to a charge-ordered (CO) state, corresponding to the transition from a high-temperature paramagnetic (PM) insulating state to a low-temperature antiferromagnetic (AF) insulating state. Furthermore, we find that the number of AF/CO clusters increases with decreasing temperature, and the clusters start to connect to each other around 250K, which causes percolating in the system. The results further verify that phase separation plays a crucial role in the electrical conductivity of LCMO. 相似文献
4.
T. Govardhan Reddy P. Yadagiri Reddy Ajay Gupta K. Rama Reddy 《Solid State Communications》2005,133(2):77-81
The electrical and magnetic transport properties of the La0.67−xEuxCa0.33MnO3 system exhibit lowering of insulator to metal and paramagnetic to ferromagnetic transition temperature (TC) with the increase of Eu concentration in addition to possessing CMR property. The temperature variation of electrical resistivity and magnetic susceptibility for x=0.21 is found to have two distinct regions in the paramagnetic state for T>TP; one with the localization of lattice polaron in the high-temperature region (T>1.5TP) satisfying the dynamics of variable range hopping (VRH) model and the other being the combination of the spin and lattice polarons in the region TP<T<1.5TP. The resistivity variation with temperature and magnetic field, the cusp in the resistivity peak and CMR phenomenon are interpreted in terms of coexistence of spin and lattice small polarons in the intermediate region (TP<T<1.5TP). The spin polaron energy in the La0.46Eu0.21Ca0.33MnO3 system is estimated to be 106.73±0.90 meV and this energy decreases with the increase of external magnetic field. The MR ratio is maximal with a value of 99.99% around the transition temperature and this maximum persists till T→0 K, at the field of 8 T. 相似文献
5.
La0.7Ca0.3MnO3:xZn0.95Co0.05O (x=0.0,0.05, 0.1, 0.15mol) composites are prepared by a sol-gel process. X- ray diffraction and energy diffraction spectroscopy reveal that there is no evidence of a reaction between the La0.7 Ca0.3 MnO3 (LCMO) and Zn0.95Co0.05 O (ZCO). Magnetization M, Curie temperature Tc and metal-insulator transition temperatures Tp are observed to decrease with increasing ZCO content. Compared with x = 0.0, a great enhancement in the magnetoresistance (MR) is observed at around Tc for x = 0.05, 0.10, 0.15. Based on the tunneling MR and percolation models, this great change of MR is well explained. 相似文献
6.
X.L. Zhang Y.G. ZhaoY.H. Sun S.N. GaoP.L. Lang X.P. ZhangM.H. Zhu 《Journal of magnetism and magnetic materials》2006
The electroresistance (ER) of La0.67Ca0.33MnO3 (LCMO) epitaxial thin films with different thicknesses was studied. For the 110 nm thick LCMO film, its ER shows a maximum at Tp, where the resistance shows a peak, and decreases to zero at lower temperatures. While for the 30 nm thick LCMO film, its ER is remarkable in a wide temperature range. Another interesting observation in this work is that the electric current can tune the magnetoresistance of the ultrathin LCMO thin film. The results were discussed by considering the coexistence of ferromagnetic metallic phase with the charge ordered phase, and the variation of the phase separation with film thickness and electric current. This work also demonstrates that electric current can tune the magnetoresistance of the manganites, which is helpful for their applications. 相似文献
7.
Y.H. Sun Y.G. ZhaoX.L. Zhang S.N. GaoP.L. Lang X.P. ZhangM.H. Zhu 《Journal of magnetism and magnetic materials》2007
The electronic transport behavior of La0.67Sr0.33MnO3 epitaxial thin films with different thicknesses has been investigated under various applied DC currents. The 20 and 70 nm thick films show a giant negative electroresistance (ER). In contrast, the films with 100 nm thickness show unusual giant positive ER, which can reach 30% with the current density of 1.8×108 A/cm2 at room temperature. It is interesting that the electric current can also change the magnetoresistance of the films. The results were explained by considering the spin polarized current induced increase of ferromagnetic metallic phase and current-induced lattice distortion via electron wind force under high current density. 相似文献
8.
Perfect epitaxial growth of La0.67Ca0.33MnO3 (LCMO) thin film has been achieved on (1 0 0) LaAlO3 (LAO) single crystal substrate by radio frequency sputtering method. X-ray diffraction (XRD) and electron diffraction analysis indicates that La0.67Ca0.33MnO3 film grows epitaxially on LaAlO3 along [1 0 0] direction of the substrate. The resistivity variation with temperature of the film shows a sharp metal to semiconductor transition peak around 253 K, which is close to that of the target. The magnetoresistance (MR) also reveals high quality epitaxy film characteristic at low temperatures and near the metal to semiconductor transition temperature. 相似文献
9.
N. Haberkorn G. Bridoux E. Osquiguil G. Nieva J. Guimpel 《Applied Surface Science》2007,254(1):222-224
We present results on the Hall coefficient RH in the normal state for a GdBa2Cu3O7−δ/La0.75Sr0.25MnO3 bilayer and a La0.75Sr0.25MnO3 film grown by dc magnetron sputtering on (1 0 0) SrTiO3. We find that the electric transport on the bilayer can be qualitatively described using a simple parallel layers model. The GdBa2Cu3O7−δ layer presents a carrier density approximately equal to that reported for 7 − δ = 6.85 oxygen doping. Also we observe an unexpected presence of two Hall resistivity regimes, effects that may be associated with the internal magnetic field induced on the superconducting layer by the ferromagnetic layer. 相似文献
10.
Structural and Optical Properties of Nanocrystal In2O3 Films by Thermal Oxidation of In2S3 Films
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In2S3 nanocrystalline films are prepared on glass substrates by the spray pyrolysis technique using indium chloride and thiourea as precursors. The deposition is carried out at 350°C on glass substrates. The films are then annealed for two hour at 200, 400, 600, and 800°C in O2 flow. This process allows the transformation of nanocrystal In2O3 films from In2S3 films and the reaction completes at 600°C. These results indicate that the In2O3 film prepared by this simple thermal oxidation method is a promising candidate for electro-optical and photovoltaic devices. 相似文献
11.
The dependence of YBCO thin film properties on the deposition conditions was studied for different substrates. The deposition conditions were optimized for the epitaxial growth of high quality YBCO thin films of 1500 Å thickness onto single crystal (100-oriented) SrTiO3 (STO), MgO and LaAlO3 (LAO) substrates by DC Inverted Cylindrical Magnetron Sputtering (ICMS). The samples were investigated in detail by means of X-ray diffraction analysis (XRD), EDX, AFM, ρ-T, magnetic susceptibility and current-voltage (I-V) characterizations. The samples show strong diamagnetic behavior and sharp transition temperatures of 89-91 K with ΔT<0.5 K. XRD of the samples exhibited highly c-axis orientation. The full width at half maximum (FWHM) values of the rocking curves were ranging typically from 0.22 to 0.28°. The samples have smooth surfaces as shown from AFM micrographs. The surface roughness, Ra, changed between 5-7 nm. I-V characteristics were obtained from the 20 μm-wide microbridges, which were patterned by a laser writing technique. The critical current densities (Jc, 1.06×106 for LAO-based YBCO, 1.39×106 for MgO-based YBCO, 1.67×106 A/cm2 for STO based YBCO) of the microbridges were evaluated from I-V curves at 77 K. 相似文献
12.
The role of vibrational anisotropy of Mn3+O6 octahedron in the phase separation behavior of La0.67−yPryCa0.33MnO3 (x=0, 0.15, 0.25 and 0.30) has been investigated by means of magnetization M, internal friction Q−1, Young's modulus E along with the X-ray powder diffraction measurements. For the samples with y=0 and 0.15, the Q−1 exhibits three peaks in the ferromagnetic region, which are attributed to the intrinsic inhomogeneity of ferromagnetic phase, i.e. the electronic phase separation with the coexistence of insulating and conducting phases. However, both the samples with y=0.25 and 0.30 undergo a magnetic phase separation with the coexistence of the antiferromagnetic and ferromagnetic phases, and the Q−1 peaks related to the electronic phase separation have not been observed. In addition, the Q−1 exhibits a peak in the paramagnetic region for all samples, which may result from the formation of magnetic clusters. We observed that the evolution from electronic to magnetic phase separation is close related to the rapid increase in the ratio of two kinds of Jahn-Teller distortion modes Q3 and Q2, i.e. Q3/Q2. A schematic phase diagram is given in the text, and it is suggested that the enhancement of vibrational anisotropy of Mn3+O6 octahedron plays a key role in the evolution from electronic to magnetic phase separation. 相似文献
13.
We report our analysis of resistivity data on Nd0.67Sr0.33MnO3 polycrystalline samples as a function of preparative conditions using a bond percolation model for a random mixture of metallic and insulating regions, assuming polaronic transport above and below the metal-insulator (M-I) transition temperature. Our analysis suggests that for oxygen deficient compounds the M-I transition that occurs at a lower temperature than the ferromagnetic transition arises from a percolation of the metallic regions. The temperature dependence of resistivity and thermopower suggests the existence of a bimodal distribution of conductivities. 相似文献
14.
Two sets of crystal field (CF) parameters have been proposed for DyFe2Si2, none of which could provide a simultaneous explanation of the available experimental data, particularly at low temperatures (below 100 K). The set derived from magnetic studies could not even explain the thermal variation of the magnetic specific heat reported in the same work. Although the set of CF parameters, obtained from a fit to the Mossbauer spectra, could provide a fairly good explanation of the thermal variation of the magnetic susceptibilities along the c-axis, it could not explain the observed thermal variation of other reported experimental findings. In the present work, an appraisal of the CF parameters proposed earlier has been done and a set of CF parameters has been derived, which provide a simultaneous explanation of all the available experimental data. The effect of substitution of Ge for Si on the magnetic properties and the magnetic specific heat of DyFe2Si2 has been studied in the framework of one electron crystal field model. The inelastic neutron scattering studies and EPR measurements are required to check the predicted Stark energies and the paramagnetic resonance g-values. 相似文献
15.
Chemical oxidation is used to induce superconductivity in La2CuO4 expitaxial thin films fabricated by pulsed laser deposition technique. Details about the influence of oxidation time on structural, surface morphology, Raman spectra, and electrical properties have been investigated. The results convince that successful uptake of oxygen occurs in the oxidized films, and the content of the inserted oxygen increases with increasing oxidation interval. The possible mechanism for the excess oxygen insertion into the film is also discussed. 相似文献
16.
17.
The structural transition of bulk and uano-size Gd2O3:Eu are studied by high pressure energy disperse x-ray diffraction (XRD) and high pressure photoluminescence. Our results show that in spite of different size of Gd2O3 particles, the cubic structure turns into a possible hexagonal one above 13.4 GPa. When the pressure is released, the sample reverses to the monoclinic structure. No cubic structure presents in the released samples. That is to say, the compression and relaxation of the sample leads to the cubic Gd2O3:Eu then turns into the monoclinic one. 相似文献
18.
The spinel structure LiV2O4 is studied by local density approximation (LDA) as well as including strong correlation correction potential, i.e. the LDA+U scheme, which concerns the strongly correlated interaction. With LDA, the orbitals of V 3d and O 2p are well separated so that it presents purely metallic heavv fermion behaviour. The total energy of ferromagnetic phase is slightly lower than that of paramagnetic phase within the LDA ap- proach. This implies that the ferromagnetic instability as a consequence of spin frustrated magnetism can be observed in experiments. The strong correlation interaction by using LDA+U enhances the exchange splitting. The heavy-fermion feature can be derived from the sharp peak around the Fermi level from the density of states. 相似文献
19.
X.H. Zhang Z.Q. Li W. Song P. Wu H.L. Bai E.Y. Jiang 《Solid State Communications》2005,135(6):356-360
The structural and magnetic properties of Pr0.75Na0.25MnO3 have been investigated experimentally. At room temperature, the compound shows paramagnetic characteristic. Along with decreasing temperature, a peak appears in the magnetization versus temperature curve around 220 K. To clarify whether this peak is associated with the ordering arrangement of Mn3+ and Mn4+ ions, electron diffraction experiments were carried out below and above 220 K respectively. Only basic Brag diffraction spots can be observed at high temperatures, however, superlattice diffraction appears below 220 K. This provides direct evidence for the existence of charge ordering in Pr0.75Na0.25MnO3. We find the Mn3+ and Mn4+ cations form zigzag chains in a-c plane by analyzing the diffraction patterns. Combining with the magnetization measurements and the results of electron spin resonance, we confirm the antiferromagnetic phase and ferromagnetic component coexist in Pr0.75Na0.25MnO3 below 120 K. 相似文献
20.
We study the electronic structures of LiMn2O4 by x-ray and ultraviolet photoelectron spectroscopy (XPS, UPS) and resonant photoelectron spectroscopy (RPES). XPS data suggest that the average oxidation state of Mn ions is 3.55, probably due to the small amount of lithium oxides on the surface. UPS and RPES data imply that Mn ions are in a high spin state, and RPES results show strong Mn3d-O2p hybridization in the LiMn2O4 valence band. 相似文献