Investigations on dynamics of interacting cavitation bubbles in strong acoustic fields

Given its importance to the dynamics of cavitation bubbles, the mutual interaction between bubbles was carefully investigated in this work. The cavitation noises emitted in different sonication conditions were recorded to study the dynamical behavior of the bubbles. The frequency spectra of the noises suggest that the dispersing state of the bubbles severely influence the oscillations of bubbles, and that the nonlinear feature of the dynamics of cavitation bubbles, imposed by the mutual bubble-bubble interaction, gradually develops with the decrease of the dispersing height. Theoretical analysis shows that the size difference between the interacting bubbles should be responsible for the increase of nonlinearity of the oscillation, and that the decrease of the distance between them could effectively enhance the nonlinear feature of the oscillation of the bubble, both of which agree well with the experimental observation.     

双泡模型共振频率的超声空化动力学研究

该研究旨在研究双泡模型的自然共振频率对超声空化的影响,通过理论计算研究了自然共振频率的影响因素,以及单频超声和双频超声与自然共振频率的关系。研究结果表明：气泡初始半径是影响自然共振频率的主要因素;低频驱动下的非线性波动程度会比高频的更加剧烈,当驱动频率等于气泡自然共振频率时,超声空化的效果更好;双频超声取气泡自然共振频率时超声空化效果远远优于单频超声驱动。该研究在超声医学和理解超声空化特性方面有着重要的意义。     

Nonlinear dynamics of a cavitation bubble pair near a rigid boundary in a standing ultrasonic wave field

The dynamics of a micrometer-sized bubble pair in water near a rigid boundary under standing ultrasonic wave excitation is investigated in this study. The viscous effect in the boundary layer at the air-water interface is considered following the viscous correction model. The evolution of the bubble surface at the collapsing stage of the bubble pair is presented for different parameter sets. The field pressure near the rigid boundary, which is induced by the oscillating bubble pair, and the high-speed water jet at the collapse stage, form the main focus of the analysis. This reveals that a horizontal configuration of the bubble pair retards the strength of the bubble jet towards the boundary, whilst a vertical configuration, especially with differently-sized bubbles, can enhance the bubble collapse. This study may help to understand the interaction of multiple bubbles in an acoustic field and its application to surface cleaning.     

固体壁面附近激光空泡的动力学特性研究

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Nonlinear dynamics and acoustic emissions of interacting cavitation bubbles in viscoelastic tissues

The cavitation-mediated bioeffects are primarily associated with the dynamic behaviors of bubbles in viscoelastic tissues, which involves complex interactions of cavitation bubbles with surrounding bubbles and tissues. The radial and translational motions, as well as the resultant acoustic emissions of two interacting cavitation bubbles in viscoelastic tissues were numerically investigated. Due to the bubble–bubble interactions, a remarkable suppression effect on the small bubble, whereas a slight enhancement effect on the large one were observed within the acoustic exposure parameters and the initial radii of the bubbles examined in this paper. Moreover, as the initial distance between bubbles increases, the strong suppression effect is reduced gradually and it could effectively enhance the nonlinear dynamics of bubbles, exactly as the bifurcation diagrams exhibit a similar mode of successive period doubling to chaos. Correspondingly, the resultant acoustic emissions present a progressive evolution of harmonics, subharmonics, ultraharmonics and broadband components in the frequency spectra. In addition, with the elasticity and/or viscosity of the surrounding medium increasing, both the nonlinear dynamics and translational motions of bubbles were reduced prominently. This study provides a comprehensive insight into the nonlinear behaviors and acoustic emissions of two interacting cavitation bubbles in viscoelastic media, it may contribute to optimizing and monitoring the cavitation-mediated biomedical applications.     

Dynamics of three cavitation bubbles with pulsation and symmetric deformation

A new system of dynamical equations was obtained by using the perturbation and potential flow theory to couple the pulsation and surface deformation of the second-order Legendre polynomials (P₂) of three bubbles in a line. The feasibility and effectiveness of the model were verified by simulating the radial oscillations, surface deformation with P₂, and shape evolution of three bubbles. The spherical radial pulsation and surface deformation of the three bubbles exhibit periodic behavior. The maximum secondary Bjerknes forces (SBFs) on the three bubbles are found not to depend on the system’s resonance frequency. Within a stable region, the SBFs of the three bubbles increase with increasing sound pressure amplitude but decrease with increasing distance between the bubbles. The primary Bjerknes force (PBF) on a bubble is significantly higher than the SBF on it.     

Evaluation of the properties of daughter bubbles generated by inertial cavitation of preformed microbubbles

Inertial cavitation (IC) of the preformed microbubbles is being investigated for ultrasound imaging and therapeutic applications. However, microbubbles rupture during IC, creating smaller daughter bubbles (DBs), which may cause undesired bioeffects in the target region. Thus, it is important to determine the properties of DBs to achieve controllable cavitation activity for applications. In this study, we theoretically calculated the dissolution dynamics of sulfur hexafluoride bubbles. Then, we applied a 1-MHz single tone burst with different peak negative pressures (PNPs) and pulse lengths (PLs), and multiple 5-MHz tone bursts with fixed acoustic conditions to elicit IC of the preformed SonoVue microbubbles and scattering of DBs, respectively. After the IC and scattering signals were received by a 7.5-MHz transducer, time- and frequency-domain analysis was performed to obtain the IC dose and scattering intensity curve. The theoretical dissolution curves and measured scattering intensity curves were combined to determine the effect of the incident pulse parameters on the lifetime, mean radius and distribution range of DBs. Increased PNP reduced the lifetime and mean size of the DBs population and narrowed the size distribution. The proportion of small DBs (less than resonance size) increased from 36.83% to 85.98% with an increase in the PNP from 0.6 to 1.6 MPa. Moreover, increased PL caused a shift of the DB population to the smaller bubbles with shorter lifetime and narrower distribution. The proportion of small bubbles increased from 25.74% to 95.08% as the PL was increased from 5 to 100 µs. Finally, increased IC dose caused a smaller mean size, shorter lifetime and narrower distribution in the DB population. These results provide new insight into the relationship between the incident acoustic parameters and the properties of DBs, and a feasible strategy for achieving controllable cavitation activity in applications.     

Electrochemical investigations of stable cavitation from bubbles generated during reduction of water

Megasonic cleaning is traditionally used for removal of particles from wafer surfaces in semiconductor industry. With the advancement of technology node, the major challenge associated with megasonic cleaning is to be able to achieve high cleaning efficiency without causing damage to fragile features. In this paper, a method based on electrochemistry has been developed that allows controlled formation and growth of a hydrogen bubbles close to a solid surface immersed in an aqueous solution irradiated with ∼1 MHz sound field. It has been shown that significant microstreaming from resonating size bubble can be induced by proper choice of transducer duty cycle. This method has the potential to significantly improve the performance of megasonic cleaning technology through generation of local microstreaming, interfacial and pressure gradient forces in close vicinity of conductive surfaces on wafers without affecting the transient cavitation responsible for feature damage.     

气泡群的动态物理特性研究

假设气泡周围流场为无黏、无旋、不可压缩的理想流体,建立气泡群相互作用的三维数值模型.将多极快速傅里叶变换方法(FFTM)与高阶边界元法(HOBEM)相结合求解气泡群的运动,在达到同样计算精度时显著加快了边界积分方程的求解速度,可以在合理的时间内模拟气泡群的动态物理特性.同时为维持气泡群模拟过程中的数值稳定性,引入了弹性网格技术(EMT),并用算例验证了数值模型及算法的有效性.基于建立的数值模型,研究了不同组合的气泡群之间的相互作用,模拟和解释了各类气泡运动的物理现象,讨论了影响气泡群膨胀、坍塌、迁移及射流 关键词： 气泡群 FFTM 射流 三维     

Comparing cleaning effects of gas and vapor bubbles in ultrasonic fields

The dynamic actions of cavitation bubbles in ultrasonic fields can clean surfaces. Gas and vapor cavitation bubbles exhibit different dynamic behaviors in ultrasonic fields, yet little attention has been given to the distinctive cleaning effects of gas and vapor bubbles. We present an experimental investigation of surface cleaning by gas and vapor bubbles in an ultrasonic field. Using high-speed videography, we found that the primary motions of gas and vapor bubbles responsible for surface cleaning differ. Our cleaning tests under different contamination conditions in terms of contaminant adhesion strength and surface wettability reveal that vapor and gas bubbles are more effective at removing contaminants with strong and weak adhesion, respectively, and furthermore that hydrophobic substrates are better cleaned by vapor bubbles. Our study not only provides a better physical understanding of the ultrasonic cleaning process, but also proposes novel techniques to improve ultrasonic cleaning by selectively employing gas and vapor bubbles depending on the characteristics of the surface to be cleaned.     

球状泡群内气泡的耦合振动

振动气泡形成辐射场影响其他气泡的运动, 故多气泡体系中气泡处于耦合振动状态. 本文在气泡群振动模型的基础上, 考虑气泡间耦合振动的影响, 得到了均匀球状泡群内振动气泡的动力学方程, 以此为基础分析了气泡的非线性声响应特征. 气泡间的耦合振动增加了系统对每个气泡的约束, 降低了气泡的自然共振频率, 增强了气泡的非线性声响应. 随着气泡数密度的增加, 振动气泡受到的抑制增强; 增加液体静压力同样可抑制泡群内气泡的振动, 且存在静压力敏感区(1–2 atm, 1 atm=1.01325×10⁵ Pa); 驱动声波对气泡振动影响很大, 随着声波频率的增加, 能够形成空化影响的气泡尺度范围变窄. 在同样的声条件、泡群尺寸以及气泡内外环境下, 初始半径小于5 μm 的气泡具有较强的声响应. 气泡耦合振动会削弱单个气泡的空化影响, 但可延长多气泡系统空化泡崩溃发生的时间间隔和增大作用范围, 整体空化效应增强.     

Shape stability of a gas bubble in a soft solid

Predicting the onset of non-spherical oscillations of bubbles in soft matter is a fundamental cavitation problem with implications to sonoprocessing, polymeric materials synthesis, and biomedical ultrasound applications. The shape stability of a bubble in a Kelvin-Voigt viscoelastic medium with nonlinear elasticity, the simplest constitutive model for soft solids, is analytically investigated and compared to experiments. Using perturbation methods, we develop a model reducing the equations of motion to two sets of evolution equations: a Rayleigh-Plesset-type equation for the mean (volume-equivalent) bubble radius and an equation for the non-spherical mode amplitudes. Parametric instability is predicted by examining the natural frequency and the Mathieu equation for the non-spherical modes, which are obtained from our model. Our theoretical results show good agreement with published experiments of the shape oscillations of a bubble in a gelatin gel. We further examine the impact of viscoelasticity on the time evolution of non-spherical mode amplitudes. In particular, we find that viscosity increases the damping rate, thus suppressing the shape instability, while shear modulus increases the natural frequency, which changes the unstable mode. We also explain the contributions of rotational and irrotational fields to the viscoelastic stresses in the surroundings and at the bubble surface, as these contributions affect the damping rate and the unstable mode. Our analysis on the role of viscoelasticity is potentially useful to measure viscoelastic properties of soft materials by experimentally observing the shape oscillations of a bubble.     

气泡的大振幅振动及其在声致发光和空化核聚变中的应用

评述了气泡大振幅振动方程，特别是R—P方程的来龙去脉，指出了该方程所存在的缺陷并对它进行了修正，将修正方程的数值解和R—P方程的数值解作了比较，在此基础上，对与气泡振动方程有关的应用(如声致发光和空化核聚变)情况作了分析。     

Cavitation characteristics analysis of a novel rotor-radial groove hydrodynamic cavitation reactor

Hydrodynamic cavitation was widely used in sterilization, emulsion preparation and other industrial fields. Cavitation intensity is the key performance index of hydrodynamic cavitation reactor. In this study, a novel rotor-radial groove (RRG) hydrodynamic cavitation reactor was proposed with good cavitation intensity and energy utilization. The cavitation performances of RRG hydrodynamic cavitation reactor was analyzed by utilizing computational fluid dynamics method. The cavitation intensity and the cavitation energy efficiency were used as evaluation indicators for RRG hydrodynamic cavitation reactor with different internal structures. The amount of generated cavitation for various shapes of the CGU, interaction distances and rotor speed were analyzed. The evolution cycle of cavitation morphology is periodicity (0.46 ms) in the CGU of RRG hydrodynamic cavitation reactor. The main cavitation regions of CGU were the outflow and inflow separation zones. The cavitation performance of rectangular-shaped CGU was better than the cylindrical-shaped CGU. In addition, the cavitation performance could be improved more effectively by increasing the rotor speed and decreasing the interaction distance. The research results could provide theoretical support for the research of cavitation mechanism of cavitation equipment.     

Laser-induced cavitation bubbles and shock waves in water near a concave surface

The interplay among the cavitation structures and the shock waves following a nanosecond laser breakdown in water in the vicinity of a concave surface was visualized with high-speed shadowgraphy and schlieren cinematography. Unlike the generation of the main cavitation bubble near a flat or a convex surface, the concave surface refocuses the emitted shock waves and causes secondary cavitation near the acoustic focus which is most pronounced when triggered by the shock wave released during the first main bubble collapse. The shock wave propagation, reflection from the concave surface and its scattering on the dominant cavity is clearly resolvable on the shadowgraphs. The schlieren approach revealed the pressure build up in the last stage of the collapse and the first stage of the rebound. A persistent low-density watermark is left behind the first collapse. The observed effects are important wherever cavities collapse near indented surfaces, such as in cavitation peening, cavitation erosion and ophthalmology.     

High-speed imaging of ultrasound driven cavitation bubbles in blind and through holes

The interest in application of ultrasonic cavitation for cleaning and surface treatment processes has increased greatly in the last decades. However, not much is known about the behavior of cavitation bubbles inside the microstructural features of the solid substrates. Here we report on an experimental study on dynamics of acoustically driven (38.5 kHz) cavitation bubbles inside the blind and through holes of PMMA plates by using high-speed imaging. Various diameters of blind (150, 200, 250 and 1000 µm) and through holes (200 and 1000 µm) were investigated. Gas bubbles are usually trapped in the holes during substrate immersion in the liquid thus preventing their complete wetting. We demonstrate that trapped gas can be successfully removed from the holes under ultrasound agitation. Besides the primary Bjerknes force and acoustic streaming, the shape oscillations of the trapped gas bubble seem to be a driving force for bubble removal out of the holes. We further discuss the bubble dynamics inside microholes for water and Cu²⁺ salt solution. It is found that the hole diameter and partly the type of liquid media influences the number, size and dynamics of the cavitation bubbles. The experiments also showed that a large amount of the liquid volume inside the holes can be displaced within one acoustic cycle by the expansion of the cavitation bubbles. This confirmed that ultrasound is a very effective tool to intensify liquid exchange processes, and it might significantly improve micro mixing in small structures. The investigation of the effect of ultrasound power on the bubble density distribution revealed the possibility to control the cavitation bubble distribution inside the microholes. At a high ultrasound power (31.5 W) we observed the highest bubble density at the hole entrances, while reducing the ultrasound power by a factor of ten shifted the bubble locations to the inner end of the blind holes or to the middle of the through holes.     

Current-driven dynamics of skyrmion bubbles in achiral uniaxial magnets

We report dynamics of skyrmion bubbles driven by spin-transfer torque in achiral ferromagnetic nanostripes using micromagnetic simulations. In a three-dimensional uniaxial ferromagnet with a quality factor that is smaller than 1, the skyrmion bubble is forced to stay at the central nanostripe by a repulsive force from the geometry border. The coherent motion of skyrmion bubbles in the nanostripe can be realized by increasing the quality factor to ～ 3.8. Our results should propel the design for future spintronic devices such as artificial neural computing and racetrack memory based on dipole-stabilized skyrmion bubbles.     

Origin of the broad-band noise in acoustic cavitation

The broad-band noise has been experimentally used to monitor the cavitation activity in a sonochemical reactor, an ultrasonic cleaning bath, a biological tissue, etc. However, the origin of the broad-band noise is still under debate. In the present review, two models for the mechanism of the broad-band noise are discussed. One is acoustic emissions from chaotically (non-periodically) pulsating bubbles. The other is acoustic emissions from bubbles with temporal fluctuation in the number of bubbles. It is suggested that the latter mechanism is sometimes dominant. Further studies are required on the role for bubble cluster dynamics as well as the bubble–bubble interaction in the broad-band noise especially at relatively low ultrasonic frequencies.     

含混合气泡液体中声波共振传播的抑制效应

当声波在含气泡的液体中传播时会出现共振传播现象,即在气泡的共振频率附近声衰减和声速会显著地增大,这是声空化领域的一个重要现象.以往的研究一般假设液体中只存在单一种类的气泡,因此忽略了声波共振传播的某些重要信息.本文研究了含混合气泡液体中声波的共振传播,混合气泡是指液体中包含多种静态半径不同的气泡.结果显示:在这种系统中存在声波共振传播的抑制效应,即与含单一种类气泡的系统相比,在含混合气泡的系统中声波的共振衰减和共振声速会明显变小.对于两种气泡混合、多种气泡混合以及气泡满足某种连续分布的系统,研究了抑制效应的本质和主要特征,此外还探究了黏性和空化率等对抑制效应的影响.本文的研究结果是对该领域现有知识的必要补充.