Dispersion and Attenuation of Surface Acoustic Waves of Various Polarizations on a Stress-Free Randomly Rough Surface of Solid

An approach to obtaining the dispersion equation of surface acoustic waves (SAWs) on a stress-free, randomly rough surface of an anisotropic elastic medium is suggested. The problem is solved in the approximation of a weakly rough surface using Green′s function technique. The dispersion and attenuation of sagittally and shear horizontally (SH) polarized SAWs are investigated both analytically and numerically for a three-dimensionally (3D) and a two-dimensionally (2D) rough surface of an isotropic medium. The results for 2D roughness are shown to be contained in the more general expressions for the 3D case, and the connection between the results for the 3D and the 2D cases is pointed out. Dispersion relations are derived for SAWs of both polarizations propagating in an arbitrary direction along a 2D rough surface. The SAW attenuation mechanisms are investigated at various incidence angles. It is concluded that all three mechanisms (viz. scattering into bulk transverse, longitudinal, and Rayleigh surface acoustic waves) are involved for the Rayleigh and SH polarized SAWs at certain incidence angles, whereas at the other angles only some of the mechanisms are. The criterion for the existence of SH polarized SAWs on a rough surface is considered. A possible increase of the SAW phase velocity on a rough surface compared with that for a flat boundary is discussed. In the limit λ a (where a is the roughness correlation length) simple explicit expressions for the phase velocities of Rayleigh and SH polarized SAWs are derived. A comparison of the results obtained herein with those of other workers is presented.     

Performance of Non-Contact Linear Actuators Driven by Surface Acoustic Waves*

A new kind of non-contact linear actuator （motor） driven by surface acoustic waves （SAWs） is presented, in which the stators are made from SAW delay lines using 128° YX-LiNbO3 substrates. A fluid layer is introduced between the slider and the stator of the actuator, and the slider is a circular aluminum disk suspended on the surface of the liquid （water） layer. As the SAW is excited on the stator, the SAW is converted to a leaky wave in the interface of the stator and the liquid, and then propagates into the liquid. Owing to the nonlinear effect of wave propagation, acoustic streaming is generated, which pushes the slider to move. By the experiments, the relations between the slider velocity and the experimental parameters, such as the exciting voltage of the SAWs, the thickness and the kinematic viscosity of the liquid layer, are obtained.     

Theoretical study on adsorption properties of methyl methacrylate and its molecular chain within metal‐organic frameworks

Utilizing metal‐organic frameworks (MOFs) as a “polymerization container” is a very effective method to prepare oriented and therefore birefringent polymer materials. In particular, the adsorption of polymer monomers and molecular chains within MOFs has a profound impact on the orientation of polymer chains. In this work, a theoretical study on the adsorption properties of methyl methacrylate (MMA) and its molecular chain within MOFs has been conducted by employing a combination of molecular dynamics, density functional theory, and Monte Carlo method, where 2 MOFs, [Zn₂(1,4‐benzenedicarboxylate)₂triethylenediamine]_n and [Zn₂(4,4′‐biphenyldicarboxylate)₂triethylenediamine]_n, were chosen. The corresponding number and degree of orientation of adsorbed molecules in these 2 MOFs were obtained from the simulations. The calculation results revealed 3 factors that affect the adsorption and orientation of MMA monomers in MOF pore channels. First, as the walls of the MOF pores are polar surfaces and consist of metal ions and organic ligands, the electrostatic interaction between the MOF channels and polar MMA molecules promotes the adsorption and orientation of the MMA monomers within the pore channel. Second, the electrostatic interactions between monomers can reduce the intermolecular gaps, which similarly assist in their orientation. Last, the relative sizes of the MOF pores and the monomers are also relevant. When the sizes of the MOF channels and monomers are similar, the molecular chains show a higher degree of orientation. The results and the findings of this work could provide predictive methods for selecting polymeric monomers or MOFs that may be ideal for the control of polymer chain orientation.     

Material transport in Al-metallizations of power-loaded SAW structures

Material transport in Al/Ti-finger electrodes on LiNbO₃ substrates of power-loaded surface acoustic wave (SAW) structures were investigated under microscopic observation with respect to stress-induced material transport. Additionally, investigations were carried out before and after SAW loading during lifetime experiments. For the experiments, a special power SAW test structure was applied realizing travelling SAWs. The results show that the microstructure of the electrodes was damaged by void and hillock formation even at moderate input power. This changes the electrical and acoustical properties of the SAW structures irreversibly. The logarithmic time-to-failure (TTF) of damaged SAW structures depends linearly on loading time and rf power.     

Applications of Acoustic Wave Devices for Sensing in Liquid Environments

Abstract

Acoustic wave devices such as thickness shear mode (TSM) resonators and shear horizontal surface acoustic wave (SH‐SAW) devices can be utilized for characterizing physical properties of liquids and for chemical sensor applications. Basic device configurations are reviewed and the relationships between experimental observables (frequency shifts and attenuation) and physical properties of liquids are presented. Examples of physical property (density and viscosity) determination and also of chemical sensing are presented for a variety of liquid phase applications. Applications of TSMs and polymer‐coated guided SH‐SAWs for chemical sensing and uncoated SH‐SAWs for “electronic tongue” applications are also discussed.     

Self-assembly of metal–organic frameworks and graphene oxide as precursors for lithium-ion battery applications

We fabricated composites of Fe₂O₃/reduced graphene oxide as lithium-ion batteries anode material with controlled structures by employing self-assembly of metal–organic frameworks (MOFs) and polymer-functionalized graphene oxide as precursors. By electrostatic interaction, the negatively charged MOFs, Prussian Blue (PB), are assembled on poly(diallyldimethylammonium chloride) (PDDA)-functionalized graphene oxide (positive charge). Then the PB cubes become FeOOH nanosheets when treated with sodium hydroxide. Upon further annealing, the FeOOH nanosheets transform to Fe₂O₃ nanoparticles while the graphene oxide become reduced graphene oxide simultaneously. It was found that the composites have good performance as anode of lithium-ion battery. This work shows a new way for self-assembling MOFs and 2D materials.     

High-efficient liquid exfoliation of 2D metal-organic framework using deep-eutectic solvents

The exfoliation of bulk two-dimensional metal–organic framework (MOF) into few-layered nanosheets has attracted much attention recently. In this work, an environmental-friendly route has been developed for layered-MOF (MAMS-1) delamination using deep eutectic solvent (DES), which is more sustainable and efficient alternative than conventional organic solvents for MOF nanosheet preparation. Under sonication condition, DES as solvents, the highest exfoliation rate of MAMS-1 is up to 70% with two host layers via poly(vinylpyrrolidone) (PVP) surfactant-assisted method. The presence of tert-butyl exteriors and the atomically thickness endow the MOF nanosheets stable suspension for at least one month. Due to the 2D structure and excellent stability, MAMS-1 nanosheet (MAMS-1-NS) was chosen as a good candidate to encapsulate Eu³⁺ cations. The obtained Eu³⁺@MAMS-1-NS acts as a multi-responsive luminescent sensor through fluorescence quenching, and can specifically recognize Fe³⁺ (LOD = 0.40 μM, K_SV = 1.05 × 10⁵ M^−l), Hg²⁺ (LOD = 0.038 μM, K_SV = 5.78 × 10⁶ M^−l), Cr₂O₇²⁻ (LOD = 0.33 μM, K_SV = 1.55 × 10⁵ M^−l) and MnO₄⁻ (LOD = 0.088 μM, K_SV = 4.49 × 10⁵ M^−l). Compared with bulk Eu³⁺@MAMS-1, the sensitivity of Eu³⁺@MAMS-1-NS is greatly improved owing to its ultrathin nanosheet morphology and highly accessible active sites on the surface.     

Effects of the piezoelectric field on the modulation of exciton–polaritons by surface acoustic waves

Surface acoustic waves (SAWs) provide a powerful tool for the modulation of polaritons in GaAs-based microcavities. In this contribution, we compare the modulation introduced by SAWs propagating along piezoelectric and non-piezoelectric crystal directions of the sample surface. Strain calculations reveal that the type-I band-gap modulation induced by the strain field is comparable for both SAW types. Piezoelectric SAWs have, however, an intrinsic longitudinal electric field, which can dissociate quantum well (QW) excitons and, thus, degrade the modulation. Images of the polariton far-field photoluminescence reveal this behavior for different excitation conditions.     

Transport of magnetic vortices by surface acoustic waves

In a thin film of superconducting Y Ba₂Cu₃O₇ the impact of surface acoustic waves (SAWs) traveling on the piezoelectric substrate is investigated. A pronounced interaction between the ultrasonic waves and the vortex system in the type II superconductor is observed. The occurrence of a SAW-induced dc voltage perpendicular to the sound path is interpreted as dragging of vortices by the piezoacoustic SAW, which acts as a conveyor for the flux quanta. The antisymmetry of this voltage with respect to the magnetic field directly evidences the induced, directed flux motion. This dynamic manipulation of vortices can be seen as an important step towards flux-based electronic devices.     

Novel method for photovoltaic energy conversion using surface acoustic waves in piezoelectric semiconductors

This paper presents a novel principle for photovoltaic (PV) energy conversion using surface acoustic waves (SAWs) in piezoelectric semiconductors. A SAW produces a periodically modulated electric potential, which spatially segregates photoexcited electrons and holes to the maxima and minima of the SAW potential. The moving SAW collectively transports the carriers with the speed of sound to the electrodes made of different materials, which extract electrons and holes separately and generate dc output. The proposed active design is expected to have higher efficiency than passive designs of the existing PV devices and to produce enough energy to sustain the SAW.     

Using coupling slabs to tailor surface-acoustic-wave band structures in phononic crystals consisting of pillars attached to elastic substrates

The propagation of surface acoustic waves (SAWs) in two-dimensional phononic crystals (PnCs) with and without coupling-enhancement slabs was theoretically investigated using a three-dimensional finite element method. Different piezoelectric substrates, for example, lithium niobate (LiNbO₃), gallium nitride (GaN), and aluminium nitride (AlN), were taken into account. Compared to the PnCs without coupling-enhancement slabs, the coupling between each pillar and its nearest neighbor was largely enhanced in the presence of slabs. The bandwidth of the first directional band gap increased markedly compared with its initial value for the PnCs without a slab (within square symmetry). In addition, with increasing thicknesses of the slabs bonded between neighboring pillars, the first directional band-gap and second directional band gap of the PnCs tend to merge. Therefore, the structure with coupling-enhancement slabs can be used as an excellent electrical band elimination filter for most electro-SAW devices, offering a new strategy to realize chip-scale applications in electroacoustic signal processing, optoacoustic modulation, and even SAW microfluidic devices.     

The temperature coefficients of delay of surface acoustic waves in LGS and LGN crystals in a wide temperature range

Numerical analysis of the first-and second-order temperature coefficients of the delay of surface acoustic waves (SAWs) in LGS and LGN crystals was carried out. The calculations were performed along thermostable directions in a wide temperature range. The effect of an aluminium layer having a finite thickness on the SAW temperature characteristics is shown.     

Enhanced Exfoliation Effect of Solid Auxiliary Agent On the Synthesis of Biofunctionalized MoS2 Using Grindstone Chemistry

Mass production and commercial availability are prerequisites for the viability and wide application of MoS₂. Here, we demonstrate enhanced grindstone chemistry for a one‐step synthesis of biofunctionalized MoS₂. By adding a SiO₂ auxiliary agent the exfoliation efficiency increases from 16.23% to 58.59% and a rapid and high‐yield exfoliation of MoS₂ is seen. SiO₂ exhibits a fragmentation effect, which reduces the lateral size and facilitates the exfoliation of MoS₂, thus inducing a high‐efficient paradigm in the top‐down fabrication of biofunctionalized MoS₂ nanosheets. The as‐prepared MoS₂‐chitosan (MoS₂‐CS) nanosheets display complete disaggregation and homogeneous dispersion, as well as a high content of chitosan (ca. 20 wt%). As a proof‐of‐concept application, the MoS₂‐CS nanosheets act as a biosorbent for Pb^II removal, exhibiting a good adsorption capacity and recyclability. This green and facile enhanced grindstone chemistry with minimal use of organic solvents and high‐throughput efficiency can be extended to the fabrication of other biocompatible inorganic 2D analogues for a variety of applications.     

Numerical study on surface acoustic wave method for determining Young's modulus of low-k films involved in multi-layered structures

The surface acoustic waves (SAWs) technique is becoming an attractive tool for accurately and nondestructively characterizing the mechanical property of the brittle low dielectric constant (low-k) thin film. The theoretical equations for describing SAWs propagating on the multi-layered structure are derived in this study. The dispersion features of SAWs propagating on different structures of low-k/SiO₂/Si substrate, SiO₂/low-k/Si substrate, low-k/Si substrate, and low-k/Cu/Si substrate are investigated to instruct an accurate and facile fitting process for determining Young's modulus of low-k films. The dependence of dispersion relation on the film thickness, elastic modulus of low-k materials as well as frequency are provided and discussed in detail. The study shows an obvious influence of layered structure on the dispersion relation of SAWs. For a fixed structure, the dispersion curvature increases with the decrease of Young's modulus of low-k films.     

Acoustically induced potential dots in GaAs quantum wells

Dynamic dots (DDs) consisting of confined and mobile potentials are realized by the interference of orthogonal surface acoustic wave (SAW) beams in GaAs quantum wells. Photoluminescence spectroscopy reveals that the DDs are characterized by a peculiar distribution of strain and piezoelectric fields dictated by the lattice symmetry, which is quite different from the one induced by a single SAW. We demonstrate the unique ability of DDs to control the flow of photogenerated electron-hole pairs and of photons by realizing an electronic switch based on SAWs.     

Magnetic and electronic properties of two-dimensional metal-organic frameworks TM_3(C_2NH)_(12)

The ferromagnetism of two-dimensional(2 D) materials has aroused great interest in recent years, which may play an important role in the next-generation magnetic devices. Herein, a series of 2 D transition metal-organic framework materials(TM-NH MOF, TM = Sc–Zn) are designed, and their electronic and magnetic characters are systematically studied by means of first-principles calculations. Their structural stabilities are examined through binding energies and abinitio molecular dynamics simulations. Their optimized lattice constants are correlated to the central TM atoms. These 2 D TM-NH MOF nanosheets exhibit various electronic and magnetic performances owing to the effective charge transfer and interaction between TM atoms and graphene linkers. Interestingly, Ni-and Zn-NH MOFs are nonmagnetic semiconductors(SM) with band gaps of 0.41 e V and 0.61 e V, respectively. Co-and Cu-NH MOFs are bipolar magnetic semiconductors(BMS), while Fe-NH MOF monolayer is a half-semiconductor(HSM). Furthermore, the elastic strain could tune their magnetic behaviors and transformation, which ascribes to the charge redistribution of TM-3 d states. This work predicts several new 2 D magnetic MOF materials, which are promising for applications in spintronics and nanoelectronics.     

Anisotropy of sound velocity for a new PbB4O7 crystal as determined by the laser ultrasonic technique

4 O₇ crystal is a new nonlinear optical crystal. For the first time the anisotropy of the velocities of its longitudinal and surface acoustic waves (SAWs) are determined by laser ultrasonic technique. The velocities of surface waves for X-, Y-, and Z-cut crystals are also calculated. The theoretical calculations of slowness curves are in good agreement with experimental results. The SAW slowness curve is elliptical for Y- or Z-cut crystal wafers, and circular for an X-cut wafer. Received: 27 January 1997/Accepted: 30 July 1997     

Study of Monte Carlo methods for generating self-avoiding walks

The concept of fractal dimensionality is used to study different statistical methods for generating self-avoiding walks (SAWs). The reliability of SAWs traced by the enrichment technique and the dynamic Monte Carlo technique is verified. The number of dynamic cycles which represent a single independent SAW ofN ₀ steps is found to be about 0.1N ₀ ³ . We show that the enrichment process for generating SAWs may be presented as a critical phenomenon.     

Numerical analysis of surface and leaky surface acoustic waves in new piezoelectric KNBO3, PKN, and LGN crystals

We perform a numerical analysis of the properties of surface acoustic waves (SAW) as well as leaky surface acoustic waves (LSAW) in piezoelectric KNbO₃, Pb₂KNb₅O₁₅ (PKN) and La₃Ga_5.5Nb_0.5O₁₄ (LGN) crystals. We determine optimal thermostable cuts and directions in which the SAWs have high phase velocity, a very high coefficient of electromechanical coupling. and a small angle between the phase and group velocities. We also found the cuts and directions in which the LSAWs can exist. The characteristics of the LSAWs (velocity, the coefficient of electromechanical coupling, angle between the phase and group velocities, temperature coefficient of velocity, and coefficient of surface absorption along the LSAW propagation direction) are calculated. N. I. Lobachevsky State University, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 42, No. 5, pp. 485–493, May 1999.     

Advanced piezoelectric crystal Ca3TaGa3Si2O14: growth,crystal structure perfection,and acoustic properties

A five-component crystal of the lanthanum–gallium silicate family Ca₃TaGa₃Si₂O₁₄ (CTGS) was grown by the Czochralski method. The CTGS crystal, like the langasite crystal (La₃Ga₅SiO₁₄, LGS), possesses unique temperature properties and the fewer number of the Ga atoms in the unit cell makes the density much lower and, consequently, increases the velocity of acoustic wave propagation. The unit-cell parameters were determined by the powder diffraction technique. The defects in the CTGS crystal structure were studied by X-ray topography, which enables the visualization of growth banding characteristics of crystals grown by the Czochralski method. Surface acoustic wave (SAW) propagation in the CTGS crystal was investigated by the high-resolution X-ray diffraction method on the BESSY II synchrotron radiation source. The velocities of propagation and power flow angles of SAWs in the Y- and X-cuts of the CTGS crystal were determined from the X-ray diffraction spectra.