Fe-Ni合金薄膜的结构和磁性

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Fe-Ni混合团簇基态结构的遗传算法研究

采用半经验的Gupta多体势结合遗传算法对不同组分的FenNim(N=n+m, N=13,38)混合团簇的基态结构和性质进行了模拟研究。结果显示：总原子数为13的混合团簇基态几何构型是基于单质团簇的基态二十面体结构,并且随着Fe原子数的增加表现出Fe原子首先占据中心位置的规律性;对总原子数为38的混合团簇,在轻混合（类掺杂）情形（ ）下基态几何构型为类似于纯单质团簇基态的截角八面体结构,而在重混合（n=16-33）时基态几何结构表现为不同于单质团簇的类截角二十面体构型;分析二级差分能表明Fe1Ni12、Fe7Ni31及Fe14Ni24具有相对高的稳定性,我们提出了基于有效键数的简化模型以解释此幻数结构序列     

δ/γ transformation in non-equilibrium solidified peritectic Fe-Ni alloy

Through phase transformation kinetic analysis and experimental observation, the δ/γ transformation occurring in the non-equilibrium peritectic Fe-4.33at.%Ni alloys was systematically investigated. According to JMA solid-state transformation kinetic theory, the Time-Temperature-Transformation (TTT) curves of the δ/γ transformation in peritectic Fe-Ni alloy were calculated. On this basis, the physical correlation between the δ/γ transformation and the initial undercooling of melt (△T) was elucidated. The results indicate that the change of △T can alter not only the overall δ/γ transformation pathways but also the transformation fraction with respect to each transformation mechanism.     

An investigation of generalized lamb waves using ultrasonic reflectivity measurements

Ultrasonic critical angle reflectivity method is used to measure the phase velocity of generalized Lamb waves in cadmium and zinc platings. In addition to the free propagating modes, leaky-wave modes are also observed. Leaky waves are considered using principles familiar from the discussion of surface waves in anisotropic media and a relatively good agreement is obtained between the theoretical computations and measured data.     

Invar Behavior in Fe-Ni Alloys is Predominantly a Local Moment Effect Arising from the Magnetic Exchange Interactions Between High Moments

I argue that the main models that have been advanced to explain Invar behavior in Fe-Ni alloys (the original, classical, Invar system) can all be shown to be critically deficient, except one: The local moment frustration model of Rancourt and Dang ( Phys. Rev. B , 54 , 12225, 1996). The latter model explains all the measured structural, magnetic, and magnetovolume features of the Fe-Ni alloys with 0-65 apc (atomic percent) Fe, based on the assumptions that these systems are predominantly high-moment in character at the temperatures of interest and that the Fe-Fe pairs have large inter-atomic separation dependencies of their magnetic exchange parameters. The large magnetovolume Fe-Fe couplings are understood (based on ab initio electronic structure calculations) as a precursor effect of the low-moment/high-moment (LM/HM) transition that has recently been observed to occur at larger Fe concentrations, as a continuous transition occurring in the range , 65-75 apc Fe (Lagarec, Ph.D. thesis, 2001).     

超声纸杯焊接技术

本文介绍一种超声纸杯焊接设备及焊接工艺。     

Ultrasonic backscattering in polycrystals with elongated single phase and duplex microstructures

An analytical solution for a three dimensional integral representation of the backscattering (BS) coefficient in polycrystals with elongated (generally ellipsoidal) grains is obtained; it is a natural generalization of the known explicit result for the BS coefficient in polycrystals with spherical grains. New insights into the dependence of the BS signal on frequency and averaged ellipsoidal grain radii are obtained. In particular it has been shown that the dominant factor for the backscattering is the averaged interaction length of the ellipsoidal grain in the direction of wave propagation, instead of the ellipsoidal cross-section. The theory was applied to a simplified model of Ti alloy duplex microstructure and was compared with experiment. For the experimental data analysis directional backscattering ratios are introduced and shown to be advantageous for characterization of duplex elongated microstructures/microtextures. In addition to the geometrical parameters of the elongated microtextures, the BS directional ratios depend on the newly introduced nondimensional material parameter q. The parameter q exhibits the relative contribution of the second phase (crystallites) to the backscattering signal, the effect of which is measurable and important. Comparison of the model with experiment shows there is a significant advantage in using the directional ratios of backscattering coefficients for data analysis.     

Ultrasonic degradation of oxalic acid in aqueous solutions

This paper describes the ultrasonic degradation of oxalic acid. The effects of ultrasonic power, H₂O₂, NaCl, external gases on the degradation of oxalic acid were investigated. Reactor flask containing oxalic acid was immersed in the ultrasonic bath with water as the coupling fluid. Representative samples withdrawn were analysed by volumetric titration. Degradation degree of oxalic acid increased with increasing ultrasonic power. It was observed that H₂O₂ has negative contribution on the degradation of oxalic acid and there was an optimum concentration of NaCl for enhancing the degradation degree of oxalic acid. Although bubbling nitrogen gave higher degradation than that for bubbling air, both gases (for 20 min before sonication and during sonication together) could not help to enhance the degradation of oxalic acid when compared with the degradation without gas passage.     

Selective etching of InP in NaF solution

The crossing porous structure of InP has been obtained by electrochemical etching in NaF solutions. The behavior of the periodic oscillation occurs at different potential ranges for the different concentrations of solutions, and it will disappear with the concentration of the solution decreased. The scanning electron microscope (SEM) image shows that the pores have two directions on the surface and are perpendicular to each other. The two directions are assigned to [0 1 1] and [], respectively. The SEM image of the cross-section also shows that the two directions are assigned to [1 1 1]B and []B. Both are due to the selective etching of F⁻ ions. The crossing porous structure of InP is a very promising feature for the three-dimensional structure of III-V compound semiconductors for photonic band gap materials.     

超声测距变结构控制系统的研究

本文在超声测距系统中采用了变结构控制理论，根据所测物体的反射界面和介质性质，自动调节超声波发射换能器的功率，建立了超声测距系统的数学模型，对系统方程进行了理论分析，研究了变结构控制系统的设计方法，并结合应用实例，对钻井法凿井用超声波测井仪中超声测距系统进行了计算机仿真，并在实验室进行了实验。     

Physico-chemical properties of micellar sodium taurodeoxycholate solutions. Ultrasonic behaviour and viscosity

Summary Ultrasonic absorption and velocity have been measured in sodium taurodeoxycholate solutions, at concentrations ranging between 0.1 and 0.4 mol kg⁻¹ and at temperatures of 25, 35 and 45°C. In addition, viscosity measurements have been performed. The ultrasonic results show that at least two kinetic processes occur in such systems. At high frequency the kinetic processes may be related to monomer-micelle exchange, while at lower frequency they may be related to the change of size and shape of the solute aggregates. The trend of the activation energy of the viscous flow confirms the increase of the aggregation number of the micelles at higher molality. Paper presented at the “Meeting on Lyotropics and Related Fields”, held in Rende, Cosenza, September 13–18, 1982.     

Measurement of viscosity of highly viscous non-Newtonian fluids by means of ultrasonic guided waves

In order to perform monitoring of the polymerisation process, it is necessary to measure viscosity. However, in the case of non-Newtonian highly viscous fluids, viscosity starts to be dependent on the vibration or rotation frequency of the sensing element. Also, the sensing element must possess a sufficient mechanical strength. Some of these problems may be solved applying ultrasonic measurement methods, however until now most of the known investigations were devoted to measurements of relatively low viscosities (up to a few Pa s) of Newtonian liquids.     

扩散场扇扫重建格林函数实现近表盲区缺陷检测

2020年5月12日定稿摘要针对结构近表盲区缺陷检测难题,发展了一种扩散声场扇扫重建格林函数的超声检测方法。在对扩散场扇扫重建格林函数理论分析的基础上,通过5 MHz超声相控阵探头对铝块近表盲区缺陷进行了检测实验并对影响成像结果的延时时间、时间窗宽和扫查方式进行了分析。结果显示,该方法可以有效检测铝块近表1.5~3 mm的盲区缺陷;扇形扫查方式的有效扩散时间较全矩阵捕获方式延长0.5 ms以上;在有效扩散时间内,随着延时接收时间和时间窗宽的增加,成像质量得到提高。本研究工作为超声检测近表盲区缺陷提供了一种有效可行的新方法。     

电沉积复合丝及其巨磁阻抗效应的研究

采用脉冲电沉积工艺在Cu丝上沉积Fe Ni合金镀层 ,成功地制备出巨磁阻抗效应 (GMI)复合丝材料 ,研究了复合丝的磁性能和巨磁阻抗效应 .复合丝外壳磁性镀层软磁性越好 ,巨磁阻抗效应越明显 ,制备的复合丝最高巨磁阻抗效应为 2 7.19% .研究了复合丝阻抗与巨磁阻抗比值GMI随外加磁场的变化 ,其变化曲线的形状受复合丝磁各向异性场的影响 .此外 ,还研究了复合丝巨磁阻抗效应与驱动交变电流频率的关系 ,复合丝Fe17Ni83 样品巨磁阻抗效应的临界频率为 30kHz(GMI为 9.95 % ) ,特征频率为 30 0kHz(GMI为 2 7.19% ) ,截止频率为 10MHz (GMI为 10 .36 % ) .如此低的临界频率和特征频率及较宽的频率段对于实际应用非常有利 .     

Studies of magnetic properties of permalloy (Fe-30%Ni) prepared by SLM technology

In the present study, a high permeability induction Fe-30%Ni alloy cubic bulk was prepared by the selective laser melting process. In order to reveal the microstructure effect on soft magnetic properties, the microstructure and magnetic properties of the Fe-30%Ni alloy were carefully investigated by scanning electron microscopy, X-ray diffraction and hysteresis measurements. The bcc-Fe (Ni) phase formation is identified by X-ray diffraction. Meanwhile, it was found that low bcc lattice parameter and high grain size could be obtained when high laser scanning velocity and low laser power were used. Moreover, the lowest value of coercivity is 88 A/m, and the highest value of saturation magnetization is 565 Am²/kg, which can be obtained at a low laser scanning velocity of 0.4 m/s and high laser power input at 110 W.     

光弹法测量超声换能器声场

超声换能器声场的测试对于超声检测具有基础性作用,而传统的超声换能器声场测试方法具有一些局限性。本文介绍了搭建的动态激光光弹实验平台,并利用动态光弹法测量了纵波换能器和横波换能器辐射声场的特征,由瞬态声场图像获得了传声介质的声波速度及超声换能器的中心频率;由稳态声场图像获得了声场的近场长度、指向性和扩散角等参数;分析了光弹实验系统和测量方法可能引起测量误差。本文结果表明动态光弹法是一种有效的定量测量超声换能器声场的方法。